CN104332587B - The structure of a kind of aluminum alloy anode and manufacture method - Google Patents
The structure of a kind of aluminum alloy anode and manufacture method Download PDFInfo
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- CN104332587B CN104332587B CN201410424756.9A CN201410424756A CN104332587B CN 104332587 B CN104332587 B CN 104332587B CN 201410424756 A CN201410424756 A CN 201410424756A CN 104332587 B CN104332587 B CN 104332587B
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- aluminium alloy
- alloy plate
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/06—Electrodes for primary cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/06—Electrodes for primary cells
- H01M4/08—Processes of manufacture
- H01M4/12—Processes of manufacture of consumable metal or alloy electrodes
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- Chemical Kinetics & Catalysis (AREA)
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- General Chemical & Material Sciences (AREA)
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Abstract
The present invention discloses structure and the manufacture method of a kind of aluminum alloy anode, including aluminium alloy plate, aluminium alloy plate reinforcement, insulating seal, conductive current collector, in the network of aluminium alloy plate reinforcement, aluminium alloy plate is set, insulating seal and conductive current collector are arranged on the one end of the unitary block of aluminum alloy electrode being made up of some aluminium alloy plates, and conductive current collector is sealed in insulated enclosure body.Technical solution of the present invention solves the thinning problem even rupturing the internal short-circuit of battery caused and the product gathering increase internal resistance of cell that the aluminium alloy negative pole in existing aluminium-air cell exists at discharge process.
Description
Technical field
The invention belongs to energy technology field, particularly to structure and the manufacture method thereof of a kind of aluminum alloy anode.
Background technology
Aluminium-air cell is a kind of novel high specific energy electrochmical power source, it with aluminium alloy electric extremely negative pole, air electrode as positive pole, neutral or alkaline aqueous solution as electrolyte, cell operation externally exports electric energy by consuming the oxygen in aluminium alloy negative pole and air.Aluminium-air cell is not required to charging, can run with maintenance battery last by supplementing the aluminium alloy negative material consumed in cell operation, therefore also referred to as metal fuel battery.Neutral aluminium-air cell is with saline solution or sea water as electrolyte, and alkalescence aluminium-air cell is with sodium hydroxide or potassium hydroxide as electrolyte.
It is presently used for the structure of the aluminium alloy negative pole of aluminium-air cell, is with screw or rivet, conductive current collector to be fixed on the suitable aluminium alloy plate of size.The subject matter that the aluminium alloy negative pole of this simple structure exists is that, in the continuous discharge process of aluminium-air cell, aluminum alloy anode constantly consumes, and aluminium sheet is the most thinning is even broken into several pieces, contacts with air electrode and causes short circuit.Additionally, the product being deposited on aluminum alloy anode is mixed between aluminium alloy plate and conductive current collector, dramatically increase the internal resistance of cell.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, for solving the thinning problem even rupturing the internal short-circuit of battery caused and the product gathering increase internal resistance of cell that the aluminium alloy negative pole in existing aluminium-air cell exists at discharge process, propose structure of a kind of novel aluminum alloy electrode and preparation method thereof, to solve the problems referred to above that existing aluminum alloy anode exists.
The technical purpose of the present invention is achieved by following technical proposals:
A kind of structure of aluminum alloy anode, including aluminium alloy plate, aluminium alloy plate reinforcement, insulating seal, conductive current collector, wherein:
Described aluminium alloy plate reinforcement is network, it is arranged on the outside of aluminium alloy plate, arrange around aluminium alloy plate, it can not only fix aluminium alloy plate, the most also aluminium alloy plate is stoped to contact with air electrode, thus prevent aluminium-air cell from running or storing or in handling process, internal short-circuit of battery；
Aluminium alloy plate is set in the network of described aluminium alloy plate reinforcement, selects to be fixed together between described aluminium alloy plate reinforcement and aluminium alloy plate, or be not fixed together；Being shaped as of described aluminium alloy plate is square, rhombus or circle；
Described insulating seal and conductive current collector are arranged on the one end of the unitary block of aluminum alloy electrode being made up of some (one or more) aluminium alloy plate, to ensure that the electric current that aluminum alloy anode produces can flow through conductive current collector output smoothly, described conductive current collector is selected to be fastened on aluminium alloy plate；Described conductive current collector is sealed in insulated enclosure body, with ensure aluminium-air cell run or store or handling process in, electrolyte or electrode reaction product will not contact with conductive current collector.
Described aluminium alloy plate selects Aluminium Alloys in Common Use material, is formed by by metallic aluminium and alloying element.
Described aluminium alloy plate reinforcement selects electrical-insulation polymeric material, or electric insulation Inorganic Non-metallic Materials.
Described insulating seal selects electrical-insulation polymeric material, or electric insulation Inorganic Non-metallic Materials.
The above-mentioned novel aluminum alloy electrode structure of the present invention is prepared by following method:
Choose aluminum alloy materials and be cut into the aluminium alloy plate of electrode size, conductive current collector is fixed on aluminium alloy plate, again with insulating sealing materials by be fixed on the conductive current collector on aluminium alloy plate and conductive current collector be connected with aluminium alloy plate position seal, form the insulating seal of aluminum alloy anode, finally use aluminium alloy plate reinforcement material, with net (grid) shape form, aluminium alloy plate is wrapped, form aluminium alloy electric electrode structure.
The method on aluminium alloy plate that conductive current collector is fixed on has: the method 1) using welding, conductive current collector is welded together with aluminium alloy plate；2) use screw or the method for rivet interlacement, conductive current collector is linked together with aluminium alloy plate；3) method using conducting resinl bonding, is bonded together conductive current collector with aluminium alloy plate；4) method using direct pressing, directly presses together conductive current collector with aluminium alloy plate, and formation is fastenedly connected.
The position that conductive current collector and conductive current collector is connected with aluminium alloy plate seals, the method forming aluminum alloy anode insulating seal has: the method 1) using injection, the position that conductive current collector and conductive current collector is connected with aluminium alloy plate seals, and forms the insulating seal of aluminum alloy anode；2) use and cold pressing or the compression method of hot pressing, together with the position that insulating seal material and conductive current collector and conductive current collector is connected with aluminium alloy plate presses to, it is achieved seal, form the insulating seal of aluminum alloy anode；3) method using coating, is coated to insulating seal material conductive current collector surface and conductive current collector and is connected with aluminium alloy plate position, it is achieved seal, the insulating seal of formation aluminum alloy anode；4) method using parcel, is wrapped in film like insulating seal material conductive current collector and conductive current collector and is connected with aluminium alloy plate position, it is achieved seal, the insulating seal of formation aluminum alloy anode；5) method using coating post-heating, is coated to insulating seal material conductive current collector surface and conductive current collector and is connected with aluminium alloy plate position, be thermally formed compacted zone afterwards, it is achieved seal, the insulating seal of formation aluminum alloy anode；6) method using parcel post-heating, is wrapped in film like insulating seal material conductive current collector and conductive current collector and is connected with aluminium alloy plate position, be thermally formed cover layer afterwards, it is achieved seal, the insulating seal of formation aluminum alloy anode；7) method soaked is used, the position that conductive current collector surface and conductive current collector is connected with aluminium alloy plate is immersed in liquid insulating seal material, take out afterwards, make insulating seal material be attached to conductive current collector and conductive current collector by such method to be connected with aluminium alloy plate position, realize sealing, form the insulating seal of aluminum alloy anode.
Wrap up aluminium alloy plate reinforcement material on aluminium alloy plate surface, the method forming aluminium alloy plate electrode structure has: 1) directly wraps aluminium alloy plate with reticulated aluminum alloy sheets reinforcement material, forms reticulated aluminum alloy sheets reinforcement；2) after reticulated aluminum alloy sheets reinforcement material being wrapped aluminium alloy plate, then use the method for pressing to enable aluminum alloy to plate reinforcement to be integrally forming with aluminium alloy plate, form reticulated aluminum alloy sheets reinforcement；3) use binding agent that reticulated aluminum alloy sheets reinforcement sticks to aluminium alloy plate surface, form reticulated aluminum alloy sheets reinforcement；4) aluminium alloy plate reinforcement material it is applied directly to aluminium alloy plate surface with web form or reheats with netted being coated in behind aluminium alloy plate surface, forming reticulated aluminum alloy sheets reinforcement；5) method using injection, enables aluminum alloy to plate reinforcement material and is attached to aluminium alloy plate surface with web form, form reticulated aluminum alloy sheets reinforcement；6) use the method soaked, aluminium alloy plate is immersed in liquid aluminium alloy plate reinforcement material, take out afterwards, enable aluminum alloy to plate reinforcement material and be attached to aluminium alloy plate surface with web form, form reticulated aluminum alloy sheets reinforcement.
The new structure aluminum alloy anode that this patent proposes, it is possible to resolve existing aluminium-air cell is discharging or even rupturing the internal short-circuit of battery caused and the problem of the product gathering increase internal resistance of cell present in storage process owing to aluminium alloy negative pole is thinning.
Accompanying drawing explanation
Fig. 1 is new structure aluminum alloy anode structural representation (1) of the present invention, and wherein 1 is aluminium alloy plate, and 2 is aluminium alloy plate reinforcement, and 3 is insulating seal, and 4 is conductive current collector.
Fig. 2 is new structure aluminum alloy anode structural representation (2) of the present invention, and wherein 1 is aluminium alloy plate, and 2 is aluminium alloy plate reinforcement, and 3 is insulating seal, and 4 is conductive current collector.
Fig. 3 is new structure aluminum alloy anode structural representation (3) of the present invention, and wherein 1 is aluminium alloy plate, and 2 is aluminium alloy plate reinforcement, and 3 is insulating seal, and 4 is conductive current collector.
Detailed description of the invention
Technical scheme is further illustrated below in conjunction with specific embodiment.
Embodiment 1
The structure of a kind of novel aluminum alloy electrode, it is made up of aluminium alloy plate 1, aluminium alloy plate reinforcement 2, insulating seal 3, conductive current collector 4.
Conductive current collector 4 is fastened on aluminium alloy plate 1, to ensure that the electric current that aluminum alloy anode produces can pass through conductive current collector output.The conductive current collector 4 being fastened on aluminium alloy plate is sealed in insulating seal 3 (Fig. 1～Fig. 3), with ensure aluminium-air cell during running or storing, electrode reaction product can not enter between conductive current collector 4 and aluminium alloy plate 1.
Aluminium alloy plate reinforcement 2 is positioned at the outside of aluminium alloy plate 1, has network, as shown in Figures 1 to 3.
The effect of aluminium alloy plate reinforcement 2 can not only fix aluminium alloy plate 1, the most also stops aluminium alloy plate 1 to contact with air electrode, thus prevents aluminium-air cell from running or during storage, internal short-circuit of battery.Aluminium alloy plate reinforcement 2 can be the grid of arbitrary shape, including, but not limited to the shape shown in Fig. 1～3.Together with can being integrally fixed between aluminium alloy plate reinforcement 2 with aluminium alloy plate 1, it is also possible to be not fixed together.
Embodiment 2
Adopt and manufacture the novel aluminum alloy electrode that this patent proposes with the following method: the aluminum alloy materials smelted is cut into and needs the aluminium alloy plate 1 of size.Afterwards, use the method for welding by welded together with aluminium alloy plate for conductive current collector 4.Again by the method adopting injection, insulating seal 3 is made to be attached to the connecting portion of conductive current collector and conductive current collector and aluminium alloy plate, it is achieved to seal.The method using injection, is attached to aluminium alloy plate surface by aluminium alloy plate reinforcement material with web form, forms aluminium alloy plate reinforcement 2, and is wrapped by aluminium alloy plate 1.
Embodiment 3
Adopt and manufacture the novel aluminum alloy electrode that this patent proposes with the following method: the aluminum alloy materials smelted is cut into and needs the aluminium alloy plate 1 of size.Afterwards, use screw or the method for rivet interlacement, conductive current collector 4 is linked together with aluminium alloy plate 1.Use and cold pressing or the compression method of hot pressing, together with the position that insulating seal material and conductive current collector and conductive current collector is connected with aluminium alloy plate presses to, it is achieved seal, form the insulating seal 3 of aluminum alloy anode.Directly wrap aluminium alloy plate with reticulated aluminum alloy sheets reinforcement material, form reticulated aluminum alloy sheets reinforcement 2.
Embodiment 4
Adopt and manufacture the novel aluminum alloy electrode that this patent proposes with the following method: the aluminum alloy materials smelted is cut into and needs the aluminium alloy plate 1 of size.Afterwards, the method using conducting resinl bonding, conductive current collector 4 is bonded together with aluminium alloy plate 1.The method using coating, is coated to insulating seal material conductive current collector surface and conductive current collector and is connected with aluminium alloy plate position, it is achieved seal, the insulating seal 3 of formation aluminum alloy anode.Use binding agent that reticulated aluminum alloy sheets reinforcement sticks to aluminium alloy plate surface, form reticulated aluminum alloy sheets reinforcement 2.
Embodiment 5
Adopt and manufacture the novel aluminum alloy electrode that this patent proposes with the following method: the aluminum alloy materials smelted is cut into and needs the aluminium alloy plate 1 of size.Afterwards, the method using direct pressing, conductive current collector 4 is directly pressed together with aluminium alloy plate 1, formation is fastenedly connected.The method using parcel, is wrapped in film like insulating seal material conductive current collector 4 and conductive current collector and is connected with aluminium alloy plate position, it is achieved seal, the insulating seal 3 of formation aluminum alloy anode.Aluminium alloy plate reinforcement material it is applied directly to aluminium alloy plate surface with web form or reheats with netted being coated in behind aluminium alloy plate surface, forming reticulated aluminum alloy sheets reinforcement 2.
Embodiment 6
Adopt and manufacture the novel aluminum alloy electrode that this patent proposes with the following method: the aluminum alloy materials smelted is cut into and needs the aluminium alloy plate 1 of size.Afterwards, the method using welding, conductive current collector 4 is welded together with aluminium alloy plate 1.The method using coating post-heating, is coated to insulating seal material conductive current collector 4 surface and conductive current collector and is connected with aluminium alloy plate position, be thermally formed compacted zone afterwards, it is achieved seal, the insulating seal 3 of formation aluminum alloy anode.The method using injection, enables aluminum alloy to plate reinforcement material and is attached to aluminium alloy plate surface with web form, form reticulated aluminum alloy sheets reinforcement 2.
Embodiment 7
Adopt and manufacture the novel aluminum alloy electrode that this patent proposes with the following method: the aluminum alloy materials smelted is cut into and needs the aluminium alloy plate 1 of size.Afterwards, use screw or the method for rivet interlacement, conductive current collector 4 is linked together with aluminium alloy plate 1.Film like insulating seal material is wrapped in conductive current collector and conductive current collector be connected with aluminium alloy plate position, is thermally formed cover layer afterwards, it is achieved seal, form the insulating seal 3 of aluminum alloy anode.Use the method soaked, aluminium alloy plate is immersed in liquid aluminium alloy plate reinforcement material, take out afterwards, enable aluminum alloy to plate reinforcement material and be attached to aluminium alloy plate surface with web form, form reticulated aluminum alloy sheets reinforcement 2.
Embodiment 8
Adopt and manufacture the novel aluminum alloy electrode that this patent proposes with the following method: the aluminum alloy materials smelted is cut into and needs the aluminium alloy plate 1 of size.Afterwards, the method using conducting resinl bonding, conductive current collector is bonded together with aluminium alloy plate.Use the method soaked, the position that conductive current collector surface and conductive current collector is connected with aluminium alloy plate is immersed in liquid insulating seal material, take out afterwards, make insulating seal material be attached to conductive current collector and conductive current collector by such method to be connected with aluminium alloy plate position, realize sealing, form the insulating seal 3 of aluminum alloy anode.After reticulated aluminum alloy sheets reinforcement material is wrapped aluminium alloy plate, then use hot pressing or the compression method colded pressing to enable aluminum alloy to plate reinforcement to be integrally forming with aluminium alloy plate, form reticulated aluminum alloy sheets reinforcement 2.
Embodiment 9
Adopt and manufacture the novel aluminum alloy electrode that this patent proposes with the following method: the aluminum alloy materials smelted is cut into and needs the aluminium alloy plate 1 of size.Afterwards, the method using welding, conductive current collector 4 is welded together with aluminium alloy plate 1.The method using parcel post-heating, is wrapped in film like insulating seal material conductive current collector and conductive current collector and is connected with aluminium alloy plate position, be thermally formed cover layer afterwards, it is achieved seal the insulating seal 3 of formation aluminum alloy anode.Use the method soaked, aluminium alloy plate is immersed in liquid aluminium alloy plate reinforcement material, take out afterwards, enable aluminum alloy to plate reinforcement material and be attached to aluminium alloy plate surface with web form, form reticulated aluminum alloy sheets reinforcement 2.
Embodiment 10
Adopt and manufacture the novel aluminum alloy electrode that this patent proposes with the following method: the aluminum alloy materials smelted is cut into and needs the aluminium alloy plate 1 of size.Afterwards, use screw or the method for rivet interlacement, conductive current collector 4 is linked together with aluminium alloy plate 1.The method using injection, the position that conductive current collector and conductive current collector is connected with aluminium alloy plate seals, it is achieved seal the insulating seal 3 of formation aluminum alloy anode.Directly wrap aluminium alloy plate with reticulated aluminum alloy sheets reinforcement material, form reticulated aluminum alloy sheets reinforcement 2.
Above the present invention has been done exemplary description; should be noted that; in the case of without departing from the core of the present invention, any simple deformation, amendment or other those skilled in the art can not spend the equivalent of creative work to each fall within protection scope of the present invention.
Claims (8)
1. a structure for aluminum alloy anode, including aluminium alloy plate, conductive current collector, it is characterised in that also include that aluminum closes
Gold plate reinforcement, insulating seal, wherein: described aluminium alloy plate reinforcement is network, is arranged on aluminium alloy plate
Outside, is arranged around aluminium alloy plate, and it can not only fix aluminium alloy plate, the most also stops aluminium alloy plate to connect with air electrode
Touch, thus prevent aluminium-air cell from running or storing or in handling process, internal short-circuit of battery；
In the network of described aluminium alloy plate reinforcement, aluminium alloy plate is set；
Described insulating seal and conductive current collector are arranged on the one of the unitary block of aluminum alloy electrode being made up of some aluminium alloy plates
End, to ensure that the electric current that aluminum alloy anode produces can flow through conductive current collector output smoothly,
Described conductive current collector is sealed in insulated enclosure body, with ensure aluminium-air cell run or store or
In handling process, electrolyte or electrode reaction product will not contact with conductive current collector.
The structure of a kind of aluminum alloy anode the most according to claim 1, it is characterised in that described aluminium alloy plate reinforcement
And select between aluminium alloy plate be fixed together or be not fixed together.
3. according to the structure of a kind of aluminum alloy anode described in claims 1 or 2, it is characterised in that described aluminium alloy plate
Be shaped as square, rhombus or circle.
The structure of a kind of aluminum alloy anode the most according to claim 3, it is characterised in that described aluminium alloy plate reinforcement
Select electrical-insulation polymeric material or electric insulation Inorganic Non-metallic Materials；Described insulating seal selects electrical-insulation polymeric
Material or electric insulation Inorganic Non-metallic Materials.
5. the preparation method of the structure of an aluminum alloy anode, it is characterised in that be prepared by following method:
Choose aluminum alloy materials and be cut into the aluminium alloy plate of electrode size, conductive current collector is fixed on aluminium alloy plate, then
The conductive current collector on aluminium alloy plate will be fixed on and conductive current collector is connected with aluminium alloy plate with insulating sealing materials
Position seals, and forms the insulating seal of aluminum alloy anode, finally uses aluminium alloy plate reinforcement material, with web form
Aluminium alloy plate is wrapped, forms aluminium alloy electric electrode structure.
The preparation method of the structure of a kind of aluminum alloy anode the most according to claim 5, it is characterised in that conduction is collected
Method that fluid is fixed on aluminium alloy plate uses one of following: the 1) method using welding, conductive current collector is closed with aluminum
Gold plate welds together；2) use screw or the method for rivet interlacement, conductive current collector and aluminium alloy plate are connected to one
Rise；3) method using conducting resinl bonding, is bonded together conductive current collector with aluminium alloy plate；4) directly pressure is used
The method closed, directly presses together conductive current collector with aluminium alloy plate, and formation is fastenedly connected.
The preparation method of the structure of a kind of aluminum alloy anode the most according to claim 5, it is characterised in that conduction is collected
Fluid and conductive current collector be connected with aluminium alloy plate position seal, formed aluminum alloy anode insulating seal method adopt
With one of following: 1) method that uses injection, be connected with aluminium alloy plate position by conductive current collector and conductive current collector
Seal, form the insulating seal of aluminum alloy anode；2) employing is colded pressing or the compression method of hot pressing, by insulating seal
Material and conductive current collector and conductive current collector are connected together with position presses to aluminium alloy plate, it is achieved seal, formed
The insulating seal of aluminum alloy anode；3) method using coating, is coated to conductive current collector table by insulating seal material
Face and conductive current collector are connected with aluminium alloy plate position, it is achieved seal, and form the insulating seal of aluminum alloy anode；4)
The method using parcel, is wrapped in conductive current collector and conductive current collector and aluminium alloy by film like insulating seal material
Plate is connected position, it is achieved seal, and forms the insulating seal of aluminum alloy anode；5) method using coating post-heating,
Insulating seal material is coated to conductive current collector surface and conductive current collector be connected with aluminium alloy plate position, afterwards
It is thermally formed compacted zone, it is achieved seal, forms the insulating seal of aluminum alloy anode；6) method using parcel post-heating,
Film like insulating seal material is wrapped in conductive current collector and conductive current collector be connected with aluminium alloy plate position, it
Post-heating forms cover layer, it is achieved seal, and forms the insulating seal of aluminum alloy anode；7) method soaked is used, will
Liquid insulating seal material is immersed at conductive current collector surface and the conductive current collector position that is connected with aluminium alloy plate
In, take out afterwards, by such method make insulating seal material be attached to conductive current collector and conductive current collector with
Aluminium alloy plate is connected position, it is achieved seal, and forms the insulating seal of aluminum alloy anode.
The preparation method of the structure of a kind of aluminum alloy anode the most according to claim 5, it is characterised in that at aluminium alloy
Plate surface parcel aluminium alloy plate reinforcement material, the method for the structure forming aluminum alloy anode uses one of following: 1) directly
Wrap aluminium alloy plate with reticulated aluminum alloy sheets reinforcement material, form reticulated aluminum alloy sheets reinforcement；2) reticulated aluminum is closed
After gold plate reinforcement material wraps aluminium alloy plate, then the method for pressing is used to enable aluminum alloy to plate reinforcement and aluminium alloy plate
It is integrally forming, forms reticulated aluminum alloy sheets reinforcement；3) use binding agent that reticulated aluminum alloy sheets reinforcement sticks to aluminum to close
Gold plate surface, forms reticulated aluminum alloy sheets reinforcement；4) aluminium alloy plate reinforcement material is applied directly to web form
Aluminium alloy plate surface or reheat with netted being coated in behind aluminium alloy plate surface, forms reticulated aluminum alloy sheets reinforcement；5)
The method using injection, enables aluminum alloy to plate reinforcement material and is attached to aluminium alloy plate surface with web form, form reticulated aluminum
Alloy sheets reinforcement；6) use the method soaked, aluminium alloy plate immersed in liquid aluminium alloy plate reinforcement material,
Take out afterwards, enable aluminum alloy to plate reinforcement material and be attached to aluminium alloy plate surface with web form, form reticulated aluminum alloy sheets
Reinforcement.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410424756.9A CN104332587B (en) | 2014-08-26 | 2014-08-26 | The structure of a kind of aluminum alloy anode and manufacture method |
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| CN201410424756.9A CN104332587B (en) | 2014-08-26 | 2014-08-26 | The structure of a kind of aluminum alloy anode and manufacture method |
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| CN104332587B true CN104332587B (en) | 2016-10-26 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP7228516B2 (en) | 2016-12-15 | 2023-02-24 | フィナジー リミテッド | Systems and methods for initializing and operating metal-air cells |
| CN108321344B (en) * | 2018-01-17 | 2021-05-07 | 重庆鼎工机电有限公司 | Aluminum-air battery, battery pack and generator set |
| CN111370709A (en) * | 2020-03-26 | 2020-07-03 | 江苏泛亚微透科技股份有限公司 | Metal-air battery positive electrode component with conductive hydrophobic expanded polytetrafluoroethylene membrane and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1060183A (en) * | 1991-09-28 | 1992-04-08 | 天津大学 | Neutral aluminium-air cell and preparation method thereof |
| CN103200595A (en) * | 2013-03-15 | 2013-07-10 | 南通爱普医疗器械有限公司 | Optimization method about 3G wireless network transmitting information |
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2014
- 2014-08-26 CN CN201410424756.9A patent/CN104332587B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1060183A (en) * | 1991-09-28 | 1992-04-08 | 天津大学 | Neutral aluminium-air cell and preparation method thereof |
| CN103200595A (en) * | 2013-03-15 | 2013-07-10 | 南通爱普医疗器械有限公司 | Optimization method about 3G wireless network transmitting information |
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