CN202503065U - Thin lithium ion battery - Google Patents
Thin lithium ion battery Download PDFInfo
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- CN202503065U CN202503065U CN2012200416808U CN201220041680U CN202503065U CN 202503065 U CN202503065 U CN 202503065U CN 2012200416808 U CN2012200416808 U CN 2012200416808U CN 201220041680 U CN201220041680 U CN 201220041680U CN 202503065 U CN202503065 U CN 202503065U
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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Abstract
The utility model provides a thin lithium ion battery belonging to the field of storage batteries. The thin lithium ion battery comprises a positive electrode, a negative electrode, electrolyte, a diaphragm, lug adhesive and a packaging film. The thin lithium ion battery is characterized in that the positive electrode comprises a positive current collector, positive paste and a positive lug, the positive current collector is made of titanium foil, titanium alloy foil or lead foil, the positive paste is adhered on the positive current collector, the positive lug is directly led out from the positive current collector; the negative electrode comprises a negative current collector, negative paste and a negative lug, the negative current collector is made of stainless steel foil, the negative paste is adhered on the negative current collector, and the negative lug is directly led out from the negative current collector. The positive current collector made of titanium foil is high in oxidation resistance. The thin lithium ion battery is low in self discharging under high voltage and is stable and reliable in storage and use and long in service life. The foil is high in melting point and strength, the thickness of the foil can be reduced, the lugs are led out from the current collectors, no breakage is caused during hot sealing, and the lithium ion battery can be thinner.
Description
Technical field
The utility model
A kind of thin lithium ion batteryBelong to the secondary cell field, particularly relate to a kind of slim lithium ion battery.
Background technology
Modern society's information is flourishing; Various magnetic cards, smart card (IC-card), identification card (ID card), bank card, radio-frequency card (electronic tag, RFID), Electronic Paper etc. are arisen at the historic moment; The not charged source of card in the past, amount of information is little, confidentiality is poor, is developing the card in charged source; Improve amount of information and confidentiality, thin battery is proposed demand.Present thin lithium ion battery thickness on the market is many at 0.4 ± 0.05mm, and the card thickness of standard is 0.8 ± 0.04mm, requires thin lithium ion battery thickness at 0.15 ~ 0.35mm, and is optimum at 0.2 ~ 0.3mm.Present thin lithium ion battery can only be used for nonstandard, thicker card.
The patent No. is that the Chinese patent of 10L200820093364.9 discloses the secondary slimline battery; Use envelope lug in advance, promptly lug glue in encapsulation in advance on aluminum strip and the nickel bar also can be described as band glue lug; To seal the lug metallic object in advance is welded on anode and the negative electrode; Use aluminum-plastic composite membrane to do packaging film, will seal lug in advance and be packaged together, make slimline battery with aluminum-plastic composite membrane.This method has two shortcomings; That (1) metallic object of pre existing envelope lug is the thinnest is 0.07 mm; That lug glue is the thinnest is 0.07 mm; Be exclusively used in the aluminum-plastic composite membrane of lithium ion battery the thinnest be 0.088mm, the thinnest battery that can make is the thinnest aluminum-plastic composite membrane of bilayer, the thinnest lug glue of bilayer, the thinnest metallic object of one deck totally 0.386 mm, such thickness is too thick for smart card; (2) seal aluminium pole ears in advance and follow anodal aluminum foil current collector through ultrasonic spot welding, after receiving ultrasonic vibration and pushing, anodal aluminum foil current collector becomes fragile, and is easy to fracture, and rate of finished products is very low.
The patent No. is that the Chinese patent of 10L98103781.X discloses thin battery; Electrode terminal that is lug have conductive member netted or porous to form; The conductive member material is introduced from electrochemical stability and is considered that aluminium, gold and carbon are suitable for doing positive pole ear most by optional in carbon, nickel, aluminium, copper, tungsten, stainless steel, iron, silver, gold and their alloy.Be actually be out of use gold and carbon and do positive pole ear.This method is done lug with conductive member netted or porous, and intensity is poorer, and needing to increase thickness could seal and don't rupture reliably.
The patent No. is that the Chinese patent of 10L201020504895.X discloses a kind of thin battery, uses aluminum-plastic composite membrane to do thin lithium ion battery, need not seal lug in advance; Positive plate and negative plate reserve anode ear and negative electrode lug respectively; When lug need encapsulate with aluminum-plastic composite membrane,, use heat sealing machine that lug and aluminum-plastic composite membrane are packaged together in the corresponding aluminum-plastic composite membrane punching of lug; Aluminum-plastic composite membrane punching place exposed portions serve anode ear and negative electrode lug can be made the battery below 0.3 mm like this.This method has three shortcomings, and (1) anodal aluminum foil current collector and negative copper foil collector be directly with aluminum-plastic composite membrane encapsulation, has aluminium foil and Copper Foil rupture break inside especially, problem that rate of finished products is low; (2) anodal aluminum foil current collector and negative copper foil collector directly with the aluminum-plastic composite membrane encapsulation, do not add lug glue, depend the adhesive layer of aluminum-plastic composite membrane alone, and be bonding unreliable, has the chance of seepage or steam, oxygen invasion, the battery poor reliability, and the life-span is short; (3) this kind way can not add lug glue, and the glue-line thickening more is prone to the disconnected lug of extruding envelope, and lug glue can block the hole that aluminum-plastic composite membrane dashes in advance again.
The conventional thin lithium ion battery uses aluminium foil or aluminium net to do positive pole ear, and aluminium foil or aluminium net fusing point are low, and intensity difference under intensity difference, especially the high temperature heat seal condition will be carried out battery and just need add thick aluminum foil, forms contradiction with wanting to do thin battery; Use anodal aluminum foil current collector and negative copper foil collector directly with aluminum-plastic composite membrane encapsulation, also have the problem that the low problem of the fracture of aluminium foil and Copper Foil, rate of finished products and bonding unreliable, battery poor reliability, life-span lack.
The utility model content
The purpose of the utility model is to existing technical barrier, and provides a kind of that more approach, the existing thickness limit of breakthrough
A kind of thin lithium ion battery
At first analyze the manufacture method of existing use aluminum-plastic composite membrane packing, directly reserve anode ear with negative electrode lug is the most convenient, and there is the problem of sealing the lug that breaks when sealing in this method with positive plate and negative plate.Tracing it to its cause, is that intensity is low because the fusing point of aluminium foil is lower, and especially under 200 ℃ of heat-sealing temperatures, the intensity of aluminium declines to a great extent, the lug of hot melt state gluing aluminium foil, stand the heat sealing machine extruding, the aluminium foil drawing crack.More specifically, the width<aluminum-plastic composite membrane closedtop hem width degree<lug glue width of general heat-sealing head, heat-sealing back lug glue protection lug metallic object can not followed aluminum metal body contact in the aluminum-plastic composite membrane and short circuit; But during heat-sealing; Heat-sealing head is depressed and, and the lug glue fusion of periphery and lug fluid sealant far away slightly is molten is pullled effect to the lug metallic object; And heat-sealing head presses down, and the lug metallic object is pullled fracture by lug glue.Attempt to widen the aluminium foil width and gain in strength, just need widen lug glue, produce bigger pulling force, aluminium foil drawing crack likewise.Only add thick aluminum foil, just can gain in strength, opposing lug glue and heat sealing machine extruding force.Here it is, and lug supplier can only provide the reason of the above aluminium pole ears of 0.07mm thickness, and thinner aluminium pole ears can not be provided.Need not be with the glue lug, oneself add when encapsulating that lug glue makes the sealing of lug place tight, reason is the same, and aluminium foil can drawing crack.Add thick aluminum foil and form contradiction with doing thin battery.When using aluminium foil to do plus plate current-collecting body to hold concurrently wrapping film, there is the problem of heat sealing machine extruding aluminium foil drawing crack equally, only if aluminium foil is enough thick.Aluminium foil is also arranged in the aluminum-plastic composite membrane, because resistant to elevated temperatures nylon layer protection is arranged, nylon layer cannot not be molten under the heat-sealing temperature, can protect the aluminium foil in the aluminum-plastic composite membrane not rupture.
Analyzing has any high-strength material can do battery afflux liquid again, sees table 1.
The performance parameter of several kinds of metal materials of table 1.
Material | Fusing point ℃ | Tensile strength MPa | Mohs' hardness | Density g/cm3 |
Aluminium | 660 | 180 | 3 | 2.702 |
Copper | 1083 | 250 | 3 | 8.920 |
Nickel | 1453 | 660 | 4 | 8.902 |
Titanium | 1668 | 1800 | 6 | 4.506 |
Chromium | 1857 | 689 | 9 | 7.1 |
Stainless steel | 1400 ~ 1455 | 1100 | 5.5 | 7.93 |
Stainless steel is non-corrosive why, is because in steel, added the alloying component of nickel, chromium or titanium.Stainless main component is an iron; Still can oxidation under high potential, dissolving; Can only make the battery below the 3.6V; Such as the plus plate current-collecting body of lithium ion batteries such as LiFePO4-graphite, LiFePO4-hard carbon, LiFePO4-lithium titanate, can not do the plus plate current-collecting body of lithium ion batteries such as cobalt acid lithium-graphite, LiMn2O4-graphite, nickel manganese cobalt acid lithium-graphite.Stainless steel is done Passivation Treatment, can slightly improve its operating voltage, still incompatible with the lithium ion battery of common 4.2V charging, and lithium ion battery has the high-tension trend of development, does plus plate current-collecting body with stainless steel and can not adapt to this kind trend.
On chemical property; Plus plate current-collecting body aluminium foil with commonly used is the same, and titanium foil, titanium alloy paper tinsel and lead foil also are easy to oxidation, but the oxide-film that oxidation produces is fine and close; Can protect body not corroded, do high-tension plus plate current-collecting body for them electrochemical conditions is provided; And on fusing point and intensity, titanium foil, titanium alloy paper tinsel and lead foil are more much bigger than aluminium foil.Though titanium foil, titanium alloy paper tinsel and lead foil are much more expensive than aluminium foil, for thin battery, consumption is few, and cost is not a subject matter.Goldleaf and platinum foil are available on chemical property, are disabled on cost.
Use aluminum-plastic composite membrane to do thin lithium ion battery; Can not use preparatory envelope lug, reducing in advance, the envelope lug reduces the welding damage of lug and pole piece with the ultrasonic bonding operation of positive plate and negative plate; Directly on plus plate current-collecting body and negative current collector, draw lug; When lug need encapsulate with aluminum-plastic composite membrane, directly between lug and aluminum-plastic composite membrane, add lug glue, use heat sealing machine that lug, lug glue and aluminum-plastic composite membrane are packaged together.Use the high-intensity foil of high-melting-point to do collector, thus the thickness of thickness attenuate battery that just can the attenuate collector.
The utility model
A kind of thin lithium ion battery comprisesPositive plate, negative plate, electrolyte, barrier film, lug glue and packaging film are formed; Barrier film separates positive plate and negative plate, fills electrolyte between barrier film and positive plate and the negative plate, adds lug glue between lug and packaging film; It is characterized in that positive plate comprises plus plate current-collecting body, anodal cream, positive pole ear composition, plus plate current-collecting body adopts titanium foil, and anodal cream coheres on plus plate current-collecting body; The plus plate current-collecting body positive pole ear of directly extending out, negative plate comprise that negative current collector, negative pole cream, negative lug form, and negative current collector adopts stainless steel foil; Negative pole cream coheres on negative current collector, and negative current collector is directly drawn negative lug.
The plus plate current-collecting body of the utility model can adopt titanium alloy paper tinsel or lead foil.
The negative current collector of the utility model can adopt Copper Foil or nickel foil or titanium foil or titanium alloy paper tinsel or lead foil.
The packaging film of the utility model adopts aluminum-plastic composite membrane.
The anode collection body thickness of the utility model is 0.001 ~ 0.1mm, and preferred thickness is 0.01 ~ 0.025mm.
The negative pole currect collecting body thickness of the utility model is 0.001 ~ 0.1mm, and preferred thickness is 0.01 ~ 0.025mm.
When used foil thickness of plus plate current-collecting body and the used foil thickness of negative current collector are 0.001 ~ 0.015mm; The lug of directly drawing from collector; Can use lug glue also can preferably use the sealing of lug glue more reliable during with the aluminum-plastic composite membrane encapsulation without lug glue.
Adopt titanium foil or titanium alloy paper tinsel or lead foil to do plus plate current-collecting body and directly draw lug, aluminum-plastic composite membrane is done packaging film, can make the thin lithium ion battery of 0.3 ± 0.1mm, can design different thickness according to desired volume.
The utility model adopts titanium foil or titanium alloy paper tinsel or lead foil to do plus plate current-collecting body, and its oxidation resistance is strong, and the self discharge under high voltage of institute's thin lithium ion battery of doing is little, store and use reliable and stable, long service life; The foil fusing point is high, and intensity is big, can attenuate foil thickness, directly draw lug from collector, and do not rupture during heat-sealing, can make thinner thin lithium ion battery; Adopt lug glue sealing lug position, rate of finished products is high, and reliability is high, adapts to the needs of slim products such as smart card, bank card, electronic tag; Adapt to the production procedure and the equipment of existing polymer, flexible packing lithium ion battery, implement easily.
Description of drawings
Accompanying drawing 1 is the front view of the positive plate of the utility model.
Accompanying drawing 1b is the sectional view of the positive plate of the utility model.
Accompanying drawing 2 is front views of the negative plate of the utility model.
Accompanying drawing 2b is the sectional view of the negative plate of the utility model.
Accompanying drawing 3 is front views that the packaging film closedtop position of the utility model adds lug glue, and the heat cover of packaging film upwards.
Accompanying drawing 4 is that the packaging film of the utility model adds that lug glue adds the front view of negative plate, and negative plate has cream towards last.
Accompanying drawing 5 is that the packaging film of the utility model adds that lug glue, negative plate add the front view of barrier film.
Accompanying drawing 6 is that the packaging film of the utility model adds that lug glue, negative plate, barrier film add the front view of positive plate, and positive plate has cream to face down.
Accompanying drawing 7 is lateral plans of packaging film parcel lug glue, negative plate, barrier film and the positive plate of the utility model.
Accompanying drawing 8 is front views that the thin lithium ion battery of the utility model is accomplished closedtop.
The thin lithium ion battery of accompanying drawing 9 the utility model is accomplished the front view of side seal.
The thin lithium ion battery of accompanying drawing 10 the utility model is accomplished the front view of vacuum seal.
Embodiment
Below in conjunction with object lesson the utility model is described further.
Among the figure: plus plate current-collecting body 01, anodal cream 02, positive pole ear 03, negative current collector 04, negative pole cream 05, negative lug 06, lug glue 07, barrier film 08, packaging film 09, folding line 10, closedtop limit 11, side seal limit 12, vacuum seal limit 13.
Shown in accompanying drawing 1, accompanying drawing 1b; The positive plate of the utility model comprises plus plate current-collecting body 01, anodal cream 02, and positive pole ear 03 is formed; Plus plate current-collecting body adopts titanium foil or titanium alloy paper tinsel or lead foil; Anodal cream 02 coheres on plus plate current-collecting body 01, the plus plate current-collecting body positive pole ear 03 of directly extending out, and the anode collection body thickness is 0.01 ~ 0.025mm.Adhesive is added stirring melt into glue in the solvent, positive active material and conductive agent are added in the glue, high-speed stirring mixes anode sizing agent; Adopt titanium foil or titanium alloy paper tinsel or lead foil to do plus plate current-collecting body; With the one side that anode sizing agent evenly prints or be coated on plus plate current-collecting body, on one side reserving space bit, plus plate current-collecting body does lug, positive plate is dried; Roll-in punches out the positive plate of being with the space bit lug; The cleaning positive pole ear.
Shown in accompanying drawing 2, accompanying drawing 2b; The negative plate of the utility model comprises negative current collector 04; Negative pole cream 05, negative lug 06 is formed, and negative current collector adopts stainless steel foil or Copper Foil or nickel foil or titanium foil or titanium alloy paper tinsel or lead foil; Negative pole cream 05 coheres on negative current collector 04, and negative current collector is directly drawn negative lug 06.The negative pole currect collecting body thickness is 0.01 ~ 0.025mm.Use graphite or hard carbon or lithium titanate or silicon or tin oxide etc. to do negative pole; Adhesive is added stirring melt into glue in the solvent, negative electrode active material and conductive agent are added in the glue, high-speed stirring mixes cathode size; Adopt stainless steel foil or Copper Foil or nickel foil or titanium foil or titanium alloy paper tinsel or lead foil to do negative current collector; With the one side that cathode size evenly prints or be coated on negative current collector, on one side reserving space bit, negative current collector does lug, negative plate is dried; Roll-in punches out the negative plate of being with the space bit lug; The cleaning negative lug; Make negative plate.
Shown in accompanying drawing 3, accompanying drawing 4, accompanying drawing 5, accompanying drawing 6, accompanying drawing 7; On the packaging film 09 closedtop position of the utility model lug glue 07 is set; Use aluminum-plastic composite membrane to do packaging film, barrier film 08 can use MIcroporous polyolefin film, or PVDF-HFP gel mould or solid electrolyte film.Barrier film is cut into the small pieces than negative maximum.Aluminum-plastic composite membrane is cut into suitable dimension, and the heat cover of aluminum-plastic composite membrane 09 upwards; Stick lug glue 07 in lug heat-sealing position, to folding folding line 10; Negative plate is installed on the aluminum-plastic composite membrane, negative plate cream is arranged towards last; Add barrier film 08; Positive plate is overlayed on the barrier film, and the cream that has of positive plate faces down; Aluminum-plastic composite membrane along folding line 10 doublings, is wrapped negative plate, barrier film and positive plate.
Shown in accompanying drawing 8, accompanying drawing 9, accompanying drawing 10, use heat sealing machine that aluminum-plastic composite membrane, lug glue, lug are sealed together, accomplish closedtop; With the heat-sealing of aluminum-plastic composite membrane side together, accomplish side seal, make the battery embryo; With the vacuumize of battery embryo.In drying box, use the situation of liquid electrolyte, drip liquid electrolyte, the fluid injection banding with the battery embryo under vacuum state closes.
According to known way, need discharge and recharge, carry out activation and partial volume, check voltage, internal resistance and size again, obtain the thin lithium ion battery finished product.
The positive pole of thin lithium ion battery can be cobalt acid lithium or LiMn2O4 or nickel manganese cobalt acid lithium or LiFePO4 or phosphoric acid vanadium lithium or lithium manganese phosphate etc.
The negative pole of thin lithium ion battery can be graphite or hard carbon or lithium titanate or silicon or tin oxide etc.
The electrolyte of thin lithium ion battery can be liquid electrolyte or gel state electrolyte or solid electrolyte.
The barrier film of thin lithium ion battery can be MIcroporous polyolefin film or nonwoven fabrics or paper or double barrier film or the double barrier film of doing of solid electrolyte done of gel state electrolyte.
Used foil thickness of plus plate current-collecting body and the used foil thickness of negative current collector are 0.001 ~ 0.1mm, and anodal foil thickness and negative pole foil thickness can equate also can be unequal; Preferably used foil thickness is 0.01 ~ 0.025mm, and anodal foil thickness and negative pole foil thickness equate.
When used foil thickness of plus plate current-collecting body and the used foil thickness of negative current collector are 0.001 ~ 0.015mm; The lug of directly drawing from collector; Can use lug glue also can preferably use the sealing of lug glue more reliable during with the aluminum-plastic composite membrane encapsulation without lug glue.
Embodiment
Use TC4 Type Titanium Alloy (Ti-6Al-4V) paper tinsel to do that plus plate current-collecting body, SUS430 type stainless steel foil are done negative current collector, aluminum-plastic composite membrane is done packaging film, nickel manganese cobalt acid lithium is done positive pole, graphite is done negative pole, polypropylene micro-pore septum, liquid electrolyte.
3gPVDF is added stirring melt into glue in the 50gNMP solvent; 95g nickel manganese cobalt acid lithium and 2g conductive carbon black are added in the glue; High-speed stirring mixes anode sizing agent, adopts the thick TC4 Type Titanium Alloy paper tinsel of 20 μ m to do plus plate current-collecting body, and anode sizing agent is coated on the plus plate current-collecting body one side; Control coated face density 160g/m2, the edge leaves some space so that go out anode ear; The oven dry pole piece; Roll-in to thickness is 66 μ m; Punch out positive plate, the positive plate main body is the rectangle of 18mm*20mm, and width one side is reserved the anode ear that is not coated with cream of the blank of 3mm*7mm; The cleaning positive pole ear; Make positive plate.
The 2gCMC adhesive is added stirring melt into glue in the 120g water, add the SBR of 4g content 50%, stir into mixing glue; 94g graphite and 2g conductive carbon black are added in the glue; High-speed stirring mixes cathode size, adopts the thick SUS430 type stainless steel foil of 20 μ m to do negative current collector, and cathode size is uniformly coated on the negative current collector one side; Control coated face density 80g/m2, the edge leaves some space so that go out negative electrode lug; The oven dry pole piece; Roll-in to thickness is 70 μ m; Punch out negative plate, the negative plate main body is the rectangle of 19mm*21mm, and width one side is reserved the blank negative electrode lug that is not coated with cream of 3mm*6mm, the cleaning negative lug; Make negative plate.
Use the thick microporous polypropylene membrane of 16 μ m to make barrier film, barrier film is cut into the rectangle of 21mm*23mm.
Use the thick aluminum-plastic composite membrane of 87 μ m to do packaging film, aluminum-plastic composite membrane is cut into the rectangle of 25mm*50mm, stick the lug glue of 0.07*2*18mm in the lug heat-sealing position of two widthwise edges of aluminum-plastic composite membrane, setting; With aluminum-plastic composite membrane in the length direction doubling; Negative plate is installed on the aluminum-plastic composite membrane, adds barrier film, positive plate is overlayed on the barrier film; Use heat sealing machine that aluminum-plastic composite membrane, lug glue, lug are sealed together, accomplish closedtop; With the heat-sealing of aluminum-plastic composite membrane side together, accomplish side seal; Make the battery embryo.With the vacuumize of battery embryo.
In drying box, use the situation of liquid electrolyte, drip the 0.03g liquid electrolyte, the fluid injection banding with the battery embryo under vacuum state closes.
Use the cabinet that changes into of 5V10mA range, the 2mA constant current charge changes constant voltage charge to 0. 2mA to 4.2V to be ended; The 2mA constant-current discharge circulates 2 times to 3V, and the 2mA constant current charge ends to 4.2V commentaries on classics constant voltage charge to 0. 2mA again.Battery is emitted the 8mAh capacity.Check voltage 4.15V and internal resistance 1450m Ω obtain finished product, and cell thickness is 0.33mm, width 25mm, length 25 mm.
Claims (5)
1. a thin lithium ion battery comprises positive plate, negative plate; Electrolyte, barrier film, lug glue and packaging film are formed, and barrier film separates positive plate and negative plate, fills electrolyte between barrier film and positive plate and the negative plate; Add lug glue between lug and packaging film, it is characterized in that positive plate comprises plus plate current-collecting body, anodal cream, positive pole ear composition, plus plate current-collecting body adopts titanium foil or titanium alloy paper tinsel or lead foil; Anodal cream coheres on plus plate current-collecting body; The plus plate current-collecting body positive pole ear of directly extending out, negative plate comprise that negative current collector, negative pole cream, negative lug form, and negative current collector adopts stainless steel foil or Copper Foil or nickel foil or titanium foil or titanium alloy paper tinsel or lead foil; Negative pole cream coheres on negative current collector, and negative current collector is directly drawn negative lug.
2. a kind of thin lithium ion battery according to claim 1 is characterized in that packaging film adopts aluminum-plastic composite membrane.
3. a kind of thin lithium ion battery according to claim 1 is characterized in that the anode collection body thickness is 0.001 ~ 0.1mm.
4. a kind of thin lithium ion battery according to claim 1 is characterized in that the negative pole currect collecting body thickness is 0.001 ~ 0.1mm.
5. a kind of thin lithium ion battery according to claim 1 is characterized in that the anode collection body thickness is 0.01 ~ 0.025mm, and the negative pole currect collecting body thickness is 0.01 ~ 0.025mm.
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CN2012200416808U CN202503065U (en) | 2012-02-09 | 2012-02-09 | Thin lithium ion battery |
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CN2012200416808U CN202503065U (en) | 2012-02-09 | 2012-02-09 | Thin lithium ion battery |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104752757A (en) * | 2013-12-26 | 2015-07-01 | 三洋电机株式会社 | Non-aqueous electrolytic secondary battery |
CN106252540A (en) * | 2016-08-31 | 2016-12-21 | 谢振华 | The structure of a kind of flexible-packed battery and manufacture method |
CN106920987A (en) * | 2017-04-01 | 2017-07-04 | 厦门日臻动力电源科技有限公司 | A kind of preparation method of secondary ultra-thin soft-packaged polymer lithium ion battery |
CN108899552A (en) * | 2018-06-21 | 2018-11-27 | 湖南格兰博智能科技有限责任公司 | A kind of positive and negative anodes base band, positive and negative anodes pole piece, high-capacity lithium ion cell and preparation method thereof |
CN109935745A (en) * | 2019-03-12 | 2019-06-25 | 武汉昊诚能源科技有限公司 | Lithium manganese slimline battery and preparation method thereof |
WO2020006968A1 (en) * | 2018-07-06 | 2020-01-09 | 惠州赛尔雷新能源科技有限公司 | Flexible battery having positive and negative gel electrodes |
CN110931885A (en) * | 2019-12-03 | 2020-03-27 | 广州丰江电池新技术股份有限公司 | Preparation method of battery core of thin lithium ion battery, and battery core and battery applying same |
TWI810408B (en) * | 2018-12-18 | 2023-08-01 | 日商日本碍子股份有限公司 | Lithium secondary battery |
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2012
- 2012-02-09 CN CN2012200416808U patent/CN202503065U/en not_active Expired - Fee Related
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104752757A (en) * | 2013-12-26 | 2015-07-01 | 三洋电机株式会社 | Non-aqueous electrolytic secondary battery |
CN106252540A (en) * | 2016-08-31 | 2016-12-21 | 谢振华 | The structure of a kind of flexible-packed battery and manufacture method |
CN106252540B (en) * | 2016-08-31 | 2019-04-23 | 谢振华 | A kind of structure and manufacturing method of flexible-packed battery |
CN106920987A (en) * | 2017-04-01 | 2017-07-04 | 厦门日臻动力电源科技有限公司 | A kind of preparation method of secondary ultra-thin soft-packaged polymer lithium ion battery |
CN108899552A (en) * | 2018-06-21 | 2018-11-27 | 湖南格兰博智能科技有限责任公司 | A kind of positive and negative anodes base band, positive and negative anodes pole piece, high-capacity lithium ion cell and preparation method thereof |
WO2020006968A1 (en) * | 2018-07-06 | 2020-01-09 | 惠州赛尔雷新能源科技有限公司 | Flexible battery having positive and negative gel electrodes |
TWI810408B (en) * | 2018-12-18 | 2023-08-01 | 日商日本碍子股份有限公司 | Lithium secondary battery |
CN109935745A (en) * | 2019-03-12 | 2019-06-25 | 武汉昊诚能源科技有限公司 | Lithium manganese slimline battery and preparation method thereof |
CN109935745B (en) * | 2019-03-12 | 2024-04-05 | 武汉昊诚锂电科技股份有限公司 | Primary lithium manganese ultrathin battery and preparation method thereof |
CN110931885A (en) * | 2019-12-03 | 2020-03-27 | 广州丰江电池新技术股份有限公司 | Preparation method of battery core of thin lithium ion battery, and battery core and battery applying same |
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Address after: 511475, Guangdong, Guangzhou province Nansha District Tung Chung Town fine Lek Village (factory building two) (plant three) Patentee after: Guangzhou FULLRIVER Battery New Technology Co., Ltd. Address before: 511400, No. 22 South Embankment Road, Shiqiao Town, Guangzhou City, Guangdong, Panyu District Patentee before: Guangzhou FULLRIVER Battery New Technology Co., Ltd. |
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Granted publication date: 20121024 Termination date: 20190209 |