CN104370486B - High-performance composite materials activation superfined flyash preparation technology and application - Google Patents
High-performance composite materials activation superfined flyash preparation technology and application Download PDFInfo
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- CN104370486B CN104370486B CN201310375580.8A CN201310375580A CN104370486B CN 104370486 B CN104370486 B CN 104370486B CN 201310375580 A CN201310375580 A CN 201310375580A CN 104370486 B CN104370486 B CN 104370486B
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- cement
- flyash
- composite materials
- bistrique
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Processing Of Solid Wastes (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
High-performance composite materials activation superfined flyash is two grades or three grades of ashes to be added while superfine grinding a small amount of exciting agent and grinding aid carries out intergrinding, meets less than 10 μm particles ratios more than more than 95%.By in 10 20% and 42.5 cement in its outer incorporation 32.5 cement 10 15%, mix homogeneously, produced cement grade is constant.By in its outer pure clinker aggregate portland cement mixing label 52.5, mix homogeneously produces cement, and outer incorporation 40 50% produces 42.5 cement, and outer incorporation 60 70% produces 32.5 cement.Using it in C40 and C30 label commerical ready-mixed concrete, substitute selecting crude drugs with winnower ash, the Binder Materials such as breeze and cement 50 70%, 28 days strength ratio benchmark C40 and C30 concrete strength exceed 3 6MPa.
Description
Art:
The invention belongs to the technical field that high-performance composite materials for building make, be specifically related to a kind of high performance composite
Material activation superfined flyash preparation technology and application.
Background technology:
China's power industry is based on thermal power generation, and wherein coal fired power generation is occupied an leading position.According to statistics, whole nation coal fired power generation
Year discharge coal ash of standing reaches more than 300,000,000 ton, utilization rate wretched insufficiency, and substantial amounts of flyash is piled up and do not only taken up a large amount of arable land, also pollutes
Environment.Therefore, the comprehensive utilization of flyash is related to the sustainable development of China's power industry and related industries.The length of flyash
Phase piles up and environment causes destruction greatly, therefore within the period that modern later is considerably long, does the comprehensive utilization of flyash well
With, for reducing the industrial residue pollution to environment, turn harm into good, turn waste into wealth and save the energy and natural resources etc., all have
There is profound significance.
Flyash is nowadays widely used in building materials industry, and especially in cement and concrete, this is the biggest
The effective way of ancestor's digestion flyash.But, now it is applied to the flyash in cement and concrete the most not at processing
Reason, added value is relatively low, and volume is all within 50%, and utilization rate is relatively low.How to prepare the flyash of high effector function, improve powder
Coal ash volume in cement, is the R&D direction deepened and utilize flyash.
Summary of the invention:
The present invention is for overcoming above deficiency, it is provided that a kind of by former flyash is carried out superfine grinding process, physics swashs
Send out and chemi-excitation, improve flyash activity, increase pure clinker aggregate portland cement or the commerical ready-mixed concrete of doping quantity of fly ash, it is achieved
Early strength increases fast, and early strength is high, and workability is good, and durability is high, and later strength increasing degree is big, the high-performance of low cost
Composite activation superfined flyash preparation technology and application.
The present invention is achieved in that described high-performance composite materials activation superfined flyash preparation technology and answers apparatus
Preparation process technology is as follows:
To meeting three grades of flyash of national standard JC/T409-2001 " silicate building products flyash " or two grades
Raw material powder coal ash, to former flyash storehouse, is then put into bistrique air flume, by bistrique air by flyash air pump after metering
Skewed slot delivers into bistrique elevator, is lifted into ultra-fine ball mill through bistrique elevator, adds in bistrique porch and accurately claims
The exciting agent of flyash weight 0.8% of amount, the grinding aid of 0.05%, flyash is milled into semi-finished product in ball mill, and half
Finished product sends into mill tail elevator through mill tail air flume, enters powder concentrator through mill tail elevator, and the fine powder selected is through bag type dust collection
Device becomes standard compliant finished product after gathering dust, meet less than 10 μm particles ratios more than 95%, be conveyed into into by finished product
Product storehouse, non-compliant semi-finished product return to bistrique elevator, enter described ball mill and again grind, select powder, gather dust.Warehouse for finished product
In superfined flyash high performance composite can dispatch from the factory or be packaged into bag by tank car is in bulk.
1. now producing 10-20% in 32.5 cement by mixing outside the present invention, mix homogeneously is tested, tested cement gel
The each age strength of sand test block is held essentially constant, and cement grade is constant, and cost reduces 10-20 yuan/ton;Existing by mixing outside the present invention
Producing 10-15% in label 42.5 cement, mix homogeneously is tested, and each age strength of tested cement mortar test block is protected substantially
Holding constant, cement grade is constant, and cost reduces 15-30 yuan/ton.
2., by the pure clinker aggregate portland cement mixing label 52.5 outside the present invention, mix homogeneously produces 42.5 and 32.5 water
Mud.Outer incorporation 40-50% mix homogeneously, can produce 42.5 cement, and outer incorporation 60-70% can produce 32.5 cement.Produced water
Mud is higher than ordinary fly ash portland cement early strength, and gain in strength is fast, and workability is good, and durability degree is high, and later strength increases
Amplitude is big, reduces 30-60 yuan/ton than common complex cement cost.
3. the present invention is used in C40 and C30 label commerical ready-mixed concrete, substitutes selecting crude drugs with winnower ash, the gelling material such as breeze and cement
Material, substitutes volume 50-70%, and 28 days strength ratio normal concrete intensity exceeds 3-6MPa, and cost declines 10-30 unit/m3, its stream
The performances such as dynamic property, slump, workability are superior to former normal concrete.
The present invention compared with prior art have fly-ash-contained greatly, mobility, slump, workability are good, durability degree
Height, later strength increasing degree is big, the advantage reduced than common complex cement cost.
Detailed description of the invention:
To meeting three grades of flyash of national standard JC/T409-2001 " silicate building products flyash " or two grades
Raw material powder coal ash, to former flyash storehouse, is then put into bistrique air flume, by bistrique air by flyash air pump after metering
Skewed slot delivers into bistrique elevator, is lifted into ultra-fine ball mill through bistrique elevator, adds in bistrique porch and accurately claims
The exciting agent of flyash weight 0.8% of amount, the grinding aid of 0.05%, flyash is milled into semi-finished product in ball mill, and half
Finished product sends into mill tail elevator through mill tail air flume, enters powder concentrator through mill tail elevator, and the fine powder selected is through bag type dust collection
Device becomes standard compliant finished product after gathering dust, meet less than 10 μm particles ratios more than 95%, be conveyed into into by finished product
Product storehouse, non-compliant semi-finished product return to bistrique elevator, enter described ball mill and again grind, select powder, gather dust.Warehouse for finished product
In superfined flyash high performance composite can dispatch from the factory or be packaged into bag by tank car is in bulk.
Embodiment 1
Now producing 10-20% in 32.5 cement by mixing outside the present invention, mix homogeneously is tested, tested cement mortar
The each age strength of test block is held essentially constant, and cement grade is constant, and cost reduces 10-20 yuan/ton;Existing producing will be mixed outside the present invention
10-15% in label 42.5 cement, mix homogeneously tests, and each age strength of tested cement mortar test block keeps substantially
Constant, cement grade is constant, and cost reduces 15-30 yuan/ton.
Embodiment 2
By in the pure clinker aggregate portland cement mixing label 52.5 outside the present invention, mix homogeneously produces 42.5 and 32.5 water
Mud.Outer incorporation 40-50% mix homogeneously, can produce 42.5 cement, and outer incorporation 60-70% can produce 32.5 cement.Produced water
Mud is higher than ordinary fly ash portland cement early strength, and gain in strength is fast, and workability is good, and durability degree is high, and later strength increases
Amplitude is big, reduces 30-60 yuan/ton than common complex cement cost.
Embodiment 3
The present invention is used in C40 and C30 label commerical ready-mixed concrete, substitutes selecting crude drugs with winnower grey, the Binder Materials such as breeze and cement,
Substituting volume 50-70%, 28 days strength ratio normal concrete intensity exceeds 3-6MPa, and cost declines 10-30 unit/m3, its flowing
The performance such as property, slump, workability is superior to former normal concrete.
Claims (4)
1. a high-performance composite materials activation superfined flyash preparation method, it is characterised in that to meeting national standard JC/
Three grades of flyash of T409-2001 " silicate building products flyash " or second class powered coal ash air pump extremely former flyash storehouse,
Then raw material powder coal ash is put into bistrique air flume after metering, bistrique air flume deliver into bistrique elevator, warp
Bistrique elevator is lifted into ultra-fine ball mill, adds the exciting of flyash weight 0.8% of accurate weighing in bistrique porch
Agent, the grinding aid of 0.05%, flyash is milled into semi-finished product in ball mill, and semi-finished product send into mill tail through mill tail air flume
Elevator, enters powder concentrator through mill tail elevator, and the fine powder selected becomes standard compliant one-tenth after bag filter gathers dust
Product, meet less than 10 μm particles ratios more than 95%, finished product are conveyed into warehouse for finished product, and non-compliant semi-finished product return to
Bistrique elevator, enters described ball mill and again grinds, selects powder, gathers dust, and the high-performance composite materials activation in warehouse for finished product is ultra-fine
Flyash can dispatch from the factory by tank car is in bulk or be packaged into bag.
The application of high-performance composite materials activation superfined flyash prepared by preparation method the most according to claim 1, its
Being characterised by its outer incorporation is now produced 10-20% in 32.5 cement, mix homogeneously is tested, tested cement mortar test block
Each age strength is held essentially constant, and cement grade is constant;Its outer incorporation is now produced 10-15% in label 42.5 cement, mixing
Uniformly testing, each age strength of tested cement mortar test block is held essentially constant, and cement grade is constant.
The application of high-performance composite materials activation superfined flyash prepared by preparation method the most according to claim 1, its
It is characterised by that mix homogeneously produces 42.5 and 32.5 cement by its outer pure clinker aggregate portland cement mixing label 52.5;Outward
Mixing 40-50% mix homogeneously, can produce 42.5 cement, outer incorporation 60-70% can produce 32.5 cement.
The application of high-performance composite materials activation superfined flyash prepared by preparation method the most according to claim 1, its
It is characterised by using it in C40 and C30 label commerical ready-mixed concrete, substitutes selecting crude drugs with winnower ash, breeze and cement, substitute volume 50-
70%, within 28 days, strength ratio normal concrete intensity exceeds 3-6MPa, and its mobility, slump, workability are superior to former benchmark and mix
Solidifying soil.
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CN201310375580.8A CN104370486B (en) | 2013-08-16 | 2013-08-16 | High-performance composite materials activation superfined flyash preparation technology and application |
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CN104370486B true CN104370486B (en) | 2016-12-28 |
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Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107056101B (en) * | 2017-06-20 | 2019-06-21 | 苏州宇希新材料科技有限公司 | A kind of environment-friendly type energy-saving construction material |
CN107216084B (en) * | 2017-06-20 | 2019-06-21 | 苏州宇希新材料科技有限公司 | A kind of activation method of environment-friendly type energy-saving construction material flyash |
CN109721262A (en) * | 2019-03-11 | 2019-05-07 | 无锡市金希达新型建材有限公司 | A kind of superfined flyash and preparation method thereof |
CN111574154A (en) * | 2020-05-25 | 2020-08-25 | 威海冠宏商品混凝土有限公司 | Method for preparing conventional concrete by using high-grade cement |
CN112024094B (en) * | 2020-08-17 | 2022-03-29 | 陕西正元麟电环保产业有限公司 | Superfine fly ash production system and production process |
CN116675449A (en) * | 2023-04-10 | 2023-09-01 | 盐城工学院 | Activation of low-grade fly ash and cement material prepared from same |
Citations (4)
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CN1238311A (en) * | 1998-06-08 | 1999-12-15 | 曹龙 | High-efficacy mixed material and its production method |
CN101367631A (en) * | 2008-09-27 | 2009-02-18 | 天津水泥工业设计研究院有限公司 | Ultra-fine coal ash based composite mineral blending material and manufacturing method thereof |
CN101654342A (en) * | 2008-08-22 | 2010-02-24 | 陈海焱 | Method for preparing microfine fly ash by comprehensively utilizing low-grade heat source and special equipment thereof |
CN101870563A (en) * | 2010-06-28 | 2010-10-27 | 长治市漳山建材有限公司 | Fly ash composition, and preparation method and application thereof |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2010163348A (en) * | 2008-12-16 | 2010-07-29 | Hiroshima Univ | Fly ash concrete |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1238311A (en) * | 1998-06-08 | 1999-12-15 | 曹龙 | High-efficacy mixed material and its production method |
CN101654342A (en) * | 2008-08-22 | 2010-02-24 | 陈海焱 | Method for preparing microfine fly ash by comprehensively utilizing low-grade heat source and special equipment thereof |
CN101367631A (en) * | 2008-09-27 | 2009-02-18 | 天津水泥工业设计研究院有限公司 | Ultra-fine coal ash based composite mineral blending material and manufacturing method thereof |
CN101870563A (en) * | 2010-06-28 | 2010-10-27 | 长治市漳山建材有限公司 | Fly ash composition, and preparation method and application thereof |
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Effective date of registration: 20180703 Address after: 037034 Donghe he village, Ma Jun Ying Township, southern suburb of Datong, Shanxi Patentee after: Shanxi and Zheng environmental building materials Co., Ltd. Address before: 045000 8 floor, Huatong building, 188 South Da Xi Street, Yangquan, Shanxi. Patentee before: Shanxi Huatong Lantian Environmental Protection Co., Ltd. |
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Granted publication date: 20161228 Termination date: 20200816 |