CN104327711A - Wear-resistant environment-friendly water-based paint with high adhesive force - Google Patents
Wear-resistant environment-friendly water-based paint with high adhesive force Download PDFInfo
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
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- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/04—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
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- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
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- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a wear-resistant environment-friendly water-based paint with a high adhesive force. The paint is prepared from the following raw materials in parts by weight: 55-58 parts of polyurethane resin, 22-25 parts of acrylic resin, 20-23 parts of glycerine epoxyiesin, 7-10 parts of modified graphene, 2-5 parts of organobentonite, 4-7 parts of mica powder, 1.3-1.6 parts of a foaming agent, 1.6-1.9 parts of a flatting agent, 1.8-2.2 parts of a dispersant, 1.2-1.5 parts of a coalescing agent, 1.6-2 parts of pigments, 2.5-2.8 parts of hydrogenated castor oil and 56-60 parts of deionized water. The paint disclosed by the invention is good in wear resistance and high in adhesive force and can be used for satisfying the demand of wear-resistant environment-friendly water-based paints with high adhesive force in the market.
Description
Technical field
The present invention relates to technical field of aqueous paint, particularly relate to the environment-friendly type aqueous coating of a kind of wear resistant high-adhesion.
Background technology
Water-borne coatings take water as the coating of solvent, few with its asepsis environment-protecting, odorlessness, volatile matter, do not fire the advantages such as not quick-fried, range of application is more and more extensive, but, the resistance to mechanical power of water-borne coatings is as not good in wear resisting property, and sticking power is poor, and coating can be peeled off along with the applying of external force, therefore, the environment-friendly type aqueous coating of a kind of wear-resisting, high adhesive force of market demand.
Summary of the invention
The technical problem that basic background technology exists, the present invention proposes the environment-friendly type aqueous coating of a kind of wear resistant high-adhesion, wear resisting property is good, sticking power is high, can meet the demand of market to the environment-friendly type aqueous coating of wear-resisting, high adhesive force.
The environment-friendly type aqueous coating of a kind of wear resistant high-adhesion that the present invention proposes, its raw material comprises by weight: urethane resin 55-58 part, acrylic resin 22-25 part, glycerol epoxy resin 20-23 part, modified graphene 7-10 part, organobentonite 2-5 part, mica powder 4-7 part, whipping agent 1.3-1.6 part, flow agent 1.6-1.9 part, dispersion agent 1.8-2.2 part, film coalescence aid 1.2-1.5 part, pigment 1.6-2 part, hydrogenated castor oil 2.5-2.8 part, deionized water 56-60 part;
In the preparation process of modified graphene, by weight 1-3 part Graphene and 20-25 part sulfuric acid/nitric acid fluid,matching are put into and carry out the first ultrasonic disperse after the first reaction vessel being placed in 62-65 DEG C of water-bath mixes and obtain material A, ultrasonic disperse time first time is 2-3h, first time, the frequency of ultrasonic disperse was 15-18KHz, and the power of ultrasonic disperse is 800-1000W for the first time; Material A is dropped into 1.2-1.6 × 10
4in part deionized water, adjust ph is first time ageing 1.1-1.4h after 6.8-7.1, and suction filtration, drying obtain material B; By material B, 16-20 part thionyl chloride, 8-11 part N, dinethylformamide puts into the second reaction vessel that temperature is 72-76 DEG C, underpressure distillation 0.6-1h after insulation 20-22h under nitrogen protection, after second time ageing 1.1-1.4h, suction filtration, drying obtain material C; Material C, 5-8 part triethylene tetramine is added the 3rd reaction vessel to mix and carry out second time ultrasonic disperse, the second time ultrasonic disperse time is 3-5h, the frequency of second time ultrasonic disperse is 55-58KHz, the power of second time ultrasonic disperse is 850-1100W, again the 3rd reaction vessel temperature is increased to 105-112 DEG C and is incubated 3.2-4h, after underpressure distillation 0.5-1h, suction filtration, drying obtain modified graphene;
The sulphuric acid soln of wherein sulfuric acid/nitric acid fluid,matching to be concentration be 96-98wt% and concentration are the mixing solutions that the salpeter solution of 52-55wt% is prepared according to the volume ratio of 4.1-4.4:1.2-1.5.
Preferably, the weight ratio of urethane resin, acrylic resin, glycerol epoxy resin is 56-57:23-24:21-22.
Preferably, the weight ratio of modified graphene, organobentonite, mica powder is 8-9:3-4:5-6 part.
Preferably, its raw material comprises by weight: urethane resin 56-57 part, acrylic resin 23-24 part, glycerol epoxy resin 21-22 part, modified graphene 8-9 part, organobentonite 3-4 part, mica powder 5-6 part, whipping agent 1.4-1.5 part, flow agent 1.7-1.8 part, dispersion agent 1.9-2.1 part, film coalescence aid 1.3-1.4 part, pigment 1.7-1.8 part, hydrogenated castor oil 2.6-2.7 part, deionized water 56-60 part.
Preferably, in the preparation process of modified graphene, by weight 1.5-2 part Graphene and 22-24 part sulfuric acid/nitric acid fluid,matching are put into and carry out the first ultrasonic disperse after the first reaction vessel being placed in 63-64 DEG C of water-bath mixes and obtain material A, ultrasonic disperse time first time is 2.2-2.5h, first time, the frequency of ultrasonic disperse was 16-17KHz, and the power of ultrasonic disperse is 840-900W for the first time; Material A is dropped into 1.3-1.5 × 10
4in part deionized water, adjust ph is first time ageing 1.2-1.3h after 6.8-7.1, and suction filtration, drying obtain material B; By material B, 17-18 part thionyl chloride, 9-10 part N, dinethylformamide puts into the second reaction vessel that temperature is 73-75 DEG C, underpressure distillation 0.7-0.8h after insulation 20.5-21h under nitrogen protection, after second time ageing 1.2-1.3h, suction filtration, drying obtain material C; Material C, 6-7 part triethylene tetramine is added the 3rd reaction vessel to mix and carry out second time ultrasonic disperse, the second time ultrasonic disperse time is 3.5-4h, the frequency of second time ultrasonic disperse is 56-57KHz, the power of second time ultrasonic disperse is 900-1000W, again the 3rd reaction vessel temperature is increased to 108-110 DEG C and is incubated 3.4-3.8h, after underpressure distillation 0.6-0.7h, suction filtration, drying obtain modified graphene; The sulphuric acid soln of wherein sulfuric acid/nitric acid fluid,matching to be concentration be 96-98wt% and concentration are the mixing solutions that the salpeter solution of 53-54wt% is prepared according to the volume ratio of 4.2-4.3:1.3-1.4.
The present invention for filmogen, makes the present invention have good sticking power and wear resisting property with urethane resin, acrylic resin and glycerol epoxy resin, the modified graphene added, organobentonite, mica powder can be good at dispersion in deionized water, wherein modified graphene is made up through triethylene tetramine modification of Graphene, in modifying process, triethylene tetramine and graphenic surface epoxy group(ing) generation ring-opening reaction, the new side chain formed can with the hydroxyl reaction on the carbon atom of ortho position, form double bond and azanol, thus substantially increase Graphene dispersiveness in deionized water on the one hand, reduce the agglomeration of Graphene, and then be easy to use material surface diffusion of the present invention, thus improve sticking power of the present invention, modified graphene interfacial energy strengthens on the other hand, effectively can embed the also degree of depth is blended in filmogen of the present invention, thus the present invention is impacted, during the reactive forces such as friction, load in the present invention can by interfacial migration on Graphene, thus absorb more reactive force, enhance wear resisting property of the present invention, and the present invention is in process of production without waste residue, waste gas, discharge of wastewater, non-environmental-pollution, in use nonpoisonous and tasteless, heavy metal content is extremely low, to human body without harm, is a kind of environment-friendly type aqueous coating.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
The environment-friendly type aqueous coating of a kind of wear resistant high-adhesion that the present invention proposes, its raw material comprises by weight: urethane resin 58 parts, acrylic resin 22 parts, glycerol epoxy resin 23 parts, modified graphene 7 parts, organobentonite 5 parts, mica powder 4 parts, whipping agent 1.6 parts, flow agent 1.6 parts, dispersion agent 2.2 parts, film coalescence aid 1.2 parts, pigment 2 parts, hydrogenated castor oil 2.5 parts, deionized water 60 parts;
In the preparation process of modified graphene, by weight 1 part of Graphene and 25 parts of sulfuric acid/nitric acid fluid,matchings are put into and carry out the first ultrasonic disperse after the first reaction vessel being placed in 62 DEG C of water-baths mixes and obtain material A, ultrasonic disperse time first time is 3h, first time, the frequency of ultrasonic disperse was 15KHz, and the power of ultrasonic disperse is 1000W for the first time; Material A is dropped into 1.2 × 10
4in part deionized water, adjust ph is 7.1 rear first time ageing 1.1h, and suction filtration, drying obtain material B; Material B, 20 parts of thionyl chlorides, 8 parts of DMFs are put into the second reaction vessel that temperature is 76 DEG C, under nitrogen protection underpressure distillation 1h after insulation 20h, after second time ageing 1.1h, suction filtration, drying obtain material C; Material C, 8 parts of triethylene tetramines are added the 3rd reaction vessel to mix and carry out second time ultrasonic disperse, the second time ultrasonic disperse time is 3h, the frequency of second time ultrasonic disperse is 58KHz, the power of second time ultrasonic disperse is 850W, again the 3rd reaction vessel temperature is increased to 112 DEG C and is incubated 3.2h, after underpressure distillation 1h, suction filtration, drying obtain modified graphene; The sulphuric acid soln of wherein sulfuric acid/nitric acid fluid,matching to be concentration be 96wt% and concentration are the mixing solutions that the salpeter solution of 55wt% is prepared according to the volume ratio of 4.1:1.5.
Embodiment 2
The environment-friendly type aqueous coating of a kind of wear resistant high-adhesion that the present invention proposes, its raw material comprises by weight: urethane resin 55 parts, acrylic resin 25 parts, glycerol epoxy resin 20 parts, modified graphene 10 parts, organobentonite 2 parts, mica powder 7 parts, whipping agent 1.3 parts, flow agent 1.9 parts, dispersion agent 1.8 parts, film coalescence aid 1.5 parts, pigment 1.6 parts, hydrogenated castor oil 2.8 parts, deionized water 56 parts;
In the preparation process of modified graphene, by weight 3 parts of Graphenes and 20 parts of sulfuric acid/nitric acid fluid,matchings are put into and carry out the first ultrasonic disperse after the first reaction vessel being placed in 65 DEG C of water-baths mixes and obtain material A, ultrasonic disperse time first time is 2h, first time, the frequency of ultrasonic disperse was 18KHz, and the power of ultrasonic disperse is 800W for the first time; Material A is dropped into 1.6 × 10
4in part deionized water, adjust ph is 6.8 rear first time ageing 1.4h, and suction filtration, drying obtain material B; Material B, 16 parts of thionyl chlorides, 11 parts of DMFs are put into the second reaction vessel that temperature is 72 DEG C, under nitrogen protection underpressure distillation 0.6h after insulation 22h, after second time ageing 1.4h, suction filtration, drying obtain material C; Material C, 5 parts of triethylene tetramines are added the 3rd reaction vessel to mix and carry out second time ultrasonic disperse, the second time ultrasonic disperse time is 5h, the frequency of second time ultrasonic disperse is 55KHz, the power of second time ultrasonic disperse is 1100W, again the 3rd reaction vessel temperature is increased to 105 DEG C and is incubated 4h, after underpressure distillation 0.5h, suction filtration, drying obtain modified graphene; The sulphuric acid soln of wherein sulfuric acid/nitric acid fluid,matching to be concentration be 98wt% and concentration are the mixing solutions that the salpeter solution of 52wt% is prepared according to the volume ratio of 4.4:1.2.
Embodiment 3
The environment-friendly type aqueous coating of a kind of wear resistant high-adhesion that the present invention proposes, its raw material comprises by weight: urethane resin 57 parts, acrylic resin 23 parts, glycerol epoxy resin 22 parts, modified graphene 8 parts, organobentonite 4 parts, mica powder 5 parts, whipping agent 1.5 parts, flow agent 1.7 parts, dispersion agent 2.1 parts, film coalescence aid 1.3 parts, pigment 1.8 parts, hydrogenated castor oil 2.6 parts, deionized water 60 parts.
In the preparation process of modified graphene, by weight 1.5 parts of Graphenes and 24 parts of sulfuric acid/nitric acid fluid,matchings are put into and carry out the first ultrasonic disperse after the first reaction vessel being placed in 63 DEG C of water-baths mixes and obtain material A, ultrasonic disperse time first time is 2.5h, first time, the frequency of ultrasonic disperse was 16KHz, and the power of ultrasonic disperse is 900W for the first time; Material A is dropped into 1.3 × 10
4in part deionized water, adjust ph is 7.1 rear first time ageing 1.2h, and suction filtration, drying obtain material B; Material B, 18 parts of thionyl chlorides, 9 parts of DMFs are put into the second reaction vessel that temperature is 75 DEG C, under nitrogen protection underpressure distillation 0.8h after insulation 20.5h, after second time ageing 1.2h, suction filtration, drying obtain material C; Material C, 7 parts of triethylene tetramines are added the 3rd reaction vessel to mix and carry out second time ultrasonic disperse, the second time ultrasonic disperse time is 3.5h, the frequency of second time ultrasonic disperse is 57KHz, the power of second time ultrasonic disperse is 900W, again the 3rd reaction vessel temperature is increased to 110 DEG C and is incubated 3.4h, after underpressure distillation 0.7h, suction filtration, drying obtain modified graphene; The sulphuric acid soln of wherein sulfuric acid/nitric acid fluid,matching to be concentration be 96wt% and concentration are the mixing solutions that the salpeter solution of 54wt% is prepared according to the volume ratio of 4.2:1.4.
Embodiment 4
The environment-friendly type aqueous coating of a kind of wear resistant high-adhesion that the present invention proposes, its raw material comprises by weight: urethane resin 56 parts, acrylic resin 24 parts, glycerol epoxy resin 21 parts, modified graphene 9 parts, organobentonite 3 parts, mica powder 6 parts, whipping agent 1.4 parts, flow agent 1.8 parts, dispersion agent 1.9 parts, film coalescence aid 1.4 parts, pigment 1.7 parts, hydrogenated castor oil 2.7 parts, deionized water 56 parts.
In the preparation process of modified graphene, by weight 2 parts of Graphenes and 22 parts of sulfuric acid/nitric acid fluid,matchings are put into and carry out the first ultrasonic disperse after the first reaction vessel being placed in 64 DEG C of water-baths mixes and obtain material A, ultrasonic disperse time first time is 2.2h, first time, the frequency of ultrasonic disperse was 17KHz, and the power of ultrasonic disperse is 840W for the first time; Material A is dropped into 1.5 × 10
4in part deionized water, adjust ph is 6.8 rear first time ageing 1.3h, and suction filtration, drying obtain material B; Material B, 17 parts of thionyl chlorides, 10 parts of DMFs are put into the second reaction vessel that temperature is 73 DEG C, under nitrogen protection underpressure distillation 0.7h after insulation 21h, after second time ageing 1.3h, suction filtration, drying obtain material C; Material C, 6 parts of triethylene tetramines are added the 3rd reaction vessel to mix and carry out second time ultrasonic disperse, the second time ultrasonic disperse time is 4h, the frequency of second time ultrasonic disperse is 56KHz, the power of second time ultrasonic disperse is 1000W, again the 3rd reaction vessel temperature is increased to 108 DEG C and is incubated 3.8h, after underpressure distillation 0.6h, suction filtration, drying obtain modified graphene; The sulphuric acid soln of wherein sulfuric acid/nitric acid fluid,matching to be concentration be 98wt% and concentration are the mixing solutions that the salpeter solution of 53wt% is prepared according to the volume ratio of 4.3:1.3.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (5)
1. the environment-friendly type aqueous coating of wear resistant high-adhesion, is characterized in that, its raw material comprises by weight: urethane resin 55-58 part, acrylic resin 22-25 part, glycerol epoxy resin 20-23 part, modified graphene 7-10 part, organobentonite 2-5 part, mica powder 4-7 part, whipping agent 1.3-1.6 part, flow agent 1.6-1.9 part, dispersion agent 1.8-2.2 part, film coalescence aid 1.2-1.5 part, pigment 1.6-2 part, hydrogenated castor oil 2.5-2.8 part, deionized water 56-60 part;
In the preparation process of modified graphene, by weight 1-3 part Graphene and 20-25 part sulfuric acid/nitric acid fluid,matching are put into and carry out the first ultrasonic disperse after the first reaction vessel being placed in 62-65 DEG C of water-bath mixes and obtain material A, ultrasonic disperse time first time is 2-3h, first time, the frequency of ultrasonic disperse was 15-18KHz, and the power of ultrasonic disperse is 800-1000W for the first time; Material A is dropped into 1.2-1.6 × 10
4in part deionized water, adjust ph is first time ageing 1.1-1.4h after 6.8-7.1, and suction filtration, drying obtain material B; By material B, 16-20 part thionyl chloride, 8-11 part N, dinethylformamide puts into the second reaction vessel that temperature is 72-76 DEG C, underpressure distillation 0.6-1h after insulation 20-22h under nitrogen protection, after second time ageing 1.1-1.4h, suction filtration, drying obtain material C; Material C, 5-8 part triethylene tetramine is added the 3rd reaction vessel to mix and carry out second time ultrasonic disperse, the second time ultrasonic disperse time is 3-5h, the frequency of second time ultrasonic disperse is 55-58KHz, the power of second time ultrasonic disperse is 850-1100W, again the 3rd reaction vessel temperature is increased to 105-112 DEG C and is incubated 3.2-4h, after underpressure distillation 0.5-1h, suction filtration, drying obtain modified graphene;
The sulphuric acid soln of wherein sulfuric acid/nitric acid fluid,matching to be concentration be 96-98wt% and concentration are the mixing solutions that the salpeter solution of 52-55wt% is prepared according to the volume ratio of 4.1-4.4:1.2-1.5.
2. the environment-friendly type aqueous coating of wear resistant high-adhesion according to claim 1, it is characterized in that, the weight ratio of urethane resin, acrylic resin, glycerol epoxy resin is 56-57:23-24:21-22.
3. the environment-friendly type aqueous coating of wear resistant high-adhesion according to claim 1 or 2, is characterized in that, the weight ratio of modified graphene, organobentonite, mica powder is 8-9:3-4:5-6 part.
4. the environment-friendly type aqueous coating of wear resistant high-adhesion according to any one of claim 1-3, it is characterized in that, its raw material comprises by weight: urethane resin 56-57 part, acrylic resin 23-24 part, glycerol epoxy resin 21-22 part, modified graphene 8-9 part, organobentonite 3-4 part, mica powder 5-6 part, whipping agent 1.4-1.5 part, flow agent 1.7-1.8 part, dispersion agent 1.9-2.1 part, film coalescence aid 1.3-1.4 part, pigment 1.7-1.8 part, hydrogenated castor oil 2.6-2.7 part, deionized water 56-60 part.
5. the environment-friendly type aqueous coating of wear resistant high-adhesion according to any one of claim 1-4, it is characterized in that, in the preparation process of modified graphene, by weight 1.5-2 part Graphene and 22-24 part sulfuric acid/nitric acid fluid,matching are put into and carry out the first ultrasonic disperse after the first reaction vessel being placed in 63-64 DEG C of water-bath mixes and obtain material A, ultrasonic disperse time first time is 2.2-2.5h, first time, the frequency of ultrasonic disperse was 16-17KHz, and the power of ultrasonic disperse is 840-900W for the first time; Material A is dropped into 1.3-1.5 × 10
4in part deionized water, adjust ph is first time ageing 1.2-1.3h after 6.8-7.1, and suction filtration, drying obtain material B; By material B, 17-18 part thionyl chloride, 9-10 part N, dinethylformamide puts into the second reaction vessel that temperature is 73-75 DEG C, underpressure distillation 0.7-0.8h after insulation 20.5-21h under nitrogen protection, after second time ageing 1.2-1.3h, suction filtration, drying obtain material C; Material C, 6-7 part triethylene tetramine is added the 3rd reaction vessel to mix and carry out second time ultrasonic disperse, the second time ultrasonic disperse time is 3.5-4h, the frequency of second time ultrasonic disperse is 56-57KHz, the power of second time ultrasonic disperse is 900-1000W, again the 3rd reaction vessel temperature is increased to 108-110 DEG C and is incubated 3.4-3.8h, after underpressure distillation 0.6-0.7h, suction filtration, drying obtain modified graphene; The sulphuric acid soln of wherein sulfuric acid/nitric acid fluid,matching to be concentration be 96-98wt% and concentration are the mixing solutions that the salpeter solution of 53-54wt% is prepared according to the volume ratio of 4.2-4.3:1.3-1.4.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610413767.6A CN106047115B (en) | 2014-11-05 | 2014-11-05 | A kind of wear resistant high-adhesion environment-friendlywater-based water-based paint |
| CN201410613222.0A CN104327711B (en) | 2014-11-05 | 2014-11-05 | A kind of wear resistant high-adhesion environment-friendlywater-based water-based paint |
| CN201610413371.1A CN106085175B (en) | 2014-11-05 | 2014-11-05 | A kind of wear resistant high-adhesion environment-friendlywater-based water-based paint |
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| CN108624209A (en) * | 2018-05-28 | 2018-10-09 | 安徽开林新材料股份有限公司 | A kind of non-toxic, environmental friendly water-repellent paint and preparation method thereof |
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| CN102167947A (en) * | 2010-11-26 | 2011-08-31 | 湖南晟通科技集团有限公司 | Waterborne anticorrosive primer acrylic resin composition and preparation method thereof |
| CN102352038A (en) * | 2011-07-21 | 2012-02-15 | 同济大学 | Preparation method for grapheme modified bismaleimide resin nanometer composite materials |
| CN104087126A (en) * | 2014-07-15 | 2014-10-08 | 南京航空航天大学 | Marine anticorrosive coating |
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| CN101486863B (en) * | 2008-01-18 | 2012-12-12 | 深圳市海川实业股份有限公司 | Environment friendly waterborne paint and preparation thereof |
| CN102093799A (en) * | 2009-12-15 | 2011-06-15 | 徐昌彪 | Water-borne metal self-drying antirusting paint |
| CN103466610B (en) * | 2013-09-25 | 2015-05-20 | 中国科学院理化技术研究所 | Graphene chemical modification method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102167947A (en) * | 2010-11-26 | 2011-08-31 | 湖南晟通科技集团有限公司 | Waterborne anticorrosive primer acrylic resin composition and preparation method thereof |
| CN102352038A (en) * | 2011-07-21 | 2012-02-15 | 同济大学 | Preparation method for grapheme modified bismaleimide resin nanometer composite materials |
| CN104087126A (en) * | 2014-07-15 | 2014-10-08 | 南京航空航天大学 | Marine anticorrosive coating |
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| CN108624209A (en) * | 2018-05-28 | 2018-10-09 | 安徽开林新材料股份有限公司 | A kind of non-toxic, environmental friendly water-repellent paint and preparation method thereof |
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| CN106085175A (en) | 2016-11-09 |
| CN106085175B (en) | 2018-06-26 |
| CN106047115A (en) | 2016-10-26 |
| CN106047115B (en) | 2018-08-10 |
| CN104327711B (en) | 2016-08-10 |
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