CN104350351B - Heat exchanger - Google Patents

Heat exchanger Download PDF

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Publication number
CN104350351B
CN104350351B CN201380029506.9A CN201380029506A CN104350351B CN 104350351 B CN104350351 B CN 104350351B CN 201380029506 A CN201380029506 A CN 201380029506A CN 104350351 B CN104350351 B CN 104350351B
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CN
China
Prior art keywords
raceway groove
heat exchanger
medium
collection
wall
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201380029506.9A
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Chinese (zh)
Other versions
CN104350351A (en
Inventor
S·凯泽
M·贝尔瑙尔
S·布伦纳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Linde GmbH
Original Assignee
Linde GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Publication of CN104350351A publication Critical patent/CN104350351A/en
Application granted granted Critical
Publication of CN104350351B publication Critical patent/CN104350351B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/001Casings in the form of plate-like arrangements; Frames enclosing a heat exchange core
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/02Header boxes; End plates
    • F28F9/026Header boxes; End plates with static flow control means, e.g. with means for uniformly distributing heat exchange media into conduits
    • F28F9/0265Header boxes; End plates with static flow control means, e.g. with means for uniformly distributing heat exchange media into conduits by using guiding means or impingement means inside the header box
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D21/00Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
    • F28D21/0017Flooded core heat exchangers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/16Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D9/00Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D9/0006Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the plate-like or laminated conduits being enclosed within a pressure vessel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F13/00Arrangements for modifying heat-transfer, e.g. increasing, decreasing
    • F28F13/06Arrangements for modifying heat-transfer, e.g. increasing, decreasing by affecting the pattern of flow of the heat-exchange media

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Details Of Heat-Exchange And Heat-Transfer (AREA)

Abstract

The present invention relates to a kind of heat exchanger (1) for the indirect heat transfer being used between first medium (F1) and second medium (F2), including:Housing (2) with the shell space (3) for receiving first medium (F1), block (4) configuration conduct heat in shell space (3), and surrounded during correct operation by first medium (F1), wherein, heat transfer block (4) is designed in the presence of first medium (F1) cool down second medium (F2), and thus gas phase (G1) formation of first medium is in shell space (3).According to the present invention, the gas phase (G1) that raceway groove (5) is provided for extracting out first medium from shell space (3) is collected in shell space (3).

Description

Heat exchanger
Technical field
The present invention relates to a kind of heat exchanger.
Background technology
In " the The Standards of The Brazed Aluminium Plate-Fin Heat of the 3rd edition in 2010 In Exchanger Manufacturer ' s Association (ALPEMA) " this heat exchanger is illustrated in the Fig. 9-1 of page 67 Feature.It has the housing for enclosing shell space, it may have at least one heat transfer block (" core body "), and it is configured described Shell space is interior and is designed as the heat exchanger of tabular.This design of heat exchanger be also referred to as " core body is in housing " or " block is in housing " heat exchanger.
Using this heat exchanger, first medium especially can be with second medium (for example, the gas phase or cooled being liquefied Liquid phase) directly conducted heat, wherein, first medium formd during heat exchanger operation cladding heat transfer block bath , and (thermosyphon action) is risen bottom-up (along vertical direction) in heat transfer block, wherein, second medium is preferably It is directed with first medium with adverse current or crossing current mode in heat transfer block body.The first medium of gas phase heat transfer block above Occur during the collection in shell space, and be extracted by least one Outlet connector being arranged on housing, And raceway groove may be collected by (outside) in the outside for being arranged on housing and be supplied to another procedure of processing.
Due to the extraction of such gas phase, the gas phase advanced towards Outlet connector is developed in shell space The velocity field of isomery, this weakens the quality of the gas-liquid separation in shell space.This effect can be by the number of Outlet connector The change of amount or size is offset, but is only cancelled limited scope, especially because the stream in collected outside raceway groove Velocity field of the dynamic characteristic also to the gas phase in shell space works.In addition, Outlet connector is referred in introductory section The piezoresistive components part of (" core body is in housing ") heat exchanger of type, thus involve great expense, in multiple Outlet connectors In the case of necessarily increase production cost.In addition, by causing Outlet connector position to be fixed on the upside of housing, around construction During part (for example, cold box, field pipe), the free degree is reduced.
The content of the invention
From here on, therefore the present invention provides improved heat exchanger regarding to the issue above based on the purpose.
The problem is solved by the heat exchanger of the present invention.
It thus provides collection channel is located in shell space and is designed to from shell space extract gas phase out.
According to one embodiment of present invention, multiple heat transfer blocks or tabular heat exchange are also provided in shell space Device, it can for example be operated in parallel or in series.
Generally, the heat exchanger of this tabular has multiple plates of configuration parallel to each other, and forms and changed for participation The substantial amounts of heat exchanger channels of the medium of heat.One preferred embodiment of the heat exchanger of tabular has multiple corrugated platings (so-called Fin), it is all configured between the plate of two parallel separation of plate heat exchanger in each case, wherein, the plate Two outermost layers of shape heat exchanger are formed by cover plate.So, medium can be flowed by it substantial amounts of parallel channel or change The passage of heat formation each two separate plate between or separation plate and cover plate between because in each case at them it Between configure fin.The medium that is flowed in adjacent heat exchanger channels thus can exchanged heat indirectly.Towards sidepiece, in each two phase Between the plate of adjacent separation, or between cover plate and the plate of adjacent separation, it is preferably provided with band (so-called side Column), for closing corresponding heat exchanger channels.Cover plate, separating plate, fin and sidebar are preferably produced by aluminium, and for example in stove In be welded together.By the corresponding collector with connector, medium can be introduced in heat exchanger channels or from these It is extracted in passage.
The housing of heat exchanger, which can especially have, surrounds (circle) cylindrical wall, its configuration in the particular design of heat exchanger It is preferably oriented under state so that the longitudinal axis (axle of cylindricality) of wall or housing extends along horizontal direction.Housing is preferably With wall relative to each other, it is connected on the wall on end face, and is extended transverse to level or the longitudinal axis.
The collection raceway groove of gas phase for extracting first medium out is preferably connected (for example in the way of flowing guiding By pipe) on Outlet connector, the Outlet connector is especially configured in the upside of the housing so that the gas phase of first medium It can be extracted from shell space by those Outlet connectors.
In one embodiment of the invention, collect raceway groove along bearing of trend to extend, the bearing of trend is oriented parallel In the longitudinal axis (axle of cylindricality) of housing or along horizontal direction, and in this case it is preferable to transverse to described The tubulose (circle) of bearing of trend (longitudinal axis) or box-like (rectangle) cross section.
Raceway groove (configuration status on the particular design of heat exchanger) is collected preferably in the ullage of first medium Or be configured in the top of heat transfer block along vertical direction in shell space so that (from heat transfer block) of first medium The gas phase of rising is contacted with collecting raceway groove.
Collect raceway groove preferably have enclose collect raceway groove inner space wall, gas phase can in the inner space court Flowed to the Outlet connector.In this case, the upside or edge of the sensing heat exchanger of each wall of raceway groove are collected The upside that the part that vertical direction is directed upwards towards is referred to as collecting raceway groove, the downside of the sensing heat exchanger of the wall of raceway groove is collected The part being oppositely arranged therefore constitute collect raceway groove downside.The upper side and lower side of raceway groove is collected preferably by collecting ditch The side wall in road is interconnected, longitudinal axis extension of the side wall along housing.In end, raceway groove is collected preferably by relative to each other End face is limited, and the end face relative to each other all causes upside, downside and side wall to interconnect in each case.
Variant of the invention is additionally provided with, and one or more in the above-mentioned part of the wall for collecting raceway groove can be by The housing of heat exchanger is formed.The upside for collecting raceway groove or the upside for the wall for collecting raceway groove are preferably formed by housing.The side Wall and end face are thus correspondingly attached on housing away from shell space.
In order to extract gas phase out, the collection raceway groove preferably has multiple ingates, and it, which is particularly formed in, collects raceway groove On downside (bottom), also, it is also formed in if appropriate on the side wall relative to each other for collecting raceway groove.In this case, shape Slit-like design is preferably into the ingate on the bottom for collecting raceway groove, and the ingate being arranged on the wall of side preferably has There is circular contour (for example, hole).
Preferably, the interval direction of the interval in adjacent entries hole and the ingate being in particular arranged on downside is collected The respective end face of raceway groove is reduced.That is, with (on bearing of trend) more towards the two of the middle part configuration for collecting raceway groove Individual adjacent ingate is compared, closer to two adjacent ingate raceway groove preferably edges of the end face positioning for collecting raceway groove The bearing of trend for collecting raceway groove on having smaller interval each other.
Quantity, distribution, the size and/or shape of ingate are preferably selected such that the first medium in raceway groove is collected The velocity field of gas phase to be configured to numerical value consistent as much as possible.In addition, according to an aspect of the present invention, collecting raceway groove and (hanging down It is straight in collecting in the plane of bearing of trend of raceway groove) cross-sectional area (and profile, if appropriate) select in this way Select:The flow field of the gas phase of first medium as uniform as possible is based upon in collection raceway groove and in shell space.Preferably, collect The cross section of raceway groove is widened/increased towards Outlet connector, and/or, the restriction of the ingate in raceway groove is collected configures knot Structure, shapes and sizes contribute to this.
In addition, housing can also have multiple Outlet connectors originally, it can connect on collection raceway groove, as described above, Or be connectable on multiple collection raceway grooves of the type illustrated before.
These positions for collecting raceway groove, size and orientation preferably so selection in this case so that empty in housing Between in it is respective collection raceway groove in first medium gas phase velocity field be established as it is numerically as consistent as possible.
In addition, at least one Outlet connector (or, even more than Outlet connector) can according to the present invention by with Put on the upper and lower and side part of the encirclement wall of housing, or be configured in an end-face wall of housing.
Entering for the present invention is illustrated in greater detail by the brief description of the drawings below exemplary embodiments referring to the drawings The details and advantage of one step.The advantageous embodiment of the present invention is disclosed in appended claims in addition.
Brief description of the drawings
In figure:
Fig. 1 shows the sectional view of the heat exchanger according to the present invention;
Fig. 2 shows another sectional view of the heat exchanger according to Fig. 1;With
Fig. 3 shows the sectional view of the collection raceway groove according to Fig. 1 and 2 heat exchanger.
Embodiment
With reference to Fig. 2 and 3, Fig. 1 shows heat exchanger 1, and it has (circle) cylindrical shell 2, the housing 2 of horizontal lying Define the shell space 3 of the heat exchanger 1.In this case, housing 2 has the cylindrical wall 14 surrounded, and it is in end face by two Individual wall 15 relative to each other is limited.
Heat transfer block 4 is configured in the shell space 3 surrounded by housing 2.In this case, it can be with multiple flat The plate heat exchanger of capable heat exchanger channels.
The heat exchanger 4 of the tabular has multiple corrugated platings (so-called fin) in this case, and it is in each case All configure between two flat separated plates of plate heat exchanger 4.So, a large amount of parallel passages or a heat exchange are logical Road formation is between each two separate plates (or a separate plates and a cover plate, referring to following), and corresponding medium can flow Pass through the passage.Two outermost layers are formed by the cover plate of plate heat exchanger, and sealed strip (so-called " sidebar ") is towards side Portion is arranged between the adjacent separated plate of each two or between separated plate and cover plate.
Shell space 3 is filled with first medium F1 during heat exchanger 1 is operated so that first medium F1 liquid phase L1 shapes Into the outdoor bathing place for surrounding heat transfer block or plate heat exchanger 4, wherein, the first medium F1 developed during operation gas phase G1 can be gathered in shell space 3 above liquid phase L1.
First medium (liquid phase L1) F1 can rise in heat transfer block 4 (in the heat exchanger channels of association), and in the mistake Because the indirect heat transfer by second medium F2 is partly evaporated in journey, second medium F2 will be cooled and for example pass It is directed in the heat exchanger channels of the association of hot block 4 with first medium F1 crossing currents.The first medium F1's produced in this period Gas phase G1 can be discharged in the upper end of block 4, and be risen in the shell space 3 of heat exchanger 1 with the speed v of determination.
Second medium F2 is directed into heat transfer block by suitable entrance O (such as by the connector on top cover) Or in plate heat exchanger 4, and by exporting O ' (such as by corresponding top cover after the heat exchanger channels by association Be connected to connector thereon) be extracted from block 4.
On the upside 8 of heat exchanger 1, in housing 2 on the inner side 2a of shell space 3, configuration is box-packed receipts Collect raceway groove 5, it extends along bearing of trend 7.The collection raceway groove 5 in particular elongated design in this case, and thus along Bearing of trend 7 with the horizontal direction of bearing of trend 7 than having bigger extension.
Collecting raceway groove 5 also has wall W, and which defines the inner space I for collecting raceway groove 5, and first medium F1 gas phase G1 is extracted out by the inner space from shell space 3.Wall W especially has upside 9, and in the case that this is current, upside 9 is by housing 2 form, and also have two side walls 11 from its extension, and the side wall 11 extends along bearing of trend 7 and by collecting ditch The bottom (downside) 10 relative with upside 9 in road 5 is interconnected.In addition, collecting raceway groove 5 or its wall W has two end faces 11a, 11b, it is set relative to one another along bearing of trend 7.
In order to extract first medium F1 gas phase G1 out from shell space 3, now collect the side wall 11 of raceway groove 5 and/or There is provided slit-like ingate 12 (being the slit-like ingate on downside 10 in current situations), gas on its downside 10 Phase G1 can be entered by the ingate in collection raceway groove 5.In this case, ingate 12 is adjacent each other along bearing of trend 7 Configuration, wherein, preferably connected in each case from outlet along the distance between adjacent ingate 13 of bearing of trend 7 Device 6 is initially towards two end face 11a, 11b reductions for collecting raceway groove 5.In this case, the longitudinal axis of these ingates 12 is every kind of In the case of all transverse to collect raceway groove 5 bearing of trend 7 extend.
In addition, in each case, there is provided round entrance on the side wall 11 for collecting raceway groove 5 and/or on downside 10 Hole 13 (being in the current situation the circular entry 13 on side wall 11), it is also along the configuration adjacent each other of bearing of trend 7.This Outside, along distance of the bearing of trend 7 between adjacent ingate 12 preferably in each case all from the court of Outlet connector 6 To two end face 11a, 11b reductions for collecting raceway groove 5.
Collect the Outlet connector 6 that raceway groove 5 is also coupled to open housing 2 in the upside 9 for collecting raceway groove 5 so that The first medium F1 entered by ingate 12,13 in the inner space I for collecting raceway groove 5 gas phase G1 can be by outlet Connector 6 is extracted from raceway groove 5 is collected.
Outlet connector 6 is arranged preferably in the middle part for collecting raceway groove 5 along bearing of trend 7, wherein, the collection raceway groove 5 downside 10 preferably has two parts 10a, 10b, and they are tilted down towards Outlet connector 6, and preferably in institute The lower section for stating Outlet connector 6 connects.
The cross section of raceway groove 5 is collected in each case along the direction of Outlet connector 6 from the end face of collection raceway groove 5 11a, 11b increase (widening), with (and in shell space 3) acquisition first medium as uniform as possible in raceway groove 5 is collected F1 gas phase G1 velocity field v.Reference numerals list

Claims (18)

1. the heat exchanger (1) for the indirect heat transfer that one kind is used between first medium (F1) and second medium (F2), has:
- housing (2), it has the shell space (3) for being used for receiving the first medium (F1),
- at least one heat transfer block (4), it is configured in the shell space (3), and by institute during specified design is operated First medium (F1) encirclement is stated, wherein, the heat transfer block (4) is designed in the presence of the first medium (F1) So that the second medium (F2) cools down and/or liquefied at least in part, thus gas phase (G1) formation of the first medium exists In the shell space (3),
- wherein, it is provided for extracting out the collection raceway groove of the gas phase (G1) of the first medium from the shell space (3) (5), it is located in the shell space (3), and extends along the bearing of trend of the longitudinal axis orientation parallel to the housing,
- and, wherein at least one described heat transfer block (4) is plate heat exchanger,
- and, wherein the collection raceway groove (5) is connected at least one Outlet connector being arranged on the housing (2) (6) on so that the gas phase (G1) of the first medium can be received by least one described Outlet connector (6) through described Collection raceway groove (5) is extracted from the shell space (3),
- and, wherein the collection raceway groove (5) has two end faces (11a, 11b), its institute along the collection raceway groove (5) Bearing of trend is stated to set relative to one another,
It is characterized in that
- collection the raceway groove (5) has transverse to the cross section of the bearing of trend (7), and it is towards the Outlet connector (6) Increase, and
- collection the raceway groove (5) has the multiple ingates (12,13) for being used for extracting the gas phase out, wherein adjacent ingate Interval towards it is described collection raceway groove (5) respective end face (11a, 11b) reduce.
2. heat exchanger according to claim 1, it is characterised in that the heat transfer block (4) is designed so that described One medium (F1) can rise during the heat exchanger (1) is operated in the heat transfer block (4), wherein, the heat transfer block Body (4) is designed in the heat transfer block (4) by with guiding institute in the way of the first medium (F1) adverse current or crossing current State second medium (F2).
3. the heat exchanger according to claims 1 or 2, it is characterised in that multiple heat transfers of plate heat exchanger form Block (4) is configured in the shell space.
4. the heat exchanger according to claims 1 or 2, it is characterised in that the collection raceway groove (5) has wall (W), its The inner space (I) of the collection raceway groove (5) is defined, the gas phase (G1) of the first medium can be in the inner space (I) flowed in towards the Outlet connector (6), and the wall (W) for collecting raceway groove (5) is along along the housing (2) bearing of trend (7) extension for the level that upside (8) is stretched.
5. heat exchanger according to claim 4, it is characterised in that the collection raceway groove (5) has prolongs transverse to described Stretch box-like or tubulose the cross section in direction (7).
6. heat exchanger according to claim 4, it is characterised in that the wall (W) of the collection raceway groove (5) has upper Side (9) and the downside (10) being oppositely arranged, wherein, the upside (9) of the wall (W) for collecting raceway groove (5) and described Downside (10) is interconnected by the side wall (11) relative to each other of the wall (W) of the collection raceway groove (5).
7. heat exchanger according to claim 6, it is characterised in that one of the wall (W) of the collection raceway groove (5) Part is formed by the housing (2).
8. heat exchanger according to claim 7, it is characterised in that the wall (W) of the collection raceway groove (5) by institute The one part for stating housing (2) formation is the upside (9) of the wall (W) of the collection raceway groove (5).
9. heat exchanger according to claim 7, it is characterised in that at least one Outlet connector (6) configuration exists It is described collect raceway groove (5) the wall (W) on one part that the housing (2) is formed.
10. the heat exchanger according to one of claim 6 to 8, it is characterised in that the collection raceway groove (5) it is described under Side (10) and/or the side wall (11) have multiple ingates (12), and the gas phase (G1) of the first medium can pass through institute Ingate is stated to flow into the collection raceway groove (5).
11. heat exchanger according to claim 10, it is characterised in that the ingate (12) is slit-like.
12. the heat exchanger according to one of claim 6 to 8, it is characterised in that the collection raceway groove (5) it is described under Side (10) and/or the side wall (11) have multiple ingates (13), and the gas phase (G1) of the first medium can pass through institute Ingate is stated to flow into the collection raceway groove (5).
13. heat exchanger according to claim 12, it is characterised in that the ingate (13) is circle.
14. the heat exchanger according to claims 1 or 2, it is characterised in that the heat exchanger (1), which has, passes through institute State and collect the additional Outlet connector (6) that raceway groove (5) is interconnected.
15. the heat exchanger according to claims 1 or 2, it is characterised in that the heat exchanger (1) has substantial amounts of Raceway groove (5) is collected, it is connected at least one Outlet connector (6) in each case.
16. the heat exchanger according to claims 1 or 2, it is characterised in that the housing (2) has transverse to described The cylindricality of bearing of trend (7) surrounds wall (14), and it causes two end-face walls (15) of the housing (2) to interconnect.
17. heat exchanger according to claim 16, it is characterised in that at least one Outlet connector (6) configuration On the encirclement wall (14) of the housing (2), or, at least one Outlet connector (6) configuration is in the housing (2) on one in the end-face wall (15).
18. heat exchanger according to claim 17, it is characterised in that at least one Outlet connector (6) configuration On upper part, side part or the lower part of the encirclement wall (14) of the housing (2).
CN201380029506.9A 2012-06-06 2013-06-06 Heat exchanger Expired - Fee Related CN104350351B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102012011328A DE102012011328A1 (en) 2012-06-06 2012-06-06 Heat exchanger
DE102012011328.5 2012-06-06
PCT/EP2013/001670 WO2013182314A1 (en) 2012-06-06 2013-06-06 Heat exchanger

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Publication Number Publication Date
CN104350351A CN104350351A (en) 2015-02-11
CN104350351B true CN104350351B (en) 2017-08-15

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US (1) US20150153115A1 (en)
EP (1) EP2859295B1 (en)
JP (1) JP6116681B2 (en)
KR (1) KR20150030229A (en)
CN (1) CN104350351B (en)
AU (1) AU2013270937B2 (en)
DE (1) DE102012011328A1 (en)
ES (1) ES2598837T3 (en)
MX (1) MX344387B (en)
WO (1) WO2013182314A1 (en)

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ES2598837T3 (en) 2017-01-30
CN104350351A (en) 2015-02-11
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MX344387B (en) 2016-12-14
DE102012011328A1 (en) 2013-12-12
MX2014014454A (en) 2015-02-12
EP2859295A1 (en) 2015-04-15
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US20150153115A1 (en) 2015-06-04
JP6116681B2 (en) 2017-04-19

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