CN103437176A - Low-carbon preparation method of one-way-moisture-conduction pure cotton clothing fabric - Google Patents

Low-carbon preparation method of one-way-moisture-conduction pure cotton clothing fabric Download PDF

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CN103437176A
CN103437176A CN 201310306767 CN201310306767A CN103437176A CN 103437176 A CN103437176 A CN 103437176A CN 201310306767 CN201310306767 CN 201310306767 CN 201310306767 A CN201310306767 A CN 201310306767A CN 103437176 A CN103437176 A CN 103437176A
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fabric
low
step
wet cotton
cotton fabric
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CN 201310306767
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闵洁
田太洲
刘保江
谢阳芬
向中林
姚金龙
唐文君
黄长根
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东华大学
江苏联发纺织股份有限公司
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Abstract

The invention relates to a low-carbon preparation method of a one-way-moisture-conduction pure cotton clothing fabric. The method comprises the following steps: preprocessing a fabric; preparing ink comprising, by mass, 2-10% of a water-repellent finishing agent, 15-40% of a surfactant, 0.1-0.5% of a bactericide, 0.1-0.5% of a pH buffering agent and 49-82.8% of deionized water; and jet-printing the fabric with patterns through adopting a digital ink jet printing technology, pre-drying, and baking. The method has the advantages of simple process, saving of a large amount of a plurality of resources comprising water, energy and the like, no sewage discharge, and benefiting for the environmental protection, and the one-way-moisture-conduction pure cotton clothing fabric has an excellent one-way moisture conduction performance, and has a wide market application prospect and a good social benefit.

Description

一种单向导湿的纯棉服装面料的低碳制备方法 A method for preparing low carbon unidirectional fabric of wet cotton

技术领域 FIELD

[0001] 本发明属于纯棉服装面料的制备领域,特别涉及一种单向导湿的纯棉服装面料的低碳制备方法。 [0001] The present invention belongs to the field of preparing cotton fabric, in particular a method for preparing a one lower guide of wet cotton fabric.

背景技术 Background technique

[0002] 随着生活水平的提高,人们对休闲和运动纺织品的服用性和功能性要求越来越高,人们期盼高品质产品,追求健康、舒适和品位的愿望日益增长。 [0002] As living standards improve, people taking leisure and sports textiles and functional requirements are high, people expect high-quality products, the pursuit of health, comfort and quality of the growing desire. 特殊功能性纺织品层出不穷,其中休闲服与运动服相互渗透和融为一体的趋势也日益受广大消费者的青睐。 Special functional textiles abound, casual wear and sportswear trend of mutual penetration and integration are increasingly popular with consumers. 棉纤维是一种亲水性天然纤维,其织物因良好的机械性能、舒适地穿着性能以及低廉的价格,一直以来都是最为普遍和流行的服装面料。 Cotton fiber is a hydrophilic natural fiber, fabric because of its good mechanical properties, wear comfortably performance and low price, it has always been the most common and popular fabric. 然而,当消费者选择棉制服装,在运动过程中较长时间适量出汗或大量出汗时,棉织物的高吸湿能力会带来一系列问题。 However, when consumers choose cotton clothing, when in motion the process for a long time the amount of sweating or profuse sweating, high moisture absorption capacity of cotton fabric will bring a series of problems. 主要表现在:服装吸湿太多、变重、由于水的重量而下垂,干燥时间长;棉制服装很容易粘在湿的皮肤上,会引起不舒适感以及运动受限;湿的棉织物也会使得穿着者感觉寒冷,尤其是在刚进入空调环境时更明显;由于出汗,加大了细菌的滋生可能,而慢速干燥可能会使得异味存在的时间更长。 Main features: absorbent garment too, becomes heavy, sagging due to the weight of water, a long drying time; cotton garments easily stick to wet skin, causing discomfort and limited movement; wet cotton fabric also It will make the wearer feel cold, especially in the more obvious when you enter the air-conditioned environment; due to perspiration, may increase the breeding of bacteria, while slow drying time may make the presence of odors longer. 消费者迫切希望能有一种在夏季或多汗状态下穿着舒适的服装,改善湿热的状态。 Consumers eager to be able to have a comfortable clothes in summer or sweating state, improving the state of the hot and humid. 基于人体对舒适度要求带来的市场需求,开发单向导湿织物具有重要的现实意义。 Has important practical significance to the development of a single wizard wet fabric based on human comfort requirements brought about by market demand.

[0003] 单向导湿是通过织物内外层的亲、疏水性不同,即织物外层亲水而内层大部分疏水,汗液从内层小部分亲水的部位传输到织物的亲水性外层,并在外层快速蒸发。 [0003] Wet unidirectional fabric by affinity inner and outer layers, different hydrophobicity, i.e., the outer fabric and the inner layer most hydrophilic of hydrophobic, small perspiration transmitted from the inner portion to the hydrophilic portion of the hydrophilic outer fabric of and fast evaporation in the outer layer. 大部分疏水性的内层使人体出汗时穿着不沾身,加之织物外层水分快速蒸发带走大量的热量,进而使人体感觉凉爽。 Most of the hydrophobic inner wear sweat when the body does not Zhanshen, coupled with the rapid evaporation of moisture in the outer layer of fabric taken away a lot of heat, and thus make the body feel cool. 吴烨芳等(吴烨芳等,单向导湿织物的开发,纺织学报,2006,27,6)采用平网印制的方式在织物上进行单面整理,使拒水整理剂以一定的图形分布在织物的一侧,并控制整理剂在织物上的渗透深度,使织物的一侧为亲水性,一侧为疏水性,构成亲疏性双侧结构。 Wu et aryl Ye (Ye aryl Wu et al., Unidirectional fabric wet development TEXTILE, 2006,27,6) using flat screen printing manner on one surface finishing fabrics to water repellent finish in a certain pattern distribution side of the fabric, and to control the depth of penetration of the finishing agent on the fabric, the fabric of one side hydrophilic, one side hydrophobic constituting the closeness of bilateral structure. 水或汗液从整理面导向整理后棉织物的热阻和湿阻相对于同规格的棉织物都有所下降,水或汗液从整理面导向织物的另一侧,并能快速扩散、蒸发,使织物内层保持相对干爽。 Water or perspiration same specifications with respect to cotton fabric have declined from the guide surface finishing of cotton fabric and a wet thermal resistance, the other side of the fabric guide water or perspiration from the finishing surface, and can quickly spread, evaporated and the the inner fabric remains relatively dry. 但是,由于采用印花法处理织物,整理方法以及相对面积比的局限性致使其单向导湿性能并不是很理想。 However, since printing method of treating a fabric, and the finishing process limitation which causes the relative area ratio unidirectional wet performance is not very satisfactory.

[0004] 何天虹等(何天虹等,双侧结构吸湿快干纯棉针织物的研制,针织工业,2007,6)采用单面整理技术开发双侧结构吸湿快干纯棉针织物,将拒水整理剂按一定图案印制于纯棉针织物的一面(贴近皮肤,使其具有非连续的疏水性,另一面仍具有良好的吸湿性,形成亲、疏水“双侧”结构的单向导湿织物。该整理方法采用平网印花,不但使织物处理方式复杂化,而且印制过程中会消耗大量的水、增加成本。 [0004] He Tianhong, etc. (He Tianhong other bilateral structure moisture absorbing cotton knitted fabric development, knitting industry, 2007,6) using single-sided finishing technology to develop moisture management knitted cotton bilateral structure, will refuse aqueous finishing agent by a pattern printed on a cotton fabric side (close to the skin, it has a discontinuous hydrophobic, the other side still has good moisture absorption, the pro-form, a hydrophobic "double-sided" configuration of unidirectional wet fabric. the finishing process using flat screen printing, the fabric is not only complicated treatment, and the printing process can consume a lot of water, an increase in cost.

[0005] 专利CN101649558A采用单面给液途径,在织物的正、反两面构造出亲、疏水性质不同的“双侧面结构”,制品的正面全部为具有良好的吸湿性能的亲水面,制品的反面非连续性地分布有具有疏水性结构的疏水区域,亲水性区域占该侧面总面积的20-80%。 [0005] Patent CN101649558A to the use of single fluid pathway, in a pro positive and negative sides of the fabric structure, the hydrophobic nature of the different "double side structure", all of the front article having good hygroscopic properties of a hydrophilic surface, the article opposite discontinuously distributed hydrophobic regions of the structure having a hydrophobic, hydrophilic regions comprise 20-80% of the total area of ​​the side surface. 由于所使用的单面给液途径是通过筛网印花实现的,筛网印花包括印花筛网的准备,印花织物的准备等多个步骤,耗费大量的时间、人力、物力,从而增加成本。 Since the liquid to one side of the route is achieved by using screen printing, screen printing preparation comprising a plurality of steps, to prepare printing cloth screen printing, etc., spend a lot of time, manpower, material resources, thereby increasing the cost. [0006] 喷墨印花主要是将喷墨印刷应用到纺织品上的一种印刷方式。 [0006] The ink-jet printing is mainly applied to a printed ink jet printing on textiles embodiment. 自20世纪90年代以来,喷墨印花开始广泛运用到纺织品上。 Since the 1990s, inkjet printers have been widely applied to the textiles. 相对于传统印花来讲,喷墨印花无需制版,批量灵活,在喷印过程中不使用水和色浆,喷印时使用的油墨是由计算机“按需分配”,在整个喷印过程中不产生废水,噪音低,是真正的清洁生产工艺。 With respect to the traditional printing is concerned, no plate ink-jet printing, flexible bulk, water is not used in the printing process and the paste, the ink used for printing is not computer "needs" throughout the printing process produce waste water, low-noise, truly clean production techniques.

[0007] 纺织品的数码喷墨印花,优越性显著,传统纺织品的生产经营观念发生了很大的变化,传统纺织品生产造成的污染问题得到了很好的解决。 Digital inkjet printing [0007] textiles, significant advantages, traditional textile production and management concept has undergone great changes, the traditional textile production pollution problem has been solved. 人们把现代高新科技和传统的纺织工业完美地结合到了一起,使纺织工业实现了从劳动力密集型产业向技术密集型产业的转变,极大地促进纺织产业的升级改良,提高了纺织工业的整体技术水平。 People of modern high-tech and traditional textile industry perfect combination together, the textile industry to achieve a shift from labor-intensive industries to technology-intensive industries, greatly facilitate the improvement of the textile industry to upgrade and improve the overall technical textile industry Level.

发明内容 SUMMARY

[0008] 本发明所要解决的技术问题是提供一种单向导湿的纯棉服装面料的低碳制备方法,该发明工艺简单,能够节约大量的水、能源等多种资源,同时无污水排放,有利于保护环境;该发明整理的织物单向导湿性能优异,具有广阔的市场应用前景和良好的社会效益。 [0008] The present invention solves the technical problem is to provide a unidirectional wet cotton fabric production method of low-carbon, the process is simple, can save a lot of water, a variety of resources and energy, while no sewage, help protect the environment; excellent finishing of the invention is a unidirectional fabric wet performance, and has broad market prospect and good social benefits.

[0009] 本发明的一种单向导湿的纯棉服装面料的低碳制备方法,包括: [0009] The method for preparing a one lower guide of the present invention a wet cotton fabric, comprising:

[0010] (I)对织物进行预处理; [0010] (I) pretreating the fabric;

[0011] (2 )配制墨水,其中按质量百分比,墨水组分为:2-10%拒水整理剂、15-40%表面活性剂、0.1-0.5%杀菌剂、0.1-0.5%pH值缓冲剂及49-82.8%去离子水; [0011] (2) Preparation of ink, wherein the percentage by mass, the ink component: water repellent finishing agent, 2-10%, 15-40% surfactant, bactericides 0.1-0.5%, 0.1-0.5%, the pH value of the buffer agents 49-82.8% deionized water;

[0012] (3)采用数码喷墨印花技术,将图案喷印在织物上,使织物表面形成一层有限的、非连续性的疏水性表层结构,然后预烘,焙烘,即得单行导湿的纯棉服装面料。 [0012] (3) the use of digital ink-jet printing technology, printing a pattern on the fabric, the fabric surface layer is limited, discontinuity of a hydrophobic surface structure, and then prebaking, baking, i.e., to obtain a single line guide wet cotton fabric.

[0013] 所述步骤(I)中织物为纯棉机织物、针织物或无纺布。 [0013] The step (I) the fabric is a cotton woven fabric, a knitted fabric or a nonwoven fabric.

[0014] 所述步骤(I)中预处理为退煮漂、染色、烧毛处理中的一种或几种。 [0014] The step (I) is pretreated scouring and bleaching, dyeing one or more singeing treatment.

[0015] 所述预处理用海藻酸钠和/或聚丙烯酸类合成增稠剂。 [0015] The pretreatment with sodium alginate, and / or polyacrylic synthetic thickener.

[0016] 所述步骤(2)中拒水整理剂为含氟有机高分子、有机硅树脂或反应性基团的长链烷基化合物的溶液或水性乳液中的一种。 [0016] The step (2) is a fluorine-containing water repellent finishing agent is an organic polymer, aqueous emulsion of a solution or a long-chain alkyl compound is a silicone resin or a reactive group in.

[0017] 所述步骤(2)中表面活性剂为丙三醇、二甘醇、乙二醇、一缩二乙二醇中的一种或几种。 [0017] The step (2) the surfactant glycerol, diethylene glycol, ethylene glycol, one or more of diethylene glycol.

[0018] 所述步骤(2)中杀菌剂为CIT/MIT-14 (上海德兼化工有限公司)。 [0018] The fungicide step (2) for CIT / MIT-14 (Hyde and Chemical Co., Ltd.).

[0019] 所述步骤(2)中pH值缓冲剂为2-羟基乙胺。 [0019] The step (2) in pH buffering of 2-hydroxyethylamine.

[0020] 所述步骤(3)中图案的亲水面积为20-40%,疏水面积为60-80%。 [0020] The step (3) in the area of ​​the hydrophilic pattern is 20-40%, 60-80% hydrophobic area.

[0021] 所述步骤(3)中预烘温度为80-90°C,预烘时间为3-5min ;焙烘温度为130_150°C,焙烘时间为2-4min。 [0021] The temperature of the prebaking step (3) is 80-90 ° C, the pre-drying time was 3-5min; baking temperature 130_150 ° C, baking time was 2-4min.

[0022] 将油墨中的染料替换成疏水性化学物质,利用数码喷墨印花技术,以一定的图案喷印在织物上,使织物表面形成一层有限的、非连续性的疏水性表层结构,预烘,焙烘,制得具有单向导湿的纯棉服装面料。 [0022] Alternatively the dye ink into the hydrophobic chemical substances, the use of digital ink-jet printing technology, printing in a pattern on the fabric, the fabric surface layer is limited, discontinuity of a hydrophobic surface structure, prebaking, baking, prepared with a single-wet cotton fabric.

[0023] 有益.效果 [0023] beneficial. Effect

[0024] (I)本发明工艺简单,并且能够节约大量的水、能源等多种资源,同时无污水排放,有利于保护环境; [0024] (I) of the present invention, the process is simple, and can save a lot of water, a variety of resources and energy, while no sewage, to protect the environment;

[0025] (2)本发明整理的织物单向导湿性能优异,具有广阔的市场应用前景和良好的社会效益。 [0025] (2) of the present invention is excellent in fabric finishing unidirectional wet performance, broad market prospects and social benefits. 附图说明 BRIEF DESCRIPTION

[0026] 图1为实施例1、2中采用的喷印图案; [0026] FIG. 1 is a printing pattern employed in Examples 1 and 2 embodiments;

[0027] 图2为实施例3中采用的喷印图案。 [0027] FIG. 2 is a print pattern used in Example 3 embodiment.

具体实施方式 Detailed ways

[0028] 下面结合具体实施例,进一步阐述本发明。 [0028] The following embodiments with reference to specific embodiments, further illustrate the present invention. 应理解,这些实施例仅用于说明本发明而不用于限制本发明的范围。 It should be understood that these embodiments are illustrative only and the present invention is not intended to limit the scope of the invention. 此外应理解,在阅读了本发明讲授的内容之后,本领域技术人员可以对本发明作各种改动或修改,这些等价形式同样落于本申请所附权利要求书所限定的范围。 Furthermore, it should be understood that, after reading the teachings of the present invention, those skilled in the art that various changes or modifications may be made to the present invention, and these equivalents also fall within the scope of the appended claims of the present application as defined.

[0029] 实施例1 [0029] Example 1

[0030] 对织物进行退煮漂处理; [0030] The fabric scouring and bleaching process;

[0031] 按照重量百分比,“墨水”组成:含氟有机高分子2% ;丙三醇;10% ;二甘醇10% ;CIT/MIT14为0.5% ;2-羟基乙胺0.3% ;其余为去离子水。 [0031] The percentage by weight, "ink" consists of: a fluorine-containing organic polymer of 2%; glycerol; 10%; Diethylene glycol 10%; CIT / MIT14 of 0.5%; 0.3% 2-hydroxyethylamine; remainder Deionized water.

[0032] 采用数码喷墨印花方式,按照附图1将上述“墨水”喷印到纯棉织物上,80°C预烘5分钟,150°C焙烘2min。 [0032] The digital inkjet printing methods, the above-described 1 "ink" to print on cotton fabric in accordance with the drawings, 80 ° C pre-bake 5 minutes, 150 ° C baking 2min.

[0033] 采用AATCC TM195—2009《织物的液态水分管理特性》测试整理后导湿快干性能,在同一样品不同位置测量3次,取平均值。 [0033] The AATCC TM195-2009 "liquid water management properties of the fabric" fast properties test finishing, measured three times at different locations of the same sample were averaged. 测得的单向传输指数达242.0589。 The measured index of unidirectional transmission 242.0589.

[0034] 实施例2 [0034] Example 2

[0035] 对织物进行退煮漂及烧毛处理; [0035] Bleaching of fabric and singeing treatment;

[0036] 按照重量百分比,“墨水”组成:有机硅树脂5% ;丙三醇;12% ;二甘醇10% ;CIT/MIT-14为0.4% ;2-羟基乙胺0.4% ;其余为去离子水。 [0036] The percentage by weight, "ink" composition: 5% of a silicone resin; glycerol; 12%; Diethylene glycol 10%; CIT / MIT-14 0.4%; 0.4% 2-hydroxyethylamine; remainder Deionized water.

[0037] 采用数码喷墨印花方式,按照附图1将上述“墨水”喷印到纯棉织物上,85°C预烘4分钟,140°C焙烘3min。 [0037] The digital inkjet printing methods, the above-described 1 "ink" to print on cotton fabric in accordance with the drawings, 85 ° C pre-baked four minutes, 140 ° C baking 3min.

[0038] 采用AATCC TM195—2009《织物的液态水分管理特性》测试整理后导湿快干性能,在同一样品不同位置测量3次,取平均值。 [0038] The AATCC TM195-2009 "liquid water management properties of the fabric" fast properties test finishing, measured three times at different locations of the same sample were averaged. 测得的单向传输指数达172.2227。 The measured index of unidirectional transmission 172.2227.

[0039] 实施例3 [0039] Example 3

[0040] 对织物进行染色处理; [0040] The fabric was dyed;

[0041] 按照重量百分比,“墨水”组成:反应性基团的长链烷基化合物8% ;丙三醇;15% ; —缩二乙二醇11% ;CIT/MIT-14为0.4% ;2_羟基乙胺0.5% ;其余为去离子水。 [0041] The percentage by weight, "ink" consists of: a long-chain alkyl compound having a reactive group of 8%; glycerol; 15%; - Diethylene glycol 11%; CIT / MIT-14 0.4%; 2_ hydroxyethylamine 0.5%; the rest is deionized water.

[0042] 采用数码喷墨印花方式,按照附图2将上述“墨水”喷印到纯棉织物上,90°C预烘3分钟,130°C焙烘4min。 [0042] The digital inkjet printing methods, the above-described 2 "ink" to print on cotton fabric in accordance with the drawings, 90 ° C prebaking 3 minutes, 130 ° C baked 4min.

[0043] 采用AATCC TM195—2009《织物的液态水分管理特性》测试整理后导湿快干性能,在同一样品不同位置测量3次,取平均值。 [0043] The AATCC TM195-2009 "liquid water management properties of the fabric" fast properties test finishing, measured three times at different locations of the same sample were averaged. 测得的单向传输指数达135.3099。 The measured index of unidirectional transmission 135.3099.

Claims (10)

1.一种单向导湿的纯棉服装面料的低碳制备方法,包括: (I)对织物进行预处理; (2 )配制墨水,其中按质量百分比,墨水组分为:2-10%拒水整理剂、15-40%表面活性剂、0.1-0.5%杀菌剂、0.1-0.5%pH值缓冲剂及49-82.8%去离子水; (3)采用数码喷墨印花技术,将图案喷印在织物上,然后预烘,焙烘,即得单行导湿的纯棉服装面料。 1. A method for preparing low carbon unidirectional wet cotton fabric, comprising: (the I) the fabric was pretreated; (2) an ink formulation, wherein the percentage by mass, the ink component: 2 to 10% repellency finishing agent water, 15-40% surfactant, bactericides 0.1-0.5%, 0.1-0.5% and the pH buffering agent 49-82.8% deionized water; (3) the use of digital ink-jet printing technology, printing a pattern on the fabric, and then prebaking, baking, i.e., to obtain a single row of cotton wicking fabric.
2.根据权利要求1所述的一种单向导湿的纯棉服装面料的低碳制备方法,其特征在于:所述步骤(I)中织物为纯棉机织物、针织物或无纺布。 The production method of claim 1. A low-carbon unidirectional wet cotton fabric as claimed in claim, wherein: said step (I) the fabric is a cotton woven fabric, a knitted fabric or a nonwoven fabric.
3.根据权利要求1所述的一种单向导湿的纯棉服装面料的低碳制备方法,其特征在于:所述步骤(I)中预处理为退煮漂、染色、烧毛处理中的一种或几种。 The method for preparing a one lower guide wet cotton fabric according to claim 1, wherein: said step (I) is pretreated scouring and bleaching, dyeing, singeing treatment one or several.
4.根据权利要求3所述的一种单向导湿的纯棉服装面料的低碳制备方法,其特征在于:所述预处理用海藻酸钠和/或聚丙烯酸类合成增稠剂。 3, according to the method of preparing a single-guide lower wet cotton fabric as claimed in claim, wherein: the pretreatment with sodium alginate, and / or polyacrylic synthetic thickener.
5.根据权利要求1所述的一种单向导湿的纯棉服装面料的低碳制备方法,其特征在于:所述步骤(2)中拒水整理剂为含氟有机高分子、有机硅树脂或反应性基团的长链烷基化合物的溶液或水性乳液中的一种。 The production method of claim 1. A low-carbon unidirectional wet cotton fabric as claimed in claim, wherein: said step (2) is a fluorine-containing water repellent finishing agent is an organic polymer, silicone resin or a solution or aqueous emulsion of long-chain alkyl compound of a reactive group of one.
6.根据权利要求1所述的一种单向导湿的纯棉服装面料的低碳制备方法,其特征在于:所述步骤(2)中表面活性剂为丙三醇、二甘醇、乙二醇、一缩二乙二醇中的一种或几种。 The production method of claim 1. A low-carbon unidirectional wet cotton fabric as claimed in claim, wherein: said step (2) the surfactant glycerol, diethylene glycol, ethylene alcohol, diethylene glycol, one or several.
7.根据权利要求1所述的一种单向导湿的纯棉服装面料的低碳制备方法,其特征在于:所述步骤(2)中杀菌剂为CIT/MIT-14。 The production method of claim 1. A low-carbon unidirectional wet cotton fabric as claimed in claim, wherein: fungicides CIT / MIT-14 (2) in the step.
8.根据权利要求1所述的一种单向导湿的纯棉服装面料的低碳制备方法,其特征在于:所述步骤(2)中pH值缓冲剂为2-羟基乙胺。 The production method of claim 1. A low-carbon unidirectional wet cotton fabric as claimed in claim, wherein: said pH of step (2) in the buffer is 2-hydroxyethylamine.
9.根据权利要求1所述的一种单向导湿的纯棉服装面料的低碳制备方法,其特征在于:所述步骤(3)中图案的亲水面积为20-40%,疏水面积为60-80%。 9. The production method of claim 1. A low-carbon unidirectional wet cotton fabric according to claim, wherein: said step (3) in the area of ​​the hydrophilic pattern is 20-40%, the hydrophobic area 60-80%.
10.根据权利要求1所述的一种单向导湿的纯棉服装面料的低碳制备方法,其特征在于:所述步骤(3)中预烘温度为80-90°C,预烘时间为3-5min ;焙烘温度为130_150°C,焙烘时间为2_4min。 10. According to one method of preparing unidirectional lower wet cotton fabric according to claim 1, characterized in that: said step (3) in the prebaking temperature is 80-90 ° C, prebaking time 3-5min; baking temperature 130_150 ° C, baking time 2_4min.
CN 201310306767 2013-07-19 2013-07-19 Low-carbon preparation method of one-way-moisture-conduction pure cotton clothing fabric CN103437176A (en)

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