CN104322494A - Water emulsion with allicin and validamycin A as effective ingredient - Google Patents
Water emulsion with allicin and validamycin A as effective ingredient Download PDFInfo
- Publication number
- CN104322494A CN104322494A CN201410584217.1A CN201410584217A CN104322494A CN 104322494 A CN104322494 A CN 104322494A CN 201410584217 A CN201410584217 A CN 201410584217A CN 104322494 A CN104322494 A CN 104322494A
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- CN
- China
- Prior art keywords
- aqueous emulsion
- allicin
- jinggangmycin
- validamycin
- grams
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000839 emulsion Substances 0.000 title claims abstract description 34
- JDLKFOPOAOFWQN-VIFPVBQESA-N Allicin Natural products C=CCS[S@](=O)CC=C JDLKFOPOAOFWQN-VIFPVBQESA-N 0.000 title claims abstract description 31
- JDLKFOPOAOFWQN-UHFFFAOYSA-N allicin Chemical compound C=CCSS(=O)CC=C JDLKFOPOAOFWQN-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 235000010081 allicin Nutrition 0.000 title claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 16
- JARYYMUOCXVXNK-UHFFFAOYSA-N Validamycin A Natural products OC1C(O)C(OC2C(C(O)C(O)C(CO)O2)O)C(CO)CC1NC1C=C(CO)C(O)C(O)C1O JARYYMUOCXVXNK-UHFFFAOYSA-N 0.000 title abstract 4
- JARYYMUOCXVXNK-CSLFJTBJSA-N validamycin A Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-CSLFJTBJSA-N 0.000 title abstract 4
- 239000004615 ingredient Substances 0.000 title abstract 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 25
- 230000003405 preventing effect Effects 0.000 claims abstract description 14
- VIESAWGOYVNHLV-UHFFFAOYSA-N 1,3-dihydropyrrol-2-one Chemical compound O=C1CC=CN1 VIESAWGOYVNHLV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 150000004996 alkyl benzenes Chemical class 0.000 claims abstract description 12
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 12
- 239000011575 calcium Substances 0.000 claims abstract description 12
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 12
- 235000007164 Oryza sativa Nutrition 0.000 claims description 25
- 235000009566 rice Nutrition 0.000 claims description 25
- 241000219112 Cucumis Species 0.000 claims description 11
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 claims description 11
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 claims description 11
- 239000003292 glue Substances 0.000 claims description 11
- 235000011187 glycerol Nutrition 0.000 claims description 11
- 239000008367 deionised water Substances 0.000 claims description 9
- 229910021641 deionized water Inorganic materials 0.000 claims description 9
- 239000004480 active ingredient Substances 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 5
- -1 organosilicon Chemical compound 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 230000001276 controlling effect Effects 0.000 abstract 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- 229920002907 Guar gum Polymers 0.000 abstract 1
- 239000000665 guar gum Substances 0.000 abstract 1
- 229960002154 guar gum Drugs 0.000 abstract 1
- 235000010417 guar gum Nutrition 0.000 abstract 1
- 230000008506 pathogenesis Effects 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 241000209094 Oryza Species 0.000 description 24
- 241000607479 Yersinia pestis Species 0.000 description 8
- 239000002131 composite material Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 240000002234 Allium sativum Species 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000000575 pesticide Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 235000004611 garlic Nutrition 0.000 description 4
- 241000234282 Allium Species 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 2
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 239000006013 carbendazim Substances 0.000 description 2
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- 241000234280 Liliaceae Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- GKIRPKYJQBWNGO-OCEACIFDSA-N clomifene Chemical compound C1=CC(OCCN(CC)CC)=CC=C1C(\C=1C=CC=CC=1)=C(\Cl)C1=CC=CC=C1 GKIRPKYJQBWNGO-OCEACIFDSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000205 computational method Methods 0.000 description 1
- 238000003745 diagnosis Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 238000002560 therapeutic procedure Methods 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a water emulsion with allicin and validamycin A as effective ingredients. The effective ingredients are allicin and validamycin A, and the auxiliaries are calcium alkylbenzene sulfonate, N-pyrrolidone, glycerol, organic silicon and guar gum. The water emulsion is obtained through a conventional preparation process, and the water emulsion composition has good preventing and controlling effects on phyricularia oryzae. Since the bactericidal activities of the allicin and the validamycin A have a synergistically adding effect, the effects of preventing and controlling the phyricularia oryzae are effectively enhanced, the obvious preventing and controlling effect can be achieved in early stage or later of pathogenesis, and the lasting period is long.
Description
Technical field
The present invention relates to the aqueous emulsion that active ingredient is allicin and jinggangmycin A, the active ingredient be specifically related to for preventing and treating rice blast is the aqueous emulsion of allicin and jinggangmycin A, belongs to field of biological pesticide.
Background technology
Allicin (Allicin) is a kind of organosulfur compound extracted from the bulb (garlic) of Liliaceae allium garlic (Allium Sativum), is also present in onion and other alliums.Formal name used at school GIUCOSinoate.Pale yellow oily liquid body.Boiling point 80-85 DEG C (0.2kPa), relative density 1.112(20/4 DEG C), index of refraction 1.561.Be dissolved in ethanol, chloroform or ether.Solvability 2.5% (quality) (10 DEG C) in water, its pH value of water solution is 6.5, has grease sediment to be formed time standing.With ethanol, ether and benzene can dissolve each other.Unstable to thermokalite, acid is stablized.By being present in the bulb of liliaceous plant garlic, under large allinase effect, transform generation by the garlic aminoacid existed.Also be present in the bulb of green onion.Have strong large garlic odour, taste is peppery.
Jinggangmeisu comprises jinggangmycin A and jinggangmeisu (mixture of jinggangmycin A and its isomer B, C, D, E, F), at present by the single dose of national agriculture chemical registration, is mainly used in control crop rice blast.Its compound formulation includes, composite with waxy Bacillus, for preventing and treating rice blast, rice blast, head blight; Composite with carbendazim, for preventing and treating rice blast, rice blast, head blight; Composite with tricyclazole, for preventing and treating rice blast, rice blast, false smut; Composite with carbendazim, for preventing and treating rice blast, false smut; With olefin conversion or ucleosides antibiotic composite, for preventing and treating rice blast, false smut; With own azoles alcohol or oxyenadenine composite, for preventing and treating rice blast; Composite with bacillus subtilis, for preventing and treating false smut.Jinggangmeisu is to people and animals' low toxicity, and to birds fish safety, absorption farm antibiotics series bactericidal agent in belonging to, by disturbing and suppressing pathogen cell normal growth to be grown, plays therapeutic action.
Rice blast has another name called rice blast, and the reasons such as the generation of this disease and environment, host, kind and control are in close relations, and sunshine is few, and the mountain area that the mist dew duration is long and the relatively mild riparian area morbidity of weather weigh.In the popular time, general underproduction 10%-20%, heavy underproduction 40%-50%, even No kernels or seeds are gathered, as in a year of scarcity for local field.Rice blast all can occur in paddy rice whole breeding time, rice shoot of causing harm, fringe, joint etc., is called seedling pest, leaf pest, fringe pest and joint pest.The county does not also find that seedling pest occur at present, mainly leaf pest, fringe pest and joint pest.Identify its symptom, for the Accurate Diagnosis state of an illness, carry out observe and predict with preventing and controlling all extremely important.
In prior art, the usage amount of agricultural chemicals is increasing, not only makes crop produce resistance, also brings serious pollution to environment, for the problems referred to above, the invention provides the aqueous emulsion that active ingredient is allicin and jinggangmycin A.
Technical scheme of the present invention is as follows:
Active ingredient is the aqueous emulsion of allicin and jinggangmycin A, and active ingredient is allicin and jinggangmycin A, and auxiliary agent is alkyl benzene calcium sulfonate, N-pyrrolidones, glycerine, organosilicon, melon glue.
Each raw material forms by mass percentage:
Allicin 0.1%-1.5%, jinggangmycin A 0.5%-3%, alkyl benzene calcium sulfonate 5%-9%, N-pyrrolidones 5%-10%, glycerine 3%-6%, organosilicon 0.3%-1%, melon glue 0.1%-0.5%, deionized water supply 100%.
Further, allicin 0.3%-1%, jinggangmycin A 1%-2%, alkyl benzene calcium sulfonate 6%-8%, N-pyrrolidones 6%-9%, glycerine 3.5%-5%, organosilicon 0.5%-0.8%, melon glue 0.2%-0.4%, deionized water supply 100%.
Further, allicin 0.5%, jinggangmycin A 1%, auxiliary agent are alkyl benzene calcium sulfonate 7%, N-pyrrolidones 7%, glycerine 4%, organosilicon 0.6%, melon glue 0.3%, deionized water supply 100%.
Aqueous emulsion of the present invention is for preventing and treating rice blast; Control stage is their early stage or morbidity later stage; Dosage is 3 grams/ha-7 grams/ha, and preferably, dosage is 4 grams/ha-5.5 grams/ha, preferred, is 4.55 grams/ha.
The present composition has extraordinary control efficiency to rice blast, the present invention utilizes the bactericidal activity of allicin and jinggangmycin A to have good synergistic effect, effectively enhance effect rice blast being had concurrently to prevention and therapy, morbidity early stage or morbidity later stage all can reach control efficiency significantly, and the lasting period is long.
Summary of the invention
Embodiment
Further describe the present invention below in conjunction with specific embodiment, advantage and disadvantage of the present invention will be more clear along with description.But embodiment is only exemplary, does not form any restriction to scope of the present invention.It will be understood by those skilled in the art that and can modify to the details of technical solution of the present invention and form or replace down without departing from the spirit and scope of the present invention, but these amendments and replacement all fall within the scope of protection of the present invention.
Embodiment 1
1.5% allicin jinggangmycin A aqueous emulsion
Each raw material forms by mass percentage:
Further, allicin 0.5%, jinggangmycin A 1%, auxiliary agent are alkyl benzene calcium sulfonate 7%, N-pyrrolidones 7%, glycerine 4%, organosilicon 0.6%, melon glue 0.3%, deionized water supply 100%.
By above-mentioned each composition application conventional pesticide process technology, the aqueous emulsion goods being applicable to agriculturally using made.In the present embodiment, the co-toxicity coefficient of allicin and jinggangmycin A is 351.12.
Embodiment 2
0.7% allicin jinggangmycin A aqueous emulsion
Each raw material forms by mass percentage:
Allicin 0.1%, jinggangmycin A 0.6%, alkyl benzene calcium sulfonate 6%, N-pyrrolidones 5%, glycerine 3%, organosilicon 0.5%, melon glue 0.3%, deionized water supply 100%.
By above-mentioned each composition application conventional pesticide process technology, the aqueous emulsion goods being applicable to agriculturally using made.In the present embodiment, the co-toxicity coefficient of allicin and jinggangmycin A is 289.51.
Embodiment 3
2% allicin jinggangmycin A aqueous emulsion
Each raw material forms by mass percentage:
Allicin 1%, jinggangmycin A 1%, alkyl benzene calcium sulfonate 8%, N-pyrrolidones 7%, glycerine 5%, organosilicon 0.6%, melon glue 0.3%, deionized water supply 100%.
By above-mentioned each composition application conventional pesticide process technology, the aqueous emulsion goods being applicable to agriculturally using made.In the present embodiment, the co-toxicity coefficient of allicin and jinggangmycin A is 279.65.
Test example 1 the present invention is to the control efficiency of rice blast
1, test process and method:
Sample 1-3: be respectively the medicament that embodiment of the present invention 1-3 is composite;
Contrast CK
1: 1% allicin aqua (commercially available);
Contrast CK
2: the solvable pulvis of 10% jinggangmycin A (commercially available);
Contrast CK
0: clear water contrasts
Rice blast their early stage starts first time medication, is the sprayer of 0.7mm, arranges process paddy rice by table 1 with injection diameter, often processes repetition 3 times, 7 days, interval, second time dispenser.
Investigation state of an illness radix before dispenser, after second time dispenser 7 days, 21 days, investigation mark incidence.Severity Scaling and drug effect computational methods are undertaken by " pesticide field efficacy medicine test criterion (one) " GB/T17980.19-2000.
The account form of control efficiency is as follows:
Rice blast control efficiency is as shown in table 1:
Table 1
Table 1 result shows, and the present invention has control efficiency significantly to rice blast.
Claims (9)
1. active ingredient is the aqueous emulsion of allicin and jinggangmycin A, it is characterized in that, in described aqueous emulsion, active ingredient is allicin and jinggangmycin A, and auxiliary agent is alkyl benzene calcium sulfonate, N-pyrrolidones, glycerine, organosilicon, melon glue.
2. aqueous emulsion according to claim 1, is characterized in that, in described aqueous emulsion, each raw material forms by mass percentage:
Allicin 0.1%-1.5%, jinggangmycin A 0.5%-3%, alkyl benzene calcium sulfonate 5%-9%, N-pyrrolidones 5%-10%, glycerine 3%-6%, organosilicon 0.3%-1%, melon glue 0.1%-0.5%, deionized water supply 100%.
3. aqueous emulsion according to claim 2, is characterized in that, in described aqueous emulsion, each raw material forms by mass percentage:
Allicin 0.3%-1%, jinggangmycin A 1%-2%, alkyl benzene calcium sulfonate 6%-8%, N-pyrrolidones 6%-9%, glycerine 3.5%-5%, organosilicon 0.5%-0.8%, melon glue 0.2%-0.4%, deionized water supply 100%.
4. aqueous emulsion according to claim 3, is characterized in that, in described aqueous emulsion, each raw material forms by mass percentage:
Allicin 0.5%, jinggangmycin A 1%, auxiliary agent are alkyl benzene calcium sulfonate 7%, N-pyrrolidones 7%, glycerine 4%, organosilicon 0.6%, melon glue 0.3%, deionized water supply 100%.
5. the aqueous emulsion as described in any one of claim 1-4, is characterized in that, described aqueous emulsion is for preventing and treating rice blast.
6. the aqueous emulsion as described in any one of claim 1-4, is characterized in that, described aqueous emulsion dispenser is their early stage or falls ill the later stage period.
7. the aqueous emulsion as described in any one of claim 1-4, is characterized in that, described aqueous emulsion dosage is 3 grams/ha-7 grams/ha.
8. aqueous emulsion according to claim 7, is characterized in that, described aqueous emulsion dosage is 4 grams/ha-5.5 grams/ha.
9. aqueous emulsion according to claim 8, is characterized in that, described aqueous emulsion dosage is 4.55 grams/ha.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410584217.1A CN104322494B (en) | 2014-10-28 | 2014-10-28 | Effective ingredient is the aqueous emulsion of garlicin and jinggangmycin A |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410584217.1A CN104322494B (en) | 2014-10-28 | 2014-10-28 | Effective ingredient is the aqueous emulsion of garlicin and jinggangmycin A |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104322494A true CN104322494A (en) | 2015-02-04 |
| CN104322494B CN104322494B (en) | 2016-08-17 |
Family
ID=52397426
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410584217.1A Expired - Fee Related CN104322494B (en) | 2014-10-28 | 2014-10-28 | Effective ingredient is the aqueous emulsion of garlicin and jinggangmycin A |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104322494B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115152764A (en) * | 2022-06-24 | 2022-10-11 | 江苏省农业科学院 | Application of allicin in preventing and treating pythium root rot of mung beans |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1121774A (en) * | 1994-12-04 | 1996-05-08 | 张长兴 | Specific pesticide for control of plant diseases |
| CN1742579A (en) * | 2005-09-26 | 2006-03-08 | 田琳 | Farm-forestry crop sterilizer |
-
2014
- 2014-10-28 CN CN201410584217.1A patent/CN104322494B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1121774A (en) * | 1994-12-04 | 1996-05-08 | 张长兴 | Specific pesticide for control of plant diseases |
| CN1742579A (en) * | 2005-09-26 | 2006-03-08 | 田琳 | Farm-forestry crop sterilizer |
Non-Patent Citations (1)
| Title |
|---|
| 邵秀芳 等: "大蒜素防治水稻稻瘟病药效试验", 《现代农业科技》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115152764A (en) * | 2022-06-24 | 2022-10-11 | 江苏省农业科学院 | Application of allicin in preventing and treating pythium root rot of mung beans |
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| Publication number | Publication date |
|---|---|
| CN104322494B (en) | 2016-08-17 |
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Effective date of registration: 20160622 Address after: 266109, No. 111, sunny road, Chengyang District, Shandong, Qingdao Applicant after: JINAN CAVIN BIOTECHNOLOGY CO., LTD. Address before: 250062, No. ten, No. 16369, Lixia District, Ji'nan City, Shandong Province Applicant before: SHANDONG ZHONGDA PHARMACEUTICAL CO., LTD. |
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Inventor after: Liu Xiaona Inventor before: Wang Hongtao Inventor before: Duan Xuewen Inventor before: Qu Lijun Inventor before: Quan Weiyu Inventor before: Zhu Liping |
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Effective date of registration: 20170717 Address after: 300000 Tianjin District of Hongqiao City Rainbow gardens 5-3201 Patentee after: Liu Xiaona Address before: 266109, No. 111, sunny road, Chengyang District, Shandong, Qingdao Patentee before: Qingdao Qingzhi Enterprise Management Consulting Co., Ltd. |
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Granted publication date: 20160817 Termination date: 20171028 |