CN104327657A - Special energy-saving heat-insulation water-resistant anticorrosive paint for architectural outer walls - Google Patents
Special energy-saving heat-insulation water-resistant anticorrosive paint for architectural outer walls Download PDFInfo
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- CN104327657A CN104327657A CN201410558806.2A CN201410558806A CN104327657A CN 104327657 A CN104327657 A CN 104327657A CN 201410558806 A CN201410558806 A CN 201410558806A CN 104327657 A CN104327657 A CN 104327657A
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- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
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- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
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Abstract
The invention discloses a special energy-saving heat-insulation water-resistant anticorrosive paint for architectural outer walls, which is prepared from the following raw materials in parts by weight: fluorine/silicon modified acrylate emulsion, epoxy resin, water-based polyurethane, foamed polyurethane, vitrified microbead, mineral wool, rutile titanium white, talcum powder, silane coupling agent, pH regulator, infrared radiation composite powder, hollow silicon dioxide microsphere, composite ferrotitanium powder, modified zinc phosphate, zinc oxide, 2-amino-2-methyl-1-propanol, defoaming agent, film formation assistant, thickener, wetting agent and water. The special energy-saving heat-insulation water-resistant anticorrosive paint for architectural outer walls has the advantages of favorable heat insulation effect, high water resistance, high adhesive force for architectural outer walls, and long service life.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to the heat insulation Waterproof corrosion coating of a kind of external wall energy-saving.
Background technology
In recent years along with the fast development that World Science technology and society is produced, people more and more recognize that environment and energy problem have become 21 century problem demanding prompt solution.There is population cluster the hugest in the world in China, all kinds of buildingss therefore having a large amount of existing structures and building.At the bottom of the year two thousand twenty, the living space in the whole nation is estimated to reach 7,000,000,000 m
2left and right, building energy consumption will increase more than 30% of national total energy consumption rapidly.Therefore, national government not only to improve China build and the energy saving igniter of building that future will build, and energy-conservation transformation to be carried out in the original building of having built.Therefore Building Energy-saving has become one of China's problem demanding prompt solution, wherein uses energy-saving heat-insulating coating to be a kind of effective approach.Meanwhile, the environmental problem of China becomes outstanding and complicated day by day, and corrosion of metal is ubiquitous.At present, China is every year because the corrosion of metallic substance causes the loss more than 5,000 hundred million yuan, iron and steel is as topmost metallic substance, and its corrosion prevention has very important significance, particularly the serious area of coastal cities smog and acid rain and environmental pollution seriously regional.Paint spraying is adopted to prevent metallic corrosion from being most widely used general, the most effective, the most most economical means.
Therefore, a kind of energy-saving heat-insulating is prepared and the coating of Waterproof corrosion is current problem demanding prompt solution.
Summary of the invention
The present invention proposes the heat insulation Waterproof corrosion coating of a kind of external wall energy-saving, its good heat-insulation effect, water tolerance and non-corrosibility are strong, for external wall strong adhesion, and long service life.
The present invention proposes the heat insulation Waterproof corrosion coating of a kind of external wall energy-saving, its raw material comprises following component by weight: fluorine silicon-modified acrylic ester emulsion 100 parts, epoxy resin 5-9 part, aqueous polyurethane 10-15 part, expansion type urethane 10-26 part, glass bead 5-9 part, mineral wool 15-30 part, Rutile type Titanium Dioxide 8-15 part, talcum powder 5-15 part, silane coupling agent 3-6 part, pH adjusting agent 3-9 part, ir radiation composite granule 5-10 part, hollow silica microsphere 10-20 part, composite iron-titanium powder 5-10 part, modified zinc phosphate 10-15 part, zinc oxide 3-7 part, 2-amino-2-methyl-1-propanol 0.2-0.6 part, defoamer 0.2-2.5 part, film coalescence aid 10-18 part, thickening material 5-8 part, wetting agent 1-3 part, water 50-70 part.
Preferably, its raw material comprises following component by weight: fluorine silicon-modified acrylic ester emulsion 100 parts, epoxy resin 6-8 part, aqueous polyurethane 12-14 part, expansion type urethane 15-20 part, glass bead 7-8.5 part, mineral wool 20-26 part, Rutile type Titanium Dioxide 10-13 part, talcum powder 7-10 part, silane coupling agent 4-5.6 part, pH adjusting agent 4-8 part, ir radiation composite granule 6-9 part, hollow silica microsphere 12-17 part, composite iron-titanium powder 7-8.5 part, modified zinc phosphate 12-13 part, zinc oxide 4-6 part, 2-amino-2-methyl-1-propanol 0.3-0.5 part, defoamer 0.8-1.5 part, film coalescence aid 12-16 part, thickening material 6-6.8 part, wetting agent 1.5-2.3 part, water 55-67 part.
Preferably, its raw material comprises following component by weight: fluorine silicon-modified acrylic ester emulsion 100 parts, epoxy resin 7 parts, aqueous polyurethane 13 parts, expansion type urethane 17 parts, glass bead 8 parts, mineral wool 23 parts, Rutile type Titanium Dioxide 12 parts, talcum powder 8 parts, silane coupling agent 5 parts, pH adjusting agent 4.6 parts, ir radiation composite granule 7.8 parts, hollow silica microsphere 13 parts, composite iron-titanium powder 8 parts, modified zinc phosphate 12.5 parts, 4.6 parts, zinc oxide, 2-amino-2-methyl-1-propanol 0.38 part, defoamer 1.3 parts, film coalescence aid 14 parts, thickening material 6.3 parts, wetting agent 2.2 parts, 60 parts, water.
Preferably, described fluorine silicon-modified acrylic ester emulsion is prepared according to following technique: dispersed with stirring 1-3h after methyl methacrylate 8-15 part, vinylbenzene 5-10 part, Sodium dodecylbenzene sulfonate 0.3-0.8 part, polyoxyethylene octylphenol ether 0.5-1.0 part, modified manometer silicon dioxide 3-8 part and the mixing of deionized water 60-100 part is obtained latex A, and the rotating speed wherein stirred is 600-800r/min; Join in reaction unit by the latex A of 1/5 volume, add 2-5 part sodium persulfate aqueous solution, be warming up to 85-90 DEG C under whipped state, stir 2-3.5h and obtain emulsion B, wherein in sodium persulfate aqueous solution, the massfraction of Sodium Persulfate is 5-10wt%; Remaining latex A and 3-8 part ammonium persulfate aqueous solution are added drop-wise in emulsion B under whipped state, wherein time for adding is 2-2.5h, in ammonium persulfate aqueous solution, the massfraction of ammonium persulphate is 10-20wt%, then 5-10 part sodium bicarbonate aqueous solution is added, stir 1.5-2.3h, add 0.05-0.1 part hydrolysis inhibitor, obtain emulsion C after regulating pH to neutrality, wherein in sodium bicarbonate aqueous solution, the massfraction of sodium bicarbonate is 10-20wt%; 15-20 part n-butyl acrylate, 10-20 part vinyltriethoxysilane, dodecafluoroheptyl methacrylate 5-15 part and 5-8 part ammonium persulfate aqueous solution are added drop-wise in emulsion C, be warming up to 85-95 DEG C, regulate pH to neutral after stirring heating 1.2-2h cooling, wherein in ammonium persulfate aqueous solution, the massfraction of ammonium persulphate is 20-30wt%.
Preferably, in the preparation process of fluorine silicon-modified acrylic ester emulsion, described hydrolysis inhibitor is one or more the combination in 1,2-PD, trolamine, Glacial acetic acid, hydrochloric acid.
Preferably, in the preparation process of fluorine silicon-modified acrylic ester emulsion, the properties-correcting agent of described modified manometer silicon dioxide is one or more the combination in linolic acid, ricinolic acid, oleic acid.
Preferably, described modified zinc phosphate is the combination of a kind of in tertiary iron phosphate zinc, phospho-molybdic acid zinc or two kinds.
Preferably, described pH adjusting agent is one or more the combination in ammoniacal liquor, sodium hydroxide, potassium hydroxide, triethylamine.
Preferably, described defoamer is the combination of a kind of in mineral oil defoaming agent and silicone based defoamer or two kinds.
Preferably, described film coalescence aid selects one or more the combination in polyoxyethylene glycol, ethylene glycol ethyl ether, propylene glycol phenylate, alcohol ester 12, butyl glycol ether.
The heat insulation Waterproof corrosion coating of external wall energy-saving of the present invention, in its raw material, the parts by weight of fluorine silicon-modified acrylic ester emulsion are 100 parts, and the parts by weight of epoxy resin can be 5.6, 6.4, 7.3, 8.2, 8.7 parts, the parts by weight of aqueous polyurethane can be 10.3, 11, 11.5, 12.6, 13.5, 14.6 parts, the parts by weight of expansion type urethane can be 10.3, 11, 11.4, 12, 12.6, 13, 13.4, 14, 14.3, 15.6, 16, 16.7, 18, 18.3, 19, 19.4, 20.4, 21, 22, 23, 23.6, 24, 24.5, 25, 25.7 parts, the parts by weight of glass bead can be 5.4, 6, 6.7, 7.3, 7.9, 8.2, 8.6 parts, the parts by weight of mineral wool can be 15.6, 16, 17, 17.8, 19, 20.3, 21, 22, 22.6, 23.4, 24, 24.5, 25, 25.6, 26.7, 27, 28, 28.5, 29, 29.4 parts, the parts by weight of Rutile type Titanium Dioxide can be 8.6, 9, 9.4, 10.3, 11, 11.5, 12.3, 13.4, 14, 14.6 parts, talcous parts by weight can be 5.6, 6, 6.3, 7.8, 8.6, 9, 9.4, 10.3, 11, 11.3, 12, 12.6, 13, 13.4, 14, 14.6 parts, the parts by weight of silane coupling agent can be 3.4, 4.5, 5.3, 5.8 parts, the parts by weight of pH adjusting agent can be 3.6, 4.3, 5, 5.4, 6, 6.3, 7, 7.8, 8.6 parts, the parts by weight of ir radiation composite granule can be 5.6, 6.3, 7, 8, 8.4, 9.6 parts, the parts by weight of hollow silica microsphere can be 10.2, 11, 11.3, 12.4, 13.6, 14, 14.5, 15, 15.3, 16, 16.3, 17.8, 18, 18.6, 19, 19.5 parts, the parts by weight of composite iron-titanium powder can be 5.6, 6, 6.3, 7.4, 8.9, 9, 9.6 parts, the parts by weight of modified zinc phosphate can be 10.4, 11, 11.5, 12.3, 13.5, 14, 14.6 parts, the parts by weight of zinc oxide can be 3.6, 4.5, 5, 5.6, 6.5 parts, the parts by weight of 2-amino-2-methyl-1-propanol can be 0.25, 0.28, 0.36, 0.4, 0.45, 0.55, 0.57 part, the parts by weight of defoamer can be 0.5, 0.7, 0.79, 0.9, 1.2, 1.35, 1.4, 1.6, 1.69, 1.7, 1.8, 1.9, 2.1, 2.2, 2.35, 2.46 parts, the parts by weight of film coalescence aid can be 10.3, 11, 11.3, 12.6, 13, 13.5, 15.2, 16.8, 17, 17.5 parts, the parts by weight of thickening material can be 5.6, 6.4, 7, 7.3, 7.9 parts, the parts by weight of wetting agent can be 1.6, 2, 2.1, 2.8 parts, the parts by weight of water can be 56, 57, 59, 60.6, 62.3, 64, 65, 66, 66.7, 68.9, 69 parts
In the present invention, fluorine silicon is utilized to carry out fluorinated silicone modified ACRYLIC EMULSION that modification obtains as substrate to ACRYLIC EMULSION, wherein, fluorine atom electronegativity is high, atomic radius is little, chemical bond energy is large, so fluoropolymer excellent performance in weathering resistance, chemical-resistant, stain resistant etc., also can form hydrophobic lotus leaf effect, have a high potential as building external paint; Si-O bond energy in silicone resin and nano silicon is also larger, and its film has the performances such as excellent heat-resisting, cold-resistant, humidity, weather-proof, resistance to chemical attack; With fluorine, silicon bi-material, modification is carried out to acrylic resin, can in conjunction with the high-performance of the two, overcome the shortcoming of organo-fluorine polymer temperature tolerance difference and organosilicon polymer resistant to chemical media difference, form complementary advantage, play synergistic effect, make fluorinated silicone modified acrylic resin have the performances such as better water tolerance, resistant of high or low temperature, guarantor's look gloss retention, sticking power and film-forming properties, thus expand its range of application further; Epoxy resin and aqueous polyurethane have that bonding force is high, intensity is large, the advantage of water-tolerant, add the sticking power and water tolerance that can improve coating in substrate to, improve that acrylic ester emulsion sticking power is low, the shortcoming of poor water resistance; Expansion type urethane, glass bead, hollow silica microsphere and mineral wool thermal conductivity is low, voidage is high, density is little, the middle air extremely low containing thermal conductivity, is added in substrate, energy-saving heat-insulating successful; The heat energy being radiated at coating surface can be that infrared wave are launched by ir radiation composite granule, and the temperature reducing body surface reaches the object of energy-saving heat-insulating; Rutile type Titanium Dioxide can reflected sunlight, thus play the object of energy-saving heat-insulating, expansion type urethane, glass bead, hollow silica microsphere, mineral wool, ir radiation composite granule, Rutile type Titanium Dioxide are added in substrate after coordinating, make it act synergistically, improve the energy-saving heat-insulating of coating; Composite iron-titanium powder is a kind of novel antirust pigment, pollution-free, cheap, be applied in modified propylene acid system, the paint film of formation smooth and free of pinholes and pore, the molecular structure of nano-powder particulate wherein there occurs variation, make molecular structure be in electron deficiency state, its electronic cloud there occurs skew, particulate positively charged, and there is between matrix strong adsorptive power, improve the sticking power between coating and matrix; Modified zinc phosphate can react with iron ion, forms that densification, hardness are high, the passive film of strong adhesion at iron surface, thus inhibits anodic polarization, has good Corrosion Protection; Because zinc oxide has the ability absorbing UV-light, it can form coordination compound with the carboxylic acid ion in coating thus reduce the susceptibility of water in film, therefore zinc oxide can improve weathering resistance and the resistance to chalking ability of film, zine ion in zinc oxide and the hydroxide radical in cathodic area react, generate zinc hydroxide thus play cathodic polarization effect, simultaneously can with surface hydroxyl, carboxyl complexing, thus improve sticking power and the impermeability of coating; Have selected composite iron-titanium powder, modified zinc phosphate and zinc oxide with the use of as protection against corrosion filler, the effect of stabilising system pH value while improving water-resistant coating and erosion resistance, can be played; Talcum powder can play the effect of skeleton, prevents pigment from sinking to the bottom caking, prevents coating sagging and coating be full of cracks, and improves the water tolerance of film, wear resistance, weather resistance, anti-ultraviolet property and brushing property; 2-amino-2-methyl-1-propanol can make colo(u)rant dispersion more abundant, is conducive to improving gloss, coordinates the pH stability that can improve coating with protection against corrosion filler simultaneously, contributes to the sudden strain of a muscle rust reducing steel and iron.
In the present invention, by selecting suitable raw material, the content of adjustment raw material is in optimum ratio, make the mutual cooperation of the performance of each raw material, the external wall energy-saving heat insulation Waterproof corrosion coating obtained is energy-conservation, heat insulation, water-tolerant, good corrosion resistance, be applied in building exterior wall surface long service life.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
In a particular embodiment, the particle diameter of hollow silica microsphere of the present invention is 350-500nm, and wall thickness is 35-50nm.
Embodiment 1
The heat insulation Waterproof corrosion coating of external wall energy-saving of the present invention, its raw material comprises following component by weight: fluorine silicon-modified acrylic ester emulsion 100 parts, epoxy resin 5 parts, aqueous polyurethane 10 parts, expansion type urethane 26 parts, glass bead 5 parts, mineral wool 15 parts, Rutile type Titanium Dioxide 15 parts, talcum powder 15 parts, silane coupling agent 3 parts, pH adjusting agent 9 parts, ir radiation composite granule 5 parts, hollow silica microsphere 20 parts, composite iron-titanium powder 5 parts, modified zinc phosphate 15 parts, 3 parts, zinc oxide, 2-amino-2-methyl-1-propanol 0.6 part, defoamer 0.2 part, film coalescence aid 18 parts, thickening material 5 parts, wetting agent 3 parts, 50 parts, water,
Wherein, described ir radiation composite granule is trichroite-zirconium white ir radiation composite granule.
Embodiment 2
The heat insulation Waterproof corrosion coating of external wall energy-saving of the present invention, its raw material comprises following component by weight: fluorine silicon-modified acrylic ester emulsion 100 parts, epoxy resin 9 parts, aqueous polyurethane 15 parts, expansion type urethane 10 parts, glass bead 9 parts, mineral wool 30 parts, Rutile type Titanium Dioxide 8 parts, talcum powder 5 parts, silane coupling agent 6 parts, pH adjusting agent 3 parts, ir radiation composite granule 10 parts, hollow silica microsphere 10 parts, composite iron-titanium powder 10 parts, modified zinc phosphate 10 parts, 7 parts, zinc oxide, 2-amino-2-methyl-1-propanol 0.2 part, defoamer 2.5 parts, film coalescence aid 10 parts, thickening material 8 parts, wetting agent 1 part, 70 parts, water,
Described fluorine silicon-modified acrylic ester emulsion is prepared according to following technique: dispersed with stirring 1h after the mixing of methyl methacrylate 8 parts, vinylbenzene 10 parts, Sodium dodecylbenzene sulfonate 0.3 part, polyoxyethylene octylphenol ether 1.0 parts, modified manometer silicon dioxide 3 parts and deionized water 100 parts is obtained latex A, and the rotating speed wherein stirred is 800r/min; Join in reaction unit by the latex A of 1/5 volume, add 2 parts of sodium persulfate aqueous solutions, be warming up to 90 DEG C under whipped state, stir 2h and obtain emulsion B, wherein in sodium persulfate aqueous solution, the massfraction of Sodium Persulfate is 10wt%; Remaining latex A and 3 parts of ammonium persulfate aqueous solutions are added drop-wise in emulsion B under whipped state, wherein time for adding is 2.5h, in ammonium persulfate aqueous solution, the massfraction of ammonium persulphate is 10wt%, then 10 parts of sodium bicarbonate aqueous solutions are added, stir 1.5h, add 0.1 part of hydrolysis inhibitor, obtain emulsion C after regulating pH to neutrality, wherein in sodium bicarbonate aqueous solution, the massfraction of sodium bicarbonate is 10wt%; The aqueous solution of 20 parts of n-butyl acrylates, 10 parts of vinyltriethoxysilanes, dodecafluoroheptyl methacrylate 15 parts and 5 parts ammonium persulphates is added drop-wise in emulsion C, be warming up to 95 DEG C, regulate pH to neutral after stirring heating 1.2h cooling, wherein, in ammonium persulfate aqueous solution, the massfraction of ammonium persulphate is 20wt%.
Embodiment 3
The heat insulation Waterproof corrosion coating of external wall energy-saving of the present invention, its raw material comprises following component by weight: fluorine silicon-modified acrylic ester emulsion 100 parts, epoxy resin 7.3 parts, aqueous polyurethane 11 parts, expansion type urethane 14.3 parts, glass bead 7.9 parts, mineral wool 22 parts, Rutile type Titanium Dioxide 11.5 parts, talcum powder 6.3 parts, silane coupling agent 5.8 parts, ammoniacal liquor 7.8 parts, ir radiation composite granule 8.4 parts, hollow silica microsphere 14 parts, composite iron-titanium powder 9 parts, 7 parts, tertiary iron phosphate zinc, 5.3 parts, phospho-molybdic acid zinc, 5.6 parts, zinc oxide, 2-amino-2-methyl-1-propanol 0.4 part, silicone based defoamer 1.6 parts, film coalescence aid 13 parts, thickening material 7.3 parts, wetting agent 2.1 parts, 66 parts, water,
Wherein, described film coalescence aid is that polyoxyethylene glycol, ethylene glycol ethyl ether, propylene glycol phenylate, alcohol ester 12, butyl glycol ether are by the combination of any weight ratio;
Described fluorine silicon-modified acrylic ester emulsion is prepared according to following technique: dispersed with stirring 1.7h after the mixing of methyl methacrylate 10 parts, vinylbenzene 6.6 parts, Sodium dodecylbenzene sulfonate 0.56 part, polyoxyethylene octylphenol ether 0.7 part, oleic acid modified manometer silicon dioxide 3.9 parts and deionized water 80 parts is obtained latex A, and the rotating speed wherein stirred is 700r/min; Join in reaction unit by the latex A of 1/5 volume, add 2.8 parts of sodium persulfate aqueous solutions, be warming up to 88 DEG C under whipped state, stir 3.3h and obtain emulsion B, wherein in sodium persulfate aqueous solution, the massfraction of Sodium Persulfate is 8wt%; Remaining latex A and 6.3 parts of ammonium persulfate aqueous solutions are added drop-wise in emulsion B under whipped state, wherein time for adding is 2.45h, in ammonium persulfate aqueous solution, the massfraction of ammonium persulphate is 20wt%, then 7 parts of sodium bicarbonate aqueous solutions are added, stir 1.9h, add 0.07 part of 1,2-PD, obtain emulsion C after regulating pH to neutrality, wherein in sodium bicarbonate aqueous solution, the massfraction of sodium bicarbonate is 16wt%; 18 parts of n-butyl acrylates, 14 parts of vinyltriethoxysilanes, dodecafluoroheptyl methacrylate 12 parts and 6.4 parts of ammonium persulfate aqueous solutions are added drop-wise in emulsion C, be warming up to 90 DEG C, regulate pH to neutral after stirring heating 1.6h cooling, wherein in ammonium persulfate aqueous solution, the massfraction of ammonium persulphate is 30wt%.
Embodiment 4
The heat insulation Waterproof corrosion coating of external wall energy-saving of the present invention, its raw material comprises following component by weight: fluorine silicon-modified acrylic ester emulsion 100 parts, epoxy resin 7 parts, aqueous polyurethane 13 parts, expansion type urethane 17 parts, glass bead 8 parts, mineral wool 23 parts, Rutile type Titanium Dioxide 12 parts, talcum powder 8 parts, silane coupling agent 5 parts, pH adjusting agent 4.6 parts, ir radiation composite granule 7.8 parts, hollow silica microsphere 13 parts, composite iron-titanium powder 8 parts, 12.5 parts, tertiary iron phosphate zinc, 4.6 parts, zinc oxide, 2-amino-2-methyl-1-propanol 0.38 part, defoamer 1.3 parts, polyoxyethylene glycol 14 parts, thickening material 6.3 parts, wetting agent 2.2 parts, 60 parts, water,
Wherein, described pH adjusting agent is that ammoniacal liquor, sodium hydroxide, potassium hydroxide, triethylamine are by the combination of any weight ratio;
Described defoamer is the combination by any weight ratio of mineral oil defoaming agent and silicone based defoamer;
Described fluorine silicon-modified acrylic ester emulsion is prepared according to following technique: dispersed with stirring 3h after the mixing of methyl methacrylate 15 parts, vinylbenzene 5 parts, Sodium dodecylbenzene sulfonate 0.8 part, polyoxyethylene octylphenol ether 0.5 part, modified manometer silicon dioxide 8 parts and deionized water 60 parts is obtained latex A, and the rotating speed wherein stirred is 600r/min; Join in reaction unit by the latex A of 1/5 volume, add 5 parts of sodium persulfate aqueous solutions, be warming up to 85 DEG C under whipped state, stir 3.5h and obtain emulsion B, wherein in sodium persulfate aqueous solution, the massfraction of Sodium Persulfate is 5wt%; Remaining latex A and 8 parts of ammonium persulfate aqueous solutions are added drop-wise in emulsion B under whipped state, wherein time for adding is 2h, in ammonium persulfate aqueous solution, the massfraction of ammonium persulphate is 15wt%, then 5 parts of sodium bicarbonate aqueous solutions are added, stir 2.3h, add 0.03 part of trolamine and 0.02 part of Glacial acetic acid, obtain emulsion C after regulating pH to neutrality, wherein in sodium bicarbonate aqueous solution, the massfraction of sodium bicarbonate is 20wt%; The aqueous solution of 15 parts of n-butyl acrylates, 20 parts of vinyltriethoxysilanes, dodecafluoroheptyl methacrylate 5 parts and 8 parts ammonium persulphates is added drop-wise in emulsion C, is warming up to 85 DEG C, after stirring heating 2h cooling, regulate pH to neutral; Wherein, wherein the massfraction of ammonium persulphate is 23wt% in ammonium persulfate aqueous solution;
The properties-correcting agent of described modified manometer silicon dioxide is that linolic acid, ricinolic acid, oleic acid are by the combination of any weight ratio.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (10)
1. the heat insulation Waterproof corrosion coating of external wall energy-saving, it is characterized in that, its raw material comprises following component by weight: fluorine silicon-modified acrylic ester emulsion 100 parts, epoxy resin 5-9 part, aqueous polyurethane 10-15 part, expansion type urethane 10-26 part, glass bead 5-9 part, mineral wool 15-30 part, Rutile type Titanium Dioxide 8-15 part, talcum powder 5-15 part, silane coupling agent 3-6 part, pH adjusting agent 3-9 part, ir radiation composite granule 5-10 part, hollow silica microsphere 10-20 part, composite iron-titanium powder 5-10 part, modified zinc phosphate 10-15 part, zinc oxide 3-7 part, 2-amino-2-methyl-1-propanol 0.2-0.6 part, defoamer 0.2-2.5 part, film coalescence aid 10-18 part, thickening material 5-8 part, wetting agent 1-3 part, water 50-70 part.
2. the heat insulation Waterproof corrosion coating of external wall energy-saving according to claim 1, it is characterized in that, its raw material comprises following component by weight: fluorine silicon-modified acrylic ester emulsion 100 parts, epoxy resin 6-8 part, aqueous polyurethane 12-14 part, expansion type urethane 15-20 part, glass bead 7-8.5 part, mineral wool 20-26 part, Rutile type Titanium Dioxide 10-13 part, talcum powder 7-10 part, silane coupling agent 4-5.6 part, pH adjusting agent 4-8 part, ir radiation composite granule 6-9 part, hollow silica microsphere 12-17 part, composite iron-titanium powder 7-8.5 part, modified zinc phosphate 12-13 part, zinc oxide 4-6 part, 2-amino-2-methyl-1-propanol 0.3-0.5 part, defoamer 0.8-1.5 part, film coalescence aid 12-16 part, thickening material 6-6.8 part, wetting agent 1.5-2.3 part, water 55-67 part.
3. the heat insulation Waterproof corrosion coating of external wall energy-saving according to claim 1 or 2, it is characterized in that, its raw material comprises following component by weight: fluorine silicon-modified acrylic ester emulsion 100 parts, epoxy resin 7 parts, aqueous polyurethane 13 parts, expansion type urethane 17 parts, glass bead 8 parts, mineral wool 23 parts, Rutile type Titanium Dioxide 12 parts, talcum powder 8 parts, silane coupling agent 5 parts, pH adjusting agent 4.6 parts, ir radiation composite granule 7.8 parts, hollow silica microsphere 13 parts, composite iron-titanium powder 8 parts, modified zinc phosphate 12.5 parts, 4.6 parts, zinc oxide, 2-amino-2-methyl-1-propanol 0.38 part, defoamer 1.3 parts, film coalescence aid 14 parts, thickening material 6.3 parts, wetting agent 2.2 parts, 60 parts, water.
4. the heat insulation Waterproof corrosion coating of external wall energy-saving according to any one of claim 1-3, it is characterized in that, described fluorine silicon-modified acrylic ester emulsion is prepared according to following technique: dispersed with stirring 1-3h after methyl methacrylate 8-15 part, vinylbenzene 5-10 part, Sodium dodecylbenzene sulfonate 0.3-0.8 part, polyoxyethylene octylphenol ether 0.5-1.0 part, modified manometer silicon dioxide 3-8 part and the mixing of deionized water 60-100 part is obtained latex A, and the rotating speed wherein stirred is 600-800r/min; Join in reaction unit by the latex A of 1/5 volume, add 2-5 part sodium persulfate aqueous solution, be warming up to 85-90 DEG C under whipped state, stir 2-3.5h and obtain emulsion B, wherein in sodium persulfate aqueous solution, the massfraction of Sodium Persulfate is 5-10wt%; Remaining latex A and 3-8 part ammonium persulfate aqueous solution are added drop-wise in emulsion B under whipped state, wherein time for adding is 2-2.5h, in ammonium persulfate aqueous solution, the massfraction of ammonium persulphate is 10-20wt%, then 5-10 part sodium bicarbonate aqueous solution is added, stir 1.5-2.3h, add 0.05-0.1 part hydrolysis inhibitor, obtain emulsion C after regulating pH to neutrality, wherein in sodium bicarbonate aqueous solution, the massfraction of sodium bicarbonate is 10-20wt%; 15-20 part n-butyl acrylate, 10-20 part vinyltriethoxysilane, dodecafluoroheptyl methacrylate 5-15 part and 5-8 part ammonium persulfate aqueous solution are added drop-wise in emulsion C, be warming up to 85-95 DEG C, regulate pH to neutral after stirring heating 1.2-2h cooling, wherein in ammonium persulfate aqueous solution, the massfraction of ammonium persulphate is 20-30wt%.
5. the heat insulation Waterproof corrosion coating of external wall energy-saving according to claim 4, it is characterized in that, in the preparation process of fluorine silicon-modified acrylic ester emulsion, described hydrolysis inhibitor is one or more the combination in 1,2-PD, trolamine, Glacial acetic acid, hydrochloric acid.
6. the heat insulation Waterproof corrosion coating of external wall energy-saving according to claim 4 or 5, it is characterized in that, in the preparation process of fluorine silicon-modified acrylic ester emulsion, the properties-correcting agent of described modified manometer silicon dioxide is one or more the combination in linolic acid, ricinolic acid, oleic acid.
7. the heat insulation Waterproof corrosion coating of external wall energy-saving according to any one of claim 1-6, is characterized in that, described modified zinc phosphate is the combination of a kind of in tertiary iron phosphate zinc, phospho-molybdic acid zinc or two kinds.
8. the heat insulation Waterproof corrosion coating of external wall energy-saving according to any one of claim 1-7, is characterized in that, described pH adjusting agent is one or more the combination in ammoniacal liquor, sodium hydroxide, potassium hydroxide, triethylamine.
9. the heat insulation Waterproof corrosion coating of external wall energy-saving according to any one of claim 1-8, is characterized in that, described defoamer is the combination of a kind of in mineral oil defoaming agent and silicone based defoamer or two kinds.
10. the heat insulation Waterproof corrosion coating of external wall energy-saving according to any one of claim 1-9, it is characterized in that, described film coalescence aid selects one or more the combination in polyoxyethylene glycol, ethylene glycol ethyl ether, propylene glycol phenylate, alcohol ester 12, butyl glycol ether.
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Effective date of registration: 20181203 Address after: 235000 South of Kaiqu East Road, Longhu High-tech Zone, Huaibei Economic Development Zone, Anhui Province Patentee after: HUAIBEI QINGFENG COATING Co.,Ltd. Address before: 241100 Huaqiao Industrial Park, Wuhu County, Wuhu, Anhui Patentee before: WUHU SHUANGBAO BUILDING MATERIAL Co.,Ltd. |
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Address after: 235000 Huaibei Longhu economic and Technological Development Zone, Longhu high tech Zone, south of Kai Canal East Road. Patentee after: Anhui Qingfeng Coating Technology Co.,Ltd. Address before: 235000 Huaibei Longhu economic and Technological Development Zone, Longhu high tech Zone, south of Kai Canal East Road. Patentee before: HUAIBEI QINGFENG COATING Co.,Ltd. |
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Denomination of invention: A special energy-saving, heat-insulating, water-resistant and anti-corrosion paint for building exterior walls Effective date of registration: 20220823 Granted publication date: 20160706 Pledgee: Bank of China Limited Huaibei branch Pledgor: Anhui Qingfeng Coating Technology Co.,Ltd. Registration number: Y2022980013355 |