CN104324627A - Ozone water solution preparing device - Google Patents

Ozone water solution preparing device Download PDF

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Publication number
CN104324627A
CN104324627A CN201410673479.5A CN201410673479A CN104324627A CN 104324627 A CN104324627 A CN 104324627A CN 201410673479 A CN201410673479 A CN 201410673479A CN 104324627 A CN104324627 A CN 104324627A
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China
Prior art keywords
water
gas
pipeline
control system
ozone
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Granted
Application number
CN201410673479.5A
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CN104324627B (en
Inventor
邓煜宝
陈达理
李长松
李彦
管雪强
周仙红
张悦丽
段陈波
刘孝永
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QINGDAO ODO ENVIRONMENTAL TECHNOLOGIES CO., LTD.
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JINAN RUNTU AGRICULTURAL TECHNOLOGY Co Ltd
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Priority to CN201410673479.5A priority Critical patent/CN104324627B/en
Priority to PCT/CN2015/000001 priority patent/WO2016078195A1/en
Publication of CN104324627A publication Critical patent/CN104324627A/en
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Publication of CN104324627B publication Critical patent/CN104324627B/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/80Forming a predetermined ratio of the substances to be mixed
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/48Treatment of water, waste water, or sewage with magnetic or electric fields
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses an ozone water solution preparing device which comprises a control system, and an air pretreating system, an ozone generating system, a gas-liquid mixing system, a water treating system, a gas output control system, a water body magnetizing system and a remote data transmitting system which are controlled by the control system, wherein the air pretreating system, the ozone generating system, the gas output control system and the gas-liquid mixing system are sequentially connected, the water treatment system comprises a water flow control system and a water storing barrel with a water level detector, the water flow control system, the water storing barrel and the gas-liquid mixing system are sequentially connected, a water outlet of the gas-liquid mixing system is connected with the water flow control system; the water body magnetizing system comprises a first-stage water magnetizing device, a second-stage water magnetizing device, a third-stage water magnetizing device and a fourth-stage water magnetizing device which are respectively arranged on pipelines related to the water flow control system, the water storing barrel and the gas-liquid mixing system. According to the ozone water solution preparing device, the problems of complicated preparation, high cost and the like when a large-flow and high-concentration ozone water solution is prepared is solved, multiple products can be provided, and the possibility of connecting into an agricultural product quality traceability system is provided.

Description

A kind of ozone water solution device for making
Technical field
What the present invention relates to the extraordinary aqueous solution produces field, a kind of ozone water solution device for making specifically for agriculturally producing.
Background technology
Last century Mo starts, advanced oxidation reaction is widely used in various fields such as control of agricultural pest, contaminated soil remediation, discarded object harmless treatments, wherein the high-concentrated ozone aqueous solution and generation thereof hydroxyl radical free radical because have that oxidisability is strong, noresidue, non-secondary pollution, become the advanced oxidation reaction solution that use is the most general.High-concentration ozone water has the advantages such as oxidisability is comparatively strong, the valid density duration is longer, is suitable as the continuous action times such as the soil prevention and control of plant diseases, pest control longer application; Have containing the high-concentration oxygen aqueous solution that oxygen content is large, the feature of magnetized drinking water, be applicable to the application of fresh water or sea-farming; Ozone gas has space sterilization advantage, is applicable to the application of agricultural products fresh-keeping process, air sterillization sterilizing.
At present, known Ozone Water producing equipment typical case forms and is: take Liqiud-gas mixing device as core, oxygen, ozone gas is produced, the equipment such as water supply is all connected on Liqiud-gas mixing device, produce ozone water solution.
In actual applications, existing Ozone Water producing equipment is producing the equipment interoperability of the higher oxide that different application needs, produce the large discharge high-concentrated ozone aqueous solution and high containing oxygen magnetized drinking water solution, equipment fault is maintainable, there is the present situation that existing design and product are difficult to meet the demands in the aspects such as the omnidistance quality tracing system of equipment access, this patent proposes innovative technique design in following several respects for this reason, solve existing patent deficiency in actual applications, this patent is in practicality, applicability, high efficiency, prior art deficiency in actual applications that the many aspects such as equipment interoperability are perfect.
For obtaining high-concentration ozone water, prior art and product take two kinds of solutions, and a kind of scheme adopts Ozone Water circulation reflux device the Ozone Water produced to be reentered in water butt to realize circulation to be produced.The actual conditions that the program occurs in actual applications are, most application needs immediately to produce, immediately use, and are difficult to meet that circulation produces waits as long for the time.Another kind of scheme adopts flow-control equipment to reduce equipment water yield, realize the lifting of water outlet consistency of ozone water, the program in actual applications, large discharge high concentration water body cannot be produced within a short period of time, as agricultural irrigation requires the ozone water solution producing 20-30 cubic meter per hour, and require ozone in water content >2PPM, O in water after process 3content and O 2the half-life requirement of content reaches 30-60 minute.
Ozone water solution, high containing oxygen magnetized drinking water solution and ozone gas as the advanced oxidation material be widely used, in each application, there is respective advantage, but prior art and product, be difficult to meet identical product and this three kinds of advanced oxidation materials can be provided, user needs according to different needs, configure different equipment, to produce wherein a kind of advanced oxidation material, reduce utilization rate of equipment and installations, the function that equipment is single is difficult to meet the requirement of different application field to same equipment interoperability, applicability.
Advanced oxidation reaction is as a kind of innoxious prevention and control of plant diseases, pest control means, instead of and spread unchecked the chemical requirements of use, to the cultivation of agricultural kind, there is important function, but as organic, nuisanceless, green kind breeding process, its data must by true, timely, standardized record, and be supplied to tracing information user as the kind breeding process after plucking, gathering in the crops in the future, and without similar application in prior art, be difficult to meet apparatus remote and access the requirement of omnidistance quality tracing system to apparatus remote mechanics of communication design.
Summary of the invention
The invention provides a kind of ozone water solution device for making, solution is produced the large discharge high-concentrated ozone aqueous solution and is produced loaded down with trivial details, high in cost of production problem, this device can provide magnetized drinking water, ozone water solution, height containing oxygen magnetized drinking water, ozone gas four kinds of products simultaneously simultaneously, meet the application needs of different field, in addition, equipment operation information remote transmission can also be preserved to data center by this device, achieve real-time, true, the standardized record to equipment operating data, making the use of equipment access agricultural product quality traceability system becomes possibility.
The present invention is by the following technical solutions: a kind of ozone water solution device for making, the air pretreatment system comprising control system and controlled by control system, ozone generation system, gas-fluid mixing systems and water treatment system, it is characterized in that, also comprise gas output control system, water body magnetizing system and remote data transmission system, described air pretreatment system, ozone generation system, gas output control system, gas-fluid mixing systems is connected successively by pipeline, described water treatment system comprises water flow control system and water butt, described water butt is provided with water level detector, described water flow control system is connected with water butt with pipeline by water inlet equipment, described water butt is connected with gas-fluid mixing systems by pipeline, the delivery port of described gas-fluid mixing systems is connected with water flow control system, described water body magnetizing system comprises one-level water magnetizing device, secondary water magnetizing device, described one-level water magnetizing device is arranged on the pipeline of water flow control system, and described secondary water magnetizing device is arranged on the pipeline between water butt and gas-fluid mixing systems, described remote data transmission system is electrically connected with control system, is used for obtaining and the service data of transmission control system record.
Further, described one-level water magnetizing device, secondary water magnetizing device are the identical water magnetizing device of structure, this water magnetizing device comprises body, the two ends of described body connect water supply connector and water out adapter respectively, described body comprises plastic inner pipe, the outside of plastic inner pipe is coated with stainless steel tube, is provided with magnetic shoe between described plastic inner pipe and stainless steel tube.
Further, the magnetism intensity of described magnetic shoe is between 3000-8000 Gausses.
Further, described gas output control system comprises the anti-backwater backflow device of gas-liquid mixing pump air inlet, gas-liquid selects threeway, gas-liquid mixing pump SCS Air Suction Control Solenoid, gas exports Controlling solenoid valve and gas output interface, described gas-liquid selects threeway to connect ozone generation system respectively, gas-liquid mixing pump SCS Air Suction Control Solenoid one end and gas export Controlling solenoid valve one end, the other end of described gas-liquid mixing pump SCS Air Suction Control Solenoid connects the import of gas-liquid mixing pump air inlet anti-backwater backflow device, the anti-backwater backflow device outlet of gas-liquid mixing pump air inlet connects gas-fluid mixing systems, the other end that described gas exports Controlling solenoid valve connects gas output interface.
Further, described gas-fluid mixing systems comprises gas-liquid mixing pump, check-valves, knockout drum, outlet three way and discharge pressure control valve, the delivery port of gas-liquid mixing pump connects check-valves by pipeline, check-valves is connected with knockout drum water inlet by pipeline, the delivery port of knockout drum connects outlet three way one end, the other end of outlet three way connects discharge pressure control valve, discharge pressure control valve connects water flow control system by pipeline, and the 3rd end of outlet three way is provided with pressure release electromagnetic valve.
Further, described water flow control system comprises inlet channel, one-level shunt conduit, secondary shunt conduit, first water outlet mouthpiece, second water outlet mouthpiece, water pump, sample bucket, described inlet channel, water inlet equipment is communicated with by the first reducing tee with one-level shunt conduit, official road between inlet channel and the first reducing tee is provided with one-level water magnetizing device, one-level shunt conduit, secondary shunt conduit is communicated with by the second reducing tee with the first water outlet mouthpiece, pipeline between first water outlet mouthpiece and the second reducing tee is provided with the first control valve, secondary shunt conduit connects one end of the 3rd reducing tee by pipeline, the other end of the 3rd reducing tee connects one end of the 4th reducing tee by pipeline, 3rd end of the 3rd reducing tee connects one end of the 5th reducing tee by pipeline, the other end of the 4th reducing tee connects the delivery port of gas-fluid mixing systems, 3rd end of the 4th reducing tee connects sample bucket water side by pipeline, the other end of the 5th reducing tee connects sample bucket by the pipeline of band water pump, described sample bucket is provided with water quality detector, 3rd end of the 5th reducing tee connects the second water outlet mouthpiece by the pipeline being provided with the second control valve.
Further, described cooling system comprises heat exchange radiator, cooling fluid adding apparatus, cooling fluid level display device, cooling water flow detector, cooling water pump, described heat exchange radiator to be arranged in water butt and an external outlet conduit and an inlet channel, outlet conduit, cooling fluid level display device is communicated with by a threeway with cooling water flow detector, described cooling fluid level display device is also connected with the outlet of cooling fluid adding apparatus, described cooling water flow detector connects cooling water pump water inlet end by pipeline, cooling water pump water side is communicated with the cooling pipe water inlet in ozone generator by pipeline, cooling pipe delivery port in ozone generator is connected with heat exchange radiator inlet pipeline.
Further, the cable that control system comprises man-machine interaction panel, producing process electric control panel and connects producing process electric control panel and other system equipment is produced described in; Described man-machine interaction panel comprises ORP oxidation-reduction potential Displaying Meter, produces solution type selection key, gas-liquid Selective type button, described producing process electric control panel comprise for control each system timesharing start timesharing starting device and cable, for control gas output control system magnetic valve open and close gas output control equipment and cable.
Further, described remote data transmission system comprises locator data and obtains equipment, wireless telecommunications transceiver and communication controller, described locator data obtains equipment and is connected with communication controller respectively by cable with wireless telecommunications transceiver, and described communication controller is connected with control system by cable.
Further, described locator data acquisition equipment is the one in following equipment: satellite Geographic mapping receiver, ID card reader, wireless short-distance location recognition transceiver.
The invention has the beneficial effects as follows:
1, advanced oxidation reaction is as a kind of innoxious prevention and control of plant diseases, pest control means, to the cultivation of agricultural kind, there is important using value, but because this technology is still in constantly in perfect process, the each accessory of equipment is due to service condition, frequency, the difference of environment for use is uncertain for its fault time, equipment provider is caused to be difficult to provide and to keep in repair timely, change the after-sale services such as parts, numerous advanced oxidation producing equipment is thought by user the product that fault rate is very high, have impact on the process that high-level oxidation technology substitutes chemical agent greatly, this patent proposes with the teletransmission of telecommunication technique realization to equipment operation condition information, Timeliness coverage equipment operation exception, fix a breakdown in time, accurately real-time after-sale service is provided.
2, in field of agricultural cultivation, very high flow and Measuring Ozone Concentration in Water requirement are proposed simultaneously to irrigation water, this patent proposes to be provided with irrigation water outlet pipeline delivery port and dilution water flow outlet pipeline delivery port, the water outlet of irrigation water outlet pipeline is directly used in once irrigates, the water outlet of mixed flow outlet pipeline ready-packaged joint is used for the secondary after once having irrigated and irrigates, immediately secondary irrigation is carried out to same soil after adopting untreated water once to irrigate, secondary irrigates the high-concentration ozone water after adopting process, this mode ensure that high-concentration ozone water is remained in the soil of below earth's surface more than 30CM, and the region that this soil layer is disease and pest comparatively to be concentrated, greatly improve the utilization rate of Ozone Water, useful effect rate, improve the effect that Ozone Water kills soil-borne disease insect pest.
3, the water body magnetizing system of design, after carrying out remagnetization to water body, the physics and chemistry character of water body there occurs change, and the solubility of water body improves 67%, plays a key effect to the half-life under the concentration of produced ozone water solution and normal temperature.
4, adopt level Four water body magnetizing system, one-level water magnetizing device is provided with between water inlet treatment system inlet pipeline and water butt, secondary water magnetizing device is provided with between water inlet treatment system and gas-fluid mixing systems, tertiary effluent magnetizing assembly is provided with between gas-fluid mixing systems gas-liquid mixing pump outlet pipeline and check-valves, level Four water magnetizing device is provided with between water flow control system dilution water flow pipeline with dilution water flow mixing reducing tee, adopt the technical scheme that this patent proposes, can when carrying out the water body process of 20 cubic metres per hour, water outlet Measuring Ozone Concentration in Water reaches 2.5PPM, in 35 DEG C of Exposure to Sunlight situations, solution reaches 2 hours with duration.
Accompanying drawing explanation
Fig. 1 is system principle structured flowchart of the present invention;
Fig. 2 is the theory structure schematic diagram of remote data transmission system of the present invention;
Fig. 3 is water magnetizing device sectional structure schematic diagram of the present invention;
Fig. 4 is the structural representation of air pretreatment system of the present invention;
Fig. 5 is the structured flowchart of gas output control system of the present invention;
Fig. 6 is the theory structure block diagram of water flow control system of the present invention;
Fig. 7 is the syndeton block diagram of water butt of the present invention and front and back system;
Fig. 8 is the theory structure block diagram of gas-fluid mixing systems of the present invention.
Fig. 9 is the structured flowchart of cooling system of the present invention.
Mark in Fig. 3: 1 water supply connector, 2 bodys, pipe in 21,22 stainless steel tubes, 23 magnetic shoes, 3 water out adapters.
Mark in Fig. 6: 4 inlet channels, 5 first reducing tees, 6 one-level shunt conduit, 7 second reducing tees, 8 first control valves, 9 first water outlet mouthpieces, 10 secondary shunt conduit, 11 one-level water magnetizing devices, 12 the 3rd reducing tees, 13 the 4th reducing tees, 14 sample buckets, 15 water quality detectors, 16 sampling water pumps, 17 the 5th reducing tees, 18 second control valves, 19 second water outlet mouthpieces.
Detailed description of the invention
A kind of ozone water solution device for making as shown in Figure 1, the air pretreatment system comprising control system and controlled by control system, ozone generation system, gas-fluid mixing systems, water treatment system, gas output control system, water body magnetizing system, remote data transmission system and cooling system, described air pretreatment system, ozone generation system, gas output control system, gas-fluid mixing systems is connected successively by pipeline, described water treatment system comprises water flow control system and water butt, described water butt is provided with water level detector, described water flow control system is connected with water butt with pipeline by water inlet equipment, described water butt is connected with gas-fluid mixing systems by pipeline, the delivery port of described gas-fluid mixing systems is also connected with water flow control system, described water body magnetizing system comprises one-level water magnetizing device, secondary water magnetizing device, described one-level water magnetizing device is arranged on the pipeline of water flow control system, and described secondary water magnetizing device is arranged on the pipeline between water butt and gas-fluid mixing systems, described remote data transmission system is electrically connected with control system, is used for obtaining and the service data of transmission control system record.
For mechanism and the function of each system, labor is as follows:
Described one-level water magnetizing device, secondary water magnetizing device are the identical water magnetizing device of structure, as shown in Figure 3, this water magnetizing device comprises body 2, the two ends of described body 2 connect water supply connector 1 and water out adapter 3 respectively, be connected on pipeline by water supply connector and water out adapter, described body 2 comprises plastic inner pipe 21, and the outside of plastic inner pipe 21 is coated with stainless steel tube 22, is provided with magnetic shoe 23 between described plastic inner pipe 21 and stainless steel tube 22.Wherein, the magnetism intensity of described magnetic shoe is 3000-8000 Gausses.
As shown in Figure 4, described air pretreatment system comprises air cooling driers, air compressor, compressed air drying bucket, SPA molecular-sieve oxygen generator, oxygen flow take into account the gas piping connecting above equipment, normal air is converted to the air being rich in oxygen.The entrance of air cooling driers sucks air, the gas outlet of air cooling driers connects the air inlet of air compressor by tracheae, the gas outlet of air compressor connects the air inlet of compressed air drying bucket by tracheae, the gas outlet of compressed air drying bucket connects the air inlet of molecular-sieve oxygen generator by tracheae, the gas outlet of molecular-sieve oxygen generator is connected with oxygen flow meter air inlet; Be placed with dried particles respectively in the dry bucket of described air inlet and compressed air drying bucket, described dried particles is repeatedly used discolour silica gel particle.When plant running, it is 2-10L/min (liter/min) that described oxygen flow meter controls oxygen flow.
The air being rich in oxygen can deliver to ozone generation system; described ozone generation system comprises ozone generator, power supply, ammeter and apparatus for protecting power supply; ozone generator comprises ozone high pressure generator tube and high-tension electricity source plate; power supply is by ammeter access high-tension electricity source plate; apparatus for protecting power supply is electrically connected with control system; the air inlet of described ozone generator is connected with oxygen flow meter, and gas outlet is connected with gas output-controlling device.
As shown in Figure 5, gas output control system comprises the anti-backwater backflow device of gas-liquid mixing pump air inlet, gas-liquid selects threeway, gas-liquid mixing pump SCS Air Suction Control Solenoid, gas exports Controlling solenoid valve and gas output interface, described gas-liquid selects threeway to connect ozone generation system respectively, gas-liquid mixing pump SCS Air Suction Control Solenoid one end and gas export Controlling solenoid valve one end, the other end of described gas-liquid mixing pump SCS Air Suction Control Solenoid connects the import of gas-liquid mixing pump air inlet anti-backwater backflow device, the anti-backwater backflow device outlet of gas-liquid mixing pump air inlet connects gas-fluid mixing systems, the other end that described gas exports Controlling solenoid valve connects gas output interface.
In use, directly can use the ozone gas of drawing from gas output interface, also gas output interface can be connected with ozone water solution device for making, produce separately the ozone water solution meeting oneself and require.
As shown in Figure 8, gas-fluid mixing systems comprises gas-liquid mixing pump, check-valves, knockout drum, outlet three way and discharge pressure control valve, the delivery port of gas-liquid mixing pump connects check-valves by pipeline, check-valves is connected with knockout drum water inlet by pipeline, the delivery port of knockout drum connects outlet three way one end, the other end of outlet three way connects discharge pressure control valve, discharge pressure control valve connects water flow control system by pipeline, and the 3rd end of outlet three way is provided with pressure release electromagnetic valve.Wherein, gas-liquid mixing pump can be substituted by ejector or static mixer, pressure between discharge pressure governor valve control knockout drum delivery port to discharge pressure control valve is 0.3-0.4Mpa, pressure release electromagnetic valve can be used for auxiliary discharge pressure control valve realize pressure regulate, prevent hypertonia, meanwhile, external pipe can be connected by the outlet three way port at pressure release electromagnetic valve place, export the ozone water solution of high concentration.
As shown in Figure 7, pipeline between water butt and gas-fluid mixing systems is provided with secondary water magnetizing device, be connected by pipeline between water butt with water inlet equipment, water inlet equipment herein comprises into water water pump, inflow Controlling solenoid valve, water level detector is respectively equipped with in water butt, water level detector comprises low water level detector and high water level detector, and described water inlet water pump, magnetic valve, low water level detector and high water level detector are electrically connected by cable to the corresponding control appliance of control system respectively.
As shown in Figure 6, described water flow control system comprises inlet channel 4, one-level shunt conduit 6, secondary shunt conduit 10, first water outlet mouthpiece 9, second water outlet mouthpiece 19, water pump 16, sample bucket 14, inlet channel 4, water inlet equipment is communicated with by the first reducing tee 5 with one-level shunt conduit 6, official road between inlet channel 4 and the first reducing tee 5 is provided with one-level water magnetizing device 11, one-level shunt conduit 6, secondary shunt conduit 10 is communicated with by the second reducing tee 7 with the first water outlet mouthpiece 9, pipeline between first water outlet mouthpiece 9 and the second reducing tee 7 is provided with the first control valve 8, secondary shunt conduit 10 connects one end of the 3rd reducing tee 12 by pipeline, the other end of the 3rd reducing tee 12 connects one end of the 4th reducing tee 13 by pipeline, 3rd end of the 3rd reducing tee 12 connects one end of the 5th reducing tee 17 by pipeline, the other end of the 4th reducing tee 13 connects the delivery port of gas-fluid mixing systems, 3rd end of the 4th reducing tee 13 connects sample bucket 14 by pipeline, the other end of the 5th reducing tee 17 connects sample bucket 14 by the pipeline of band water pump 16, described sample bucket 14 is provided with water quality detector 15, 3rd end of the 5th reducing tee 17 connects the second water outlet mouthpiece 19 by the pipeline being provided with the second control valve 18.
Light water in inlet pipeline 4 flows through one-level water magnetizing device 11, become magnetic water solution, what the first water outlet mouthpiece 9 flowed out is magnetization irrigation water, and the first control valve 8, by the water flow of control first water outlet mouthpiece 9, realizes the control to entering secondary distribution pipeline 10 discharge; Enter current in secondary distribution pipeline 10 through the 3rd reducing tee 12, meanwhile, the high-concentration ozone water of low discharge incorporates in the large discharge magnetized drinking water flowing through the 3rd reducing tee 12 through the 4th reducing tee 13, certain density high oxygen enrichment magnetic water is formed after abundant mixed diluting, flow through the 5th reducing tee 17, flow out finally by the second water outlet mouthpiece 19.
Be provided with the sample bucket 14 of water quality detector 15, the 5th reducing tee 17 is connected by being with the pipeline of water pump 16, thus realize the sampling Detection of oxidation-reduction potential device being exported to the aqueous solution, it should be noted that, first control valve 8, by the water flow of control first water outlet mouthpiece 9, realizes the control to entering secondary distribution pipeline 10 discharge; The ratio of mixing is as the criterion with the data of control system collection, and the first water outlet mouthpiece 9 water outlet is used for directly once irrigating, and the second water outlet mouthpiece 19 water outlet is used for the secondary after once having irrigated and irrigates.
The ozone water solution that gas-fluid mixing systems generates or high heavy-oxygen-enriched water solution are after the sampling Detection of oxidation-reduction potential, by described man-machine interaction panel ORP oxidation-reduction potential Displaying Meter display data, contrast the oxidation-reduction potential standard value corresponding to this application, artificial or automatic control operation adjusts the aperture of the first control valve 8 and the second control valve 18, form the ozone water solution or high oxygen enrichment magnetic water solution that adapt to plant growth requirement, finally flow out from the second water outlet mouthpiece 19.
As shown in Figure 9, described cooling system comprises heat exchange radiator, cooling fluid adding apparatus, cooling fluid level display device, cooling water flow detector, cooling water pump, described heat exchange radiator to be arranged in water butt and an external outlet conduit and an inlet channel, outlet conduit, cooling fluid level display device is communicated with by a threeway with cooling water flow detector, described cooling fluid level display device is also connected with the outlet of cooling fluid adding apparatus, described cooling water flow detector connects cooling water pump water inlet end by pipeline, cooling water pump water side is communicated with the cooling pipe water inlet in ozone generator by pipeline, cooling pipe delivery port in ozone generator is connected with heat exchange radiator inlet pipeline.
Cooling pipe is positioned at ozone generator, for snakelike, annular etc. meets the pipe shape of cooling requirements; Load cooling fluid by cooling fluid adding apparatus in cooling water pump and connecting line thereof, and protect it and be in airtight in flow process all the time, do not leak; Heat exchange radiator is arranged in water butt, and cooling fluid and inner bucket water body realize Rapid Thermal and exchange.
In order to better control each above-mentioned system, described control system comprises man-machine interaction panel, producing process electric control panel and connects the cable of producing process electric control panel and other system equipment.
Producing process electric control panel comprises water inlet control appliance for opening and closing water inlet equipment and cable, water butt water level monitoring equipment and cable, for opening and closing gas control equipment and the cable of air pretreatment system and ozone generation system, for opening and closing gas-liquid mixing pump Control protection equipment and the cable of gas-liquid mixing pump, for opening and closing cooling water pump Control protection equipment and the cable of cooling water pump, for connecting cooling water flow detector, monitoring cooling water flow, the cooling water flow watch-dog of protection ozone generation system and cable, for closing the pressure release electromagnetic valve and cable of shutting down and automatically controlling pressure relief equipment, water controlling equipment and cable is gone out for what control described water flow control system, for controlling timesharing starting device and the cable of each system timesharing startup, for controlling gas output control equipment and the cable of the keying of gas output control system magnetic valve.
The water inlet control appliance opening and closing water inlet equipment is electrically connected by cable with water inlet water pump, Controlling solenoid valve of intaking, described water butt water level monitoring equipment is electrically connected by cable with high water level and low water level detector, water butt water level monitoring equipment is electrically connected by cable with cooling water flow watch-dog, and gas control equipment is electrically connected by cable with air cooling driers, air compressor, SPA molecular-sieve oxygen generator and ozone generator, gas-liquid mixing pump Control protection equipment is electrically connected by cable with gas-liquid mixing pump, cooling water pump Control protection equipment is electrically connected by cable with cooling water pump, cooling water flow watch-dog is electrically connected by cable with cooling water flow detector, cooling water flow watch-dog and gas control equipment, gas-liquid mixing pump Control protection equipment, cooling water pump Control protection equipment, pressure release electromagnetic valve is electrically connected by cable, pressure release electromagnetic valve with automatically control pressure relief equipment and be electrically connected by cable, go out water controlling equipment and described water flow control system water quality detector, water sample is extracted water pump and is electrically connected by cable, timesharing starting device is electrically connected by cable with above control appliance, described gas output control equipment is connected with control gas output control system gas-liquid mixing pump SCS Air Suction Control Solenoid by cable, gas output control equipment exports Controlling solenoid valve by cable and gas and is connected.
Producing process electric control panel control appliance, comprises DC coil A.C. contactor, direct current auxiliary reclay, direct current 24V Switching Power Supply, the time relay; Described producing process electric control panel controls each system A.C. contactor by the time relay and realizes timesharing startup, to reduce the requirement of device start electric current to electric power system.
Man-machine interaction panel comprises low water level indicator lamp, high water level indicator lamp, system power supply indicator lamp, system starts button, system cloud gray model button, water quality Displaying Meter, produce solution type selection key, produce gas-liquid Selective type button, producing process electric control panel is produced solution selection key by cable and man-machine interaction panel and is connected, produce solution type selection key and be in down state, described producing process electric control panel controls described gas control equipment by the cable connected on it, start described ozone generation system ozone generator, produce ozone gas, and finally form ozone water solution, producing solution type selection key is in by the state of rising, producing process electric control panel controls described gas control equipment by the cable connected on it, close described ozone generation system ozone generator, produce high-concentration oxygen gas, and the final height that formed is containing oxygen magnetized drinking water solution.
The requirement of omnidistance quality tracing system to apparatus remote mechanics of communication design is accessed in order to meet apparatus remote, as shown in Figure 2, described remote data transmission system comprises locator data and obtains equipment, wireless telecommunications transceiver and communication controller, described locator data obtains equipment and is connected with communication controller respectively by cable with wireless telecommunications transceiver, and described communication controller is connected with control system by cable.
When reality uses, locator data acquisition equipment is the one in satellite Geographic mapping receiver, ID card reader, wireless short-distance location recognition transceiver, in order to obtain the accurate geographical position that equipment runs; Communication controller sends data command to described wireless telecommunications transceiver, and this instruction is sent to remote control center receiver by wireless communication networks by wireless telecommunications transceiver, and wireless communication networks is the wireless data transmission network such as existing 3G and note; Communication controller obtains equipment, wireless telecommunications transceiver by cable and locator data, is arranged on water quality Displaying Meter data-out port on man-machine interaction panel and other related system equipment connections, described communication controller in each equipment running process by device start time, running time, produce the information such as water water outlet ORP oxidation-reduction potential numerical value, equipment run location, be sent to remote control center receiver by described wireless telecommunications transceiver; The control instruction that communication controller receives the transmission of remote control center transmitter by described wireless telecommunications transceiver in each equipment running process realizes Long-distance Control field apparatus.
Optimum Operation scheme has been found in the actual debugging and running of this patent scheme:
1, present patent application side is through long term test, to water flow velocity to O in magnetized water treatment Water Under 3content and O 2the impact of content results is reached a conclusion: the flow velocity regulating water is 0.1m./s, 0.3m/s, 0.5m/s, 0.6m/s, 0.8m/s, 1.0m/s, measure the change of ozone and oxygen content, result shows, under identical magnetization condition, flow velocity dissolves content at 0.5m/s magnetization ozone in water and oxygen and reaches maximum.
2, present patent application side is through long term test, to cutting magnetic field number of times to O in magnetized water treatment Water Under 3content and O 2the impact of content results is reached a conclusion: under identical magnetization condition, our selected flow velocity is 0.5m/s is optimum flow rate, under this flow conditions, regulates water to iterate through the number of times in magnetic field, be respectively 1 time, 2 times, 3 times, 4 times, 5 times, 7 times, 9 times, measure electrical conductivity, pH, O 3content and O 2the change of content, electrical conductivity, pH, O 3content and O 2content starts increase with the number of times by magnetic field and increase, and finally no longer increases, and declines after fluctuation near certain value, and then above fluctuation of rising repeatedly; After magnetization, ozone content has and very significantly raises, O when magnetizing 3 times, 4 times, 5 times 3content and O 2content reaches maximum, magnetizes 3 times, 5 times, 7 times O in solution under tender feeling condition often 3half-life and O 2half-life reaches maximum, O when magnetizing 5 times 3content and O 2content reduces, and magnetizes 9 O 3content and O 2content is close to untreated water.
3, present patent application side is through long term test, to containing high concentration O 3and O 2magnetized drinking water dissolves O in the water entered in large discharge water under treatment conditions 3content and O 2the impact of content results is reached a conclusion: under identical magnetization condition, and our selected flow velocity is 0.5m/s is optimum flow rate, under this flow conditions, regulates water to iterate through magnetic field 3 times, O in water 3content and O 2content reaches maximum, regulates water to dissolve respectively and enters untreated water, magnetized drinking water through magnetization treatment, obtain as a result, after dissolving and entering the magnetized drinking water of magnetization treatment, O in its water 3content and O 2content is dissolve to enter as O in the water of magnetization treatment respectively 3content and O 2237% of content and 183%, O in solution in normal temperature situation 3half-life and O 2increased Plasma Half-life 532% and 261%.
When reality uses, obtain good effect, concrete case is as follows:
In July, 2014, plant protection research institute of Shandong Academy of Agricultural Sciences adopts this art solutions, inactivation test is carried out for fragrant-flowered garlic maggot 3 instar larvae and pupa, average mortality reaches 97%, inactivation test is carried out for root-knot nematode, average mortality reaches 93%, all meets and exceeds the killing effect of similar Pesticidal products.
In August, 2014, Agricultural Products Research Institute, Shandong Academy of Agricultural Sciences adopts this art solutions, carries out controlling experiment for P. viticola, and effective control rate reaches 75.80%, meets and exceeds the killing effect of similar Pesticidal products.
In August, 2014, intensive processing technology key lab of Shandong Academy of Agricultural Sciences of Agricultural Products Research Institute, Shandong Academy of Agricultural Sciences adopts this art solutions, determination test is carried out for grape normal-temperature fresh-keeping effect, weight-loss ratio reduces 14.39%, fruit drop rate reduces 68.07%, and rotting rate reduces 73.27%.
Except structure of the present invention, all the other are prior art.
The above is the preferred embodiment of the present invention, and for those skilled in the art, under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications are also regarded as protection scope of the present invention.

Claims (10)

1. an ozone water solution device for making, the air pretreatment system comprising control system and controlled by control system, ozone generation system, gas-fluid mixing systems and water treatment system, it is characterized in that, also comprise gas output control system, water body magnetizing system and remote data transmission system, described air pretreatment system, ozone generation system, gas output control system, gas-fluid mixing systems is connected successively by pipeline, described water treatment system comprises water flow control system and water butt, described water butt is provided with water level detector, described water flow control system is connected with water butt with pipeline by water inlet equipment, described water butt is connected with gas-fluid mixing systems by pipeline, the delivery port of described gas-fluid mixing systems is connected with water flow control system, described water body magnetizing system comprises one-level water magnetizing device, secondary water magnetizing device, described one-level water magnetizing device is arranged on the pipeline of water flow control system, and described secondary water magnetizing device is arranged on the pipeline between water butt and gas-fluid mixing systems, described remote data transmission system is electrically connected with control system, is used for obtaining and the service data of transmission control system record.
2. a kind of ozone water solution device for making according to claim 1, it is characterized in that, described one-level water magnetizing device, secondary water magnetizing device are the identical water magnetizing device of structure, this water magnetizing device comprises body, the two ends of described body connect water supply connector and water out adapter respectively, described body comprises plastic inner pipe, and the outside of plastic inner pipe is coated with stainless steel tube, is provided with magnetic shoe between described plastic inner pipe and stainless steel tube.
3. a kind of ozone water solution device for making according to claim 2, is characterized in that, the magnetism intensity of described magnetic shoe is between 3000-8000 Gausses.
4. a kind of ozone water solution device for making according to claim 1-3 any one, it is characterized in that, described gas output control system comprises the anti-backwater backflow device of gas-liquid mixing pump air inlet, gas-liquid selects threeway, gas-liquid mixing pump SCS Air Suction Control Solenoid, gas exports Controlling solenoid valve and gas output interface, described gas-liquid selects threeway to connect ozone generation system respectively, gas-liquid mixing pump SCS Air Suction Control Solenoid one end and gas export Controlling solenoid valve one end, the other end of described gas-liquid mixing pump SCS Air Suction Control Solenoid connects the import of gas-liquid mixing pump air inlet anti-backwater backflow device, the anti-backwater backflow device outlet of gas-liquid mixing pump air inlet connects gas-fluid mixing systems, the other end that described gas exports Controlling solenoid valve connects gas output interface.
5. a kind of ozone water solution device for making according to claim 4, it is characterized in that, described gas-fluid mixing systems comprises gas-liquid mixing pump, check-valves, knockout drum, outlet three way and discharge pressure control valve, the delivery port of gas-liquid mixing pump connects check-valves by pipeline, check-valves is connected with knockout drum water inlet by pipeline, the delivery port of knockout drum connects outlet three way one end, the other end of outlet three way connects discharge pressure control valve, discharge pressure control valve connects water flow control system by pipeline, 3rd end of outlet three way is provided with pressure release electromagnetic valve.
6. a kind of ozone water solution device for making according to claim 5, it is characterized in that, described water flow control system comprises inlet channel, one-level shunt conduit, secondary shunt conduit, first water outlet mouthpiece, second water outlet mouthpiece, water pump, sample bucket, described inlet channel, water inlet equipment is communicated with by the first reducing tee with one-level shunt conduit, official road between inlet channel and the first reducing tee is provided with one-level water magnetizing device, one-level shunt conduit, secondary shunt conduit is communicated with by the second reducing tee with the first water outlet mouthpiece, pipeline between first water outlet mouthpiece and the second reducing tee is provided with the first control valve, secondary shunt conduit connects one end of the 3rd reducing tee by pipeline, the other end of the 3rd reducing tee connects one end of the 4th reducing tee by pipeline, 3rd end of the 3rd reducing tee connects one end of the 5th reducing tee by pipeline, the other end of the 4th reducing tee connects the delivery port of gas-fluid mixing systems, 3rd end of the 4th reducing tee connects sample bucket water side by pipeline, the other end of the 5th reducing tee connects sample bucket by the pipeline of band water pump, described sample bucket is provided with water quality detector, 3rd end of the 5th reducing tee connects the second water outlet mouthpiece by the pipeline being provided with the second control valve.
7. a kind of ozone water solution device for making according to claim 6, it is characterized in that, described cooling system comprises heat exchange radiator, cooling fluid adding apparatus, cooling fluid level display device, cooling water flow detector, cooling water pump, described heat exchange radiator to be arranged in water butt and an external outlet conduit and an inlet channel, outlet conduit, cooling fluid level display device is communicated with by a threeway with cooling water flow detector, described cooling fluid level display device is also connected with the outlet of cooling fluid adding apparatus, described cooling water flow detector connects cooling water pump water inlet end by pipeline, cooling water pump water side is communicated with the cooling pipe water inlet in ozone generator by pipeline, cooling pipe delivery port in ozone generator is connected with heat exchange radiator inlet pipeline.
8. a kind of ozone water solution device for making according to claim 7, is characterized in that, described in produce the cable that control system comprises man-machine interaction panel, producing process electric control panel and connect producing process electric control panel and other system equipment; Described man-machine interaction panel comprises ORP oxidation-reduction potential Displaying Meter, produces solution type selection key, gas-liquid Selective type button, described producing process electric control panel comprise for control each system timesharing start timesharing starting device and cable, for control gas output control system magnetic valve open and close gas output control equipment and cable.
9. a kind of ozone water solution device for making according to claim 8, it is characterized in that, described remote data transmission system comprises locator data and obtains equipment, wireless telecommunications transceiver and communication controller, described locator data obtains equipment and is connected with communication controller respectively by cable with wireless telecommunications transceiver, and described communication controller is connected with control system by cable.
10. a kind of ozone water solution device for making according to claim 9, is characterized in that, described locator data acquisition equipment is the one in following equipment: satellite Geographic mapping receiver, ID card reader, wireless short-distance location recognition transceiver.
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CN107741342A (en) * 2017-11-14 2018-02-27 河南省产品质量监督检验院 A kind of oil loading automatic sampling device
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