CN104362411A - Aluminum alloy air battery system - Google Patents
Aluminum alloy air battery system Download PDFInfo
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- CN104362411A CN104362411A CN201410690605.8A CN201410690605A CN104362411A CN 104362411 A CN104362411 A CN 104362411A CN 201410690605 A CN201410690605 A CN 201410690605A CN 104362411 A CN104362411 A CN 104362411A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
- H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
- H01M12/065—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode with plate-like electrodes or stacks of plate-like electrodes
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Abstract
The invention relates to an aluminum alloy air battery system which comprises a shell and a liquid storage tank, wherein the shell is internally provided with an anode and a cathode; the anode is provided with an anode extraction electrode, and the cathode is provided with a cathode extraction electrode; the shell is also internally provided with an electrolyte solution; the anode is an aluminum-sodium alloy or an aluminum-potassium alloy; the electrolyte solution is sodium hydroxide or potassium hydroxide correspondingly; the liquid storage tank is connected with the shell through a pipeline, and the pipeline is provided with an electrolyte pump so that the electrolyte solution flows between the liquid storage tank and the shell. According to the aluminum alloy air battery system, the aluminum-sodium alloy or the aluminum-potassium alloy is adopted as the anode, so that the sodium hydroxide content or potassium hydroxide content of the electrolyte solution can not be reduced; the specific energy and specific power of a battery can be enhanced, and high discharge velocity is achieved. The aluminum alloy air battery system disclosed by the invention has the characteristics of high efficiency, high practicability, low self-corrosion reaction rate and stability and controllability in work.
Description
Technical field
The present invention relates to the technical field of metal-air cell, particularly a kind of aluminium alloy air battery system.
Background technology
In known metal-air chemical cell, aluminum-air cell principle and the present invention are the most close.Aluminum-air cell utilizes aluminium as the anode of battery, and catalytic oxygen does negative electrode, strong alkali solution as electrolyte solution, when there is chemical reaction respectively at the two poles of the earth in aluminium and oxygen, battery discharge.The chemical reaction that example that to take electrolyte as NaOH (the very close electrolyte solution of chemical property of potassium and sodium also available hydrogen potassium oxide solution replaces NaOH potassium solution) solution be now occurs in battery has:
Anode: 4Al-12e=4Al3
+
Negative electrode: 3O
2+ 6H
2o+12e=12OH
-
Net reaction: 4Al+3O
2+ 6H
2o+4NaOH=4NaAl (OH) 4+E (electricity) ↑+H (heat) ↑
4NaAl(OH)4＝4NaOH+4Al(OH)3
Anode surface can occur from rotten reaction simultaneously:
2Al+6H
2O+2NaOH＝2NaAl(OH)4+3H
2↑
The maximum advantage of aluminum-air cell is for providing the continuation of the journey of ultra-long time for various power consumption equipment, and in automobile continuation of the journey power supply, preferably record changes an aluminum-air cell course continuation mileage to reach 1600 kilometers at present.The actual specific energy of 2014 on the books aluminum-air cells reaches 350wh/kg, is 8 times of lead-acid battery, 5.8 times of Ni-MH battery, 2.3 times of lithium battery.But the theoretical energy values of aluminum-air cell is 8100wh/kg, this means that aluminum current air cell has a large amount of energy to be wasted, the specific energy of battery needs significantly to be improved.By analyzing the biggest factor that known certainly rotten reaction is aluminum-air cell energy reactive power consumption, the self discharge effect that battery occurs after quitting work simultaneously is also another factor of energy content of battery reactive power consumption.Current another reason of restriction aluminum-air cell large-scale application is that discharge rate is too slow, voltage delay, be immersed in electrolyte solution because current aluminum-air cell adopts the pure aluminum plate of 99.99% to do anode mostly, certain with electrolyte solution contacts face sizes values like this, and this value is little, so the aluminium atomic quantity participating in chemical reaction is certain and the less battery discharge that causes of numerical value is slow, and the velocity of discharge is uncontrollable.When aluminum-air cell works, also create a large amount of heats while aluminium and oxygen generation chemical reaction generating electric energy, get rid of not in time if amount of heat is assembled in battery, light then battery operated instability can be caused, heavy then cause cell damage, even can blast, produce safety problem.Current aluminum-air cell is a set of simple and effective heat-extraction system and method not.Therefore, only have and the above-mentioned bottleneck problem of aluminum-air cell effectively solved, aluminum-air cell just can be used widely.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of aluminium alloy air battery system, and can improve specific energy and the specific power of battery, the velocity of discharge is fast.In preferred scheme, the velocity of discharge of battery is controlled, concentration of electrolyte solutions is not elongated in time and reduce, less from corruption reaction, self discharge reaction reactive power consumption aluminium, electrolyte solution automatically can input, discharge, air automatically can input, discharge, and is convenient to heat radiation, reduces the security risk produced because of heat.
For solving the problems of the technologies described above, the technical solution adopted in the present invention is: a kind of aluminium alloy air battery system, comprise housing, anode and negative electrode is provided with in housing, anode is provided with anode extraction electrode, and negative electrode is provided with negative electrode extraction electrode, is also provided with electrolyte solution in housing, described anode is aluminium sodium alloy or aluminium potassium-sodium alloy, and electrolyte solution is correspondingly NaOH or potassium hydroxide.
Preferably, in aluminium sodium alloy, the volume ratio of sodium is 0.1 ~ 30%;
In aluminium potassium-sodium alloy, the volume ratio of potassium is 0.1 ~ 30%.
Preferred further, in aluminium sodium alloy, the volume ratio of sodium is 4%;
In aluminium potassium-sodium alloy, the volume ratio of potassium is 4%.
Described anode is provided with multiple vertical columnar gap.
Preferably, be also provided with fluid reservoir, fluid reservoir is connected with enclosure interior by pipeline, and pipeline is provided with electrolyte pump, flows between fluid reservoir and housing to make electrolyte solution.
Preferably, described negative electrode is concrete dynamic modulus money base catalytic cathode plate, and negative electrode is positioned at the below of anode, and negative electrode top is provided with gas skirt, and blast pipe upper end open is positioned at the position near gas skirt inner top;
Blast pipe is communicated with exhaust pump, and be connected with air inlet pipe bottom concrete dynamic modulus money base catalytic cathode plate, air inlet pipe is communicated with air intake pump;
The first liquid level sensor and the second liquid level sensor is also provided with in gas skirt.
Preferably, described negative electrode is slidably supported in insulated enclosure shell by multiple support wheel, and can fluctuate.
Preferably, be also provided with heat-pipe radiating apparatus, heat pipe evaporation ends is positioned at housing, and condensation end is connected with radiating fin, in housing, be also provided with temperature sensor.
Preferably, case top is also provided with hydrogen discharge pipe, and hydrogen discharge pipe is provided with hydrogen waste cock valve, is provided with hydrogen gas concentration sensor in housing.
Preferably, case top at least diagonal position is provided with inversion electrolyte exudate pipe, is inverted electrolyte exudate pipe and is provided with the first inversion-prevention valve and the second inversion-prevention valve, be inverted on electrolyte exudate pipe and be also provided with inversion-prevention pump, be also provided with inversion-prevention switch at housing.
A kind of aluminium alloy air battery system provided by the invention, the beneficial effect had is as follows:
1, by galvanic anode being adopted aluminium sodium alloy or aluminium potassium-sodium alloy, NaOH correspondingly in electrolyte solution or potassium hydroxide are slowly supplemented all the time, concentration of electrolyte solutions is not elongated in time to be reduced by the trace acidic gas consumption in air gradually, because battery discharge is also relevant with concentration of electrolyte solutions, therefore this structure can increase the stability of cell discharge performance.Its principle is when battery operated, because the active character of metal of sodium or potassium is better than aluminium, can prior to aluminium generation chemical reaction at the sodium of anode surface or potassium atom, as follows for sodium reactional equation:
Anode: 4Na-4e=4Na
+
Negative electrode: O2+2H
2o+4e=4OH
-
Net reaction: 4Na+O
2+ 2H
2o=4NaOH
Reaction end product is NaOH or potassium hydroxide, supplements into electrolyte solution.
Anode adopts aluminium sodium alloy or aluminium potassium-sodium alloy, and sodium or potassium proportional amount are between 0.1%-30%, and NaOH or potassium hydroxide content in electrolyte solution can not be declined.And after sodium or potassium formerly reacts, have spot corrosion effect for anode, also can accelerate follow-up reaction rate.
2, as shown in Figure 1, by by the vibrational power flow of anode being, the bulk of multiple columnar gap or column Al alloy block or aluminum alloy sheet is had from bottom to end face, make anode increase can with the contact area of electrolyte solution contacts, can battery discharge be increased substantially compared with the simple aluminium sheet of same volume.Anode adopts this structure also for the present invention realizes the velocity of discharge and can control to provide necessary condition.Battery discharge control principle is: by rising or reducing the electrolyte solution liquid level in battery, change the contact area size of anode and electrolyte solution, thus the electric speed that control battery is put.
The present invention is by adopting aluminium sodium alloy or aluminium potassium-sodium alloy to do after anode contains the acting in conjunction of columnar gap structure with anode, and the velocity of discharge significantly improves compared with existing monomer-type pure aluminum plate air cell.
3, as shown in Figure 1, by arranging the external fluid reservoir of electrolyte solution, fluid,matching level sensor and electrolyte pump, the liquid surface lifting control system of electrolyte solution is realized.Namely be equivalent to control the depth that anode immerses electrolyte solution, thus control the velocity of discharge of battery.When battery does not need work, electrolyte solution liquid level can be down to below anode bottom face by electrolyte solution liquid surface lifting control system, anode is made to depart from electrolyte solution, so not only stop the self discharge reaction of battery because of not used time generation, and reacting from corruption of a large amount of reactive power consumption anode is now also stopped, the aluminium avoided in anode is wasted in a large number, thus significantly improves the specific energy of aluminium sodium alloy air cell.
After electrolyte solution liquid surface lifting control system coordinates jointly, the anode consumed from rotten reaction significantly reduces, and specific energy significantly improves compared with existing monomer-type pure aluminum plate air cell.
And after electrolyte solution liquid surface lifting control system coordinates jointly, the velocity of discharge realizes controlling.
4, as shown in Figure 1, the negative electrode made by concrete dynamic modulus money base catalytic air cathode plate by the oxygen catalytic in air, at negative electrode generation chemical reaction after make oxygen obtain electronics that anode electrode transports.By installing the float of enough buoyancy additional at the both sides side-lower of concrete dynamic modulus money base catalytic air cathode plate, multiple support wheel is respectively installed in both sides, and the mode that top arranges spacing screen keeps the object of fixed range and attitude stabilization with anode all the time to reach negative electrode, thus make battery discharge more stable.By installing gas skirt additional to collect the surplus air consuming oxygen above negative electrode.Avoid oxygen loss everywhere in the battery residual in surplus air, the aluminium directly and in anode and sodium generation chemical reaction, thus avoid the reactive power consumption energy content of battery.Oxygen is provided to concrete dynamic modulus money base catalytic air cathode plate by air inlet pipe.Discharged the air in gas skirt by the blast pipe in gas skirt, preferably, the top of blast pipe is positioned at the top of gas skirt.Make air automatically input timely and to discharge by air inlet, gas exhaust inspecting, ensure the normal work of battery.Cathode construction of the present invention and respective air be defeated, heat-extraction system automatically, makes discharge performance more stable.
5, as shown in Figure 1, the heat pipe made by utilizing heat pipe principle, the structure of heat exchanger fin and fin, coordinate temperature sensor and control device composition battery automatic radiating system, the heat produced when the present invention is battery operated is constantly expelled to outside battery, avoid inside battery to cause internal temperature of battery too high because of heat accumulation, and produce adverse consequences.Automatic radiating system makes battery realize high efficiency and heat radiation.
6, the row's hydrogen device arranged and inversion-prevention device, the safety guaranteeing battery can be had, when density of hydrogen is higher, unnecessary hydrogen is discharged from hydrogen discharge pipe, when battery occurs inverted, for avoiding security incident, be discharged in fluid reservoir by electrolyte solution by inversion-prevention pump, inversion-prevention pump is by extra powered battery.
Accompanying drawing explanation
Below in conjunction with drawings and Examples, the invention will be further described:
Fig. 1 is overall structure schematic diagram of the present invention.
In figure: anode 1, metal sealing shell 2, insulating material capsul 3, column hole 4, electrolyte solution 5, gas skirt 6, support wheel 7, float 8, concrete dynamic modulus money base catalytic cathode plate 9, first liquid level sensor 10, air inlet pipe 11, blast pipe 12, negative electrode extraction electrode 13, second liquid level sensor 14, 3rd liquid level sensor 15, temperature sensor 16, air intake pump 17, exhaust pump 18, inversion-prevention switch 19, control device 20, rechargeable battery 21, fan 22, the electrolyte solution 23 stored, fluid reservoir 24, positive displacement pump 25, infusion pump 26, liquid pipe 27, heat pipe 28, radiating fin 29, inversion-prevention pump 30, second inversion-prevention valve 31, anode extraction electrode 32, hydrogen gas concentration sensor 33, hydrogen waste cock valve 34, hydrogen discharge pipe 35, be inverted electrolyte exudate pipe 36, first inversion-prevention valve 37, spacing screen 38, negative electrode 39.
Embodiment
As shown in fig. 1, a kind of aluminium alloy air battery system, comprise housing, housing in this example adopts double-deck structure, internal layer adopts corrosion resistant plastics, outer employing metal material, anode 1 and negative electrode 39 is provided with in housing, anode is provided with anode extraction electrode 32, negative electrode is provided with negative electrode extraction electrode 13 provides power supply respectively to external world negative pole and positive pole by wire, for connecting load, is also provided with electrolyte solution 5 in housing, described anode 1 is aluminium sodium alloy or aluminium potassium-sodium alloy, and electrolyte solution 5 is correspondingly NaOH or potassium hydroxide.
Preferably, in aluminium sodium alloy, the volume ratio of sodium is 0.1 ~ 30%;
In aluminium potassium-sodium alloy, the volume ratio of potassium is 0.1 ~ 30%.
Preferably, in aluminium sodium alloy, the volume ratio of sodium is 3 ~ 12%;
In aluminium potassium-sodium alloy, the volume ratio of potassium is 3 ~ 12%.
Preferred further, in aluminium sodium alloy, the volume ratio of sodium is 4%;
In aluminium potassium-sodium alloy, the volume ratio of potassium is 4%.NaOH or potassium hydroxide content in electrolyte solution can not be declined.Improve the stability of battery discharge.
Described anode 1 is provided with multiple vertical columnar gap 104.To increase the contact area with electrolyte solution.For guaranteeing that area increases and reduce the retention wire sexual intercourse along with liquid level lifting, therefore, this example have employed vertical columnar gap 104 structure.
Preferred as in Fig. 1, be also provided with fluid reservoir 24, fluid reservoir 24 is connected with enclosure interior by pipeline, and pipeline is provided with electrolyte pump, flows between fluid reservoir 24 and housing to make electrolyte solution.When needs increase energy output, infusion pump 26 starts, and is input in housing by electrolyte solution, and when needs reduce energy output, electrolyte solution is drained in fluid reservoir 24 by positive displacement pump 25.Infusion pump 26 and positive displacement pump 25 can be driven by self power generation, also can arrange independent battery-operated.
When the present invention needs to quit work, control device 20 drives positive displacement pump 25 to be discharged in fluid reservoir 24 from the housing of battery by liquid pipe 27 by electrolyte solution, until stop when the 3rd liquid level sensor 15 provides the signal of electrolyte solution liquid level.Anode is now made to depart from electrolyte solution, so not only stop the self discharge reaction of battery because of not used time generation, and reacting from corruption of a large amount of reactive power consumption anode is now also stopped, the aluminium avoided in anode is wasted in a large number, thus significantly improves the specific energy of aluminium sodium alloy air cell.According to the voltage exported or electric current, control the height of electrolyte solution submergence anode 1, the size of output voltage or electric current can be controlled.
Preferably as Fig. 1, in this example, employing negative electrode is positioned at the structure below anode, and described negative electrode is concrete dynamic modulus money base catalytic cathode plate 9, and negative electrode top is provided with gas skirt 6, and blast pipe 12 upper end open is positioned at the position near gas skirt 6 inner top;
Blast pipe 12 is communicated with exhaust pump 18, and be connected with air inlet pipe 11 bottom concrete dynamic modulus money base catalytic cathode plate 9, air inlet pipe 11 is communicated with air intake pump 17;
The first liquid level sensor 10 and the second liquid level sensor 14 is also provided with in gas skirt 6.In use, air intake pump 17 continuous firing, gas enters into concrete dynamic modulus money base catalytic cathode plate 9 by air inlet pipe 11, and the oxygen in air issues biochemical reaction in the catalysis of silver-based material, and is consumed.Consumed the air of oxygen through the upwards loss of crinosity pore money base catalytic air cathode plate 6, whole collection is covered by gas collection 4, when the gas produced in course of reaction makes the gas in gas skirt 6 too much, now the second liquid level sensor 14 obtains liquid level signal, driving control device, such as single-chip microcomputer, start the exhaust pump 18 on blast pipe 12, unnecessary gas is discharged, until stop when the first liquid level sensor 10 obtains liquid level signal.
Preferably, described negative electrode is slidably supported in insulated enclosure shell 3 by multiple support wheel 7, and fluctuates.At negative electrode, multiple float is installed, float to make negative electrode, spacing screen 38 is provided with at the top of negative electrode, to make to keep suitable distance between negative electrode and positive electrode, under the driving of float, whole negative electrode is tending towards upwards floating, until spacing screen 38 touches the lower end of anode 1, thus the distance limited between negative electrode and positive electrode, to obtain best generating efficiency.Due to anode continuous loss of meeting in power generation process, negative electrode can continue to float after anode loss, remains between negative electrode and positive electrode to be best generator compartment distance.Support wheel 7 is for making negative electrode more steady in location free procedure.
Preferably, be also provided with heat abstractor, heat pipe 28 evaporation ends is positioned at housing, and condensation end is connected with radiating fin 29, and radiating fin 29 side is provided with fan 22, in housing, be also provided with temperature sensor 16.Heat is directed to radiating fin 29 by heat pipe 28, is then dispelled the heat by fan.Fan in this example is preferably by independently powered battery.
Preferably, case top is also provided with hydrogen discharge pipe 35, and hydrogen discharge pipe 35 is provided with hydrogen waste cock valve 34, is provided with hydrogen gas concentration sensor 33 in housing.When density of hydrogen being detected higher than set point, namely control device 20 controls hydrogen waste cock valve 34 and opens, and discharges hydrogen, guarantees cell safety.
Preferably, case top at least diagonal position is provided with inversion electrolyte exudate pipe 36, be inverted electrolyte exudate pipe 36 and be provided with the first inversion-prevention valve 37 and the second inversion-prevention valve 31, be inverted on electrolyte exudate pipe 36 and be also provided with inversion-prevention pump 30, be also provided with inversion-prevention switch 19 at housing.Structure thus, when battery topples, inversion-prevention switch 19 sends signal, the inversion-prevention valve that control device 20 controls to be positioned among now the first inversion-prevention valve 37 and the second inversion-prevention valve 31 below is opened, inversion-prevention pump 30 starts simultaneously, electrolyte solution is discharged into fluid reservoir 24, to guarantee safety.Further preferred, inversion-prevention pump 30, first inversion-prevention valve 37 and the second inversion-prevention valve 31 adopt extra battery-operated, to avoid cannot obtaining power supply when aluminium alloy air cell breaks down.Preferred further, be also provided with security solenoid valve, security solenoid valve, obtaining electricity condition closedown, is opened, is made the electrolyte solution in aluminium alloy air cell emptying under power failure state.
The above embodiments are only the preferred technical solution of the present invention; and should not be considered as restriction of the present invention; the technical scheme that protection scope of the present invention should be recorded with claim, the equivalents comprising technical characteristic in the technical scheme of claim record is protection range.Namely the equivalent replacement within the scope of this improves, also within protection scope of the present invention.
Claims (10)
1. an aluminium alloy air battery system, comprise housing, anode (1) and negative electrode (39) is provided with in housing, anode is provided with anode extraction electrode (32), negative electrode is provided with negative electrode extraction electrode (13), also be provided with electrolyte solution (5) in housing, it is characterized in that: described anode (1) is aluminium sodium alloy or aluminium potassium-sodium alloy, and electrolyte solution (5) is correspondingly NaOH or potassium hydroxide.
2. a kind of aluminium alloy air battery system according to claim 1, is characterized in that: in aluminium sodium alloy, the volume ratio of sodium is 0.1 ~ 30%;
In aluminium potassium-sodium alloy, the volume ratio of potassium is 0.1 ~ 30%.
3. a kind of aluminium alloy air battery system according to claim 2, is characterized in that: in aluminium sodium alloy, the volume ratio of sodium is 4%;
In aluminium potassium-sodium alloy, the volume ratio of potassium is 4%.
4. a kind of aluminium alloy air battery system according to claim 1, is characterized in that: described anode (1) is provided with multiple vertical columnar gap (104).
5. a kind of aluminium alloy air battery system according to claim 1, it is characterized in that: be also provided with fluid reservoir (24), fluid reservoir (24) is connected with enclosure interior by pipeline, pipeline is provided with electrolyte pump, flows between fluid reservoir (24) and housing to make electrolyte solution.
6. a kind of aluminium alloy air battery system according to claim 5, it is characterized in that: described negative electrode is concrete dynamic modulus money base catalytic cathode plate (9), negative electrode is positioned at the below of anode (1), negative electrode top is provided with gas skirt (6), and blast pipe (12) upper end open is positioned at the position near gas skirt (6) inner top;
Blast pipe (12) is communicated with exhaust pump (18), and concrete dynamic modulus money base catalytic cathode plate (9) bottom is connected with air inlet pipe (11), and air inlet pipe (11) is communicated with air intake pump (17);
The first liquid level sensor (10) and the second liquid level sensor (14) is also provided with in gas skirt (6).
7. a kind of aluminium alloy air battery system according to claim 6, is characterized in that: described negative electrode is slidably supported in insulated enclosure shell (3) by multiple support wheel (7), and fluctuates.
8. a kind of aluminium alloy air battery system according to claim 6, it is characterized in that: be also provided with heat abstractor, heat pipe (28) evaporation ends is positioned at housing, and condensation end is connected with radiating fin (29), is also provided with temperature sensor (16) in housing.
9. a kind of aluminium alloy air battery system according to claim 1 or 5, it is characterized in that: case top is also provided with hydrogen discharge pipe (35), hydrogen discharge pipe (35) is provided with hydrogen waste cock valve (34), is provided with hydrogen gas concentration sensor (33) in housing.
10. a kind of aluminium alloy air battery system according to claim 1 or 5, it is characterized in that: case top at least diagonal position is provided with inversion electrolyte exudate pipe (36), be inverted electrolyte exudate pipe (36) and be provided with the first inversion-prevention valve (37) and the second inversion-prevention valve (31), be inverted on electrolyte exudate pipe (36) and be also provided with inversion-prevention pump (30), be also provided with inversion-prevention switch (19) at housing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410690605.8A CN104362411B (en) | 2014-11-18 | 2014-11-18 | Aluminium alloy air battery system |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410690605.8A CN104362411B (en) | 2014-11-18 | 2014-11-18 | Aluminium alloy air battery system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104362411A true CN104362411A (en) | 2015-02-18 |
| CN104362411B CN104362411B (en) | 2018-12-07 |
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ID=52529651
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|---|---|---|---|
| CN201410690605.8A Expired - Fee Related CN104362411B (en) | 2014-11-18 | 2014-11-18 | Aluminium alloy air battery system |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113690469A (en) * | 2021-08-25 | 2021-11-23 | 浙江大学 | Aluminum-water electrochemical cell system |
| CN114335759A (en) * | 2020-09-25 | 2022-04-12 | 包头昊明稀土新电源科技有限公司 | Separated liquid type long-life water system power battery and preparation method thereof |
| CN115939450A (en) * | 2022-12-20 | 2023-04-07 | 河南科技大学 | Aluminum-potassium ferricyanide energy-saving battery circulating device |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202737061U (en) * | 2012-04-10 | 2013-02-13 | 德阳东深新能源科技有限公司 | High-power aluminum-air battery system |
| CN103125047A (en) * | 2010-10-07 | 2013-05-29 | 住友化学株式会社 | Air battery |
| JP2014203552A (en) * | 2013-04-02 | 2014-10-27 | 冨士色素株式会社 | Metal air battery |
-
2014
- 2014-11-18 CN CN201410690605.8A patent/CN104362411B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103125047A (en) * | 2010-10-07 | 2013-05-29 | 住友化学株式会社 | Air battery |
| CN202737061U (en) * | 2012-04-10 | 2013-02-13 | 德阳东深新能源科技有限公司 | High-power aluminum-air battery system |
| JP2014203552A (en) * | 2013-04-02 | 2014-10-27 | 冨士色素株式会社 | Metal air battery |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114335759A (en) * | 2020-09-25 | 2022-04-12 | 包头昊明稀土新电源科技有限公司 | Separated liquid type long-life water system power battery and preparation method thereof |
| CN114335759B (en) * | 2020-09-25 | 2023-07-25 | 包头昊明稀土新电源科技有限公司 | Chaotropic long-life water system power battery and preparation method thereof |
| CN113690469A (en) * | 2021-08-25 | 2021-11-23 | 浙江大学 | Aluminum-water electrochemical cell system |
| CN115939450A (en) * | 2022-12-20 | 2023-04-07 | 河南科技大学 | Aluminum-potassium ferricyanide energy-saving battery circulating device |
| CN115939450B (en) * | 2022-12-20 | 2024-04-12 | 河南科技大学 | Aluminum-potassium ferricyanide energy-saving battery circulating device |
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| CN104362411B (en) | 2018-12-07 |
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Granted publication date: 20181207 Termination date: 20211118 |