CN104403836A - Environment-friendly cleaning agent for indicating pesticide residue on surface of fruit and preparation method of environment-friendly cleaning agent - Google Patents

Environment-friendly cleaning agent for indicating pesticide residue on surface of fruit and preparation method of environment-friendly cleaning agent Download PDF

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Publication number
CN104403836A
CN104403836A CN201410664143.2A CN201410664143A CN104403836A CN 104403836 A CN104403836 A CN 104403836A CN 201410664143 A CN201410664143 A CN 201410664143A CN 104403836 A CN104403836 A CN 104403836A
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China
Prior art keywords
parts
pesticide
cleaner
sodium
environmental protection
Prior art date
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Application number
CN201410664143.2A
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Chinese (zh)
Inventor
凌云
夏戊君
陆赛君
金可心
陈亮
程胜
凌天阳
陆鼎
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SUZHOU YOUJUN ENVIRONMENTAL SCIENCE AND TECHNOLOGY Co Ltd
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SUZHOU YOUJUN ENVIRONMENTAL SCIENCE AND TECHNOLOGY Co Ltd
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Priority to CN201410664143.2A priority Critical patent/CN104403836A/en
Publication of CN104403836A publication Critical patent/CN104403836A/en
Withdrawn legal-status Critical Current

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Abstract

The invention relates to an environment-friendly cleaning agent for indicating pesticide residue on the surface of fruit and a preparation method of the environment-friendly cleaning agent, and belongs to the field of daily chemicals. The environment-friendly cleaning agent comprises the following raw materials in parts by mass: 22 to 32 parts of terpilenol, 15 to 25 parts of shell powder, 6 to 18 parts of sodium carbonate, 5 to 9 parts of sodium citrate, 15 to 22 parts of sodium chloride, 1 to 3 parts of acetic acid, 10 to 15 parts of paeonol, 6 to 12 parts of calcium hydrophosphate and 50 to 70 parts of water. The environment-friendly cleaning agent is very high in cleaning rate, and can remove pesticide residue on the surface of the fruit completely. Moreover, during use, the environment-friendly cleaning agent can become yellow sensitively to indicate the pesticide quantity in the water with which the fruit is washed.

Description

Cleaner in environmental protection of instruction fruit surface remains of pesticide and preparation method thereof
Technical field
The invention belongs to household chemicals field, be specifically related to a kind ofly indicate cleaner in environmental protection of fruit surface remains of pesticide and preparation method thereof.
 
Background technology
Nowadays, in order to prevent fruit generation insect pest, in the process of fruit maturation, all can spray a certain amount of agricultural chemicals to prevent insect pest, thus improve output.The agricultural chemicals removing fruit surface residual is particularly important, if the agricultural chemicals cleaning of its remained on surface is not thorough, can endanger the health of people.In order to thoroughly remove the residual agricultural chemicals of fruit surface further, people have also found out the method for various cleaning fruit.As first used clean water fruit, after water is outwelled, be wrapped in fruit surface with flour, rub fruit with hand, treat that flour fully contacts with fruit surface, then rinse well with clear water.But regardless of which kind of purging method, the agricultural chemicals that fruit surface remains thoroughly cleans up not yet.
Existing many reports about melon and fruit clean-out system at present, but these clean-out systems are not good to the clearance rate of agricultural chemicals, main removing be the dirt of fruit surface, the residual agricultural chemicals of fruit surface can only be removed by small portion, in addition these clean-out systems are after cleaning fruit, also difficult removing is clean for himself, also has part and remains in fruit surface.
Therefore how to overcome the deficiencies in the prior art and become existing field technical barrier urgently to be resolved hurrily.
 
Summary of the invention
The object of the invention is to solve the deficiencies in the prior art, providing a kind of and indicating cleaner in environmental protection of fruit surface remains of pesticide and preparation method thereof, this sanitising agent safety non-toxic, the pesticides removal residual to fruit surface is thorough.
The technical solution used in the present invention is as follows:
The cleaner in environmental protection of instruction fruit surface remains of pesticide, comprises the following raw material according to mass fraction meter: Terpineol 350 22-32 part, oyster shell whiting 15-25 part, sodium carbonate 6-18 part, Trisodium Citrate 5-9 part, sodium-chlor 15-22 part, acetic acid 1-3 part, Paeonol 10-15 part, secondary calcium phosphate 6-12 part, water 50-70 part.
The cleaner in environmental protection of described instruction fruit surface remains of pesticide, comprises the following raw material according to mass fraction meter: Terpineol 350 24-30 part, oyster shell whiting 17-23 part, sodium carbonate 8-17 part, Trisodium Citrate 6-8 part, sodium-chlor 17-20 part, acetic acid 1-2 part, Paeonol 11-14 part, secondary calcium phosphate 8-10 part, water 55-78 part.
The cleaner in environmental protection of described instruction fruit surface remains of pesticide, comprises the following raw material according to mass fraction meter: Terpineol 350 26-28 part, oyster shell whiting 18-22 part, sodium carbonate 10-16 part, Trisodium Citrate 6-7 part, sodium-chlor 18-19 part, acetic acid 1-2 part, Paeonol 12-13 part, secondary calcium phosphate 8-9 part, water 60-70 part.
The cleaner in environmental protection of described instruction fruit surface remains of pesticide, comprises the following raw material according to mass fraction meter: Terpineol 350 24 parts, oyster shell whiting 17 parts, 8 parts, sodium carbonate, Trisodium Citrate 6 parts, 17 parts, sodium-chlor, acetic acid 1 part, Paeonol 11 parts, secondary calcium phosphate 8 parts, 55 parts, water.
The cleaner in environmental protection of described instruction fruit surface remains of pesticide, comprises the following raw material according to mass fraction meter: Terpineol 350 30 parts, oyster shell whiting 23 parts, 17 parts, sodium carbonate, Trisodium Citrate 8 parts, 20 parts, sodium-chlor, acetic acid 2 parts, Paeonol 14 parts, secondary calcium phosphate 10 parts, 78 parts, water.
The cleaner in environmental protection of described instruction fruit surface remains of pesticide, comprises the following raw material according to mass fraction meter: Terpineol 350 26 parts, oyster shell whiting 18 parts, 10 parts, sodium carbonate, Trisodium Citrate 6 parts, 18 parts, sodium-chlor, acetic acid 1 part, Paeonol 12 parts, secondary calcium phosphate 8 parts, 60 parts, water.
The cleaner in environmental protection of described instruction fruit surface remains of pesticide, comprises the following raw material according to mass fraction meter: Terpineol 350 28 parts, oyster shell whiting 22 parts, 16 parts, sodium carbonate, Trisodium Citrate 7 parts, 19 parts, sodium-chlor, acetic acid 2 parts, Paeonol 13 parts, secondary calcium phosphate 9 parts, 70 parts, water.
The preparation method of the cleaner in environmental protection of described instruction fruit surface remains of pesticide, comprise the steps: according to quality proportioning, Terpineol 350, oyster shell whiting, sodium carbonate, Trisodium Citrate, sodium-chlor, acetic acid, Paeonol, secondary calcium phosphate and water are mixed, be warming up to 50-60 DEG C, stir 30-40min, rear naturally cooling, obtains the cleaner in environmental protection of described instruction fruit surface remains of pesticide.
 
compared with prior art, its beneficial effect is in the present invention:
Clean-out system of the present invention has high clearance rate to the fruit that fruit surface remains, and thoroughly can remove the agricultural chemicals that fruit surface is residual, clean-out system of the present invention in use in addition, and displaing yellow that can be sensitive is indicate the pesticide volume cleaned after fruit in washing water; Cleaning agent formula of the present invention is excellent, and safety and environmental protection, can not remain in fruit surface and cause secondary pollution to fruit; Preparation method of the present invention is simple, easy and simple to handle, can promote the use of on a large scale.
 
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, the raw material used in the present invention unless otherwise noted, all by commercial acquisition.
 
embodiment 1
The cleaner in environmental protection of instruction fruit surface remains of pesticide, comprises the following raw material according to mass fraction meter: Terpineol 350 22 parts, oyster shell whiting 15 parts, 6 parts, sodium carbonate, Trisodium Citrate 5 parts, 15 parts, sodium-chlor, acetic acid 1 part, Paeonol 10 parts, secondary calcium phosphate 6 parts, 50 parts, water.
The preparation method of the cleaner in environmental protection of described instruction fruit surface remains of pesticide, comprise the steps: according to quality proportioning, Terpineol 350, oyster shell whiting, sodium carbonate, Trisodium Citrate, sodium-chlor, acetic acid, Paeonol, secondary calcium phosphate and water are mixed, be warming up to 50 DEG C, stir 40min, rear naturally cooling, obtains the cleaner in environmental protection of described instruction fruit surface remains of pesticide.
 
embodiment 2
The cleaner in environmental protection of instruction fruit surface remains of pesticide, comprises the following raw material according to mass fraction meter: Terpineol 350 32 parts, oyster shell whiting 25 parts, 18 parts, sodium carbonate, Trisodium Citrate 9 parts, 22 parts, sodium-chlor, acetic acid 3 parts, Paeonol 15 parts, secondary calcium phosphate 12 parts, 70 parts, water.
The preparation method of the cleaner in environmental protection of described instruction fruit surface remains of pesticide, comprise the steps: according to quality proportioning, Terpineol 350, oyster shell whiting, sodium carbonate, Trisodium Citrate, sodium-chlor, acetic acid, Paeonol, secondary calcium phosphate and water are mixed, be warming up to 60 DEG C, stir 30min, rear naturally cooling, obtains the cleaner in environmental protection of described instruction fruit surface remains of pesticide.
 
embodiment 3
The cleaner in environmental protection of instruction fruit surface remains of pesticide, comprises the following raw material according to mass fraction meter: Terpineol 350 24 parts, oyster shell whiting 17 parts, 8 parts, sodium carbonate, Trisodium Citrate 6 parts, 17 parts, sodium-chlor, acetic acid 1 part, Paeonol 11 parts, secondary calcium phosphate 8 parts, 55 parts, water.
The preparation method of the cleaner in environmental protection of described instruction fruit surface remains of pesticide, comprise the steps: according to quality proportioning, Terpineol 350, oyster shell whiting, sodium carbonate, Trisodium Citrate, sodium-chlor, acetic acid, Paeonol, secondary calcium phosphate and water are mixed, be warming up to 55 DEG C, stir 35min, rear naturally cooling, obtains the cleaner in environmental protection of described instruction fruit surface remains of pesticide.
 
embodiment 4
The cleaner in environmental protection of instruction fruit surface remains of pesticide, comprises the following raw material according to mass fraction meter: Terpineol 350 30 parts, oyster shell whiting 23 parts, 17 parts, sodium carbonate, Trisodium Citrate 8 parts, 20 parts, sodium-chlor, acetic acid 2 parts, Paeonol 14 parts, secondary calcium phosphate 10 parts, 78 parts, water.
The preparation method of the cleaner in environmental protection of described instruction fruit surface remains of pesticide, comprise the steps: according to quality proportioning, Terpineol 350, oyster shell whiting, sodium carbonate, Trisodium Citrate, sodium-chlor, acetic acid, Paeonol, secondary calcium phosphate and water are mixed, be warming up to 52 DEG C, stir 32min, rear naturally cooling, obtains the cleaner in environmental protection of described instruction fruit surface remains of pesticide.
 
embodiment 5
The cleaner in environmental protection of instruction fruit surface remains of pesticide, comprises the following raw material according to mass fraction meter: Terpineol 350 26 parts, oyster shell whiting 18 parts, 10 parts, sodium carbonate, Trisodium Citrate 6 parts, 18 parts, sodium-chlor, acetic acid 1 part, Paeonol 12 parts, secondary calcium phosphate 8 parts, 60 parts, water.
The preparation method of the cleaner in environmental protection of described instruction fruit surface remains of pesticide, comprise the steps: according to quality proportioning, Terpineol 350, oyster shell whiting, sodium carbonate, Trisodium Citrate, sodium-chlor, acetic acid, Paeonol, secondary calcium phosphate and water are mixed, be warming up to 54 DEG C, stir 34min, rear naturally cooling, obtains the cleaner in environmental protection of described instruction fruit surface remains of pesticide.
 
embodiment 6
The cleaner in environmental protection of instruction fruit surface remains of pesticide, comprises the following raw material according to mass fraction meter: Terpineol 350 28 parts, oyster shell whiting 22 parts, 16 parts, sodium carbonate, Trisodium Citrate 7 parts, 19 parts, sodium-chlor, acetic acid 2 parts, Paeonol 13 parts, secondary calcium phosphate 9 parts, 70 parts, water.
The preparation method of the cleaner in environmental protection of described instruction fruit surface remains of pesticide, comprise the steps: according to quality proportioning, Terpineol 350, oyster shell whiting, sodium carbonate, Trisodium Citrate, sodium-chlor, acetic acid, Paeonol, secondary calcium phosphate and water are mixed, be warming up to 56 DEG C, stir 36min, rear naturally cooling, obtains the cleaner in environmental protection of described instruction fruit surface remains of pesticide.
 
reference examples 1
The cleaner in environmental protection of instruction fruit surface remains of pesticide, comprises the following raw material according to mass fraction meter: Terpineol 350 24 parts, 8 parts, sodium carbonate, Trisodium Citrate 6 parts, 17 parts, sodium-chlor, acetic acid 1 part, Paeonol 11 parts, secondary calcium phosphate 8 parts, 55 parts, water.
The preparation method of the cleaner in environmental protection of described instruction fruit surface remains of pesticide, comprise the steps: according to quality proportioning, Terpineol 350, sodium carbonate, Trisodium Citrate, sodium-chlor, acetic acid, Paeonol, secondary calcium phosphate and water are mixed, be warming up to 55 DEG C, stir 35min, rear naturally cooling, obtains the cleaner in environmental protection of described instruction fruit surface remains of pesticide.
 
reference examples 2
The cleaner in environmental protection of instruction fruit surface remains of pesticide, comprises the following raw material according to mass fraction meter: Terpineol 350 24 parts, oyster shell whiting 17 parts, 8 parts, sodium carbonate, 17 parts, sodium-chlor, acetic acid 1 part, Paeonol 11 parts, secondary calcium phosphate 8 parts, 55 parts, water.
The preparation method of the cleaner in environmental protection of described instruction fruit surface remains of pesticide, comprise the steps: according to quality proportioning, Terpineol 350, oyster shell whiting, sodium carbonate, sodium-chlor, acetic acid, Paeonol, secondary calcium phosphate and water are mixed, be warming up to 55 DEG C, stir 35min, rear naturally cooling, obtains the cleaner in environmental protection of described instruction fruit surface remains of pesticide.
 
performance test
The test embodiment of the present invention 1 to 6 and reference examples 1 to 2 products obtained therefrom, test result sees the following form 1.
Table 1 product performance test data
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Reference examples 1 Reference examples 2
Fruit surface dirt removal rate, % 98 99 100 98 99 98 52 48
Remains of pesticide clearance rate, % 100 100 100 100 100 100 30 35
At fruit surface residual rate, % 0 0 0 0 0 0 30 40
The embodiment of the present invention 1 to 6 gained finished product all has excellent performance, and wherein, embodiment 3 can be considered most preferred embodiment.

Claims (8)

1. indicate the cleaner in environmental protection of fruit surface remains of pesticide, it is characterized in that, comprise the following raw material according to mass fraction meter: Terpineol 350 22-32 part, oyster shell whiting 15-25 part, sodium carbonate 6-18 part, Trisodium Citrate 5-9 part, sodium-chlor 15-22 part, acetic acid 1-3 part, Paeonol 10-15 part, secondary calcium phosphate 6-12 part, water 50-70 part.
2. the cleaner in environmental protection of the instruction fruit surface remains of pesticide according to claims 1, it is characterized in that, comprise the following raw material according to mass fraction meter: Terpineol 350 24-30 part, oyster shell whiting 17-23 part, sodium carbonate 8-17 part, Trisodium Citrate 6-8 part, sodium-chlor 17-20 part, acetic acid 1-2 part, Paeonol 11-14 part, secondary calcium phosphate 8-10 part, water 55-78 part.
3. the cleaner in environmental protection of the instruction fruit surface remains of pesticide according to claims 1, it is characterized in that, comprise the following raw material according to mass fraction meter: Terpineol 350 26-28 part, oyster shell whiting 18-22 part, sodium carbonate 10-16 part, Trisodium Citrate 6-7 part, sodium-chlor 18-19 part, acetic acid 1-2 part, Paeonol 12-13 part, secondary calcium phosphate 8-9 part, water 60-70 part.
4. the cleaner in environmental protection of the instruction fruit surface remains of pesticide according to claims 1, it is characterized in that, comprise the following raw material according to mass fraction meter: Terpineol 350 24 parts, oyster shell whiting 17 parts, 8 parts, sodium carbonate, Trisodium Citrate 6 parts, 17 parts, sodium-chlor, acetic acid 1 part, Paeonol 11 parts, secondary calcium phosphate 8 parts, 55 parts, water.
5. the cleaner in environmental protection of the instruction fruit surface remains of pesticide according to claims 1, it is characterized in that, comprise the following raw material according to mass fraction meter: Terpineol 350 30 parts, oyster shell whiting 23 parts, 17 parts, sodium carbonate, Trisodium Citrate 8 parts, 20 parts, sodium-chlor, acetic acid 2 parts, Paeonol 14 parts, secondary calcium phosphate 10 parts, 78 parts, water.
6. the cleaner in environmental protection of the instruction fruit surface remains of pesticide according to claims 1, it is characterized in that, comprise the following raw material according to mass fraction meter: Terpineol 350 26 parts, oyster shell whiting 18 parts, 10 parts, sodium carbonate, Trisodium Citrate 6 parts, 18 parts, sodium-chlor, acetic acid 1 part, Paeonol 12 parts, secondary calcium phosphate 8 parts, 60 parts, water.
7. the cleaner in environmental protection of the instruction fruit surface remains of pesticide according to claims 1, it is characterized in that, comprise the following raw material according to mass fraction meter: Terpineol 350 28 parts, oyster shell whiting 22 parts, 16 parts, sodium carbonate, Trisodium Citrate 7 parts, 19 parts, sodium-chlor, acetic acid 2 parts, Paeonol 13 parts, secondary calcium phosphate 9 parts, 70 parts, water.
8. the preparation method of the cleaner in environmental protection of the instruction fruit surface remains of pesticide described in claims 1, it is characterized in that, comprise the steps: according to quality proportioning, Terpineol 350, oyster shell whiting, sodium carbonate, Trisodium Citrate, sodium-chlor, acetic acid, Paeonol, secondary calcium phosphate and water are mixed, be warming up to 50-60 DEG C, stir 30-40min, rear naturally cooling, obtains the cleaner in environmental protection of described instruction fruit surface remains of pesticide.
CN201410664143.2A 2014-11-19 2014-11-19 Environment-friendly cleaning agent for indicating pesticide residue on surface of fruit and preparation method of environment-friendly cleaning agent Withdrawn CN104403836A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105695133A (en) * 2016-02-03 2016-06-22 朱仕龙 Disinfectant cleaning agent for melons and fruits and production process thereof
CN107090371A (en) * 2017-06-19 2017-08-25 浩宇康宁健康科技(湖北)有限公司 Vegetables and fruits cleaning agent and its preparation method and application
CN114794158A (en) * 2022-05-24 2022-07-29 武汉新华扬生物股份有限公司 Composition for preventing germs and removing pesticide residues of tea leaves and preparation method and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005281657A (en) * 2004-03-29 2005-10-13 Shinichiro Itoi Detergent for vegetable/fruit
CN102676323A (en) * 2012-06-01 2012-09-19 南通市海顺化工有限公司 Natural fragrant detergent
CN103122291A (en) * 2011-11-21 2013-05-29 天津市浩宇助剂有限公司 Detergent for cleaning pesticide on fruits and vegetables
CN103740505A (en) * 2013-12-16 2014-04-23 芜湖欣荣管业科技有限公司 Environment-friendly fruit surface cleaning agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005281657A (en) * 2004-03-29 2005-10-13 Shinichiro Itoi Detergent for vegetable/fruit
CN103122291A (en) * 2011-11-21 2013-05-29 天津市浩宇助剂有限公司 Detergent for cleaning pesticide on fruits and vegetables
CN102676323A (en) * 2012-06-01 2012-09-19 南通市海顺化工有限公司 Natural fragrant detergent
CN103740505A (en) * 2013-12-16 2014-04-23 芜湖欣荣管业科技有限公司 Environment-friendly fruit surface cleaning agent

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105695133A (en) * 2016-02-03 2016-06-22 朱仕龙 Disinfectant cleaning agent for melons and fruits and production process thereof
CN105695133B (en) * 2016-02-03 2018-12-25 江苏朸健生命科技发展有限公司 A kind of disinfection cleaning agent and its production technology for melon and fruit
CN107090371A (en) * 2017-06-19 2017-08-25 浩宇康宁健康科技(湖北)有限公司 Vegetables and fruits cleaning agent and its preparation method and application
CN114794158A (en) * 2022-05-24 2022-07-29 武汉新华扬生物股份有限公司 Composition for preventing germs and removing pesticide residues of tea leaves and preparation method and application thereof

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Application publication date: 20150311