CN104386927A - Building block prepared from titanium-bearing blast furnace slag and process of building block - Google Patents

Building block prepared from titanium-bearing blast furnace slag and process of building block Download PDF

Info

Publication number
CN104386927A
CN104386927A CN201410594353.9A CN201410594353A CN104386927A CN 104386927 A CN104386927 A CN 104386927A CN 201410594353 A CN201410594353 A CN 201410594353A CN 104386927 A CN104386927 A CN 104386927A
Authority
CN
China
Prior art keywords
building block
titanium
furnace slag
blast furnace
containing blast
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410594353.9A
Other languages
Chinese (zh)
Inventor
代春晏
赵杰
秦明
肖必忠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GANGCHENG GROUP LIANGSHAN RUIHAI INDUSTRIAL Co Ltd
Original Assignee
GANGCHENG GROUP LIANGSHAN RUIHAI INDUSTRIAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GANGCHENG GROUP LIANGSHAN RUIHAI INDUSTRIAL Co Ltd filed Critical GANGCHENG GROUP LIANGSHAN RUIHAI INDUSTRIAL Co Ltd
Priority to CN201410594353.9A priority Critical patent/CN104386927A/en
Publication of CN104386927A publication Critical patent/CN104386927A/en
Pending legal-status Critical Current

Links

Landscapes

  • Processing Of Solid Wastes (AREA)

Abstract

The invention belongs to the field of comprehensive utilization of a blast furnace slag, particularly relates to a building block prepared from a titanium-bearing blast furnace slag and a process of the building block, and aims at providing a process which is simple in method and is used for preparing the building block from the titanium-bearing blast furnace slag. The process comprises the following steps: stirring smelted liquid titanium-bearing blast furnace slag evenly; molding by casting; and cooling to form a building block. The building block is simple and feasible in process, does not need pretreatment of layer pouring and the like on the titanium-bearing blast furnace slag, and is free of other raw materials. The crushing value of the building block produced by the process disclosed by the invention is smaller than or equal to 10%, and is obviously improved in comparison with the crushing value of 17%-22% of the original building block prepared from the titanium-bearing blast furnace slag.

Description

Titanium-containing blast furnace slag prepares gained building block and technique thereof
Technical field
The invention belongs to blast furnace slag field of comprehensive utilization, be specifically related to a kind of titanium-containing blast furnace slag and prepare gained building block and technique thereof.
Background technology
At present, the treatment process of titanium-containing blast furnace slag is mainly hot application, shrend, carries titanium etc., and these methods not only can cause too much the taking of land resources, and to increasing the pressure of environment protection.Titanium-containing blast furnace slag is made building block, not only utilization of waste material has been carried out to titanium-containing blast furnace slag, decrease taking and protecting environment land resources.Titanium-containing blast furnace slag mainly consists of TiO 2, CaO, SiO 2, MgO and A1 2o 3, wherein TiO 2content is 13% ~ 18%.
In prior art, prepared from Ti-containing blast-furnace building block normally sinters after titanium-containing blast furnace slag and other material matchings, the pretreatment process such as hot application, shrend is still needed to carry out pre-treatment to titanium-containing blast furnace slag, consume great lot of water resources, operation is numerous and diverse, and products obtained therefrom crush values is up to 17% ~ 22%.
The people such as Wang Huaibin take high-titanium blast furnace slag as main raw material, with addition of the method for shale, yellow sand, coal gangue, mineralizer sintering slag brick processed, but the high-titanium blast furnace slag that the method uses still needs to carry out the pre-treatment such as hot application, and only have 40% with addition of amount, other batching is more, and need to sinter, cost is high, complex process.
The people such as Kong Xiangwen add polystyrene emulsion, venamul, benzene emulsion 8%-20% as gelatinous material in titanium-containing blast furnace slag, are aided with additive, and oil pressure is non-burning brickly shaping.But still need in the method to add gelatinous material and additive, and the titanium-containing blast furnace slag used still needs to carry out the pre-treatment such as hot application, cost is high, complex process.
Therefore, those skilled in the art need the technique of the simpler prepared from Ti-containing blast-furnace building block of a kind of method.
Summary of the invention
Technical problem to be solved by this invention is to provide the technique of the simple prepared from Ti-containing blast-furnace building block of a kind of method.
For solving the problems of the technologies described above, the technical solution adopted in the present invention is: casting after being stirred by the liquid titanium-containing blast furnace slag after having smelted, is cooled to building block.
Adopt technique scheme, liquid titanium-containing blast furnace slag is directly poured into a mould sizing, can avoid the pretreated water consumption of hot application, meanwhile, the ultimate compression strength of gained building block is higher, and crush values is more low to moderate 10%.
Preferably, lower the temperature after liquid titanium-containing blast furnace slag ingress of air, surface hardening is lumpd, and reduces the mobility of liquid titanium-containing blast furnace slag, the liquid titanium-containing blast furnace slag heating after having smelted can be hardened to avoid surface.Contriver puts into practice discovery, stir, cast time can contact with air that causing rapidly lower the temperature harden affect pours into a mould, for avoiding this situation to occur, heat that more than titanium-containing blast furnace slag temperature to 950 DEG C effectively can delay stirring, titanium-containing blast furnace slag hardens speed when pouring into a mould.The temperature of concrete heating titanium-containing blast furnace slag is depending on the amount of titanium-containing blast furnace slag and pouring speed, and pouring speed is slow, titanium-containing blast furnace slag temperature should be higher to delay scleroma speed.Specifically titanium-containing blast furnace slag can be sent into high temperature channel heating to delay its scleroma speed.
Titanium-containing blast furnace slag divides upper, middle and lower-ranking, and wherein upper foam slag is in the majority, if do not mixed directly building block processed, gained building block quality gap can be made comparatively large, cannot satisfy the demands, therefore casting again after titanium-containing blast furnace slag can being stirred.But carry out as stirred and heating, the inflammable gas effusion be mingled with, easily causes blast accident occurs, therefore stirs and need carry out after the heating simultaneously.Liquid titanium-containing blast furnace slag extreme temperatures, conventional stirring equipment is difficult to use, easily damaged, and contriver finds, passes into gas cost lower, and can play good stirring action.Wherein, the flow of gas, air pressure without particular requirement, so that titanium-containing blast furnace slag can be made to stir, specifically depending on the amount of titanium-containing blast furnace slag.Concrete, described gas can be the regular industrial such as air, nitrogen gas.
Concrete, for ease of the demoulding, described casting can adopt detachable refractory-material dies.
High temperature channel described in the present invention can adopt existing conventional high temperature passage to carry out, can be warming up to more than 950 DEG C to titanium-containing blast furnace slag.
The present invention also provides and adopts the building block of above-mentioned technique gained.
Beneficial effect of the present invention is as follows:
1, present invention process takes full advantage of output is large, cost is low titanium-containing blast furnace slag as the raw material of building block, turns waste into wealth, protection of the environment.
2, present invention process is simple, cost is low, does not need to carry out the pre-treatment such as hot application to titanium-containing blast furnace slag, without the need to adding other raw materials, also reduces production cost.
3, present invention process produce building block fragmentation after crush values be low to moderate≤10%, the crush values 17% ~ 22% after more original prepared from Ti-containing blast-furnace building block fragmentation has obvious progress.
4, the building block that present invention process is produced can be used for wall construction, also can cut into fritter, can be used as building construction brick, and engraving building block can be made into artwork etc.
Embodiment
Below in conjunction with embodiment, the present invention is further described.But therefore protection scope of the present invention is not limited among scope of embodiments.Especially, the equipment in following embodiment, temperature are equipment and the condition control of applicant's actual production employing, and not from the limited effect, equipment and the method that can realize the object of the invention all may be used for the inventive method.
Embodiment 1
Prepared from Ti-containing blast-furnace building block technique, step is as follows:
(1) titanium-containing blast furnace slag is transported to production scene by slag car;
(2) titanium-containing blast furnace slag is toppled over above high temperature channel, is heated up to titanium-containing blast furnace slag by high temperature channel, makes titanium-containing blast furnace slag temperature remain on about 1200 DEG C, slows down surface scleroma;
(3) titanium-containing blast furnace slag after heating up is stirred by high-speed air;
(4) titanium-containing blast furnace slag after stirring is cast in removable high-temperature resistance die and shapes;
(5) stripping forming after naturally cooling.
Embodiment 2
Prepared from Ti-containing blast-furnace building block technique, step is as follows:
(1) titanium-containing blast furnace slag is transported to production scene by slag car;
(2) titanium-containing blast furnace slag is toppled over above high temperature channel, is heated up to titanium-containing blast furnace slag by high temperature channel, makes titanium-containing blast furnace slag temperature remain on more than 950 DEG C, slows down surface scleroma;
(3) titanium-containing blast furnace slag after heating up is stirred by high-speed air;
(4) titanium-containing blast furnace slag after stirring is cast in removable high-temperature resistance die and shapes;
(5) stripping forming after naturally cooling.
Find by carrying out detection to gained building block, the present invention is that building block made by raw material with titanium-containing blast furnace slag, building block good physical performance, detect according to GB/T14685-2011 after fragmentation, crush values≤10%, crush values 17% ~ 22% after the building block fragmentation that more original method utilizes titanium-containing blast furnace slag to obtain has obvious progress, meets novel wall material requirement, can be used for wall construction.And present invention process is compared with existing prepared from Ti-containing blast-furnace building block method, the liquid prepared from Ti-containing blast-furnace building block of direct utilization, without the need to the pre-treatment step such as hot application and sintering step, save hot application water, sintering energy consumption and cost of labor, and without the need to adding other raw materials except titanium-containing blast furnace slag, technique is simpler, production cost is lower.

Claims (6)

1. the technique of prepared from Ti-containing blast-furnace building block, is characterized in that: casting after being stirred by the liquid titanium-containing blast furnace slag after having smelted, cools to obtain building block.
2. the technique of prepared from Ti-containing blast-furnace building block according to claim 1, is characterized in that: the liquid titanium-containing blast furnace slag after having smelted first is heated to more than 950 DEG C and stirs.
3. the technique of prepared from Ti-containing blast-furnace building block according to claim 2, is characterized in that: described in be heated to be and titanium-containing blast furnace slag sent into high temperature channel heating.
4. the technique of the prepared from Ti-containing blast-furnace building block according to any one of claims 1 to 3, is characterized in that: described stirring is for passing into gas stirring.
5. the technique of the prepared from Ti-containing blast-furnace building block according to any one of Claims 1 to 4, is characterized in that: described casting adopts detachable refractory-material dies casting.
6. any one of Claims 1 to 5 technique gained building block.
CN201410594353.9A 2014-10-29 2014-10-29 Building block prepared from titanium-bearing blast furnace slag and process of building block Pending CN104386927A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410594353.9A CN104386927A (en) 2014-10-29 2014-10-29 Building block prepared from titanium-bearing blast furnace slag and process of building block

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410594353.9A CN104386927A (en) 2014-10-29 2014-10-29 Building block prepared from titanium-bearing blast furnace slag and process of building block

Publications (1)

Publication Number Publication Date
CN104386927A true CN104386927A (en) 2015-03-04

Family

ID=52604908

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410594353.9A Pending CN104386927A (en) 2014-10-29 2014-10-29 Building block prepared from titanium-bearing blast furnace slag and process of building block

Country Status (1)

Country Link
CN (1) CN104386927A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114854470A (en) * 2022-06-09 2022-08-05 陕西恩福聚化燃料科技有限公司 Polymerization environment-friendly additive produced by utilizing coal gangue and preparation method and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85101592A (en) * 1985-04-01 1987-01-10 武汉钢铁学院 Use high value cinder product made from slag processed by spraying powder method
CN1246454A (en) * 1998-09-02 2000-03-08 东北大学钎具开发研究中心 Process for preparing decorative devitrified glass tile and its products
CN101705730A (en) * 2009-11-26 2010-05-12 攀钢集团研究院有限公司 Sintered hollow brick and manufacturing method thereof
CN101717226A (en) * 2009-11-27 2010-06-02 同济大学 Method for solidifying blast furnace slag into building material
CN104098272A (en) * 2014-08-11 2014-10-15 北京璞晶科技有限公司 Method for using blast furnace slag to produce micro-crystalline light brick

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85101592A (en) * 1985-04-01 1987-01-10 武汉钢铁学院 Use high value cinder product made from slag processed by spraying powder method
CN1246454A (en) * 1998-09-02 2000-03-08 东北大学钎具开发研究中心 Process for preparing decorative devitrified glass tile and its products
CN101705730A (en) * 2009-11-26 2010-05-12 攀钢集团研究院有限公司 Sintered hollow brick and manufacturing method thereof
CN101717226A (en) * 2009-11-27 2010-06-02 同济大学 Method for solidifying blast furnace slag into building material
CN104098272A (en) * 2014-08-11 2014-10-15 北京璞晶科技有限公司 Method for using blast furnace slag to produce micro-crystalline light brick

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114854470A (en) * 2022-06-09 2022-08-05 陕西恩福聚化燃料科技有限公司 Polymerization environment-friendly additive produced by utilizing coal gangue and preparation method and application thereof

Similar Documents

Publication Publication Date Title
KR101480894B1 (en) Method for manufacturing stone material using molten slag
CN109369020A (en) A kind of calendering technology method producing devitrified glass or stone slab using liquid manganese slag
CN103086728B (en) Explosion proofing castable for steel ladle working layer
CN104003741B (en) Tundish covering castable and preparation method thereof
CN107188411B (en) Method for preparing microlite by smelting high-temperature molten slag through manganese alloy
CN109095779A (en) A method of crystallite stone material or road dental calculus are prepared using high calcium liquid manganese slag
CN104261804A (en) Preparation method of ceramic mold
EP2623614B1 (en) Method for manufacturing planar inorganic non-metallic material using molten slag
CN110183243A (en) A kind of preparation method of exterior insulation
CN105622070A (en) Magnesia-carbon brick prepared from residual magnesia-carbon bricks and preparation method of magnesia-carbon brick
CN113061015A (en) Method for preparing artificial decorative stone by utilizing manganese-silicon alloy hot-melt slag
CN106588048A (en) Steelmaking tundish guard plate and castable therefor
CN104313211A (en) Method for directly producing building brick by fusing blast furnace slags
CN102351473B (en) Preparation method of grating plate
CN102978345B (en) Low-chrome refractory material RH refining furnace and building method thereof
CN102786314A (en) Fused-rebonded magnesite-chrome brick with excellent thermal shock resistance and production process
CN104193370A (en) Preparation method of steel ladle carbon-free precast block
CN103253867B (en) A kind of molten state yellow phosphorus furnace slag prepares the Technology of devitrified glass
CN104386927A (en) Building block prepared from titanium-bearing blast furnace slag and process of building block
CN102303976B (en) Zircon hearth prefabricated part for heating furnace and preparation method thereof
CN105272141A (en) Method for producing stone plate by using melting blast furnace slag
CN107586056A (en) Method for preparing expansion agent used in a kind of slag micropowder production
CN104550685A (en) Preparation method of environment-friendly type forsterite foundry sand
CN105948494A (en) Method for preparing microcrystalline material through waste residues
CN102699286B (en) Casting method of iron casting

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20150304

RJ01 Rejection of invention patent application after publication