CN104312368A - Water-soluble phenolic anti-rust paint and preparation method thereof - Google Patents
Water-soluble phenolic anti-rust paint and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
- C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
- C08G8/10—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenol
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
- C08K2003/2272—Ferric oxide (Fe2O3)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/328—Phosphates of heavy metals
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Abstract
The invention discloses water-soluble phenolic resin anti-rust paint. The water-soluble phenolic resin anti-rust paint comprises the following raw materials in part by weight: 30-55 parts of water-soluble phenolic resin, 8-20 parts of anti-rust material, 10-20 parts of filler and 15-30 parts of water. The invention further discloses a preparation method of the water-soluble phenolic resin anti-rust paint. The water-soluble phenolic anti-rust paint takes water as a diluent, so that the security coefficient of the water-soluble phenolic anti-rust paint is greatly increased and VOC emission is significantly reduced during production, transportation and use; the flash point of the water-soluble phenolic anti-rust paint reaches the flash point of a non-hazardous chemical and the technical indexes of the water-soluble phenolic anti-rust paint reach and are higher than the oily indexes of similar products in China; the water-soluble phenolic anti-rust paint, as special finished paint, is applicable to primers of all types of oil products, and truly embodies the features of security, environment friendliness and wide application range.
Description
Technical field
The present invention relates to painting technical field, particularly relate to a kind of phenolic antirust paint and preparation method thereof.
Background technology
Phenolic antirust paint is by resol, antirust material, pigment, the clouts such as No. 200 industrial napthas, cobalt, manganese, lead, through grinding, paint, a kind of priming paint to metallic surface antirust function of generation, be characterized in good antirust property water-tolerant, can as the priming paint of fat glue class, alcohol acids finish paint.But in production and use procedure, safety coefficient is low, VOC quantity discharged is large, inflammable, explosive in transport, use, production process, brings great inconvenience.
Summary of the invention
For overcoming problems of the prior art, the present invention aims to provide a kind of water soluble phenol resin rust-inhibiting paint and preparation method thereof.
On the one hand, the invention provides a kind of water soluble phenol resin rust-inhibiting paint, comprise the raw material of following weight proportion: water soluble phenol resin 30-55 part, antirust material 8-20 part, filler 10-20 part and water 15-30 part.
Alternatively, according to water soluble phenol resin rust-inhibiting paint of the present invention, described rust-inhibiting paint comprises the anti-sagging agent of the water-soluble wetting agent of 0.3-0.8 weight part, the water soluble dispersing agent of 0.3-0.8 weight part and 0.3-0.8 weight part further.
Alternatively, according to water soluble phenol resin rust-inhibiting paint of the present invention, described rust-inhibiting paint comprises the pigment of 5-15 weight part further.
Alternatively, according to water soluble phenol resin rust-inhibiting paint of the present invention, described rust-inhibiting paint comprises the siccative of 0.3 weight part further.
Alternatively, water soluble phenol resin rust-inhibiting paint of the present invention, described antirust material is red iron oxide or polyphosphoric acid zinc; Described filler is calcium powder or talcum powder.
Alternatively, according to water soluble phenol resin rust-inhibiting paint of the present invention, described water-soluble wetting agent is organosilicon wetting agent, and described water soluble dispersing agent is organic-silicon-modified dispersion agent, and described anti-sagging agent is inorganic bentonite.
Alternatively, according to water soluble phenol resin rust-inhibiting paint of the present invention, described siccative is made up of the manganese iso-octoate of the cobalt iso-octoate of 0.1 weight part, the zirconium iso-octoate of 0.1 weight part and 0.1 weight part.
On the other hand, the invention provides a kind of preparation method of water soluble phenol resin rust-inhibiting paint, comprise the steps:
A whipping step: join in whipping appts by the resol of 30-55 weight part, stirs 10-20 minute under the rotating speed of 600-800 rev/min;
Secondary stirring step: adding the antirust material of 8-20 weight part and the filler of 10-20 weight part to completing in the resol that once stirs, stirring 15-30 minute under the rotating speed of 1200-1400 rev/min;
Grinding steps: the material completing secondary stirring is placed in sand mill, is ground to granularity and is less than 40 μm;
Triple mixing step: the water adding 15-30 weight part in the material after described grinding, stirs 20-40 minute under the rotating speed of 1200-1400 rev/min.
Alternatively, preparation in accordance with the present invention, in a described whipping step, also adds the water soluble dispersing agent of water-soluble wetting agent and the 0.3-0.8 weight part having 0.3-0.8 weight part; In described secondary stirring step, also add the pigment having 5-15 weight part; In described triple mixing step, also add the anti-sagging agent having 0.3-0.8 weight part.
Alternatively, preparation in accordance with the present invention, comprises four whipping steps further: the siccative adding 0.3 weight part in the material completing triple mixing, stirs 3-10 minute.
Water soluble phenolic rust-inhibiting paint of the present invention is using water as thinner; make this product in production, transport, use procedure; safety coefficient significantly improves; the discharge of VOC reduces in a large number; its product flash-point reaches non-harmful influence flash-point; the technical indicator of its product reaches and higher than national like product index, and can be applicable to the priming paint of all kinds of oil product as a kind of special lacquering, real embodies safety, environmental protection widely applicable feature.
Accompanying drawing explanation
By reading hereafter detailed description of the preferred embodiment, various other advantage and benefit will become cheer and bright for those of ordinary skill in the art.Accompanying drawing only for illustrating the object of preferred implementation, and does not think limitation of the present invention.In the accompanying drawings:
Fig. 1 is the schematic flow sheet of water soluble phenol resin rust-inhibiting paint preparation method of the present invention.
Embodiment
The invention provides many applicable creative concepts, this creative concept can be reflected in a large number of in concrete context.The specific embodiment described in following embodiments of the present invention only as the exemplary illustration of the specific embodiment of the present invention, and does not form limitation of the scope of the invention.
Below in conjunction with accompanying drawing and concrete embodiment, the invention will be further described.
On the one hand, the invention provides a kind of water soluble phenol resin rust-inhibiting paint, it comprises the raw material of following weight proportion: water soluble phenol resin 30-55 part, antirust material 8-20 part, filler 10-20 part and water 15-30 part.
Wherein, in water soluble phenol resin rust-inhibiting paint of the present invention, the antirust material of use is preferably red iron oxide or polyphosphoric acid zinc.Red iron oxide, stable in properties, strong covering power, particle is trickle, can play good effect in paint film, and it is heat-resisting, photostabilization good, highly stable to the effect of air, bases and diluted acid, adds in paint or coating have good rust protection effect as antirust material.The polyphosphoric acid zinc products such as such as tripolyphosphate zinc are the rust-stabilising pigments of white non-toxic, can generate complex compound, therefore, have good rust-proof effect with a lot of Action of Metal Ions.It is not leaded waits heavy metal, nontoxic, pollution-free, and also have no stimulation to skin, Heat stability is good, antirust good, antirust power are strong.
Wherein, in water soluble phenol resin rust-inhibiting paint of the present invention, the filler of use is preferably calcium powder or talcum powder.After adding calcium powder or talcum powder, rust-inhibiting paint not sedimentation can be made, easily disperse, good luster, improving product quality.
Further, water-soluble wetting agent, the water soluble dispersing agent of 0.3-0.8 weight part, the anti-sagging agent of 0.3-0.8 weight part of 0.3-0.8 weight part is also comprised in water soluble phenolic rust-inhibiting paint of the present invention.By adding wetting agent and dispersion agent, resol, antirust material, filler can be made fully wetting by water, and then shorten jitter time, improve gloss, improve tinting strength and opacifying power, improve color developing and toning property, prevent floating, prevent flocculation, prevent sedimentation.By adding anti-sagging agent, the viscosity of paint can be improved, can sagging be stoped in paint solidification or construction process.
Preferably, described water-soluble wetting agent is organosilicon wetting agent, and described water soluble dispersing agent is organic-silicon-modified dispersion agent, and described anti-sagging agent is inorganic bentonite.Wherein, inorganic bentonite is that between montmorillonite layer, interchangeability thing is the wilkinite of the hydrophilic oleophobic of inorganics, and be that the organobentonite in order to distinguish hydrophobic oleophilic oil is what divide, it is widely used in paint or coating industry.Be understandable that, conventional wetting agent well known in the prior art and dispersion agent are also applicable to the present invention.
Again further, water soluble phenol resin rust-inhibiting paint of the present invention also comprises the pigment of 5-15 weight part, thus can the rust-inhibiting paint of production department's different color, realizes the variation of product.Usually, described pigment is titanium dioxide, red iron oxide, red or carbon black.
Again further, water soluble phenol resin rust-inhibiting paint of the present invention also comprises the siccative of 0.3 weight part.The siccative added can accelerate paint film oxidation, polymerization, dry, shortens paint solidification film formation time, increases coating strength and resistance to water-soluble, also helps moistening, the viscoelasticity that disperses, improve coating of pigment simultaneously.In the present invention, described siccative is made up of the manganese iso-octoate of the cobalt iso-octoate of 0.1 weight part, the zirconium iso-octoate of 0.1 weight part and 0.1 weight part.
On the other hand, the invention provides a kind of preparation method of water soluble phenol resin rust-inhibiting paint, Fig. 1 shows the schematic flow sheet of water soluble phenol resin rust-inhibiting paint preparation method of the present invention.As shown in Figure 1, this comprises the steps:
A whipping step S1100: join in whipping appts by the resol of 30-55 weight part, stirs 10-20 minute under the rotating speed of 600-800 rev/min;
Secondary stirring step S1200: adding the antirust material of 8-20 weight part and the filler of 10-20 weight part to completing in the resol that once stirs, stirring 15-30 minute under the rotating speed of 1200-1400 rev/min;
Grinding steps S1300: the material completing secondary stirring is placed in sand mill, is ground to granularity and is less than 40 μm;
Triple mixing step S1400: the water adding 15-30 weight part in the material after described grinding, stirs 20-40 minute under the rotating speed of 1200-1400 rev/min.
Wherein, in a described whipping step S1100, the antirust material of use is preferably red iron oxide or polyphosphoric acid zinc, and the filler of use is preferably calcium powder or talcum powder.In this step, the water soluble dispersing agent of water-soluble wetting agent and the 0.3-0.8 weight part having 0.3-0.8 weight part is also preferably added.More preferably, described water-soluble wetting agent is organosilicon wetting agent, and described water soluble dispersing agent is organic-silicon-modified dispersion agent.
In described secondary stirring step S1200, also add the pigment having 5-15 weight part.Described pigment is titanium dioxide, red iron oxide, red or carbon black.
In described triple mixing step S1300, also add the anti-sagging agent having 0.3-0.8 weight part.Described anti-sagging agent is inorganic bentonite.
Further, preparation method of the present invention also comprises four whipping step S1400: the siccative adding 0.3 weight part in the material completing triple mixing, stirs 3-10 minute.Wherein, described siccative is made up of the manganese iso-octoate of the cobalt iso-octoate of 0.1 weight part, the zirconium iso-octoate of 0.1 weight part and 0.1 weight part.
The water soluble phenol resin rust-inhibiting paint proposed according to the present invention and the optional element of rust-inhibiting paint preparation method more, various embodiments can be designed, therefore specific embodiment is only as the exemplary illustration of specific implementation of the present invention, and does not form limitation of the scope of the invention.In order to concrete description the present invention, following examples are selected to carry out exemplary illustration.
Embodiment 1
The proportioning raw materials of the present embodiment water soluble phenol resin rust-inhibiting paint is: water soluble phenol resin 30 weight part, antirust material 20 weight part, filler 20 weight part and water 30 weight part.
The preparation method of the present embodiment water soluble phenol resin rust-inhibiting paint is:
Resol is joined in a mixing bowl, stir 15 minutes under the rotating speed of 600-800 rev/min; Adding antirust material and filler to completing in the resol that once stirs, stirring 20 minutes under the rotating speed of 1200-1400 rev/min, make material be easier to grinding; The material completing secondary stirring is placed in sand mill, is ground to granularity and is less than 40 μm; In the material after described grinding, add water, stir 20 minutes under the rotating speed of 1200-1400 rev/min, be packaged as finished product paint.
Embodiment 2
The proportioning raw materials of the present embodiment water soluble phenol resin rust-inhibiting paint is: water soluble phenol resin 55 weight part, antirust material 8 weight part, filler 10 weight part and water 27 weight part.
The preparation method of the present embodiment water soluble phenol resin rust-inhibiting paint is identical with embodiment 1.
Embodiment 3
The proportioning raw materials of the present embodiment water soluble phenol resin rust-inhibiting paint is: water soluble phenol resin 40 weight part, antirust material 20 weight part, filler 20 weight part and water 20 weight part.
The preparation method of the present embodiment water soluble phenol resin rust-inhibiting paint is identical with embodiment 1.
Embodiment 4
The proportioning raw materials of the present embodiment water soluble phenol resin rust-inhibiting paint is: water soluble phenol resin 40 weight part, antirust material 10 weight part, filler 20 weight part, water 18.5 weight part, pigment 10 weight part, water-soluble wetting agent 0.5 weight part, water soluble dispersing agent 0.5 weight part, anti-sagging agent 0.5 weight part and siccative 0.3 weight part.
The preparation method of the present embodiment water soluble phenol resin rust-inhibiting paint is:
Resol, water-soluble wetting agent and water soluble dispersing agent are joined in a mixing bowl, stirs 15 minutes under the rotating speed of 600-800 rev/min; Adding pigment, antirust material and filler to completing in the material that once stirs, stirring 20 minutes under the rotating speed of 1200-1400 rev/min, make material be easier to grinding; The material completing secondary stirring is placed in sand mill, is ground to granularity and is less than 40 μm; In the material after described grinding, add water and anti-sagging agent, stir 20 minutes under the rotating speed of 1200-1400 rev/min; Finally add siccative, stir 5 minutes, be packaged as finished product paint.
Embodiment 5
The proportioning raw materials of the present embodiment water soluble phenol resin rust-inhibiting paint is: water soluble phenol resin 55 weight part, antirust material 8 weight part, filler 15.5 weight part, water 15 weight part, pigment 5 weight part, water-soluble wetting agent 0.5 weight part, water soluble dispersing agent 0.5 weight part, anti-sagging agent 0.5 weight part and siccative 0.3 weight part.
The preparation method of the present embodiment water soluble phenol resin rust-inhibiting paint is identical with embodiment 4.
Embodiment 6
The proportioning raw materials of the present embodiment water soluble phenol resin rust-inhibiting paint is: water soluble phenol resin 35 weight part, antirust material 15 weight part, filler 10 weight part, water 23.5 weight part, pigment 15 weight part, water-soluble wetting agent 0.5 weight part, water soluble dispersing agent 0.5 weight part, anti-sagging agent 0.5 weight part and siccative 0.3 weight part.
The preparation method of the present embodiment water soluble phenol resin rust-inhibiting paint is identical with embodiment 4.
The technical indicator of the rust-inhibiting paint prepared by above-described embodiment is reached and higher than national like product index, specific targets and measured value as shown in table 1 below.
Table 1
Water soluble phenol resin rust-inhibiting paint of the present invention, using water as solvent, not only reduces the discharge of VOC in a large number, safety, environmental protection, and simultaneously compared to using gasoline as solvent, its production cost also significantly reduces; As can be seen from table 1 also, its flash-point, up to 70 DEG C, reaches non-harmful influence flash-point, produces, to use and the safety coefficient of transportation significantly improves.
It should be noted, the present invention will be described instead of limit the invention for above-described embodiment, and those skilled in the art can design alternative embodiment when not departing from the scope of claims.In the claims, any reference symbol between bracket should be configured to limitations on claims.Word " comprises " not to be got rid of existence and does not arrange element in the claims or step.Word first, second and third-class use do not represent any order, can be title by these word explanations.
Claims (10)
1. a water soluble phenol resin rust-inhibiting paint, comprises the raw material of following weight proportion: water soluble phenol resin 30-55 part, antirust material 8-20 part, filler 10-20 part and water 15-30 part.
2. water soluble phenol resin rust-inhibiting paint according to claim 1, wherein, described rust-inhibiting paint comprises the anti-sagging agent of the water-soluble wetting agent of 0.3-0.8 weight part, the water soluble dispersing agent of 0.3-0.8 weight part and 0.3-0.8 weight part further.
3. water soluble phenol resin rust-inhibiting paint according to claim 2, wherein, described rust-inhibiting paint comprises the pigment of 5-15 weight part further.
4. water soluble phenol resin rust-inhibiting paint according to claim 3, wherein, described rust-inhibiting paint comprises the siccative of 0.3 weight part further.
5. the water soluble phenol resin rust-inhibiting paint according to any one of claim 1-4, wherein, described antirust material is red iron oxide or polyphosphoric acid zinc; Described filler is calcium powder or talcum powder.
6. water soluble phenol resin rust-inhibiting paint according to claim 2, wherein, described water-soluble wetting agent is organosilicon wetting agent, and described water soluble dispersing agent is organic-silicon-modified dispersion agent, and described anti-sagging agent is inorganic bentonite.
7. water soluble phenol resin rust-inhibiting paint according to claim 4, wherein, described siccative is made up of the manganese iso-octoate of the cobalt iso-octoate of 0.1 weight part, the zirconium iso-octoate of 0.1 weight part and 0.1 weight part.
8. a preparation method for water soluble phenol resin rust-inhibiting paint, comprises the steps:
A whipping step (S1100): join in whipping appts by the resol of 30-55 weight part, stirs 10-20 minute under the rotating speed of 600-800 rev/min;
Secondary stirring step (S1200): adding the antirust material of 8-20 weight part and the filler of 10-20 weight part to completing in the resol that once stirs, stirring 15-30 minute under the rotating speed of 1200-1400 rev/min;
Grinding steps (S1300): the material completing secondary stirring is placed in sand mill, is ground to granularity and is less than 40 μm;
Triple mixing step (S1400): the water adding 15-30 weight part in the material after described grinding, stirs 20-40 minute under the rotating speed of 1200-1400 rev/min.
9. preparation method according to claim 8, wherein,
In a described whipping step (S1100), also add the water soluble dispersing agent of water-soluble wetting agent and the 0.3-0.8 weight part having 0.3-0.8 weight part;
In described secondary stirring step (S1200), also add the pigment having 5-15 weight part;
In described triple mixing step (S1400), also add the anti-sagging agent having 0.3-0.8 weight part.
10. preparation method according to claim 8, wherein, comprises four whipping steps (S1500) further: the siccative adding 0.3 weight part in the material completing triple mixing, stirs 3-10 minute.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410619224.0A CN104312368A (en) | 2014-11-05 | 2014-11-05 | Water-soluble phenolic anti-rust paint and preparation method thereof |
| KR1020150134982A KR20160053769A (en) | 2014-11-05 | 2015-09-23 | A water-soluble phenol-formaldehyde resin antirust paint and preparation method thereof |
| DE102015116792.1A DE102015116792A1 (en) | 2014-11-05 | 2015-10-02 | A water-soluble phenol-formaldehyde resin anti-rust paint and a process for its preparation |
| ITUB2015A005164A ITUB20155164A1 (en) | 2014-11-05 | 2015-11-04 | Anti-rust paint in water-soluble phenol-formaldehyde resin and relative preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410619224.0A CN104312368A (en) | 2014-11-05 | 2014-11-05 | Water-soluble phenolic anti-rust paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104312368A true CN104312368A (en) | 2015-01-28 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410619224.0A Pending CN104312368A (en) | 2014-11-05 | 2014-11-05 | Water-soluble phenolic anti-rust paint and preparation method thereof |
Country Status (4)
| Country | Link |
|---|---|
| KR (1) | KR20160053769A (en) |
| CN (1) | CN104312368A (en) |
| DE (1) | DE102015116792A1 (en) |
| IT (1) | ITUB20155164A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234644A (en) * | 2020-02-13 | 2020-06-05 | 上海果石实业(集团)有限公司 | Transparent antirust paint and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6250368A (en) * | 1985-08-28 | 1987-03-05 | Nippon Paint Co Ltd | Corrosion-resistant paint composition |
| DE4341659A1 (en) * | 1993-12-07 | 1995-06-08 | Schaeffler Waelzlager Kg | Corrosion-resistant lacquer contg. zinc@ alloy pigment |
| CN1702130A (en) * | 2004-05-24 | 2005-11-30 | 上海涂料有限公司上海长风化工厂 | Aqueous rust proof coating and preparation method thereof |
| CN103436136A (en) * | 2013-07-24 | 2013-12-11 | 广州擎天材料科技有限公司 | Room-temperature-curable aqueous anticorrosion primer used for coating external surface of construction crane and preparation method of primer |
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2014
- 2014-11-05 CN CN201410619224.0A patent/CN104312368A/en active Pending
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2015
- 2015-09-23 KR KR1020150134982A patent/KR20160053769A/en active Search and Examination
- 2015-10-02 DE DE102015116792.1A patent/DE102015116792A1/en not_active Withdrawn
- 2015-11-04 IT ITUB2015A005164A patent/ITUB20155164A1/en unknown
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| JPS6250368A (en) * | 1985-08-28 | 1987-03-05 | Nippon Paint Co Ltd | Corrosion-resistant paint composition |
| DE4341659A1 (en) * | 1993-12-07 | 1995-06-08 | Schaeffler Waelzlager Kg | Corrosion-resistant lacquer contg. zinc@ alloy pigment |
| CN1702130A (en) * | 2004-05-24 | 2005-11-30 | 上海涂料有限公司上海长风化工厂 | Aqueous rust proof coating and preparation method thereof |
| CN103436136A (en) * | 2013-07-24 | 2013-12-11 | 广州擎天材料科技有限公司 | Room-temperature-curable aqueous anticorrosion primer used for coating external surface of construction crane and preparation method of primer |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234644A (en) * | 2020-02-13 | 2020-06-05 | 上海果石实业(集团)有限公司 | Transparent antirust paint and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| ITUB20155164A1 (en) | 2017-05-04 |
| DE102015116792A1 (en) | 2016-05-12 |
| KR20160053769A (en) | 2016-05-13 |
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