CN104411173B - 包括有敌草隆的间疏剂 - Google Patents
包括有敌草隆的间疏剂 Download PDFInfo
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- CN104411173B CN104411173B CN201380027406.2A CN201380027406A CN104411173B CN 104411173 B CN104411173 B CN 104411173B CN 201380027406 A CN201380027406 A CN 201380027406A CN 104411173 B CN104411173 B CN 104411173B
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- 239000005510 Diuron Substances 0.000 title claims abstract description 22
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- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 claims description 9
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- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 7
- 150000004675 formic acid derivatives Chemical class 0.000 claims description 6
- 239000013543 active substance Substances 0.000 claims description 5
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- -1 for example Chemical class 0.000 description 30
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
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- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 4
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- 229920000642 polymer Polymers 0.000 description 3
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- 239000011591 potassium Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- UDPGUMQDCGORJQ-UHFFFAOYSA-N (2-chloroethyl)phosphonic acid Chemical compound OP(O)(=O)CCCl UDPGUMQDCGORJQ-UHFFFAOYSA-N 0.000 description 2
- XUNYDVLIZWUPAW-UHFFFAOYSA-N (4-chlorophenyl) n-(4-methylphenyl)sulfonylcarbamate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC(=O)OC1=CC=C(Cl)C=C1 XUNYDVLIZWUPAW-UHFFFAOYSA-N 0.000 description 2
- HOKKPVIRMVDYPB-UVTDQMKNSA-N (Z)-thiacloprid Chemical compound C1=NC(Cl)=CC=C1CN1C(=N/C#N)/SCC1 HOKKPVIRMVDYPB-UVTDQMKNSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- A—HUMAN NECESSITIES
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- A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
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- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
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Abstract
本发明涉及一种间疏方法,具体地用于水果间疏,该方法使用3‑(3,4‑二氯苯基)‑1,1‑二甲基脲(敌草隆),并且涉及包括敌草隆的间疏剂。
Description
本发明涉及一种间疏(Ausdünnung)方法,具体地用于水果间疏,该方法使用3-(3,4-二氯苯基)-1,1-二甲基脲(敌草隆),并且涉及包括敌草隆的间疏组合物(间疏剂)。
间疏在水果生产中一直是最重要的做法之一,其中间疏被理解是指减少授粉花的数量和/或果实的数量。典型地以机械地,手工地或使用一种机器,或者另外地通过化学方式来完成间疏。
通过间疏可以实现的优势具体地是果实大小、果实颜色和/或果实品质的改善,这与实质上提高的收益率有关。
观察到的其他方面为在开花性良好的后一年中改善的开花性,或阻断并且防止濒危种类和幼林中的隔年结果,以及避免作物过多的枝的折断、严重的树的耗竭及其引起的树的减低的寒冷耐受性。
在大部分生长区中,由于财务原因手工间疏是禁止的。机器间疏仅可以在有限的范围使用,因为它需要将这些树培养成一种特定的形状并且典型地对植物造成高程度的附带伤害。
因此化学间疏是有利的。
然而,已知的化学间疏剂如尿素和硫代硫酸铵(例如在德国,它们不被批准用于此目的),缺少令人满意的作用可靠性并且在所使用的浓度下(这些浓度必然地较高)植物对其耐受性通常较差。其他间疏剂的活性和植物耐受性也不是特别适合实践条件,因为(根据果实的发育阶段和气候条件)在施用过程中或在施用过程后,总是观察到非常高度显著的、依赖于品种的可靠活性的缺失。
所有这些已知的间疏剂是通过植物激素平衡起作用的,例如,通过苹果中的植物激素生长素和乙烯。结果是,当使用这些间疏剂时频繁地观察到不希望的活性,如,例如,在低浓度下有降低的活性,在施用时间点上在不利条件下的过度间疏,或在一些情况中甚至增强水果作物负载。很多国家所使用的这些甲氨酸酯类试剂额外地作为杀虫剂并且因此仅可以在有限的范围使用。
用于水果间疏的抑制光合作用的活性物质的使用已在以下文件中描述:1990年115(1):14-19的美国园艺科学会志(J.Amer.Soc.Hort.Sci.115(1):14-19(1990))。然而,在其说明中提及的这些活性物质未发现有作为间疏剂的商业用途,因为植物耐受性不令人满意,例如在嗪草酮的情况中。
EP 1427 286 A披露了一种间疏组合物的用途,该间疏组合物包括抑制光合作用的活性物质苯嗪草酮。
已知苯嗪草酮有对植物伤害性的潜在可能。为避免叶坏死,因此其施用在时机和量方面必须是非常精确的。
因此一个目的是提供一种替代的间疏组合物,该间疏组合物有效并且易于使用。
现已发现包括敌草隆的间疏组合物特别适合。本发明因此包括一种间疏方法,其特征在于将一种包括敌草隆的组合物施用于植物器官。进而,本发明包括包括敌草隆的组合物用于间疏的的用途。
这里应该注意的是,本发明的范围延伸至上文和下文提及的成分、数据和/或方法参数的范围(无论一般的或优选的范围)的任何希望的和可能的组合。
可将这些间疏组合物用于间疏花或果实,并且优选果实间疏。
根据本发明的方法特别适合于间疏,具体地水果间疏,仁果和梨果作物,并且优选地是梨果作物。优选的梨果作物为以下那些种类:所有种类的苹果,如,例如,博斯科普(Boskoop)、布瑞本(Braeburn)、考克斯橙(Cox Orange)、艾尔斯塔(Elstar)、嘎啦(Gala)、格劳斯特(Gloster)、金冠(Golden Delicious)、富士(Fuji)、坎齐(Kanzi)、洋巴(Jamba)、詹姆斯·格里夫(James Grieve)、乔纳金(Jonagold)、红玉(Jonathan)、拉宝(Lobo)、麦金托什(McIntosh)、元帅(Red Delicious)、斯巴达(Spartan),所有种类的梨如,例如,康富伦斯(Conference)、榅桲(Quitte)以及亚洲梨(asiatische Birne)。
优选的仁果作物为这些作物:甜樱桃、酸樱桃(Süβ-und Sauerkirschen)、桃、杏以及李。另外优选的作物为橄榄、阿月浑子果(Pistazien)、奇异果、葡萄藤或柑橘类水果如,例如,橘。
如果间疏水果,在例如3到30mm的果期,优选地在6到30mm的果期,优选地在8到17mm的果期进行水果间疏,特别在梨果作物的情况中,优选的作物是相同的。在甜樱桃和酸樱桃的情况中,在例如3到17mm的果期下进行水果间疏。
根据本发明的方法使用了多种组合物,特别是包括了敌草隆的可立即使用的间疏组合物,这些组合物中的一些是新颖的并且在这种情况中同样是本发明主题内容。
这些组合物(在下文同义地还被称为可立即使用的间疏组合物)优选地包括
●按重量至少70%,优选地按重量至少80%,特别优选地按重量至少90%的水
●按重量0.001%到按重量0.2%,优选地按重量0.002%到按重量0.1%并且特别优选地按重量0.002%到0.2%的敌草隆。
除敌草隆和水外,根据本发明的这些间疏组合物任选地额外包括添加剂。
此外,根据本发明的这些组合物还包括(或在每种情况中不包括)其他的间疏剂、生长调节剂以及其他另外的农药活性物质。
以下提及的彼此相互独立的这些添加剂也可以不存在。
可以存在的添加剂为,例如,
●用于调节湿度的吸湿性物质和/或湿润剂:吸湿性物质是,例如,吸湿性无机盐如,例如,氯化钙或硝酸钙;氯化镁或硝酸镁。适合的湿润剂的实例为有机物质如,例如,甘油、聚右旋糖、山梨糖醇、木糖醇、丙二醇、聚乙二醇或这些多元醇的混合物。
●表面活性物质,例如表面活性剂。表面活性剂可以是,例如非离子的、阳离子的以及两性的表面活性剂,优选阴离子表面活性剂。适合的阴离子表面活性剂的实例为烷基硫酸盐、烷基醚硫酸盐、烷基芳基磺酸盐、烷基琥珀酸盐、烷基磺基琥珀酸盐、N-烷基肌氨酸盐、酰基牛磺酸盐、酰基羟乙基磺酸盐、烷基磷酸盐、烷基醚磷酸盐、烷基醚羧酸盐、α-烯烃磺酸盐,具体地,碱金属盐和碱土金属盐,例如,钠、钾、镁、钙以及铵和三乙醇胺盐。在每种情况下,这些烷基醚硫酸盐、烷基醚磷酸盐以及烷基醚羧酸盐可以具有例如在1与10个之间的环氧乙烷或环氧丙烷单元,优选1至3个环氧乙烷单元。适合的实例为月桂基硫酸钠、月桂基硫酸铵、月桂基醚硫酸钠、月桂基醚硫酸铵、月桂基肌氨酸钠、油基琥珀酸钠、月桂基磺基琥珀酸铵、十二烷基苯磺酸钠、十二烷基苯磺酸三乙醇胺盐。
●润湿剂如,例如,碱金属、碱土金属或铵的如下酸的盐:芳香族磺酸类,例如,木质素磺酸、苯酚磺酸、萘-以及二丁基萘磺酸;以及脂肪酸类,烷基-和烷基-芳基磺酸盐、烷基硫酸盐、月桂基醚硫酸盐和脂肪醇硫酸盐;以及硫酸化的己基-、庚基-以及十八基醇或脂肪醇乙二醇醚的盐,磺化萘及其与甲醛的衍生物的缩聚物,萘的缩聚物或萘磺酸与苯酚和甲醛的缩聚物,聚环氧乙烷辛基酚醚,乙氧基化的异辛基酚、辛基酚或壬基酚,烷基酚聚乙二醇醚或三丁基苯基聚乙二醇醚,烷基芳基聚醚醇,异三癸基醇,脂肪醇/环氧乙烷缩聚物,乙氧基化的蓖麻油,聚氧化乙烯烷基醚或聚氧化丙烯,月桂基醇聚乙二醇醚醋酸酯,山梨糖醇酯,木质素-亚硫酸盐废液或甲基纤维素。
●乳化剂如,例如,钠、钾以及铵的链长C12-C20的直链脂肪族羧酸盐,羟基十八烷磺酸钠,钠、钾以及铵的链长C12-C20的羟基脂肪酸盐以及其硫化或乙酰化产物,烷基硫酸盐,又如三乙醇胺盐、烷基(C10-C20)-磺酸盐、烷基(C10-C20)-芳基磺酸盐、二甲基二烷基(C8-C18)-氯化铵,酰基-、烷基-、油基-以及烷基芳氧基乙氧基化物及其硫化产物,与链长C4-C16的脂肪族饱和一元醇的磺基琥珀酸酯的碱金属盐,与链长C10-C12的单羟基脂肪醇的聚乙二醇醚的磺基琥珀酸4-酯(二钠盐),与聚乙二醇壬基苯基醚的磺基琥珀酸4-酯(二钠盐),磺基琥珀酸双-环己基酯(钠盐),木质磺酸及其钙盐、镁盐、钠盐和铵盐,带有20个环氧乙烷基团的聚氧乙烯山梨聚糖单油酸酯,树脂酸,加氢的和脱氢的树脂酸及其碱金属盐,十二烷基化二苯基醚二磺酸钠,以及具有按重量最少10%的环氧乙烷的环氧乙烷和环氧丙烷的共聚物。以下项被优选地用作乳化剂:月桂基硫酸钠、月桂基醚硫酸钠、乙氧基化物(3个环氧乙烷基团);油醇的聚乙二醇-(4-20)醚以及壬基酚的聚环氧乙烷(4-14)醚。
●分散剂如,例如,烷基酚聚乙二醇醚。
●稳定剂如,例如,纤维素以及纤维素衍生物。
●黏着剂,如,羧甲基纤维素、以粉末、颗粒或乳胶的形式的天然的和合成的聚合物,如,阿拉伯树胶、聚乙烯醇、聚醋酸乙烯酯、以及天然磷脂如脑磷脂和卵磷脂、以及合成磷脂和液体石蜡。
●铺展剂如,例如,肉豆蔻酸异丙酯、聚氧乙烯壬基苯基醚以及聚氧乙烯月桂基苯基醚。
●有机溶剂如,例如,单或多元醇、酯、酮以及烃。适合的溶剂实例为石蜡,例如矿物油馏分、矿物和植物油、丁醇或乙二醇及其醚和酯,酮如丙酮、甲基乙基酮、甲基异丁基酮或环己酮。
●芳香剂和着色剂,如无机颜料,例如氧化铁、氧化钛、普鲁士蓝,以及有机染料如茜素、偶氮以及金属酞菁盐染料和痕量养分如铁盐、锰盐、硼盐、铜盐、钴盐、钼盐以及锌盐。
●缓冲剂、缓冲体系或pH调节剂。
●结晶抑制剂如N-烷基-吡咯烷酮类,如,例如,N-辛基-吡咯烷酮和N-十二烷基吡咯烷酮、此外的聚乙烯吡咯烷酮与聚乙烯醇的共聚物,如,例如,以名称Luviskol VA64(R)(巴斯夫(BASF))已知的聚乙烯吡咯烷酮/聚乙烯醇共聚物,此外的二甲基烷基羧酰胺类,如二甲基癸酰胺,或以名称Hallcomid(R)(霍尔公司(Hall Comp.))已知的二甲基C6-12-烷基羧酰胺混合物,以及此外的乙二胺与环氧乙烷和环氧丙烷的共聚物如,例如,以名称Synperonic(R)T 304(有利凯玛(Uniqema))已知的产品。
其他的间疏剂可以例如从由以下各项组成的组中选择:
苯嗪草酮、西维因(Carbaryl)、2-(1-萘基)醋酸(NAA)、苄基腺嘌呤、萘氧乙酸(NES)、赤霉酸、多效唑、硫代硫酸铵和尿素、以及乙烯形成物如乙烯利,特别地在难以间疏并且/或展现轻度的隔年结果的苹果种类(如艾尔斯塔或元帅)的情况中。
可以使用的生长调节剂的一个实例是调环酸钙。
这些间疏组合物可包括的另外的农药活性物质的实例是杀菌剂和杀虫剂。
杀菌剂可以例如选自由以下各项组成的组:硫(可湿润的硫)、铜制剂、苯并咪唑、联苯三唑醇、苯氟磺胺、咪唑菌酮、氯苯嘧啶醇、环酰菌胺、咯菌腈、氟吡菌酰胺、三乙磷酸铝、异菌脲、腈菌唑、戊菌唑、唑菌醇、乙烯菌核利、甲苯氟磺胺(Euparen M(R))、克菌丹、甲基代森锌、戊唑醇肟菌酯、醚菌酯、二噻农、环丙嘧啶、嘧霉胺、代森锰锌(DithaneUltra(R))以及代森联。
杀虫剂可以例如选自由以下各项组成的组:乐果(Dimethoate)、砜吸磷、马拉赛昂(Malathion)、苄氯菊酯、双甲脒、螨死净(Clofentezin)、三氯氟氰菊酯、高效氟氯氰菊酯(Beta-cyfluthrin)、唑螨酯、二氟脲、甲氧虫酰肼、虫酰肼、吡虫啉、噻虫啉、噻虫嗪、季酮螨酯、四螨嗪、苯氧威、XenTari(R)、虫酰肼、二氟脲、抗蚜威(Pirimicarb)、吡螨胺、唑螨酯、菜籽油、矿物油以及卵磷脂,并且特别着重于吡虫啉和噻虫啉。
根据本发明所使用的组合物以及根据本发明的组合物优选地此外包括
●钙盐以及优选地另外的
●甲酸盐。
可将该钙和这些甲酸盐以任何化合物的形式引入到这些组合物中。为了引入甲酸盐,优选的是碱金属甲酸盐如,例如,甲酸钾和甲酸钠、碱金属二甲酸盐如,例如,二甲酸钾和二甲酸钠、以及碱土金属甲酸盐如,例如,甲酸钙,或这些类甲酸盐的混合物。为了引入钙,优选的是甲酸钙和其他的有机羧酸钙盐、氯化钙、硝酸钙以及其他的无机钙盐,优选地是甲酸钙和氯化钙并且特别优选地是甲酸钙。
在一个实施例中,敌草隆、以氧化钙计算的钙以及以甲酸计算的甲酸盐的重量比为1:(0.1到500):(0.16到900),优选地1:(0.5到100):(0.8到180)。
特别优选地使用甲酸钙,因为它避免了与常规地用于农药配制品的其他钙盐相关的情况下可能发生的问题。因此,例如,甲酸钙并非是如可商购的CaCl2那样吸湿性的或被碱性污染物(Ca(OH)2)污染的,并且不像碳酸钙那样微溶于水。包括了甲酸钙的配制品此外具有比这些经常使用的钙盐(硝酸盐、碳酸盐以及氯化物)更好的耐雨性。
观察到的钙盐的一个副作用是,当施用于幼小的植物器官(叶和果实)时,根据本发明的这些组合物很适合于避免这些植物并且特别地是这些果实中的缺钙症状,例如,苹果中的苦陷病。
出人意料地,甲酸钙特别地使有待根据本发明使用的组合物以及根据本发明的组合物具有可能的良好的配制性质。
优选地从组合物浓缩物,例如通过与水混合,来获得这些可立即使用的间疏组合物,从而简化制备、存储以及运输。
组合物浓缩物可以按所希望的配制。适合的配制品为,例如,微囊悬浮剂(CS)、水可溶浓缩物(SL)、悬浮浓缩物(SC)、可湿润粉剂(WP)、水可分散粒剂(WG),并且一般地优选水可溶浓缩物(SL)、悬浮浓缩物(SC)以及水可分散粒剂(WG)。原则上,优选的配制品类型本质上将依赖于所使用的组合物及其物理性质。然而,因为这些是已知的,技术工人在少量实验中确定一个优选配制品类型是惯常做法。
组合物浓缩物可包括例如
●多于按重量0.2%到按重量30%,优选地按重量0.5%到按重量30%并且特别优选地按重量2到20%的敌草隆。
根据本发明的组合物浓缩物此外任选地包括
●按重量0.2%到按重量30%,优选地按重量2%到按重量30%的以氧化钙计算的钙盐,
并且任选地此外
●按重量0.2%到按重量30%,优选地按重量2%到按重量30%的以甲酸计算的甲酸盐。
关于这些组合物浓缩物的除敌草隆外的这些另外的成分,如添加剂、其他间疏剂、生长调节剂以及其他另外的农药活性物质,上文所述的可立即使用的间疏组合物类似地适用于此。
通过常规方法施用这些可立即使用的组合物,这就是说例如通过喷洒、灌注、喷雾、注射或涂覆。该施用优选地直接实施到植物器官,具体地到叶和/或果实。
为实施根据本发明的方法,例如施用这样的量的可立即使用的组合物,即,每次施用优选地施用0.005到2kg/ha,优选地0.01到1kg/ha,特别优选地0.01到0.5kg/ha的敌草隆。
施用次数可以是,例如,一次到六次,优选地一次、两次或三次。本发明的优点是提供了一种有效的间疏组合物,在没有其他的实质性植物伤害的情况下施用该间疏组合物。
实例
在一个实验田中,该实验田种植有于2006年春种植的苹果树栽培变种布瑞本马瑞丽红M9(Braeburn Mariri Red M9)(种植距离3.5×1.0m),每种情况四块5棵树的样地,在2012年5月21日当该花具有10mm的果实大小时以及在2012年5月30日当最后的花具有10mm的大小时对每棵树喷洒在下文定义的确定量的组合物。在那5棵树中,每种情况中根据以下表1中指定的指标对具有均匀量花的3棵树的3个被标记的枝进行评估并且根据表2中指定的指标完全地评估这3棵树。以500l/水每公顷和冠高米数的这些可立即使用的组合物的施用量,这在本文中对应为1000l每公顷,来执行该处理。
对照实验(1):无间疏
手工(9):专门地手工执行间疏
实验1到3:以上述的量的可立即使用的组合物执行间疏,这些组合物通过混合下文所述的量的一种悬浮浓缩物来获得,该悬浮浓缩物包括808g/l的敌草隆、50g/l的乙二醇、34g/l的表面活性剂以及另外的配制佐剂和380g/l的水:
实验1(X0):每10l水7500g的该悬浮浓缩物(约600ppm)
实验2(X1):每10l水3750g的该悬浮浓缩物(约300ppm)
实验3(X2):每10l水1875g的该悬浮浓缩物(约150ppm)
表1:对每种情况中每块样地三棵树上的三个被标记枝的评估
表2:对每块样地这3棵被标记的树的评估
Claims (11)
1.一种水果间疏方法,其特征在于在6到30mm的果期将一种包括敌草隆的组合物施用于梨果作物的植物器官,其中所用组合物是一种包括以下各项的组合物:
●按重量至少70%的水
●按重量0.001%到按重量0.2%的敌草隆
并且其中选择包括敌草隆的组合物的量使得每次施用施用0.01到0.5kg/ha的敌草隆。
2.根据权利要求1所述的方法,其特征在于该间疏在各种苹果上进行。
3.根据权利要求1所述的方法,其特征在于所述梨果作物选自由以下所组成的组中:博斯科普、布瑞本、考克斯橙、艾尔斯塔、嘎啦、格劳斯特、金冠、富士、坎齐、洋巴、詹姆斯·格里夫、乔纳金、红玉、拉宝、麦金托什、元帅、斯巴达、康富伦、榅桲以及亚洲梨。
4.根据权利要求1或2所述的方法,其特征在于该水果间疏在8到17mm的果期进行。
5.根据权利要求1所述的方法,其特征在于该组合物额外地包括添加剂。
6.根据权利要求5所述的方法,其特征在于该组合物还包括其他的间疏剂、生长调节剂以及其他另外的农药活性物质。
7.根据权利要求5所述的方法,其特征在于该组合物不包括其他的间疏剂、生长调节剂以及其他另外的农药活性物质。
8.根据权利要求6或7所述的方法,其特征在于该组合物还包括:
●钙盐。
9.根据权利要求8所述的方法,其特征在于它包括甲酸钙,并且敌草隆、以氧化钙计算的钙、和以甲酸计算的甲酸盐的重量比是1:0.1到500:0.16到900。
10.根据权利要求1或2所述的方法,其特征在于实施该方法使得包括敌草隆的组合物在一次到六次施用中被施用。
11.根据权利要求8所述的方法,其特征在于该组合物还包括甲酸盐。
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