CN104403224A - Antimony-free flame-retardant polyvinyl chloride wire and cable material and preparation method thereof - Google Patents
Antimony-free flame-retardant polyvinyl chloride wire and cable material and preparation method thereof Download PDFInfo
- Publication number
- CN104403224A CN104403224A CN201310698990.6A CN201310698990A CN104403224A CN 104403224 A CN104403224 A CN 104403224A CN 201310698990 A CN201310698990 A CN 201310698990A CN 104403224 A CN104403224 A CN 104403224A
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- Prior art keywords
- parts
- polyvinyl chloride
- cable material
- epoxy
- retardant
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
Abstract
The invention relates to the field of a polyvinyl chloride wire and cable material, especially to an antimony-free flame-retardant polyvinyl chloride wire and cable material. The formula of the wire and cable material contains the following ingredients, by weight, a. 100 parts of polyvinyl chloride (PVC); b. 45-55 parts of one or more substances selected from aliphatic dibasic acid ester, trimellitate, polyester and an epoxy plasticizer; c. 5-11 parts of one or more substances selected from a compound stabilizer and an epoxy compound; d. 10-50 parts of one or more substances selected from hydrous zinc borate, magnesium hydroxide, aluminium hydroxide, huntite and a compound flame retardant; e. 4-25 parts of one or more substances selected from kaolin, ceramic microbead and silica-alumina mineral powder; f. 0-6 parts of zero or more substances selected form ethylene chloride and acrylate; g. 0.5-0.8 part of one or more substances selected from stearic acid, polyethylene wax and a compound lubricant; and h. 1-2 parts of color masterbatch. By the technical scheme, latent personal safety threat existing due to antimony can be minimized, pollution is reduced, and the wire and cable material is more environmentally-friendly and has higher safety.
Description
Technical field
The present invention relates to polyvinyl chloride wire cable material field, particularly a kind of without antimony flame-retardant polyvinyl chloride wire cable material and preparation method thereof.
Background technology
Polyvinyl chloride is a kind of excellent wire cable insulating material.At wires and cables industry always in occupation of important share, because itself is chloride, can be fire-retardant with antimonous oxide synergistic, be particularly suitable for some high flame retardant occasions.But along with the enhancing of people's environmental consciousness, there are some researches show that antimony and compound thereof can enter human body by approach such as respiratory tract, digestive tube or skins, the eye of people, nose, throat and skin can be stimulated, continuous contact can destroy heart and liver function, still do not get rid of at present its potentially dangerous to human body, therefore many areas and country are all classified as antimony as priority pollutant, clearly forbid the use of antimony.
Summary of the invention
The embodiment of the present invention first object is to provide a kind of without antimony flame-retardant polyvinyl chloride wire cable material, and apply this technical scheme and can reduce because the potential personnel safety existed containing antimony threatens, decreasing pollution, more environmental protection, security is higher.
The embodiment of the present invention second object is to provide a kind of preparation method without antimony flame-retardant polyvinyl chloride wire cable material, applying this technical scheme can produce without antimony flame-retardant polyvinyl chloride wire cable material, reduce because the potential personnel safety existed containing antimony threatens, decreasing pollution, more environmental protection, security is higher.
In order to realize foregoing invention object, complete skill scheme of the present invention is:
A kind of without antimony flame-retardant polyvinyl chloride wire cable material, it is characterized in that, its recipe ingredient is by weight:
A. polyvinyl chloride (PVC) 100 parts;
B. one or more materials 45-55 part of fatty group dibasic acid, trimellitate, polyester, epoxy plasticiser;
C. one or more materials 5-11 part of one package stabilizer, epoxy compounds;
D. one or more materials 10-50 part of hydration zinc borate, magnesium hydroxide, aluminium hydroxide, huntite, composite flame-retardant agent;
E. one or more materials 4-25 part of kaolin, ceramic fine bead, sial ore powder;
F. more than zero kind or zero kind material 0-6 part of ethylene chloride, CALCIUM ACRYLATE;
G. one or more materials 0.5-0.8 part of stearic acid, polyethylene wax, compounded lubricant;
H. colour batch 1-2 part.
Prepare a method for said wires CABLE MATERIALS, its step comprises:
1) first material a is joined in high-speed mixer, add powder or oily substance c again, low speed mixing, after 1 minute, adds the material b of component half, mixing machine proceeds to high-speed mixing after 5 minutes by low speed, add the material b fluidizer of second half component, mixing machine proceeds to high-speed mixing to 90 DEG C by low speed, finally adds d, e, f, g and h, proceed to high-speed mixing and obtain compound to 115-125 DEG C after low speed;
I. compound is joined banburying in Banbury mixer and obtain grog to 160 DEG C, then the single-screw machine using major diameter smaller in grog is extruded into particulate state colour masterbatch;
J. single-screw machine plasticizing compound being joined length-to-diameter ratio larger is extruded into particulate state colour masterbatch;
2) colour masterbatch is extruded wire rod finished product by single-screw machine, obtain without antimony flame-retardant polyvinyl chloride wire cable material.
Concrete, its recipe ingredient is by weight:
Polyvinyl chloride (PVC) 100 parts;
Trioctyl trimellitate (TOTM) 48 parts;
Epoxy soybean oil (EPOXY) 4 parts;
One package stabilizer 5 parts;
Polynite class composite flame-retardant agent 10 parts;
Kaolin 10 parts;
Sial ore powder 15 parts;
Compounded lubricant 0.6 part.
Concrete, its recipe ingredient is by weight:
Polyvinyl chloride (PVC) 100 parts;
Trioctyl trimellitate (TOTM) 48 parts;
Epoxy soybean oil (EPOXY) 4 parts;
One package stabilizer 5 parts;
Composite flame-retardant agent 10 parts;
Kaolin 10 parts;
Sial ore powder 15 parts;
Compounded lubricant 0.6 part.
Concrete, its recipe ingredient is by weight:
Polyvinyl chloride (PVC) 100 parts;
Trioctyl trimellitate (TOTM) 48 parts;
Epoxy soybean oil (EPOXY) 4 parts;
One package stabilizer 7 parts;
Hydration zinc borate 10 parts;
Magnesium hydroxide 15 parts;
25 parts, aluminium hydroxide;
Ethylene chloride 6 parts;
Compounded lubricant 0.6 part.
Therefore application the present embodiment technical scheme, can produce without antimony flame-retardant polyvinyl chloride wire cable material, and reduce because the potential personnel safety existed containing antimony threatens, decreasing pollution, more environmental protection, security is higher.The mechanical performance index of the embodiment of the present invention all meets UL1581 standard-required, reach 105 DEG C of temperature resistant grades, meet performance requriements, and cheap, can meet VW-1 burn class requirement, meet European Union ROHS, REACH standard completely and meet concerned countries without the requirement of antimony environmental standard.
Embodiment
Described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
embodiment 1:
Present embodiment discloses a kind of without antimony flame-retardant polyvinyl chloride wire cable material, its recipe ingredient is by weight:
A. polyvinyl chloride (PVC) 100 parts;
B. one or more materials 45-55 part of fatty group dibasic acid, trimellitate, polyester, epoxy plasticiser;
C. one or more materials 5-11 part of one package stabilizer, epoxy compounds;
D. one or more materials 10-50 part of hydration zinc borate, magnesium hydroxide, aluminium hydroxide, huntite, composite flame-retardant agent;
E. one or more materials 4-25 part of kaolin, ceramic fine bead, sial ore powder;
F. more than zero kind or zero kind material 0-6 part of ethylene chloride, CALCIUM ACRYLATE;
G. one or more materials 0.5-0.8 part of stearic acid, polyethylene wax, compounded lubricant;
H. colour batch 1-2 part.
The present embodiment also discloses a kind of method preparing said wires CABLE MATERIALS, and its step comprises:
1) first material a is joined in high-speed mixer, add powder or oily substance c again, low speed mixing, after 1 minute, adds the material b of component half, mixing machine proceeds to high-speed mixing after 5 minutes by low speed, add the material b fluidizer of second half component, mixing machine proceeds to high-speed mixing to 90 DEG C by low speed, finally adds d, e, f, g and h, proceed to high-speed mixing and obtain compound to 115-125 DEG C after low speed;
I. compound is joined banburying in Banbury mixer and obtain grog to 160 DEG C, then the single-screw machine using major diameter smaller in grog is extruded into particulate state colour masterbatch;
J. single-screw machine plasticizing compound being joined length-to-diameter ratio larger is extruded into particulate state colour masterbatch;
2) colour masterbatch is extruded wire rod finished product by single-screw machine, obtain without antimony flame-retardant polyvinyl chloride wire cable material.
Wherein, step I and J can select arbitrarily a kind of.
embodiment 2:
Present embodiment discloses another kind of concrete recipe ingredient, its recipe ingredient is by weight:
Polyvinyl chloride (PVC) 100 parts;
Trioctyl trimellitate (TOTM) 48 parts;
Epoxy soybean oil (EPOXY) 4 parts;
One package stabilizer 5 parts;
Polynite class composite flame-retardant agent 10 parts;
Kaolin 10 parts;
Sial ore powder 15 parts;
Compounded lubricant 0.6 part.
embodiment 3:
Present embodiment discloses another kind of concrete recipe ingredient, its recipe ingredient is by weight:
Polyvinyl chloride (PVC) 100 parts;
Trioctyl trimellitate (TOTM) 48 parts;
Epoxy soybean oil (EPOXY) 4 parts;
One package stabilizer 5 parts;
Composite flame-retardant agent 10 parts;
Kaolin 10 parts;
Sial ore powder 15 parts;
Compounded lubricant 0.6 part.
embodiment 4:
Present embodiment discloses another kind of concrete recipe ingredient, its recipe ingredient is by weight:
Polyvinyl chloride (PVC) 100 parts;
Trioctyl trimellitate (TOTM) 48 parts;
Epoxy soybean oil (EPOXY) 4 parts;
One package stabilizer 7 parts;
Hydration zinc borate 10 parts;
Magnesium hydroxide 15 parts;
25 parts, aluminium hydroxide;
Ethylene chloride 6 parts;
Compounded lubricant 0.6 part.
Above-described embodiment, does not form the restriction to this technical scheme protection domain.The amendment done within any spirit at above-mentioned embodiment and principle, equivalently to replace and improvement etc., within the protection domain that all should be included in this technical scheme.
Claims (5)
1. without an antimony flame-retardant polyvinyl chloride wire cable material, it is characterized in that, its recipe ingredient is by weight:
A. polyvinyl chloride (PVC) 100 parts;
B. one or more materials 45-55 part of fatty group dibasic acid, trimellitate, polyester, epoxy plasticiser;
C. one or more materials 5-11 part of one package stabilizer, epoxy compounds;
D. one or more materials 10-50 part of hydration zinc borate, magnesium hydroxide, aluminium hydroxide, huntite, composite flame-retardant agent;
E. one or more materials 4-25 part of kaolin, ceramic fine bead, sial ore powder;
F. more than zero kind or zero kind material 0-6 part of ethylene chloride, CALCIUM ACRYLATE;
G. one or more materials 0.5-0.8 part of stearic acid, polyethylene wax, compounded lubricant;
H. colour batch 1-2 part.
2. prepare a method for wire cable material according to claim 1, its step comprises:
1) first material a is joined in high-speed mixer, add powder or oily substance c again, low speed mixing, after 1 minute, adds the material b of component half, mixing machine proceeds to high-speed mixing after 5 minutes by low speed, add the material b fluidizer of second half component, mixing machine proceeds to high-speed mixing to 90 DEG C by low speed, finally adds d, e, f, g and h, proceed to high-speed mixing and obtain compound to 115-125 DEG C after low speed;
I. compound is joined banburying in Banbury mixer and obtain grog to 160 DEG C, then the single-screw machine using major diameter smaller in grog is extruded into particulate state colour masterbatch;
J. single-screw machine plasticizing compound being joined length-to-diameter ratio larger is extruded into particulate state colour masterbatch;
2) colour masterbatch is extruded wire rod finished product by single-screw machine, obtain without antimony flame-retardant polyvinyl chloride wire cable material.
3. according to claim 1 a kind of without antimony flame-retardant polyvinyl chloride wire cable material, it is characterized in that, its recipe ingredient is by weight:
Polyvinyl chloride (PVC) 100 parts;
Trioctyl trimellitate (TOTM) 48 parts;
Epoxy soybean oil (EPOXY) 4 parts;
One package stabilizer 5 parts;
Polynite class composite flame-retardant agent 10 parts;
Kaolin 10 parts;
Sial ore powder 15 parts;
Compounded lubricant 0.6 part.
4. according to claim 1 a kind of without antimony flame-retardant polyvinyl chloride wire cable material, it is characterized in that, its recipe ingredient is by weight:
Polyvinyl chloride (PVC) 100 parts;
Trioctyl trimellitate (TOTM) 48 parts;
Epoxy soybean oil (EPOXY) 4 parts;
One package stabilizer 5 parts;
Composite flame-retardant agent 10 parts;
Kaolin 10 parts;
Sial ore powder 15 parts;
Compounded lubricant 0.6 part.
5. according to claim 1 a kind of without antimony flame-retardant polyvinyl chloride wire cable material, it is characterized in that, its recipe ingredient is by weight:
Polyvinyl chloride (PVC) 100 parts;
Trioctyl trimellitate (TOTM) 48 parts;
Epoxy soybean oil (EPOXY) 4 parts;
One package stabilizer 7 parts;
Hydration zinc borate 10 parts;
Magnesium hydroxide 15 parts;
25 parts, aluminium hydroxide;
Ethylene chloride 6 parts;
Compounded lubricant 0.6 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310698990.6A CN104403224A (en) | 2013-12-19 | 2013-12-19 | Antimony-free flame-retardant polyvinyl chloride wire and cable material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310698990.6A CN104403224A (en) | 2013-12-19 | 2013-12-19 | Antimony-free flame-retardant polyvinyl chloride wire and cable material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104403224A true CN104403224A (en) | 2015-03-11 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310698990.6A Pending CN104403224A (en) | 2013-12-19 | 2013-12-19 | Antimony-free flame-retardant polyvinyl chloride wire and cable material and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103804819A (en) * | 2014-01-26 | 2014-05-21 | 深圳市领亚电子有限公司 | Antimony-free flame-retardant composite material |
| CN109486053A (en) * | 2018-09-18 | 2019-03-19 | 百通赫思曼工业（苏州）有限公司 | A kind of PVC cable material of low-k |
| CN109912902A (en) * | 2019-01-25 | 2019-06-21 | 江西博硕电子有限公司 | A kind of low-k polyvinyl chloride cable material and preparation method thereof |
| CN112745602A (en) * | 2020-12-30 | 2021-05-04 | 威海市泓淋电力技术股份有限公司 | Semi-hard environment-friendly antimony-free polyvinyl chloride |
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| US5886072A (en) * | 1993-05-24 | 1999-03-23 | Teknor Apex Company | Flame retardant composition |
| CN101456996A (en) * | 2008-12-30 | 2009-06-17 | 深圳市领亚电子有限公司 | Oil-resistant polyvinyl chloride composition for wire cable and preparation method |
| CN103172945A (en) * | 2011-12-21 | 2013-06-26 | 日立电线株式会社 | Polyvinyl chloride resin composite, and wire and cable using the same |
| CN103450594A (en) * | 2013-08-30 | 2013-12-18 | 江苏达胜高聚物有限公司 | Production process of inflaming-retarding PVC (Polyvinyl Chloride) cable material |
-
2013
- 2013-12-19 CN CN201310698990.6A patent/CN104403224A/en active Pending
Patent Citations (4)
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|---|---|---|---|---|
| US5886072A (en) * | 1993-05-24 | 1999-03-23 | Teknor Apex Company | Flame retardant composition |
| CN101456996A (en) * | 2008-12-30 | 2009-06-17 | 深圳市领亚电子有限公司 | Oil-resistant polyvinyl chloride composition for wire cable and preparation method |
| CN103172945A (en) * | 2011-12-21 | 2013-06-26 | 日立电线株式会社 | Polyvinyl chloride resin composite, and wire and cable using the same |
| CN103450594A (en) * | 2013-08-30 | 2013-12-18 | 江苏达胜高聚物有限公司 | Production process of inflaming-retarding PVC (Polyvinyl Chloride) cable material |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103804819A (en) * | 2014-01-26 | 2014-05-21 | 深圳市领亚电子有限公司 | Antimony-free flame-retardant composite material |
| CN109486053A (en) * | 2018-09-18 | 2019-03-19 | 百通赫思曼工业（苏州）有限公司 | A kind of PVC cable material of low-k |
| CN109912902A (en) * | 2019-01-25 | 2019-06-21 | 江西博硕电子有限公司 | A kind of low-k polyvinyl chloride cable material and preparation method thereof |
| CN112745602A (en) * | 2020-12-30 | 2021-05-04 | 威海市泓淋电力技术股份有限公司 | Semi-hard environment-friendly antimony-free polyvinyl chloride |
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Application publication date: 20150311 |