CN104404787A - All-cotton composite functional fabric with all-cotton water-proof, oil-proof and antifouling properties - Google Patents

All-cotton composite functional fabric with all-cotton water-proof, oil-proof and antifouling properties Download PDF

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Publication number
CN104404787A
CN104404787A CN201410568369.2A CN201410568369A CN104404787A CN 104404787 A CN104404787 A CN 104404787A CN 201410568369 A CN201410568369 A CN 201410568369A CN 104404787 A CN104404787 A CN 104404787A
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fabric
cotton
nano
composite functional
waterproof
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CN201410568369.2A
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CN104404787B (en
Inventor
叶远丽
陈太球
顾继东
董晓明
李飞
刘灵燕
傅佳佳
王鸿博
高卫东
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SHENGHUADUN CLOTHING Co Ltd
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SHENGHUADUN CLOTHING Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/02Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
    • D06M10/025Corona discharge or low temperature plasma
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/02Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising animal or vegetable substances, e.g. cork, bamboo, starch
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/022 layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/20All layers being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06Vegetal fibres
    • B32B2262/062Cellulose fibres, e.g. cotton
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/01Stain or soil resistance
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10Repellency against liquids
    • D06M2200/11Oleophobic properties
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10Repellency against liquids
    • D06M2200/12Hydrophobic properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention discloses an all-cotton composite functional fabric with water-proof, oil-proof and antifouling properties; the all-cotton composite functional fabric includes a composite fabric having a surface layer and an inner layer, the surface layer is a machine-woven fabric layer, and the inner layer is a knitted fabric layer; the composite fabric is subjected to a pretreatment process by a cellulase and low-temperature oxygen plasma combination way; then a 'double-nano' finishing agent is applied to the fabric surface by using a physical vapor deposition method, a layer of thin film with 'three protection' function is formed on the fabric surface; the 'double-nano' finishing agent is a mixture of nano fluoride and ceramic powder nano particles. The composite functional fabric is pretreated by the cellulase and low-temperature oxygen plasma combination way, neps and impurities on the fabric surface are removed, the fabric softness is increased, and a final using effect is improved; and at the same time, with combination of the low-temperature plasma treatment process, and through the etching effect of plasma, the combination fastness of the finishing agent with the fabric surface is greatly improved, and the durability of functional finishing is improved.

Description

The cotton composite functional fabric of a kind of cotton waterproof, grease proofing, antifouling property
Technical field
The present invention relates to a kind of fabric, be specifically related to the cotton composite functional fabric that one has three anti-(waterproof, grease proofing, antifouling) performance, belong to field of textile.
Background technology
Along with the development of science and technology, the progress of society and growth in the living standard, textiles extends to the functions such as attractive in appearance, comfortable, fashion, protection from the basic function hiding body resisting cold.The requirement of people to quality of life is more and more higher, the attention rate of functional fabric is also obviously strengthened, the present invention relates to fabric functional three anti-(waterproof, grease proofing, antifouling) function, be intended to propose the new approaches of a kind of cotton three anti-(waterproof, grease proofing, antifouling) composite functional fabric processing.
In some special environment (as work of electric power system environment), waterproof, grease proofing, antifouling property are the requisite functions of operation garment material, for the problem that existing fabric function is relatively single, need to invent a kind of novel cotton three anti-(waterproof, grease proofing, antifouling) composite functional fabric, this fabric has good water proofing property, grease proofness and soil resistance simultaneously, also should take into account and have good snugness of fit.
Summary of the invention
The object of the invention is to design the cotton composite material that one has three anti-(waterproof, grease proofing, antifouling) performance, this fabric has good water proofing property, grease proofness and soil resistance, has good snugness of fit simultaneously.
For achieving the above object, the present invention adopts following technical scheme:
There is a cotton composite functional fabric for waterproof, grease proofing, antifouling property, comprise the composite construction of top layer and nexine, adopt cellulase and Low-temperature oxygen plasma combination to carry out preliminary treatment; Then adopt physical gas-phase deposite method that " double nano " finishing agent is applied to fabric face, form one deck at this web surface and have the film of " three is anti-" function; Described " double nano " finishing agent is the mixture of nano fluoride and ceramic powders nano particle.
Wherein, pretreatment process method is as follows:
1) woven fabric layer and the knitted side bed of material are combined with each other by moulding technology, then use pH=3.5 ~ 7.8, enzyme content is that the cellulose enzyme of 1%-2% is washed, and at 50 DEG C of temperature, enzyme washes 20 ~ 30min;
2) by step 1) in enzyme washing lotion boil deactivation; Then wash, dry;
3) cryogenic oxygen ion processing 10 ~ 20min is carried out again; Wherein, vacuum is 5Pa, passes into oxygen, and power is 50W.
Washed the surface energy reducing fabric by cellulase, realize the waterproof of cotton composite functional fabric, grease proofing, antifouling modification, namely give fabric " three prevent " function.And fabric is after repeatedly washing, it is fine that " three prevent " effect still keeps.
Described cellulase is primarily of compositions such as circumscribed 1,4 beta-glucanase, Endo-β-glucanase and beta-glucosidases.Be selected from trade name and have one in B963,8000L and cellusoft L.
Further, the all-cotton fabric of described table nexine composite construction, what its top layer adopted is cotton woven fabric, what nexine adopted is knit fabric, take full advantage of excellent DIMENSIONAL STABILITY and the durability of woven fabric, give full play to flexible, breathable and performance comfortable and easy to wear that knit fabric has simultaneously.Then, lamination and special adhesive is utilized top layer and nexine compound to be become table nexine composite structure fabric fabric.
Described finishing technique is as follows:
1) pretreated fabric is rolled through two leachings two, dipping 1min, pick-up 70% ~ 80%;
2) then at 80 DEG C of temperature after preliminary drying 5min, then carry out baking acquisition.
Described " double nano " finishing agent nano fluoride and the applying mass ratio of ceramic powders nano particle are: 1:1.Can ensure that " three prevent " function gives full play to like this.
Preliminary finish technique adopts biology enzyme assisted plasma processing mode, cellulase is adopted to remove cotton knot on cloth cover and impurity, increase the pliability of cloth, promote final effect, simultaneously in conjunction with low-temperature plasma treatment process, fabric face microstructure is changed, is greatly improved the binding strength of finishing agent and cloth cover by isoionic corrasion, and then improve the endurance quality of finishing functions.
" three prevent " finishing technique is the mode adopting nano fluoride finishing agent to combine with ceramic powders nano particle " double nano ", make full use of small-size effect, surface and interface effect that nanoscale functional finishing agent has, thin and the film of densification is formed at web surface, drastically increase the waterproof of fabric, grease proofing, antifouling effect, obtain excellent wash durability simultaneously.Ceramic powders nano particle itself has certain electric conductivity, can reduce the quantity of electric charge of fiber surface, thus reduces dirt by the Electrostatic Absorption between electric charge to the chance on fiber, enhances anti-fouling effect.Adding of ceramic powders nano particle, enhance " three prevent " finishing effect of nano fluoride, also give the nano materials such as fabric uv resistance, antibiotic property intrinsic characteristic simultaneously.
Compared with prior art, advantage of the present invention and beneficial effect are:
(1) in the present invention, functional fabric have employed cotton table nexine composite construction, and fabric nexine is all-cotton knitting fabric, and skin is cotton mechanism fabric.It is soft, ventilative that this has just given full play to knit fabric, the characteristic of the characteristics such as skin-friendly is good and woven fabric good stability of the dimension, high abrasion resistance.
(2) cellulase and Low-temperature oxygen plasma combination is adopted to carry out preliminary treatment to composite functional fabric, remove cotton knot and the impurity of web surface, increase the pliability of cloth, promote it and final take effect, simultaneously in conjunction with low-temperature plasma treatment process, greatly improved the binding strength of finishing agent and cloth cover by isoionic corrasion, and then improve the endurance quality of finishing functions.
(3) mode adopting nano fluoride finishing agent to combine with ceramic powders nano particle " double nano ", make full use of small-size effect, surface and interface effect that nanoscale functional finishing agent has, thin and the film of densification is formed at web surface, drastically increase the waterproof of fabric, grease proofing, antifouling effect, obtain excellent wash durability simultaneously.Ceramic powders nano particle itself has certain electric conductivity, can reduce the quantity of electric charge of fiber surface, thus reduces dirt by the Electrostatic Absorption between electric charge to the chance on fiber, enhances anti-fouling effect.Adding of ceramic powders nano particle, enhance " three prevent " finishing effect of nano fluoride, also give the nano materials such as fabric uv resistance, antibiotic property intrinsic characteristic simultaneously.
Accompanying drawing explanation
Fig. 1 is the vertical section structure schematic diagram of composite functional fabric of the present invention.
Wherein: 1, " three prevent " arranges oxidant layer; 2, woven fabric layer; 3, the knitted side bed of material.
Detailed description of the invention
Be described in further detail the present invention below in conjunction with drawings and Examples, wherein following examples are only for clearly illustrating technical scheme of the present invention, and can not limit the scope of the invention with this.
Shown in Figure 1, comprise " three prevent " and arrange oxidant layer (1) and woven fabric layer (2), in order to improve the snugness of fit of garment material, the knitted side bed of material (3) is also added between woven fabric layer (2) and skin, two shell fabrics are combined with each other by moulding technology, arranged by finishing agent again, namely obtain cotton three anti-(waterproof, grease proofing, antifouling) composite functional fabric.
The process route adopted is as follows:
Wherein, pretreating process is as follows:
Fabric → cellulose enzyme is washed (pH 3.5 ~ 7.8, enzyme content 1%-2%, 50 DEG C, 20 ~ 30min) → boil deactivation → washing → oven dry → cryogenic oxygen ion processing (back end vacuum 5Pa, pass into oxygen, power 50W, time 10 ~ 20min)
" three prevent " finishing technique is as follows:
Fabric → bis-soak two and roll (dipping 1min, pick-up about 70% ~ 80%) → preliminary drying (80 DEG C, 5min) → bake.
Embodiment
Woven fabric layer: employing be plain weave, the yarn raw material of employing is cotton yarn, and the yarn number through weft yarn is 15.6tex, and select 620/10 centimetres through close, filling density selects 336/10 centimetres.
The knitted side bed of material:
What adopt is rib stitch, and the yarn raw material of employing is also cotton yarn, and institute uses yarn number for 5.9tex, horizontal closely selects 164 stringer/10 centimetre, indulges closely to select 150 line/10 centimetre, and pin number employing 36 or 40G, weave and form on large circle machine.
Preliminary treatment:
Adopt acid cellulose ferment treatment, in conjunction with Low Temperature Plasma Treating technique.
" three prevent " finishing agent:
Comprise nano fluoride finishing agent and ceramic powders nano particle.
Finally " three prevent " performance test and washability test (washing 5 times) are carried out to cotton three anti-(waterproof, grease proofing, antifouling) composite functional fabric.Test result shows: the composite functional fabric " three prevent " in the present invention is respond well, water proofing property 100 points, grease proofness 150 points, soil resistance 4 grades.After 5 washings, " three prevent " effect of this fabric still keeps good, and water proofing property still can reach 100 points, and grease proofness and antifouling property slightly decline, but still within function protecting allowed band, so the water-wash resistance of this fabric is excellent.
In existing result of study, organic fluoride and modified Nano emulsion is adopted fabric to be carried out to the test result display of finishing functions under optimum process condition, fabric " three prevent " is respond well, water resistance is good, after washing 5 times, water proofing property still can reach 100 points, and grease proofness slightly declines, but its antifouling property is down to 2 grades from 4 grades, declines by a big margin.Compared to existing achievement in research, " three prevent " the cotton composite functional fabric in the present invention has good wash durability.
The foregoing is only the specific embodiment of the present invention and preferred embodiment; should be understood that; for those skilled in the art; under the prerequisite not departing from the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (7)

1. have a cotton composite functional fabric for waterproof, grease proofing, antifouling property, comprise the composite material with top layer and nexine, it is characterized in that: described top layer is woven fabric layer, nexine is the knitted side bed of material; Cellulase and Low-temperature oxygen plasma combination is adopted by composite material to carry out pretreating process; Then adopt physical gas-phase deposite method that " double nano " finishing agent is applied to fabric face, form one deck at this web surface and have the film of " three is anti-" function; Described " double nano " finishing agent is the mixture of nano fluoride and ceramic powders nano particle.
2. a kind of cotton composite functional fabric with waterproof, grease proofing, antifouling property according to claim 1, is characterized in that: described pretreatment process method is as follows:
1) woven fabric layer and the knitted side bed of material are combined with each other by moulding technology, then use pH=3.5 ~ 7.8, enzyme content is that the cellulose enzyme of 1%-2% is washed, and at 50 DEG C of temperature, enzyme washes 20 ~ 30min;
2) by step 1) in enzyme washing lotion boil deactivation; Then wash, dry;
3) cryogenic oxygen ion processing 10 ~ 20min is carried out again; Wherein, vacuum is 5Pa, passes into oxygen, and power is 50W.
3. a kind of cotton composite functional fabric with waterproof, grease proofing, antifouling property according to claim 1 and 2, is characterized in that: described cellulase is primarily of compositions such as circumscribed 1,4 beta-glucanase, Endo-β-glucanase and beta-glucosidases.
4. a kind of cotton composite functional fabric with waterproof, grease proofing, antifouling property according to claim 3, is characterized in that: described cellulase is selected from trade name one in B963,8000L and cellusoft L.
5. a kind of cotton composite functional fabric with waterproof, grease proofing, antifouling property according to claim 1, is characterized in that: described " double nano " finishing agent nano fluoride and the applying mass ratio of ceramic powders nano particle are: 1: 1.
6. a kind of cotton composite functional fabric with waterproof, grease proofing, antifouling property according to claim 1, it is characterized in that: what described woven fabric layer adopted is plain weave, the yarn raw material adopted is cotton yarn, yarn number through weft yarn is 15.6tex, select 620/10 centimetres through close, filling density selects 336/10 centimetres.
7. a kind of cotton composite functional fabric with waterproof, grease proofing, antifouling property according to claim 1, it is characterized in that: what the described knitted side bed of material adopted is rib stitch, the yarn raw material adopted also is cotton yarn, use yarn number for 5.9tex, horizontal stroke is close selects 164 stringer/10 centimetre, vertical closely select 150 line/10 centimetre, pin number adopts 36 or 40G, weaves and form on large circle machine.
CN201410568369.2A 2014-10-22 2014-10-22 All-cotton composite functional fabric with all-cotton water-proof, oil-proof and antifouling properties Active CN104404787B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105220457A (en) * 2015-10-20 2016-01-06 湖州申祥丝织有限责任公司 New far infrared cotton fiber that a kind of infant is suitable for and preparation method thereof
CN115418862A (en) * 2022-09-19 2022-12-02 雅戈尔服装制造有限公司 Fluorine-free antifouling finishing method for textiles

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CN202045959U (en) * 2011-03-19 2011-11-23 达利丝绸(浙江)有限公司 Multi-functional silk composite fabric modified by nano material
CN103088645A (en) * 2012-12-30 2013-05-08 浙江工业职业技术学院 Heavy pure cotton fabric cold padding and stacking pretreatment method
CN103194908A (en) * 2013-03-19 2013-07-10 上海嘉乐股份有限公司 Cool wool knitted fabric and processing method thereof
CN103835002A (en) * 2013-11-10 2014-06-04 姜著川 Method for degumming ambary by low-temperature plasma and biological enzyme

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CN101694056A (en) * 2009-10-13 2010-04-14 安徽南澳地毯有限公司 Preparation method of environment-friendly type three-prevention automobile needling finishing material
CN202045959U (en) * 2011-03-19 2011-11-23 达利丝绸(浙江)有限公司 Multi-functional silk composite fabric modified by nano material
CN103088645A (en) * 2012-12-30 2013-05-08 浙江工业职业技术学院 Heavy pure cotton fabric cold padding and stacking pretreatment method
CN103194908A (en) * 2013-03-19 2013-07-10 上海嘉乐股份有限公司 Cool wool knitted fabric and processing method thereof
CN103835002A (en) * 2013-11-10 2014-06-04 姜著川 Method for degumming ambary by low-temperature plasma and biological enzyme

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105220457A (en) * 2015-10-20 2016-01-06 湖州申祥丝织有限责任公司 New far infrared cotton fiber that a kind of infant is suitable for and preparation method thereof
CN115418862A (en) * 2022-09-19 2022-12-02 雅戈尔服装制造有限公司 Fluorine-free antifouling finishing method for textiles

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Address after: 214413 Tin Road, Gushan Town, Wuxi, Jiangsu, Jiangyin 180

Applicant after: SWOTO PROTECTION AND TECHNOLOGY Co.,Ltd.

Address before: 214413 Tin Road, Gushan Town, Wuxi, Jiangsu, Jiangyin 180

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Denomination of invention: A kind of all cotton composite functional fabric with waterproof, oil proof and antifouling properties

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Denomination of invention: A kind of cotton composite functional fabric with waterproof, oil-proof and antifouling properties

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Denomination of invention: A cotton composite functional fabric with waterproof, oil resistant, and stain resistant properties

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