CN104356750A - Low-smoke and environment-friendly water-based ink containing sandalwood powder - Google Patents
Low-smoke and environment-friendly water-based ink containing sandalwood powder Download PDFInfo
- Publication number
- CN104356750A CN104356750A CN201410541591.3A CN201410541591A CN104356750A CN 104356750 A CN104356750 A CN 104356750A CN 201410541591 A CN201410541591 A CN 201410541591A CN 104356750 A CN104356750 A CN 104356750A
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- CN
- China
- Prior art keywords
- parts
- water
- ink
- sandalwood powder
- resin emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to the field of printing ink, in particular to low-smoke and environment-friendly water-based ink containing sandalwood powder. The ink is prepared by raw materials in parts by weight as follows: 1-2 parts of ammonium polyphosphate, 3-6 parts of shinyleaf yellowhorn oil, 0.1-0.2 parts of cyclopropylboronic acid, 1-1.5 parts of ethy diaminedhephen acetic-Na, 0.01-0.02 parts of sandalwood powder, 20-25 parts of water-based amino resin emulsion with solid content accounting for 50%-60%, 10-18 parts of water-based acrylic resin emulsion with solid content accounting for 40%-50%, 1-3 parts of sldium lauryl sulfate, 10-15 parts of pigments, 18-25 parts of deionized water and 1-2 parts of an auxiliary. According to the ink, water-based amino resin emulsion and water-based acrylic resin emulsion are mixed to be taken as vehicle, the mixture of the pigments and the sandalwood powder treated by a mixed aqueous solution of raw materials including ammonium polyphosphate, cyclopropylboronic acid, shinyleaf yellowhorn oil and the like has good dispersive capacity and flame retarding effect, the auxiliary can improve wettability of the ink, and the condition that the decoration effect is influenced by coating bubbles is prevented; and the ink is safe, non-toxic, environment-friendly, lasting in fragrance, good in printing effect and durable in use and produces little smoke when burnt.
Description
Technical field
The present invention relates to printing-ink field, be specifically related to a kind of low cigarette Environmental-protection water-based ink containing Sandalwood powder.
Background technology
Ink is a class coloured material very conventional in daily life, it is by the mode of the printing carrier as word and pattern, it is the gluey fluid of a kind of stickiness, be widely used in the various printings such as books and periodicals, packing and decorating, building decoration, along with social demand increases, ink kind and output is respective extension and growth also, improves the use properties of ink, and the production model reaching efficient energy-saving is the inevitable direction of following ink development all the time.
The factor affecting the use properties of ink is mainly the performance of the moietys such as pigment, low-melting ink vehicle, stopping composition and auxiliary agent, and such as pigment affects weather resistance and the tinting strength of ink; Low-melting ink vehicle directly affects set speed, the rate of drying and printing quality etc. of ink.Therefore, improve the use properties of ink, the performance from improving these compositions is needed to set about, improve the consistency between each raw material simultaneously, reach collaborative effect promoted, thus improve existing ink ubiquitous heap ink, fall the problems such as printing quality such as version, scumming, dirty version, set-off, to enhance productivity, avoid the waste of resource.
Summary of the invention
The object of the invention is to, provide a kind of low cigarette Environmental-protection water-based ink containing Sandalwood powder, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of low cigarette Environmental-protection water-based ink containing Sandalwood powder, it is characterized in that, this ink is made up of the raw material of following weight part: water-borne acrylic resin emulsion 10-18, sodium laurylsulfate 1-3, pigment 10-15, deionized water 18-25, auxiliary agent 1-2 that the water-compatible amino resin emulsion 20-25 that the adjacent sodium 1-1.5 of ammonium polyphosphate 1-2, shinyleaf yellowhorn oil 3-6, cyclopropylboronic acid 0.1-0.2, quadrol two, Sandalwood powder 0.01-0.02, solid content are 50-60%, solid content are 40-50%;
The raw material of following weight part is comprised: trolamine 0.1-0.2, alumina sol 4-6, microfine diatomaceous 1-2, limonene 1-2, dehydrated alcohol 3-5, nano rare earth cerium colloidal sol 0.2-0.4 in described auxiliary agent, preparation method is: first by trolamine, the abundant stirring and dissolving of limonene in dehydrated alcohol, add microfine diatomaceous subsequently, after ground and mixed 30-40min, gained pulp concentration is dry, the powder obtained mixes with alumina sol, nano rare earth cerium colloidal sol again, after complete dispersed with stirring is even.
Described a kind of low cigarette Environmental-protection water-based ink containing Sandalwood powder, its preparation method is: be first dissolved in deionized water by ammonium polyphosphate, cyclopropylboronic acid, sodium laurylsulfate, and Sandalwood powder, shinyleaf yellowhorn oil, pigment are put in solution, after dispersed with stirring 1-2h, regulator solution pH is weakly alkaline, then adds other remaining component, continue to be stirred to material and dissolve dispersion completely, all drop into fully grinding in sand mill again, make the particle diameter of gained slurry be≤20 μm, to obtain final product.
Ink prepared by the present invention mixes as low-melting ink vehicle using water-compatible amino resin emulsion and aqueous acrylic emulsion, there is good stability and adhesive ability, pigment after the mixed aqueous solution process of ammonium polyphosphate, cyclopropylboronic acid, Wood of Shinyleaf Yellowhorn wet goods raw material and Sandalwood powder, there is good dispersive ability and flame retardant effect, also effectively extend the work-ing life of Sandalwood powder simultaneously, prevent its premature deterioration from degenerating, thus make goods can keep unique santal for a long time, in addition, the auxiliary agent added can improve the wettability of ink, prevents coating bubbles and affects decorative effect; Ink asepsis environment-protecting of the present invention, fragrant odour is unique, and printing effect is good, and durable in use, during burning, smoke which is few, more Environmental Safety.
Embodiment
Embodiment
Printing-ink prepared by the present embodiment is made up of the raw material of following weight part: water-borne acrylic resin emulsion 12, sodium laurylsulfate 2, pigment 12, deionized water 25, auxiliary agent 1.5 that the water-compatible amino resin emulsion 25 that the adjacent sodium 1.5 of ammonium polyphosphate 1, shinyleaf yellowhorn oil 3, cyclopropylboronic acid 0.1, quadrol two, Sandalwood powder 0.01, solid content are 60%, solid content are 50%; Wherein auxiliary agent is made up of the raw material of following weight part: trolamine 0.1, alumina sol 4, microfine diatomaceous 1, limonene 2, dehydrated alcohol 5, nano rare earth cerium colloidal sol 0.2, preparation method is: first by trolamine, the abundant stirring and dissolving of limonene in dehydrated alcohol, add microfine diatomaceous subsequently, after ground and mixed 30min, gained pulp concentration is dry, the powder obtained mixes with alumina sol, nano rare earth cerium colloidal sol again, after complete dispersed with stirring is even.
The preparation method of this printing-ink is: be first dissolved in deionized water by ammonium polyphosphate, cyclopropylboronic acid, sodium laurylsulfate, and Sandalwood powder, shinyleaf yellowhorn oil, pigment are put in solution, after dispersed with stirring 1.5h, regulator solution pH is weakly alkaline, add other remaining component again, continue to be stirred to material and dissolve dispersion completely, more all drop into fully grinding in sand mill, make the particle diameter of gained slurry be≤20 μm, to obtain final product.
By the ink printing obtained by the present embodiment on paper, after its complete drying, this ink in the performance test results of substrate surface is:
Above-mentioned test is all followed relevant criterion and is carried out.
Claims (2)
1. the low cigarette Environmental-protection water-based ink containing Sandalwood powder, it is characterized in that, this printing-ink is made up of the raw material of following weight part: water-borne acrylic resin emulsion 10-18, sodium laurylsulfate 1-3, pigment 10-15, deionized water 18-25, auxiliary agent 1-2 that the water-compatible amino resin emulsion 20-25 that the adjacent sodium 1-1.5 of ammonium polyphosphate 1-2, shinyleaf yellowhorn oil 3-6, cyclopropylboronic acid 0.1-0.2, quadrol two, Sandalwood powder 0.01-0.02, solid content are 50-60%, solid content are 40-50%;
Described auxiliary agent is made up of the raw material of following weight part: trolamine 0.1-0.2, alumina sol 4-6, microfine diatomaceous 1-2, limonene 1-2, dehydrated alcohol 3-5, nano rare earth cerium colloidal sol 0.2-0.4, preparation method is: first by trolamine, the abundant stirring and dissolving of limonene in dehydrated alcohol, add microfine diatomaceous subsequently, after ground and mixed 30-40min, gained pulp concentration is dry, the powder obtained mixes with alumina sol, nano rare earth cerium colloidal sol again, after complete dispersed with stirring is even.
2. a kind of low cigarette Environmental-protection water-based ink containing Sandalwood powder as claimed in claim 1, its preparation method is: be first dissolved in deionized water by ammonium polyphosphate, cyclopropylboronic acid, sodium laurylsulfate, and Sandalwood powder, shinyleaf yellowhorn oil, pigment are put in solution, after dispersed with stirring 1-2h, regulator solution pH is weakly alkaline, then adds other remaining component, continue to be stirred to material and dissolve dispersion completely, all drop into fully grinding in sand mill again, make the particle diameter of gained slurry be≤20 μm, to obtain final product.
Priority Applications (1)
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CN201410541591.3A CN104356750A (en) | 2014-10-14 | 2014-10-14 | Low-smoke and environment-friendly water-based ink containing sandalwood powder |
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CN201410541591.3A CN104356750A (en) | 2014-10-14 | 2014-10-14 | Low-smoke and environment-friendly water-based ink containing sandalwood powder |
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CN104356750A true CN104356750A (en) | 2015-02-18 |
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CN201410541591.3A Pending CN104356750A (en) | 2014-10-14 | 2014-10-14 | Low-smoke and environment-friendly water-based ink containing sandalwood powder |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08218026A (en) * | 1995-02-17 | 1996-08-27 | Toyo Ink Mfg Co Ltd | Aqueous printing ink composition |
CN1290728A (en) * | 2000-10-26 | 2001-04-11 | 中山大学 | Water ink for plastic film relief printing and its producing method |
CN1547604A (en) * | 2001-08-28 | 2004-11-17 | ���Ͽع�����˾ | Water-based screen printing ink |
CN103319945A (en) * | 2013-06-05 | 2013-09-25 | 苏州凹凸彩印厂 | Green intaglio ink for wallpapers and preparation method thereof |
-
2014
- 2014-10-14 CN CN201410541591.3A patent/CN104356750A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08218026A (en) * | 1995-02-17 | 1996-08-27 | Toyo Ink Mfg Co Ltd | Aqueous printing ink composition |
CN1290728A (en) * | 2000-10-26 | 2001-04-11 | 中山大学 | Water ink for plastic film relief printing and its producing method |
CN1547604A (en) * | 2001-08-28 | 2004-11-17 | ���Ͽع�����˾ | Water-based screen printing ink |
CN103319945A (en) * | 2013-06-05 | 2013-09-25 | 苏州凹凸彩印厂 | Green intaglio ink for wallpapers and preparation method thereof |
Non-Patent Citations (2)
Title |
---|
尹卫平等: "《精细化工产品及工艺》", 31 August 2009, 华东理工大学出版社 * |
朱万强: "《涂料基础教程》", 30 June 2013, 西南交通大学出版社 * |
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Application publication date: 20150218 |