CN104341853A - Environment-friendly doodle cleaning agent and preparation method thereof - Google Patents
Environment-friendly doodle cleaning agent and preparation method thereof Download PDFInfo
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- CN104341853A CN104341853A CN201410595783.2A CN201410595783A CN104341853A CN 104341853 A CN104341853 A CN 104341853A CN 201410595783 A CN201410595783 A CN 201410595783A CN 104341853 A CN104341853 A CN 104341853A
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- mass parts
- environment
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- out system
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/04—Chemical paint or ink removers with surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D9/00—Chemical paint or ink removers
- C09D9/005—Chemical paint or ink removers containing organic solvents
Abstract
The invention discloses an environment-friendly doodle cleaning agent and a preparation method thereof. The environment-friendly doodle cleaning agent comprises the following raw materials in parts by mass: 20-80 parts of a main solvent, 3-40 parts of a cosolvent, 1-10 parts of an accelerant, 1-5 parts of a thickener, 0.2-8 parts of a surfactant and 1-60 parts of deionized water. The preparation method comprises the following steps: (1) mixing the main solvent, the cosolvent and the accelerant according to the ratio, and stirring evenly to obtain a solution; (2) dissolving the thickener into deionized water, and stirring evenly to obtain a solution; (3) mixing the two solutions, adding the surfactant, and stirring evenly. The doodle cleaning agent disclosed by the invention is environment-friendly, non-toxic, high in cleaning efficiency and good in cleaning effect.
Description
Technical field
The present invention relates to a kind of environment-friendly type scribble clean-out system and preparation method thereof.
Background technology
Scribble refers to the word or pattern scribbled on some curtain walls, and its main component is various paint, wherein based on acrylic paint.Common body material has concrete, metal, marble, glass etc.The worth appreciation of scribble that content is positive, can retain; The scribble that content is vulgar, affects the appearance of the city, must remove.
The method removing scribble is divided into two kinds, Physical and chemical method.Physical comprises: the coating 1, adopting the worn matrix surface of mechanical means.2, pure color paint is adopted.3, laser ablation process is adopted.Physical is easy and simple to handle, but working conditions is severe, and elimination effect is not ideal enough.Comparatively speaking, chemical method is more conventional.Chemical method utilizes clean-out system dissolved by paint film or come off with paint film generation chemical reaction, and reach the object of removing.According to the difference of action principle, chemical can be divided into two classes, and a class is response type, mainly basic solution, utilizes highly basic that macromolecular chain is ruptured, and the small soluble molecules obtained in water or can be washed away, thus obtains the matrix of surface clean.Tian Jingqiang. a kind of paint clean-out system (CN 102964903 A), Pan Zhanchang, Cheng Guo etc. a kind of preparation of aq. type paint remover and the clean-out system described in using method (CN 103013221 A), it is all this type, although they are respond well, but need heating, for the scribble paint film on body of wall, cannot implementation and operation.Another kind of is solvent type, and main representative has methylene dichloride, phenylcarbinol, N-Methyl pyrrolidone and diester etc.Such clean-out system mainly utilizes solvent to the infiltration of macromolecule paint film and swelling action, and paint film and body material bonding force are weakened, thus departs from matrix surface.Such clean-out system cleaning performance is fine, but majority of organic solvent toxicity is comparatively large, volatile, or expensive.Wang Cheng, Wang Wen etc. a kind of paint remover and preparation method thereof and application (CN 102964902 A), James De Keer. the scribble cleaning solution (CN 101517058 A) etc. comprising non-aqueous concentrate and dilute aqueous solution has above-mentioned shortcoming.For above-mentioned situation, research and develop a kind of environmental protection, nontoxic, efficient, the free from corrosion novel scribble clean-out system of matrix is necessary.
Summary of the invention
The object of the present invention is to provide a kind of environment-friendly type scribble clean-out system and preparation method thereof.
The technical solution used in the present invention is:
A kind of environment-friendly type scribble clean-out system, it is made up of the raw material of following mass parts: the main solvent of 20-80 mass parts, the solubility promoter of 3-40 mass parts, the promotor of 1-10 mass parts, the thickening material of 1-5 mass parts, the tensio-active agent of 0.2-8 mass parts, the deionized water of 1-60 mass parts.
A kind of environment-friendly type scribble clean-out system, it is made up of the raw material of following mass parts: the main solvent of 50-80 mass parts, the solubility promoter of 5-10 mass parts, the promotor of 2-5 mass parts, the thickening material of 1.5-4 mass parts, the tensio-active agent of 0.5-7 mass parts, the deionized water of 40-50 mass parts.
Described main solvent is at least one in hexalin, pimelinketone, propyl carbinol, methylcarbonate, dimethyl succinate, Methyl glutarate.
Described solubility promoter is at least one in Virahol, n-propyl alcohol, ethanol, methyl alcohol.
Described promotor is at least one in formic acid, acetic acid, hydrogen peroxide, trolamine.
Described thickening material is at least one in ether of cellulose and derivative thereof, association type alkali swollen thickener, polyurethane thickener.
Described thickening material is ether of cellulose and derivative thereof.
Described tensio-active agent is at least one in aniorfic surfactant, cationic surfactant, nonionic surface active agent, double ion type tensio-active agent.
Described tensio-active agent is nonionic surface active agent.
A preparation method for environment-friendly type scribble clean-out system, step is as follows:
1) by main solvent, solubility promoter, promotor proportionally mixes, and stirs, and obtains solution;
2) thickening material is dissolved in deionized water, stirs, obtain solution;
3) by above two solution mixing, then add tensio-active agent, stir.
The invention has the beneficial effects as follows: scribble clean-out system of the present invention, environment-protecting asepsis, cleaning efficiency is high, and cleaning performance is good.
Embodiment
A kind of environment-friendly type scribble clean-out system, it is made up of the raw material of following mass parts: the main solvent of 20-80 mass parts, the solubility promoter of 3-40 mass parts, the promotor of 1-10 mass parts, the thickening material of 1-5 mass parts, the tensio-active agent of 0.2-8 mass parts, the deionized water of 1-60 mass parts.
Preferably, a kind of environment-friendly type scribble clean-out system, it is made up of the raw material of following mass parts: the main solvent of 50-80 mass parts, the solubility promoter of 5-10 mass parts, the promotor of 2-5 mass parts, the thickening material of 1.5-4 mass parts, the tensio-active agent of 0.5-7 mass parts, the deionized water of 40-50 mass parts.
Described main solvent is at least one in hexalin, pimelinketone, propyl carbinol, methylcarbonate, dimethyl succinate, Methyl glutarate.
Described solubility promoter is at least one in Virahol, n-propyl alcohol, ethanol, methyl alcohol.
Described promotor is at least one in formic acid, acetic acid, hydrogen peroxide, trolamine.
Described thickening material is at least one in ether of cellulose and derivative thereof, association type alkali swollen thickener, polyurethane thickener; Preferably, described thickening material is ether of cellulose and derivative thereof, further preferably, is at least one in methylcellulose gum, carboxymethyl cellulose, Natvosol, Vltra tears.
Described tensio-active agent is at least one in aniorfic surfactant, cationic surfactant, nonionic surface active agent, double ion type tensio-active agent; Preferably, described tensio-active agent is nonionic surface active agent; Further preferred, be at least one in the ethylene oxide adduct of alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid methyl ester ethoxylate, polypropylene glycol, sorbitan ester, sucrose ester, alkylol amide type, non-ion fluorin carbon surface active agent, polyvinylpyrrolidone; Preferred further, be at least one in alkylphenol polyoxyethylene, fatty alcohol oxyethylene ether, polyvinylpyrrolidone, sapn, tween.
The present invention is described further to solve specific embodiment below:
embodiment 1:
A kind of raw material of environment-friendly type scribble clean-out system consists of the following composition:
table 1: the raw material composition of environment-friendly type scribble clean-out system
embodiment 2:
A kind of raw material of environment-friendly type scribble clean-out system consists of the following composition:
table 2: the raw material composition of environment-friendly type scribble clean-out system
embodiment 3:
A kind of raw material of environment-friendly type scribble clean-out system consists of the following composition:
table 3: the raw material composition of environment-friendly type scribble clean-out system
embodiment 4:
A kind of raw material of environment-friendly type scribble clean-out system consists of the following composition:
table 4: the raw material composition of environment-friendly type scribble clean-out system
After testing: the clean-out system of embodiment 1-4 has good elimination effect for the scribble paint of metal, glass, marble surface, and 1mL clean-out system can remove about 20cm
2scribble, and to matrix not damaged.
embodiment 5:
A kind of raw material of environment-friendly type scribble clean-out system consists of the following composition:
table 5: the raw material composition of environment-friendly type scribble clean-out system
embodiment 6:
A kind of raw material of environment-friendly type scribble clean-out system consists of the following composition:
table 6: the raw material composition of environment-friendly type scribble clean-out system
embodiment 7:
A kind of raw material of environment-friendly type scribble clean-out system consists of the following composition:
table 7: the raw material composition of environment-friendly type scribble clean-out system
After testing, the clean-out system of embodiment 5-7 has good elimination effect for the scribble paint of plastics, metal, glass, marble surface, and 1mL clean-out system can remove about 20cm
2scribble, and to matrix not damaged, especially to plastic substrate, swelling, deliquescing can not be caused.Just can clean up within general 10 minutes for the scribble on plastics, marble, metallic matrix, matrix is without obvious corrosion; For the scribble paint on glass, within about 5 minutes, just can clean up.
Claims (10)
1. an environment-friendly type scribble clean-out system, it is characterized in that: it is made up of the raw material of following mass parts: the main solvent of 20-80 mass parts, the solubility promoter of 3-40 mass parts, the promotor of 1-10 mass parts, the thickening material of 1-5 mass parts, the tensio-active agent of 0.2-8 mass parts, the deionized water of 1-60 mass parts.
2. a kind of environment-friendly type scribble clean-out system according to claim 1, it is characterized in that: it is made up of the raw material of following mass parts: the main solvent of 50-80 mass parts, the solubility promoter of 5-10 mass parts, the promotor of 2-5 mass parts, the thickening material of 1.5-4 mass parts, the tensio-active agent of 0.5-7 mass parts, the deionized water of 40-50 mass parts.
3. a kind of environment-friendly type scribble clean-out system according to claim 1, is characterized in that: described main solvent is at least one in hexalin, pimelinketone, propyl carbinol, methylcarbonate, dimethyl succinate, Methyl glutarate.
4. a kind of environment-friendly type scribble clean-out system according to claim 1, is characterized in that: described solubility promoter is at least one in Virahol, n-propyl alcohol, ethanol, methyl alcohol.
5. a kind of environment-friendly type scribble clean-out system according to claim 1, is characterized in that: described promotor is at least one in formic acid, acetic acid, hydrogen peroxide, trolamine.
6. a kind of environment-friendly type scribble clean-out system according to claim 1, is characterized in that: described thickening material is at least one in ether of cellulose and derivative thereof, association type alkali swollen thickener, polyurethane thickener.
7. a kind of environment-friendly type scribble clean-out system according to claim 6, is characterized in that: described thickening material is ether of cellulose and derivative thereof.
8. a kind of environment-friendly type scribble clean-out system according to claim 1, is characterized in that: described tensio-active agent is at least one in aniorfic surfactant, cationic surfactant, nonionic surface active agent, double ion type tensio-active agent.
9. a kind of environment-friendly type scribble clean-out system according to claim 8, is characterized in that: described tensio-active agent is nonionic surface active agent.
10. the preparation method of a kind of environment-friendly type scribble clean-out system according to claim 1, is characterized in that: step is as follows:
1) by main solvent, solubility promoter, promotor proportionally mixes, and stirs, and obtains solution;
2) thickening material is dissolved in deionized water, stirs, obtain solution;
3) by above two solution mixing, then add tensio-active agent, stir.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410595783.2A CN104341853A (en) | 2014-10-30 | 2014-10-30 | Environment-friendly doodle cleaning agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410595783.2A CN104341853A (en) | 2014-10-30 | 2014-10-30 | Environment-friendly doodle cleaning agent and preparation method thereof |
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| CN104341853A true CN104341853A (en) | 2015-02-11 |
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| CN201410595783.2A Pending CN104341853A (en) | 2014-10-30 | 2014-10-30 | Environment-friendly doodle cleaning agent and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104804515A (en) * | 2015-04-23 | 2015-07-29 | 广东工业大学 | Novel environment-friendly nontoxic paint remover and preparation method thereof |
| CN105219152A (en) * | 2015-11-10 | 2016-01-06 | 荆门市拓达科技有限公司 | A kind of efficient paint remover |
| CN107619621A (en) * | 2017-10-11 | 2018-01-23 | 厦门大学 | A kind of clothing ink blok removes composition |
| CN107987604A (en) * | 2018-01-24 | 2018-05-04 | 深圳市瑞世兴科技有限公司 | A kind of sapphire glass detergent for ink and preparation method thereof |
| CN109517429A (en) * | 2017-09-20 | 2019-03-26 | 蓝思科技（长沙）有限公司 | For stripping the deinking agent, aluminium alloy spraying clamp tool deinking process and aluminium alloy spraying clamp tool of aluminium alloy spraying clamp tool ink |
| CN110041749A (en) * | 2019-04-28 | 2019-07-23 | 祝亚琴 | A kind of paint stripper of metal surface polyurethane paint |
| CN110713747A (en) * | 2019-10-09 | 2020-01-21 | 房新民 | Environment-friendly and nontoxic water-based paint remover and preparation method thereof |
| CN111073382A (en) * | 2019-12-30 | 2020-04-28 | 郑州轻工业大学 | Novel environment-friendly cleaning agent and preparation method and application thereof |
| CN112481051A (en) * | 2020-06-19 | 2021-03-12 | 新安洁环境卫生股份有限公司 | Marking pen cleaning agent, preparation method thereof and marking pen mark cleaning method |
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| CN101319105A (en) * | 2008-07-18 | 2008-12-10 | 东南大学 | Paint stripper of oil emulsion-in-water |
| CN101684213A (en) * | 2009-07-31 | 2010-03-31 | 南京师范大学 | Multifunctional chorine-free and benzene-free compound paint stripper and production method thereof |
| EP2669341A1 (en) * | 2012-06-01 | 2013-12-04 | LCM GmbH | Cleaning agent |
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| CN101319105A (en) * | 2008-07-18 | 2008-12-10 | 东南大学 | Paint stripper of oil emulsion-in-water |
| CN101684213A (en) * | 2009-07-31 | 2010-03-31 | 南京师范大学 | Multifunctional chorine-free and benzene-free compound paint stripper and production method thereof |
| EP2669341A1 (en) * | 2012-06-01 | 2013-12-04 | LCM GmbH | Cleaning agent |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104804515A (en) * | 2015-04-23 | 2015-07-29 | 广东工业大学 | Novel environment-friendly nontoxic paint remover and preparation method thereof |
| CN105219152A (en) * | 2015-11-10 | 2016-01-06 | 荆门市拓达科技有限公司 | A kind of efficient paint remover |
| CN109517429A (en) * | 2017-09-20 | 2019-03-26 | 蓝思科技（长沙）有限公司 | For stripping the deinking agent, aluminium alloy spraying clamp tool deinking process and aluminium alloy spraying clamp tool of aluminium alloy spraying clamp tool ink |
| CN109517429B (en) * | 2017-09-20 | 2022-02-08 | 蓝思科技（长沙）有限公司 | Deinking agent for removing ink of aluminum alloy spraying clamp jig, deinking process of aluminum alloy spraying clamp jig and aluminum alloy spraying clamp jig |
| CN107619621A (en) * | 2017-10-11 | 2018-01-23 | 厦门大学 | A kind of clothing ink blok removes composition |
| CN107987604A (en) * | 2018-01-24 | 2018-05-04 | 深圳市瑞世兴科技有限公司 | A kind of sapphire glass detergent for ink and preparation method thereof |
| CN110041749A (en) * | 2019-04-28 | 2019-07-23 | 祝亚琴 | A kind of paint stripper of metal surface polyurethane paint |
| CN110713747A (en) * | 2019-10-09 | 2020-01-21 | 房新民 | Environment-friendly and nontoxic water-based paint remover and preparation method thereof |
| CN111073382A (en) * | 2019-12-30 | 2020-04-28 | 郑州轻工业大学 | Novel environment-friendly cleaning agent and preparation method and application thereof |
| CN111073382B (en) * | 2019-12-30 | 2022-04-05 | 郑州轻工业大学 | Novel environment-friendly cleaning agent and preparation method and application thereof |
| CN112481051A (en) * | 2020-06-19 | 2021-03-12 | 新安洁环境卫生股份有限公司 | Marking pen cleaning agent, preparation method thereof and marking pen mark cleaning method |
| CN112481051B (en) * | 2020-06-19 | 2022-02-22 | 新安洁环境卫生股份有限公司 | Marking pen cleaning agent, preparation method thereof and marking pen mark cleaning method |
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Application publication date: 20150211 |
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