CN104403318A - Modified silicone rubber cable material with high flame retardance and high wear resistance - Google Patents
Modified silicone rubber cable material with high flame retardance and high wear resistance Download PDFInfo
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Abstract
The invention discloses a modified silicone rubber cable material with high flame retardance and high wear resistance. The modified silicone rubber cable material is prepared from the following raw materials: silicone rubber, ethylene-propylene-diene monomer rubber, butyl rubber, ethylene-vinyl acetate rubber, polyurethane, modified alumina, nylon 6, 2,2,6,6-tetramethylpiperidinooxy, nanometer calcium carbonate, a carboxylation carbon nanotube, a coupling agent, dicumyl peroxide, modified enzymatic hydrolysis lignin, zinc oxide, stearic acid, ultra-fine aluminum hydroxide, ethyl glycol tetraethyl diphosphate, diethylene glycol tetraethyl diphosphate, a red phosphorus microcapsule, triallyl isocyanurate, acrylic acid, an accelerant, an anti-ageing agent, and a softener. The modified silicone rubber cable material with high flame retardance and high wear resistance disclosed by the invention is good in flame retardance, high in wear resistance, high in mechanical strength, and long in service life.
Description
Technical field
The present invention relates to cable material technical field, particularly relate to a kind of high flame retardant high abrasion modified silicon rubber cable material.
Background technology
Silicon rubber is one of important kind in special synthetic rubber, compared with general organic rubber, silicon rubber has high bond energy and high-flexibility concurrently, there is excellent heat-resisting, weather-proof, ageing resistance and electrical resistance, low compression set, has a wide range of applications in fields such as aerospace, electric, electric wires at present.But, along with improving constantly of industrialized level, the requirement of people to silicon rubber is also more and more higher, has inflammable shortcoming as high molecular silicon rubber, the requirement of society can not be met as its mechanicalness of silicon rubber of cable material, wear resistance and flame retardant resistance, need to carry out modification.
Summary of the invention
The present invention proposes a kind of high flame retardant high abrasion modified silicon rubber cable material, its good flame resistance, wear resistance is high, and physical strength is high, long service life.
The present invention proposes a kind of high flame retardant high abrasion modified silicon rubber cable material, its raw material comprises following component by weight: silicon rubber 50-65 part, terpolymer EP rubber 5-15 part, isoprene-isobutylene rubber 3-8 part, ethylene-vinyl acetate rubber 5-12 part, urethane 3-10 part, modified aluminas 10-23 part, nylon 63-8 part, tetramethyl piperidine oxygen 0.3-2 part, nano-calcium carbonate 10-23 part, carboxylation carbon nanotube 20-35 part, coupling agent 2-3.8 part, dicumyl peroxide 2-3.8 part, modified enzymolysis lignin 5-18 part, zinc oxide 2-3 part, stearic acid 1-1.8 part, ultrafine aluminium hydroxide 5-20 part, ethylene glycol pyrodust 2-6 part, glycol ether pyrodust 1-3.5 part, microencapsulated powder oil 2-10 part, iso-cyanuric acid triallyl ester 0.2-1.3 part, vinylformic acid 1-2.5 part, promotor 1.2-2.8 part, anti-aging agent 2-3.5 part, tenderizer 0.2-1 part.
Preferably, its raw material comprises following component by weight: silicon rubber 55-58 part, terpolymer EP rubber 8-9.3 part, isoprene-isobutylene rubber 6-7.2 part, ethylene-vinyl acetate rubber 10-10.7 part, urethane 8-9.2 part, modified aluminas 17-20 part, nylon 65-5.7 part, tetramethyl piperidine oxygen 1.1-1.5 part, nano-calcium carbonate 18-20 part, carboxylation carbon nanotube 29-31.2 part, coupling agent 2.9-3.2 part, dicumyl peroxide 2.9-3.2 part, modified enzymolysis lignin 9-9.9 part, zinc oxide 2.3-2.8 part, stearic acid 1.3-1.6 part, ultrafine aluminium hydroxide 12-17 part, ethylene glycol pyrodust 3.5-4.2 part, glycol ether pyrodust 1.7-2.4 part, microencapsulated powder oil 6-7.3 part, iso-cyanuric acid triallyl ester 0.8-1.1 part, vinylformic acid 1.9-2.1 part, promotor 2-2.5 part, anti-aging agent 2.7-3.1 part, tenderizer 0.6-0.86 part.
Preferably, its raw material comprises following component by weight: 57 parts, silicon rubber, terpolymer EP rubber 8.5 parts, isoprene-isobutylene rubber 6.5 parts, ethylene-vinyl acetate rubber 10.3 parts, urethane 9 parts, modified aluminas 18 parts, nylon 65.3 parts, tetramethyl piperidine oxygen 1.2 parts, nano-calcium carbonate 19 parts, carboxylation carbon nanotube 30 parts, coupling agent 3 parts, dicumyl peroxide 3 parts, modified enzymolysis lignin 9.5 parts, 2.6 parts, zinc oxide, stearic acid 1.4 parts, ultrafine aluminium hydroxide 13 parts, ethylene glycol pyrodust 4 parts, glycol ether pyrodust 2 parts, microencapsulated powder oil 6.6 parts, iso-cyanuric acid triallyl ester 1 part, 2 parts, vinylformic acid, promotor 2.3 parts, 2.8 parts, anti-aging agent, tenderizer 0.8 part.
Preferably, the properties-correcting agent of described modified aluminas is one or more the combination in hexadecyl trimethoxy silane, γ-aminopropyl triethoxysilane, vinyl three ('beta '-methoxy oxyethyl group) silane.
Preferably, described modified enzymolysis lignin is prepared according to following technique: after 20-40 part enzymolysis xylogen, 20-35 part water and 10-30 part formaldehyde being uniformly mixed by weight, the pH of regulation system is 8-9, be warming up to 62-70 DEG C, add 20-40 part urea, be warming up to 85-90 DEG C, dripping 2-5 part concentration after stirring reaction 2-4h is the hydrochloric acid soln of 1mol/L, obtains described modified enzymolysis lignin through standing, washing, filtration, drying.
Preferably, the fineness of described ultrafine aluminium hydroxide is 9500-9800 order.
Preferably, described promotor is one or more the combination in altax, accelerant CZ, accelerant N A-22, Vulcanization accelerator TMTD, promotor E, vulkacit D BX.
Preferably, described anti-aging agent is one or more the combination in antioxidant 4010NA, antioxidant A W, anti-aging agent RD, aging inhibitor FR.
Preferably, described tenderizer is vegetables oil.
In the present invention, take silicon rubber as rubber major ingredient, and with the addition of terpolymer EP rubber, isoprene-isobutylene rubber, ethylene-vinyl acetate rubber and urethane for sharing glue, major ingredient and shared glue coordinate makes the cable material obtained have high tensile strength, elongation at break and wear resistance, modified aluminas, nylon 6, nano-calcium carbonate, carboxylation carbon nanotube are uniformly dispersed in cable material, performance is worked in coordination with, and further increases intensity and the wear resistance of cable material, modified enzymolysis lignin is good dispersity in rubber, with ultrafine aluminium hydroxide, ethylene glycol pyrodust, glycol ether pyrodust and microencapsulated powder oil coordinate as flame-retardant system, in the process of cable material burning, flame-retardant system can decompose a large amount of gas of generation, form expansion densification and the protective layer of continuous uniform, isolated thermal source plays a protective role, the temperature around thermal source can be reduced simultaneously, play the effect pressing down cigarette and press down combustion, improve tensile strength and the elongation at break of cable material simultaneously, in addition, the ethylene-vinyl acetate rubber added can as additional acid source under acrylic acid assisting, oil-proofness and the thermotolerance of cable material is improved while coordinating with flame-retardant system the flame retardant properties improving cable material.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
In a particular embodiment, high flame retardant high abrasion modified silicon rubber cable material of the present invention, in its raw material, the weight part of silicon rubber can be 50.3, 51, 51.6, 52, 52.4, 53, 53.8, 54, 54.6, 55.3, 56, 56.7, 57.4, 58.6, 59, 59.4, 60, 60.3, 61, 61.3, 62, 62.5, 63, 63.4, 64, 64.7 parts, the weight part of terpolymer EP rubber can be 5.2, 6, 6.3, 7, 7.5, 8.3, 9, 9.4, 10, 10.3, 11, 11.5, 12, 12.6, 13, 13.4, 14, 14.7 parts, the weight part of isoprene-isobutylene rubber can be 3.2, 3.8, 4, 4.2, 4.6, 5, 5.3, 5.8, 6.3, 6.8, 7, 7.5, 7.8 parts, the weight part of ethylene-vinyl acetate rubber can be 5.3, 6, 6.4, 7, 7.5, 8, 8.6, 9, 9.3, 10.5, 11, 11.2, 11.7 parts, the weight part of urethane can be 3.2, 3.7, 4, 4.5, 5, 5.3, 5.8, 6, 6.4, 6.8, 7, 7.5, 8.6, 9.4 parts, the weight part of modified aluminas can be 10.5, 11, 11.6, 12, 12.3, 13, 13.8, 14, 14.6, 15, 15.6, 16, 16.4, 17.5, 18.3, 19, 19.4, 20.6, 21, 21.8, 22, 22.3 parts, the weight part of nylon 6 can be 3.2, 3.6, 4, 4.5, 4.8, 6, 6.4, 6.8, 7, 7.2, 7.7 parts, the weight part of tetramethyl piperidine oxygen can be 0.35, 0.4, 0.46, 0.5, 0.56, 0.6, 0.63, 0.7, 0.74, 0.8, 0.86, 0.9, 0.94, 1.0, 1.05, 1.16, 1.23, 1.3, 1.38, 1.4, 1.45, 1.56, 1.6, 1.68, 1.7, 1.79, 1.8, 1.85, 1.9, 1.93 parts, the weight part of nano-calcium carbonate can be 10.3, 11, 11.5, 12, 12.6, 13, 13.8, 14, 14.6, 15, 15.3, 16, 16.7, 17, 17.5, 18.9, 19.5, 20.3, 21, 21.6, 22, 22.3 parts, the weight part of carboxylation carbon nanotube can be 20.6, 21, 21.5, 22, 22.3, 23, 23.6, 24, 24.5, 25, 25.6, 26, 26.9, 27, 27.5, 28, 28.4, 29.4, 30.6, 31, 31.5, 32, 32.6, 33, 33.8, 34, 34.7 parts, the weight part of coupling agent can be 2.1, 2.26, 2.3, 2.35, 2.4, 2.46, 2.5, 2.6, 2.67, 2.7, 2.78, 2.9, 3.0, 3.05, 3.1, 3.15, 3.2, 3.26, 3.3, 3.34, 3.4, 3.45, 3.5, 3.56, 3.6, 3.67, 3.7, 3.75 parts, the weight part of dicumyl peroxide can be 2.1, 2.2, 2.35, 2.4, 2.56, 2.6, 2.68, 2.8, 2.95, 3.35, 3.5, 3.56, 3.67, 3.7, 3.74 parts, the weight part of modified enzymolysis lignin can be 5.3, 6, 6.4, 7, 7.5, 8, 8.6, 9.6, 10, 10.3, 11, 11.5, 12, 12.8, 13, 13.4, 14, 14.6, 15, 15.7, 16, 16.9, 17, 17.5 parts, the weight part of zinc oxide can be 2.1, 2.2, 2.35, 2.4, 2.46, 2.5, 2.56, 2.68, 2.7, 2.74, 2.86, 2.9, 2.94 parts, stearic weight part can be 1.06, 1.1, 1.15, 1.2, 1.28, 1.39, 1.5, 1.54, 1.67 parts, the weight part of ultrafine aluminium hydroxide can be 5.6, 6, 6.4, 7, 7.5, 8, 8.6, 9, 9.3, 10, 10.6, 11, 11.5, 12.8, 13.4, 14, 14.5, 15, 15.9, 16, 16.7, 17.5, 18, 18.6, 19, 19.3 parts, the weight part of ethylene glycol pyrodust can be 2.3, 2.8, 3, 3.4, 3.8, 4.3, 4.8, 5, 5.3, 5.8 parts, the weight part of glycol ether pyrodust can be 1.03, 1.2, 1.35, 1.5, 1.56, 1.79, 1.8, 1.86, 1.9, 2.3, 2.45, 2.5, 2.6, 2.67, 2.8, 2.89, 2.9, 3.0, 3.1, 3.25, 3.3, 3.36, 3.4, 3.45 parts, the weight part of microencapsulated powder oil can be 2.3, 2.8, 3, 3.5, 4, 4.5, 5, 5.6, 6.7, 7, 7.5, 8, 8.6, 9, 9.3 parts, the weight part of iso-cyanuric acid triallyl ester can be 0.26, 0.3, 0.38, 0.4, 0.46, 0.5, 0.59, 0.7, 0.75, 0.86, 0.9, 0.94, 1.05, 1.16, 1.2, 1.26 parts, acrylic acid weight part can be 1.05, 1.1, 1.2, 1.26, 1.3, 1.35, 1.4, 1.46, 1.5, 1.58, 1.6, 1.67, 1.7, 1.75, 1.8, 1.86, 1.94, 2.05, 2.2, 2.23, 2.3, 2.35, 2.4, 2.46 parts, the weight part of promotor can be 1.26, 1.3, 1.34, 1.4, 1.5, 1.56, 1.6, 1.67, 1.7, 1.78, 1.8, 1.86, 1.9, 1.94, 2.05, 2.1, 2.2, 2.23, 2.34, 2.4, 2.46, 2.56, 2.6, 2.67, 2.7, 2.74 parts, the weight part of anti-aging agent can be 2.1, 2.13, 2.2, 2.25, 2.3, 2.36, 2.4, 2.45, 2.5, 2.56, 2.6, 2.67, 2.78, 2.86, 2.9, 2.94, 3, 3.01, 3.2, 3.25, 3.3, 3.34, 3.4, 3.46 parts, the weight part of tenderizer can be 0.26, 0.3, 0.34, 0.4, 0.45, 0.5, 0.56, 0.67, 0.7, 0.78, 0.9, 0.94 part.
Embodiment 1
High flame retardant high abrasion modified silicon rubber cable material of the present invention, its raw material comprises following component by weight: 50 parts, silicon rubber, terpolymer EP rubber 15 parts, isoprene-isobutylene rubber 8 parts, ethylene-vinyl acetate rubber 5 parts, urethane 10 parts, modified aluminas 23 parts, nylon 68 parts, tetramethyl piperidine oxygen 0.3 part, nano-calcium carbonate 23 parts, carboxylation carbon nanotube 35 parts, coupling agent 2 parts, dicumyl peroxide 3.8 parts, modified enzymolysis lignin 18 parts, 2 parts, zinc oxide, stearic acid 1.8 parts, ultrafine aluminium hydroxide 5 parts, ethylene glycol pyrodust 6 parts, glycol ether pyrodust 1 part, microencapsulated powder oil 10 parts, iso-cyanuric acid triallyl ester 1.3 parts, 1 part, vinylformic acid, promotor 1.2 parts, 3.5 parts, anti-aging agent, tenderizer 0.2 part.
Embodiment 2
High flame retardant high abrasion modified silicon rubber cable material of the present invention, its raw material comprises following component by weight: 65 parts, silicon rubber, terpolymer EP rubber 5 parts, isoprene-isobutylene rubber 3 parts, ethylene-vinyl acetate rubber 12 parts, urethane 3 parts, modified aluminas 10 parts, nylon 63 parts, tetramethyl piperidine oxygen 2 parts, nano-calcium carbonate 10 parts, carboxylation carbon nanotube 20 parts, coupling agent 3.8 parts, dicumyl peroxide 2 parts, modified enzymolysis lignin 5 parts, 3 parts, zinc oxide, stearic acid 1 part, ultrafine aluminium hydroxide 20 parts, ethylene glycol pyrodust 2 parts, glycol ether pyrodust 3.5 parts, microencapsulated powder oil 2 parts, iso-cyanuric acid triallyl ester 0.2 part, 2.5 parts, vinylformic acid, promotor 2.8 parts, 2 parts, anti-aging agent, tenderizer 1 part,
Wherein, the properties-correcting agent of described modified aluminas is that hexadecyl trimethoxy silane, γ-aminopropyl triethoxysilane, vinyl three ('beta '-methoxy oxyethyl group) silane are by the combination of any weight ratio; The fineness of described ultrafine aluminium hydroxide is 9700 orders; Described promotor is altax; Described anti-aging agent is that antioxidant 4010NA, antioxidant A W, anti-aging agent RD, aging inhibitor FR are by the combination of any weight ratio;
Described modified enzymolysis lignin is prepared according to following technique: after 20 parts of enzymolysis xylogens, 20 parts of water and 30 parts of formaldehyde being uniformly mixed by weight, the pH of regulation system is 8, be warming up to 70 DEG C, add 20 parts of urea, be warming up to 90 DEG C, dripping 5 parts of concentration after stirring reaction 2h is the hydrochloric acid soln of 1mol/L, obtains described modified enzymolysis lignin through standing, washing, filtration, drying.
Embodiment 3
High flame retardant high abrasion modified silicon rubber cable material of the present invention, its raw material comprises following component by weight: 62 parts, silicon rubber, terpolymer EP rubber 11 parts, isoprene-isobutylene rubber 5.8 parts, ethylene-vinyl acetate rubber 8.6 parts, urethane 8.6 parts, modified aluminas 18.3 parts, nylon66 fiber .4 part, tetramethyl piperidine oxygen 1.68 parts, nano-calcium carbonate 14 parts, carboxylation carbon nanotube 25 parts, coupling agent 3.4 parts, dicumyl peroxide 3.5 parts, modified enzymolysis lignin 15 parts, 2.7 parts, zinc oxide, stearic acid 1.5 parts, ultrafine aluminium hydroxide 16 parts, ethylene glycol pyrodust 4.8 parts, glycol ether pyrodust 2.6 parts, microencapsulated powder oil 7 parts, iso-cyanuric acid triallyl ester 0.75 part, 1.7 parts, vinylformic acid, promotor 1.8 parts, 2.56 parts, anti-aging agent, vegetables oil 0.9 part,
Wherein, the properties-correcting agent of described modified aluminas is the combination of γ-aminopropyl triethoxysilane, vinyl three ('beta '-methoxy oxyethyl group) silane ratio 1:3 by weight; The fineness of described ultrafine aluminium hydroxide is 9800 orders; Described promotor is that accelerant N A-22, Vulcanization accelerator TMTD, promotor E are by the combination of 1:2:4 weight ratio; Described anti-aging agent is the combination of antioxidant A W, anti-aging agent RD, aging inhibitor FR ratio 1:3:2 by weight;
Described modified enzymolysis lignin is prepared according to following technique: after 40 parts of enzymolysis xylogens, 35 parts of water and 10 parts of formaldehyde being uniformly mixed by weight, the pH of regulation system is 9, be warming up to 62 DEG C, add 40 parts of urea, be warming up to 85 DEG C, dripping 2 parts of concentration after stirring reaction 4h is the hydrochloric acid soln of 1mol/L, obtains described modified enzymolysis lignin through standing, washing, filtration, drying.
Embodiment 4
High flame retardant high abrasion modified silicon rubber cable material of the present invention, its raw material comprises following component by weight: 57 parts, silicon rubber, terpolymer EP rubber 8.5 parts, isoprene-isobutylene rubber 6.5 parts, ethylene-vinyl acetate rubber 10.3 parts, urethane 9 parts, modified aluminas 18 parts, nylon 65.3 parts, tetramethyl piperidine oxygen 1.2 parts, nano-calcium carbonate 19 parts, carboxylation carbon nanotube 30 parts, coupling agent 3 parts, dicumyl peroxide 3 parts, modified enzymolysis lignin 9.5 parts, 2.6 parts, zinc oxide, stearic acid 1.4 parts, ultrafine aluminium hydroxide 13 parts, ethylene glycol pyrodust 4 parts, glycol ether pyrodust 2 parts, microencapsulated powder oil 6.6 parts, iso-cyanuric acid triallyl ester 1 part, 2 parts, vinylformic acid, promotor 2.3 parts, 2.8 parts, anti-aging agent, tenderizer 0.8 part,
Wherein, the properties-correcting agent of described modified aluminas is hexadecyl trimethoxy silane; The fineness of described ultrafine aluminium hydroxide is 9500 orders; Described promotor is that altax, accelerant CZ, accelerant N A-22, Vulcanization accelerator TMTD, promotor E, vulkacit D BX are by the combination of any weight ratio; Described anti-aging agent is antioxidant 4010NA;
Described modified enzymolysis lignin is prepared according to following technique: after 32 parts of enzymolysis xylogens, 27 parts of water and 19 parts of formaldehyde being uniformly mixed by weight, the pH of regulation system is 8, be warming up to 67 DEG C, add 33 parts of urea, be warming up to 87 DEG C, dripping 2.8 parts of concentration after stirring reaction 3.2h is the hydrochloric acid soln of 1mol/L, obtains described modified enzymolysis lignin through standing, washing, filtration, drying.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (9)
1. a high flame retardant high abrasion modified silicon rubber cable material, it is characterized in that, its raw material comprises following component by weight: silicon rubber 50-65 part, terpolymer EP rubber 5-15 part, isoprene-isobutylene rubber 3-8 part, ethylene-vinyl acetate rubber 5-12 part, urethane 3-10 part, modified aluminas 10-23 part, nylon 63-8 part, tetramethyl piperidine oxygen 0.3-2 part, nano-calcium carbonate 10-23 part, carboxylation carbon nanotube 20-35 part, coupling agent 2-3.8 part, dicumyl peroxide 2-3.8 part, modified enzymolysis lignin 5-18 part, zinc oxide 2-3 part, stearic acid 1-1.8 part, ultrafine aluminium hydroxide 5-20 part, ethylene glycol pyrodust 2-6 part, glycol ether pyrodust 1-3.5 part, microencapsulated powder oil 2-10 part, iso-cyanuric acid triallyl ester 0.2-1.3 part, vinylformic acid 1-2.5 part, promotor 1.2-2.8 part, anti-aging agent 2-3.5 part, tenderizer 0.2-1 part.
2. high flame retardant high abrasion modified silicon rubber cable material according to claim 1, it is characterized in that, its raw material comprises following component by weight: silicon rubber 55-58 part, terpolymer EP rubber 8-9.3 part, isoprene-isobutylene rubber 6-7.2 part, ethylene-vinyl acetate rubber 10-10.7 part, urethane 8-9.2 part, modified aluminas 17-20 part, nylon 65-5.7 part, tetramethyl piperidine oxygen 1.1-1.5 part, nano-calcium carbonate 18-20 part, carboxylation carbon nanotube 29-31.2 part, coupling agent 2.9-3.2 part, dicumyl peroxide 2.9-3.2 part, modified enzymolysis lignin 9-9.9 part, zinc oxide 2.3-2.8 part, stearic acid 1.3-1.6 part, ultrafine aluminium hydroxide 12-17 part, ethylene glycol pyrodust 3.5-4.2 part, glycol ether pyrodust 1.7-2.4 part, microencapsulated powder oil 6-7.3 part, iso-cyanuric acid triallyl ester 0.8-1.1 part, vinylformic acid 1.9-2.1 part, promotor 2-2.5 part, anti-aging agent 2.7-3.1 part, tenderizer 0.6-0.86 part.
3. high flame retardant high abrasion modified silicon rubber cable material according to claim 1 or 2, it is characterized in that, its raw material comprises following component by weight: 57 parts, silicon rubber, terpolymer EP rubber 8.5 parts, isoprene-isobutylene rubber 6.5 parts, ethylene-vinyl acetate rubber 10.3 parts, urethane 9 parts, modified aluminas 18 parts, nylon 65.3 parts, tetramethyl piperidine oxygen 1.2 parts, nano-calcium carbonate 19 parts, carboxylation carbon nanotube 30 parts, coupling agent 3 parts, dicumyl peroxide 3 parts, modified enzymolysis lignin 9.5 parts, 2.6 parts, zinc oxide, stearic acid 1.4 parts, ultrafine aluminium hydroxide 13 parts, ethylene glycol pyrodust 4 parts, glycol ether pyrodust 2 parts, microencapsulated powder oil 6.6 parts, iso-cyanuric acid triallyl ester 1 part, 2 parts, vinylformic acid, promotor 2.3 parts, 2.8 parts, anti-aging agent, tenderizer 0.8 part.
4. high flame retardant high abrasion modified silicon rubber cable material according to any one of claim 1-3, it is characterized in that, the properties-correcting agent of described modified aluminas is one or more the combination in hexadecyl trimethoxy silane, γ-aminopropyl triethoxysilane, vinyl three ('beta '-methoxy oxyethyl group) silane.
5. high flame retardant high abrasion modified silicon rubber cable material according to any one of claim 1-4, it is characterized in that, described modified enzymolysis lignin is prepared according to following technique: after 20-40 part enzymolysis xylogen, 20-35 part water and 10-30 part formaldehyde being uniformly mixed by weight, the pH of regulation system is 8-9, be warming up to 62-70 DEG C, add 20-40 part urea, be warming up to 85-90 DEG C, dripping 2-5 part concentration after stirring reaction 2-4h is the hydrochloric acid soln of 1mol/L, obtains described modified enzymolysis lignin through standing, washing, filtration, drying.
6. high flame retardant high abrasion modified silicon rubber cable material according to any one of claim 1-5, is characterized in that, the fineness of described ultrafine aluminium hydroxide is 9500-9800 order.
7. high flame retardant high abrasion modified silicon rubber cable material according to any one of claim 1-6, it is characterized in that, described promotor is one or more the combination in altax, accelerant CZ, accelerant N A-22, Vulcanization accelerator TMTD, promotor E, vulkacit D BX.
8. high flame retardant high abrasion modified silicon rubber cable material according to any one of claim 1-7, is characterized in that, described anti-aging agent is one or more the combination in antioxidant 4010NA, antioxidant A W, anti-aging agent RD, aging inhibitor FR.
9. high flame retardant high abrasion modified silicon rubber cable material according to any one of claim 1-8, it is characterized in that, described tenderizer is vegetables oil.
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| CN108192371A (en) * | 2017-12-15 | 2018-06-22 | 安徽嘉中金属材料有限公司 | A kind of corrosion-resistant cold-resistant cable material and preparation method thereof |
| WO2019232818A1 (en) * | 2018-06-07 | 2019-12-12 | 盐城申源塑胶有限公司 | Granule for cable having relatively high tensile strength and hardness, and preparation process thereof |
| CN109438986A (en) * | 2018-09-07 | 2019-03-08 | 安徽华网电缆有限公司 | A kind of highly effective flame-retardant, wear-resisting Metro Cable and preparation method thereof |
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