CN104388644A - Quenching agent - Google Patents

Quenching agent Download PDF

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Publication number
CN104388644A
CN104388644A CN201410614556.XA CN201410614556A CN104388644A CN 104388644 A CN104388644 A CN 104388644A CN 201410614556 A CN201410614556 A CN 201410614556A CN 104388644 A CN104388644 A CN 104388644A
Authority
CN
China
Prior art keywords
parts
quenching agent
quenching
workpiece
cooling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410614556.XA
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Chinese (zh)
Inventor
李大志
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUHU JINLONG MOLD FORGING CO Ltd
Original Assignee
WUHU JINLONG MOLD FORGING CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUHU JINLONG MOLD FORGING CO Ltd filed Critical WUHU JINLONG MOLD FORGING CO Ltd
Priority to CN201410614556.XA priority Critical patent/CN104388644A/en
Publication of CN104388644A publication Critical patent/CN104388644A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/56General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
    • C21D1/60Aqueous agents

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatments In General, Especially Conveying And Cooling (AREA)

Abstract

The invention discloses a quenching agent, belonging to the field of heat treatment of metals. The quenching agent comprises the following components in parts by weight: 15-20 parts of polyoxyethylene ether, 5-8 parts of triisopropanolamine, 3-7 parts of polyvinyl acetate, 1-4 parts of sodium benzoate, 0.5-2 parts of a defoaming agent and 70-80 parts of water. By applying the quenching agent to the heat treatment of the metals, the high-temperature cooling speed can be effectively increased, the high-temperature cooling time can be prolonged, and the cracking of workpieces can be prevented; furthermore, the quenching agent is safe and environmental friendly in use, extremely low in environmental pollution and cost, and easy to industrially produce.

Description

A kind of quenching medium
Technical field
The invention belongs to metal heat treatmet field, specifically, relate to a kind of quenching medium.
Background technology
In order to obtain the steel of different performance, needing to improve the performance of metallic substance, normally heat-treating the workpiece of metal material, conventional thermal treatment process has the heat treating methods such as quenching, tempering, annealing, normalizing.Wherein, quenching refers to and the workpiece being such as heated to austenitic state is quickly cooled to speed more than critical cooling velocity quenching structures such as forming martensite, after quench treatment, can improve the hardness of workpiece.In the process of quenching, the process of cooling of workpiece is generally divided into three phases, namely the boiling point that metallic substance is surrounded by the steam of quenchant first stage (steam film stage), the subordinate phase (boiling stage) of vapor film breakage boiling, the temperature of metallic substance reach quenchant captures the phase III (convection current stage) of heat below by way of convection current, be then cooled to room temperature.
Conventional quenchant has water-based quenching agent and oiliness quenching medium, the feature of water-based quenching agent all has very high speed of cooling in whole process of cooling, can impel in the speed of cooling that the high temperature cooling stage is high and form the tiny workpiece of crystal grain, be conducive to improving the final performance of workpiece, but at cold stage, too fast speed of cooling makes the internal stress of workpiece excessive, therefore easily causes workpiece to ftracture.Compared with water-based quenching agent, the feature of oiliness quenching medium is that the speed of cooling of whole cooling stages is slow, although can prevent workpiece cold stage due to internal stress excessive and cause cracking, but because hot stage speed of cooling is slower, therefore easily cause workpiece crystal grain comparatively large, reduce the performance after workpiece quenching.In addition, traditional oiliness quenching medium is oil based on the mineral oil with petroleum fractions usually, is equipped with additive and forms.The distinctive performance of mineral oil determines and can produce a large amount of smog when quenching, therefore easy contaminate environment, and environment-friendly function is poor.And, the oiliness quenching medium speed of cooling narrow range based on mineral oil.In addition, mineral oil flash is low, and easy initiation fire uses dangerous.
Summary of the invention
the problem that 1, will solve
There is speed of cooling narrow range for existing quenching medium, contaminate environment, use uneasy congruent problem, the invention provides a kind of safety, environmental protection, can cool fast when high temperature and at low temperature time slow down the quenching medium of speed of cooling, effectively can improve workpiece performance, prevent workpiece from ftractureing.
2, technical scheme
For solving the problem, technical scheme of the present invention is:
A kind of quenching medium, its component and massfraction as follows:
Soxylat A 25-7 15-20 part;
Tri-isopropanolamine 5-8 part;
Polyvinyl acetate 3-7 part;
Sodium Benzoate 1-4 part;
Defoamer 0.5-2 part;
Water 70-80 part.
Preferably, described defoamer is organo-siloxane.
Preferably, its component and massfraction as follows:
Soxylat A 25-7 15 parts;
Tri-isopropanolamine 8 parts;
Polyvinyl acetate 4 parts;
Sodium Benzoate 1 part;
Defoamer 2 parts;
70 parts, water.
3, beneficial effect
Compared to prior art, beneficial effect of the present invention is:
(1) the present invention is made up of Soxylat A 25-7, tri-isopropanolamine, polyvinyl acetate, Sodium Benzoate, defoamer, water, can effectively shorten the high temperature cooling time, and the subcooling that slows down speed, prevents workpiece from ftractureing;
(2) defoamer of the present invention is organo-siloxane, can froth breaking lastingly, has good stability, the advantages such as consumption is few;
(3) safety of the present invention, environmental protection, environmental pollution is minimum;
(4) cost of the present invention is low, and realization condition is simple, is conducive to well promoting the use of.
Embodiment
Specific embodiment introduces the present invention in detail below.
embodiment 1
A kind of quenching medium, its component and massfraction as follows:
Soxylat A 25-7 15 parts;
Tri-isopropanolamine 8 parts;
Polyvinyl acetate 4 parts;
Sodium Benzoate 1 part;
Defoamer 2
70 parts, water
Use the present invention when quenching to workpiece, cooling time when effectively can shorten high temperature, slow down low temperature time speed of cooling, workpiece is without cracking phenomena, functional.
embodiment 2
With embodiment 1, difference is the content of each material: Soxylat A 25-7 20 parts; Tri-isopropanolamine 6 parts; Polyvinyl acetate 3 parts; Sodium Benzoate 4 parts; 75 parts, defoamer 1 water.
Use the present invention when quenching to workpiece, cooling time when effectively can shorten high temperature, slow down low temperature time speed of cooling, workpiece is without cracking phenomena, functional.
embodiment 3
With embodiment 1, difference is the content of each material: Soxylat A 25-7 18 parts;
Tri-isopropanolamine 5 parts;
Polyvinyl acetate 7 parts;
Sodium Benzoate 3 parts;
Defoamer 0.5
80 parts, water.
Use the present invention when quenching to workpiece, cooling time when effectively can shorten high temperature, slow down low temperature time speed of cooling, workpiece is without cracking phenomena, functional.

Claims (3)

1. a quenching medium, its component and massfraction as follows:
Soxylat A 25-7 15-20 part;
Tri-isopropanolamine 5-8 part;
Polyvinyl acetate 3-7 part;
Sodium Benzoate 1-4 part;
Defoamer 0.5-2 part;
Water 70-80 part.
2. a kind of quenching medium according to claim 1, is characterized in that, described defoamer is organo-siloxane.
3. a kind of quenching medium according to claim 1, is characterized in that, component and massfraction as follows:
Soxylat A 25-7 15 parts;
Tri-isopropanolamine 8 parts;
Polyvinyl acetate 4 parts;
Sodium Benzoate 1 part;
Defoamer 2;
70 parts, water.
CN201410614556.XA 2014-11-05 2014-11-05 Quenching agent Pending CN104388644A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410614556.XA CN104388644A (en) 2014-11-05 2014-11-05 Quenching agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410614556.XA CN104388644A (en) 2014-11-05 2014-11-05 Quenching agent

Publications (1)

Publication Number Publication Date
CN104388644A true CN104388644A (en) 2015-03-04

Family

ID=52606600

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410614556.XA Pending CN104388644A (en) 2014-11-05 2014-11-05 Quenching agent

Country Status (1)

Country Link
CN (1) CN104388644A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105907931A (en) * 2016-06-16 2016-08-31 安庆市吉安汽车零件锻轧有限公司 Quenching agent for wear-resistant shaft type part
CN106834619A (en) * 2016-12-30 2017-06-13 万向钱潮(桂林)汽车底盘部件有限公司 A kind of car ball stud surface heat treatment process
CN107201430A (en) * 2017-06-01 2017-09-26 汪建军 A kind of heat treatment of workpieces quenching medium and preparation method thereof
CN108315537A (en) * 2018-05-09 2018-07-24 合肥汇之新机械科技有限公司 A kind of multicomponent alloy cast member quenching medium and preparation method thereof
CN108676980A (en) * 2018-06-13 2018-10-19 张富群 One type oil type substitutes the water based quenching agent of quenching oil

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2908303A1 (en) * 1979-03-03 1980-09-18 Basf Ag Quenching bath for tempering metals - contains alkali, ammonium or amine salt of carboxy gp. contg. crosslinked polymer and pref. nitrogen contg. polyether
CN101660027A (en) * 2008-08-29 2010-03-03 中国石油天然气股份有限公司 Water-soluble polyether quenching medium
CN101892363A (en) * 2010-07-29 2010-11-24 山东卡松科技有限公司 Quenching agent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2908303A1 (en) * 1979-03-03 1980-09-18 Basf Ag Quenching bath for tempering metals - contains alkali, ammonium or amine salt of carboxy gp. contg. crosslinked polymer and pref. nitrogen contg. polyether
CN101660027A (en) * 2008-08-29 2010-03-03 中国石油天然气股份有限公司 Water-soluble polyether quenching medium
CN101892363A (en) * 2010-07-29 2010-11-24 山东卡松科技有限公司 Quenching agent

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
胡尧良主编: "《延迟焦化装置技术手册》", 30 April 2013 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105907931A (en) * 2016-06-16 2016-08-31 安庆市吉安汽车零件锻轧有限公司 Quenching agent for wear-resistant shaft type part
CN106834619A (en) * 2016-12-30 2017-06-13 万向钱潮(桂林)汽车底盘部件有限公司 A kind of car ball stud surface heat treatment process
CN107201430A (en) * 2017-06-01 2017-09-26 汪建军 A kind of heat treatment of workpieces quenching medium and preparation method thereof
CN108315537A (en) * 2018-05-09 2018-07-24 合肥汇之新机械科技有限公司 A kind of multicomponent alloy cast member quenching medium and preparation method thereof
CN108676980A (en) * 2018-06-13 2018-10-19 张富群 One type oil type substitutes the water based quenching agent of quenching oil

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PB01 Publication
CB02 Change of applicant information

Address after: 605-606 room 35, electronic Pioneer Park, Hengshan Road, Wuhu economic and Technological Development Zone, Anhui 241006, China

Applicant after: Wuhu Jinlong Mold Forging Co.,Ltd.

Address before: 241006 Anhui Province, Wuhu City Development Zone, Wuyi Road No. 13 (City Industrial Park)

Applicant before: Wuhu Jinlong Mold Forging Co.,Ltd.

C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150304

WD01 Invention patent application deemed withdrawn after publication