CN1044029A - The synthetic method of the amino acid with rare earth that mixes - Google Patents
The synthetic method of the amino acid with rare earth that mixes Download PDFInfo
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- CN1044029A CN1044029A CN 89105853 CN89105853A CN1044029A CN 1044029 A CN1044029 A CN 1044029A CN 89105853 CN89105853 CN 89105853 CN 89105853 A CN89105853 A CN 89105853A CN 1044029 A CN1044029 A CN 1044029A
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- amino acid
- mixing
- rare earth
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- earth
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Abstract
The present invention is the synthetic method of the amino acid with rare earth of mixing.It makes raw material with the useless albumen of animal and plant, makes the mixed hydrolysis liquid that contains ten several amino acids through hydrolysis, adds after rare-earth mineral or mixed rear earth compound directly react, and through removal of impurities, allocating technology makes the amino acid with rare earth of mixing.Product is as disinfectant use in agriculture and plant growth regulator.Be applicable to large, medium and small type plant produced.
Description
The invention belongs to pesticide production technology.
Inorganic rare earth because its hypotoxicity to plant, a little less than accumulate, teratogenesis not, not mutagenesis and in crops characteristics such as low-residual be used as fertilizer application in agricultural production, in the research and the application of the existing this respect of China; The amino acids agricultural chemicals mainly is the amino acid copper complex as disinfectant use in agriculture, still is in initial stage in the research of China with using, and its amino acid whose raw material sources only limit to the animal ceratin hydrolysis.
The objective of the invention is rare earth, especially the rare earth compound of rare-earth mineral or mixing is introduced disinfectant use in agriculture and plant growth regulator field, seek to produce a kind of can sterilization, the agricultural organic bactericide that can promote plant growth again, increase output, the improves quality synthetic method of plant growth regulator of holding concurrently.
Utilize discarded animal and plant albumen to make raw material among the present invention, make the hydrolyzate of the mixing that contains ten several amino acids through acid hydrolysis, this is domestic prior art.Chief component of the present invention is that the amino acid hydrolyticsolution of this mixing is directly reacted with rare-earth mineral or mixed rare earth compound, is swift in response for making, adds certain network agent that helps fully.The proportioning of used rare-earth mineral or mixed rear earth compound and mixed amino acid hydrolysis liquid is 1: the 1-10(weight per volume).Complex reaction is carried out 0.5-6 hour complexing time under acid and 40 ° of-120 ℃ of temperature condition.After complex reaction is finished, remove the objectionable impurities in the mixed liquor, and PH is transferred to 2-7 with alkali compounds such as calcium oxide, slaked lime, barium monoxide, barium hydroxide, calcium carbonate, two stages of ammoniacal liquor five equilibrium.Add ionic or nonionic surface active agent in the soup after the removal of impurities and allocate, dilution or concentrate then obtains sepia, concentration is the soup of 10-80%, or makes pulvis, and its main component is the amino acid with rare earth product of mixing.
The amino acid with rare earth that mixes is as disinfectant use in agriculture, and prove through several years drug effect or efficiency test indoor, the field: the wide protection effect of its fungicidal spectrum is remarkable, outside the decapacitation sterilizing disease prevention, promotes plant growth in addition, increases output, improves the effect of quality; Show that through toxicity test it is a kind of to the person poultry harmless, the organic agricultural chemicals of the little toxicity of tool.
Example one: execute control cotton seedling blight and anthracnose with the amino acid with rare earth water liquid filling that 500PPm mixes, result of the test shows: it is 83.90% to the relative control effect of damping off, and has only 75.6% with the carbendazim person of comparing relative control effect; The former survival rate of seedlings is 100%, and the latter has only 11.4%; The former is 68.2% to the relative control effect of anthracnose, and is close substantially with carbendazim.Carry out cotton seed soaking test with 0.1% mixed amino acid rare earth compound water liquid in addition, emergence rate or cotton seedling premunition all are higher than the contrast carbendazim significantly.
Example two: the amino acid with rare earth water liquid that mixes with 75PPm carries out the indoor antibacterial test result to vegetables and is: its fungistatic effect eggplant verticillium wilt reaches 69.24%, cucumber fusarium axysporum 58.05%, wax gourd eqpidemic disease 54.2%, tomato early blight 53.4%, pepper ralstonia solanacearum 75.0%.Field efficiency test result to vegetables is: the control efficiency to eggplant verticillium wilt reaches 81.87%, tomato early blight 82.17%, and soft rot of Chinese cabbage 76.40% is synthetically seen, the preventive effect obvious results in field is higher than indoor fungistatic effect.
Example three, the test that the amino acid with rare earth of mixing carries out on citrus shows: press down, kill the effect except that anthracnose of orange being had preferably, increase the effect of sugar in addition.Spray the fruit analysis result as the soup with 100PPm: the total sugar content comparison is according to increasing 4.4-8.6%, and monose increases 6.5-5.4%, and sucrose increases 10.0-13.0%(kind difference, and it is slightly variant to increase sugared amplitude).With soup to citrus fruit adopt before and adopt post processing, the analysis showed that: its soluble solid increases by 11.11% and 8.89% respectively; The sugar gram number that contains of per 100 milliliters of fruit juice increases by 21.89% and 13.88% respectively; Contain acid gram number in per 100 milliliters of fruit juice and descend 2.47% and 16.89% respectively; Sugar-acid ratio increases by 24.97% and 36.69% respectively; Ascorbic milligram number increases by 16.11% and 6.37% in per 100 milliliters of fruit juice.
The amino acid with rare earth soup that mixes is used in the effect of all observing tangible promotion growth in the crop production such as wheat, potato, vegetables, and showing as single-strain grain number increases; Stem tuber increases slightly, increases, and the number that produces effect increases as capsicum, tomato etc.
Technological process of the present invention is simple, and raw material are easy to obtain on the spot, and are with low cost, free from environmental pollution, and product can be gone into operation in large, medium and small type factory.
Process chart of the present invention is attached, wherein:
1. represent the amino acid hydrolyticsolution of the mixing that makes by the useless proteolysis of animal and plant.
(1) adds rare-earth mineral or mixed rare earth compound.
2. complex reaction takes place in the amino acid hydrolyticsolution of representative mixing and rare-earth mineral or mixed rare earth compound under the condition that helps the network agent.
(2) add alkali compounds.
3. representative is through adding the mixed amino acid rare earth compound after alkali compounds is removed objectionable impurities.
(3) add surfactant.
4. the mixed amino acid rare earth compound product after representative adding ionic or nonionic surface active agent are allocated.
Claims (4)
1, a kind of synthetic method of amino acid with rare earth of mixing, comprise and utilize the useless albumen of animal and plant to make raw material, after acid hydrolysis, make the amino acid hydrolyticsolution of mixing, it is characterized in that the amino acid hydrolyticsolution of this kind mixing and rare-earth mineral or mixed rear earth compound directly react, through removal of impurities, allocating technology, make a kind of amino acid with rare earth of mixing, as disinfectant use in agriculture and plant growth regulator.
2, in accordance with the method for claim 1, it is characterized in that rare-earth mineral or mixed rear earth compound are 1 with the proportioning of the amino acid hydrolyticsolution that mixes: the 1-10(weight per volume), add in the course of reaction and help the network agent.
3, in accordance with the method for claim 1, it is characterized in that carrying out removal of impurities with alkali compounds.
4, in accordance with the method for claim 1, it is characterized in that allocating with ionic or nonionic surface active agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89105853 CN1033257C (en) | 1989-01-13 | 1989-01-13 | Synthetic method of mixing amino acid with rare earth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89105853 CN1033257C (en) | 1989-01-13 | 1989-01-13 | Synthetic method of mixing amino acid with rare earth |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1044029A true CN1044029A (en) | 1990-07-25 |
| CN1033257C CN1033257C (en) | 1996-11-13 |
Family
ID=4856488
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 89105853 Expired - Fee Related CN1033257C (en) | 1989-01-13 | 1989-01-13 | Synthetic method of mixing amino acid with rare earth |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1033257C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008116354A1 (en) * | 2007-03-23 | 2008-10-02 | Nanjing Normal University | A ternary complex on rare earth-amino acid-vitamin used as plant growth regulator and the preparation thereof |
| CN101955397A (en) * | 2010-09-15 | 2011-01-26 | 李成保 | Biological liquid for preventing seasonal febrile diseases in ginger growth and preparation process thereof |
| CN101962307A (en) * | 2010-09-15 | 2011-02-02 | 李成保 | Biological preparation for controlling water quality deterioration and preparation process thereof |
| CN108902477A (en) * | 2018-09-12 | 2018-11-30 | 任德兵 | A kind of additive for farm animal feed and preparation method thereof |
-
1989
- 1989-01-13 CN CN 89105853 patent/CN1033257C/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008116354A1 (en) * | 2007-03-23 | 2008-10-02 | Nanjing Normal University | A ternary complex on rare earth-amino acid-vitamin used as plant growth regulator and the preparation thereof |
| CN101955397A (en) * | 2010-09-15 | 2011-01-26 | 李成保 | Biological liquid for preventing seasonal febrile diseases in ginger growth and preparation process thereof |
| CN101962307A (en) * | 2010-09-15 | 2011-02-02 | 李成保 | Biological preparation for controlling water quality deterioration and preparation process thereof |
| CN101955397B (en) * | 2010-09-15 | 2012-06-27 | 李成保 | Biological liquid for preventing seasonal febrile diseases in ginger growth and preparation process thereof |
| CN101962307B (en) * | 2010-09-15 | 2012-06-27 | 李成保 | Biological preparation for controlling water quality deterioration and preparation process thereof |
| CN108902477A (en) * | 2018-09-12 | 2018-11-30 | 任德兵 | A kind of additive for farm animal feed and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1033257C (en) | 1996-11-13 |
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