CN104406981A - Method for quickly and qualitatively discriminating fibers - Google Patents

Method for quickly and qualitatively discriminating fibers Download PDF

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Publication number
CN104406981A
CN104406981A CN201410709676.8A CN201410709676A CN104406981A CN 104406981 A CN104406981 A CN 104406981A CN 201410709676 A CN201410709676 A CN 201410709676A CN 104406981 A CN104406981 A CN 104406981A
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fiber
fibre
differentiates
fast qualitative
measured
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CN104406981B (en
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赖朝坤
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CNTAC DONGGUAN INSPECTION TECHNOLOGY SERVICE Co.,Ltd.
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DONGGUAN FENGTAI DETECTION INSTRUMENT Co Ltd
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Abstract

The invention belongs to the technical field of textile testing and particularly relates to a method for quickly and qualitatively discriminating fibers. The method comprises the following steps: firstly, putting fibers to be tested on a glass slide and covering with the cover glass; secondly, observing the longitudinal morphological characteristics of an obtained sample under a projection microscope, and dropping a reagent such as hydrochloric acid, concentrated nitric acid or glycerin on the glass slide to observe the fiber change so as to discriminate the fibers. The whole discriminating process is quick and accurate, the problem of relatively low qualitative discriminating speed of common fibers in a textile fiber content test process is solved, and the labor intensity of testers is reduced.

Description

A kind of fast qualitative differentiates the method for fiber
Technical field
The invention belongs to textile test technical field, be specifically related to a kind of method that fast qualitative differentiates fiber.
Background technology
Textile fibres is the important source material taking textile, household textiles and fabrics for industrial use, in production and daily life, fiber understood by which kind of fiber is, fabric is planted fiber spinning by which kind of or which and is made, you can be made to grasp the performance of fiber and textile better, and this is to normally to produce and daily life has very important meaning.The kind of textile fiber is a lot, and along with a large amount of development of man-made fiber, the textile of blending and intertexture is also increasing, and the performance of textile is closely related with the fibre property of this textile of composition.Therefore, in textile production management or product analysis, differentiate just even more important to fiber science of carrying out.The mode of appearance of various textile fiber or inwardness have similar place, also have difference.Fibre identification utilizes fiber appearance form or inwardness difference exactly, adopts various method that they are made a distinction.The phase difference of various natural fiber is comparatively obvious, and of a sort phase keeps certain substantially.Therefore, differentiate that natural fiber is mainly according to outward appearance phase Characteristics.The mode of appearance basic simlarity of many man-made fiber particularly general synthon, its cross section mostly is circular, but along with the development of profile fibre, the man-made fiber of one species can be made into different section morphologies, this is just difficult to distinguish fiber species from phase Characteristics, therefore must differentiate in conjunction with additive method.Because the material the Nomenclature Composition and Structure of Complexes of various chemical substance is different, their physical property difference is very large.Therefore, man-made fiber is mainly differentiated according to fibrous physics and chemical property difference.
Differentiate that the method for fiber has microscopic examination method, combustion method, dissolution method, coloring medicine method, melting point method, densimetry and By Birefringence Method etc.In addition, also fiber can be differentiated according to fibrous molecular structure, as X-ray diffraction method and infrared absorption spectroscopy etc.
At present, using maximum is microscopic method and dissolution method.These two kinds of methods are that the basis being based upon feel ocular estimate and combustion method is empirically carried out, and general fibre common at present, finally can be differentiated it by these two parts.But these two kinds of methods also come with some shortcomings, such as microscopic method, conventional is biological microscope, the film-making process (particularly cross-sectional slices) of fibre section is more loaded down with trivial details, human eye is needed to go to observe the fiber on microslide by eyepiece, visual field opereating specification is more limited, and microscopic method qualitative progress needs to spend many time to go to distinguish fiber.Dissolution method, be the method differentiating fiber on the basis of microscopic method further, carry out separately with regard to current technical needs, course of dissolution needs about 5 minutes, and some also may need heating.The discriminating time is long and loaded down with trivial details.
Summary of the invention
In order to solve the problem, the object of the invention is to, provide a kind of simple to operate, the fast qualitative that qualification accuracy rate is high differentiates fiber process.
The present invention is achieved through the following technical solutions:
Fast qualitative differentiates a method for fiber, comprises following preparation process:
A. prepare hydrochloric acid and red fuming nitric acid (RFNA), be placed in different reagent bottles respectively;
B. get appropriate fiber to be measured to be placed on microslide, and covered;
C. be first placed on the glass objective table of projection microscope by the microslide with fiber to be measured, under amplifying 100 ~ 500 times of conditions, mobile microslide makes fiber be projected on screen, observes the form of fiber, and tentatively identifies fiber;
D. in reagent bottle, get described hydrochloric acid drops in fiber to be measured, and covered observes state change and the situation of dissolving of fiber;
E. finally on fiber to be measured, instill described red fuming nitric acid (RFNA), observe state change and the situation of dissolving of fiber, indulge face morphological feature with the standard of microscopic method and contrast, qualitative judgement fibre property.
Wherein, projection microscope adopts Wuxi optical instrument manufacturing plant, JTT/D type, projection microscope.
Preferably, the concentration of volume percent of described hydrochloric acid is 20%.
Preferably, the concentration of volume percent of described red fuming nitric acid (RFNA) is 65% ~ 68%.
Preferably, in described step C, if observed bast-fibre, then separately get a sample instillation glycerine and determined bast-fibre further.
Preferably, before described steps A, feel ocular estimate and combustion method tentatively judge.
Preferably, described fiber to be measured is animal wool fiber, regenerated celulose fibre, polyamide fibre, acrylic fibers, CUP, acetate fiber, Populus deltoides cotton, bast-fibre, silk, dacron or some snapback fibre.
Preferably, described animal wool fiber is wool, cashmere, the rabbit hair or mohair yarn etc.
Preferably, described regenerated celulose fibre is sticky fibre, Modal or lyocell.
Preferably, described snapback fibre is again for being spandex, polyolefin elastic fiber, elastodiene fibre (rubber) etc.
The present invention utilizes simple reagent (glycerine, 20% hydrochloric acid, red fuming nitric acid (RFNA)) to process fiber to be measured successively by described method, and under projection microscope observation period longitudinal morphological feature, carry out qualification to fiber to judge, wherein under 20%HCl normal temperature, volatility is little, can dissolve polyamide fibre; The concentration of red fuming nitric acid (RFNA) is 65.0 ~ 68.0%, and under normal temperature, solubilized acrylic fibers, silk, vinegar fibre etc., can make wool fibre expand.The present invention first drips hydrochloric acid, then drips red fuming nitric acid (RFNA), and can make wool fibre undergoes rapid expansion after two acid mixing, the some dyes that can destroy on fiber reaches the object of fading, and regenerated celulose fibre can be made to become more penetrating, is more conducive to observing fibre morphology.Whole qualification process is fast (only needing 1 ~ 2 minute) not only, and accurately, solve problem slow to common fiber Qualitive test in textile fiber content test process, reduce the labour intensity of tester simultaneously.
Accompanying drawing explanation
Fig. 1 is that ramie indulges face aspect graph, and Fig. 2 is that flax indulges face aspect graph,
Fig. 3 is that hemp indulges face aspect graph, and Fig. 4 is that bluish dogbane indulges face aspect graph,
Fig. 5 is that jute indulges face aspect graph, and Fig. 6 is cotton vertical face aspect graph,
Fig. 7 is that mercerized cotton indulges face aspect graph, and Fig. 8 is that wool indulges face aspect graph,
Fig. 9 is that face aspect graph indulged by cashmere, and Figure 10 is that the rabbit hair indulges face aspect graph,
Figure 11 is that face aspect graph indulged by alpaca fibre, and Figure 12 is that mohair yarn indulges face aspect graph,
Figure 13 is that mulberry silk indulges face aspect graph, and Figure 14 is that tussah silk indulges face aspect graph,
Figure 15 is that face aspect graph indulged by Modal fibre, and Figure 16 is that Lyocell fibers indulges face aspect graph,
Figure 17 is that face aspect graph indulged by terylene, and Figure 18 is that face aspect graph indulged by acrylic fibers,
Figure 19 is that face aspect graph indulged by polyamide fibre, and Figure 20 is that face aspect graph indulged by polypropylene fibre,
Figure 21 is sticky fine vertical face aspect graph.
concrete embodiment
Below in conjunction with embodiment, the present invention is described in further detail, understands the present invention to help those skilled in the art.
Fast qualitative differentiates the method for fiber, comprises following preparation process:
One, first fiber to be measured is observed:
(1), as all short in fruit fiber and thin, normal with various impurity and fault, have combustion paper taste after so burning, tentatively can be judged as cotton fiber;
(2) if feel is more thick and stiff, there is combustion paper taste after so burning, tentatively can be judged as flaxen fiber.
(3) if curling and high resilience, singe after so burning and send out a taste, tentatively can be judged as animal origin.
(4) if long filament, long and very thin, there is special gloss, singe after so burning and send out taste, tentatively can be judged as silk.
(5), as fruit fiber dry, the powerful difference of wet condition large, have molten contracting phenomenon during burning, tentatively can be judged as man-made fiber.
(6), as fruit fiber has very large elasticity, at room temperature its length can be stretched to more than five times, tentatively can be judged as snapback fibre.
Two, projection microscope Rapid identification is carried out again:
1 if fiber crops
Be placed in through observing this fiber to be measured of classifying out on microslide, and covered; Be placed on by microslide with fiber to be measured on the glass objective table of projection microscope, under amplifying 100 ~ 500 times of conditions, mobile microslide makes fiber be projected on screen, observes the form of fiber, and determines further;
Then in reagent bottle, get glycerine drops in this fiber, and covered observes the state change of fiber,
(1), as fruit fiber is comparatively thick, there is microscler striped and the horizontal joint of bamboo shape (see Fig. 1), can ramie be judged to be;
(2), as fruit fiber is comparatively thick, there is the horizontal joint of bamboo shape (see Fig. 2), can flax be judged to be;
(3) if fibre diameter and morphological differences are very large, horizontal joint not obvious (see Fig. 3), can be judged to be hemp;
(4), as glossy in fruit fiber, but horizontal joint not obvious (see Fig. 4), can be judged to be bluish dogbane;
(5), as fruit fiber has microscler striped, the horizontal joint of bamboo shape not obvious (see Fig. 5), can be judged to be jute;
2 if other
Be placed in through observing this fiber to be measured of classifying out on microslide, and covered; Be placed on by microslide with fiber to be measured on the glass objective table of projection microscope, under amplifying 100 ~ 500 times of conditions, mobile microslide makes fiber be projected on screen, observes the form of fiber, and determines further;
Then in reagent bottle, get described hydrochloric acid drops in this cotton fiber, and covered observes state change and the situation of dissolving of fiber; Finally on fiber to be measured, instill described red fuming nitric acid (RFNA), observe state change and the situation of dissolving of fiber.
(1) when, being tentatively judged as cotton fiber:
If face form indulged by the fiber under projection microscope is flat belt-like, slightly natural curvature (see Fig. 6), then judge that this fiber is as cotton.
If face form indulged by the fiber under projection microscope is approximate circle column, glossy and crack (see Fig. 7), then judge that this fiber is as mercerized cotton.
(2) when, being tentatively judged as animal origin:
If rough surface has scale (see Fig. 8), wool can be judged to be.
If smooth surface, scale is thinner and Bao Cheng is more complete, and scale spacing comparatively large (see Fig. 9), can be judged to be cashmere.
If scale is less is longitudinally skewed with fiber, pulp cavity has single-row, and biserial, multiple row (see Figure 10), can be judged to be the rabbit hair.
If scale is glossy, what have has entire body or is interrupted pulp cavity (see Figure 11), can be judged to be alpaca fibre.
If scale is more glossy, diameter is comparatively thick, and what have has spot (see Figure 12), can be judged to be mohair yarn.
(3) if be tentatively judged as silk:
If glossy, fibre diameter and form variant (see Figure 13), can be judged to be mulberry silk.
If flat belt-like, there is fine streaks.(see Figure 14), can be judged to be tussah silk.
(4) if be tentatively judged as regenerated celulose fibre:
If surface smoothing, there is groove (see Figure 15), can Modal fibre be judged to be.
If surface smoothing, glossy (see Figure 16), can be judged to be Lyocell fibers.
If surface smoothing, there is clear striped (see Figure 21), can be judged to be sticky fine.
(5) if be tentatively judged as man-made fiber:
If surface smoothing, what have has pore (see Figure 17), and can be judged to be terylene, terylene is dissolved in the concentrated sulphuric acid.
If surface smoothing, have smooth surface, have groove and (or) striped (see Figure 18), visible its of instillation red fuming nitric acid (RFNA) dissolves, and can be judged to be acrylic fibers.
If smooth surface, have pore (see Figure 19), visible its of instillation hydrochloric acid dissolves, and can be judged to be nylon fibre.
If surface smoothing, have with scar (see Figure 20), can be judged to be polypropylene fibre, polypropylene fibre is insoluble to the concentrated sulphuric acid.
Above-described embodiment, just preferred embodiment of the present invention, is not used for limiting the scope of the present invention, therefore all equivalences done with the feature described in the claims in the present invention and principle change or modify, and all should be included within the claims in the present invention scope.

Claims (9)

1. fast qualitative differentiates a method for fiber, it is characterized in that, comprises following preparation process:
A. prepare hydrochloric acid and red fuming nitric acid (RFNA), be placed in different reagent bottles respectively;
B. get appropriate fiber to be measured to be placed on microslide, and covered;
C. be first placed on the glass objective table of projection microscope by the microslide with fiber to be measured, under amplifying 100 ~ 500 times of conditions, mobile microslide makes fiber be projected on screen, observes the form of fiber, and tentatively identifies fiber;
D. in reagent bottle, get described hydrochloric acid drops in fiber to be measured, and covered observes state change and the situation of dissolving of fiber;
E. finally on fiber to be measured, instill described red fuming nitric acid (RFNA), observe state change and the situation of dissolving of fiber, indulge face morphological feature with the standard of microscopic method and contrast, qualitative judgement type of fibers.
2. fast qualitative differentiates the method for fiber as claimed in claim 1, and it is characterized in that, the concentration of volume percent of described hydrochloric acid is 20%.
3. fast qualitative differentiates the method for fiber as claimed in claim 1, and it is characterized in that, the concentration of volume percent of described red fuming nitric acid (RFNA) is 65% ~ 68%.
4. fast qualitative differentiates the method for fiber as claimed in claim 1, it is characterized in that, in described step C, if observed bast-fibre, has then separately got a sample instillation glycerine and determines bast-fibre further.
5. fast qualitative differentiates the method for fiber as claimed in claim 1, and it is characterized in that, before described steps A, feel ocular estimate and combustion method tentatively judge.
6. as fast qualitative as described in any one in claim 1-5 differentiates the method for fiber, it is characterized in that, described fiber to be measured is animal wool fiber, regenerated celulose fibre, polyamide fibre, acrylic fibers, CUP, acetate fiber, cotton, kapok, bast-fibre, silk, dacron or snapback fibre.
7. fast qualitative differentiates the method for fiber as claimed in claim 6, and it is characterized in that, described animal wool fiber is wool, cashmere, the rabbit hair or mohair yarn.
8. fast qualitative differentiates the method for fiber as claimed in claim 6, it is characterized in that, described regenerated celulose fibre is sticky fibre, Modal or lyocell.
9. fast qualitative differentiates the method for fiber as claimed in claim 6, and it is characterized in that, described snapback fibre is spandex, polyolefin elastic fiber, elastodiene fibre.
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Cited By (9)

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CN105970589A (en) * 2016-08-01 2016-09-28 太仓市鑫泰针织有限公司 Simple identification method for cashmere knitted fabric
CN106018410A (en) * 2016-08-01 2016-10-12 太仓市鑫泰针织有限公司 Method for identifying fiber variety of knitted fabrics
CN106226258A (en) * 2016-08-10 2016-12-14 四川大学 Method for identifying bamboo pulp fiber and common viscose fiber
CN107561078A (en) * 2017-10-17 2018-01-09 北京和众视野科技有限公司 Textile fiber detection method
CN109142124A (en) * 2018-08-30 2019-01-04 必维申优质量技术服务江苏有限公司 A kind of improved modified acrylic fibre qualitative and quantitative analysis method
CN109187370A (en) * 2018-08-10 2019-01-11 江苏恒神股份有限公司 A kind of carbon fiber color difference detection method
CN113447483A (en) * 2021-06-25 2021-09-28 山东东宏管业股份有限公司 Method for testing fiber length in short fiber composite plastic
CN113533329A (en) * 2021-07-12 2021-10-22 公安部物证鉴定中心 Fiber comparison sheet for forensic science polarized light microscope test and preparation method thereof

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105842384A (en) * 2016-03-23 2016-08-10 苏州市纤维检验所 Qualitative detection method of aromatic polyoxadiazole fiber
CN105970589A (en) * 2016-08-01 2016-09-28 太仓市鑫泰针织有限公司 Simple identification method for cashmere knitted fabric
CN106018410A (en) * 2016-08-01 2016-10-12 太仓市鑫泰针织有限公司 Method for identifying fiber variety of knitted fabrics
CN106226258A (en) * 2016-08-10 2016-12-14 四川大学 Method for identifying bamboo pulp fiber and common viscose fiber
CN106226258B (en) * 2016-08-10 2018-10-19 四川大学 Method for identifying bamboo pulp fiber and common viscose fiber
CN107561078A (en) * 2017-10-17 2018-01-09 北京和众视野科技有限公司 Textile fiber detection method
CN109187370B (en) * 2018-08-10 2021-04-02 江苏恒神股份有限公司 Carbon fiber color difference detection method
CN109187370A (en) * 2018-08-10 2019-01-11 江苏恒神股份有限公司 A kind of carbon fiber color difference detection method
CN109142124B (en) * 2018-08-30 2020-12-08 必维申优质量技术服务江苏有限公司 Improved qualitative and quantitative analysis method for modified polyacrylonitrile fiber
CN109142124A (en) * 2018-08-30 2019-01-04 必维申优质量技术服务江苏有限公司 A kind of improved modified acrylic fibre qualitative and quantitative analysis method
CN113447483A (en) * 2021-06-25 2021-09-28 山东东宏管业股份有限公司 Method for testing fiber length in short fiber composite plastic
CN113447483B (en) * 2021-06-25 2022-07-12 山东东宏管业股份有限公司 Method for testing fiber length in short fiber composite plastic
CN113533329A (en) * 2021-07-12 2021-10-22 公安部物证鉴定中心 Fiber comparison sheet for forensic science polarized light microscope test and preparation method thereof

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