CN103436120B - A kind of aqueous alkide resin modified acrylic acid emulsion metallic paint and preparation method thereof - Google Patents

A kind of aqueous alkide resin modified acrylic acid emulsion metallic paint and preparation method thereof Download PDF

Info

Publication number
CN103436120B
CN103436120B CN201310340294.8A CN201310340294A CN103436120B CN 103436120 B CN103436120 B CN 103436120B CN 201310340294 A CN201310340294 A CN 201310340294A CN 103436120 B CN103436120 B CN 103436120B
Authority
CN
China
Prior art keywords
parts
aqueous alkide
alkide resin
water
emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201310340294.8A
Other languages
Chinese (zh)
Other versions
CN103436120A (en
Inventor
王辉
梁淑华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Pentium Qi Ye Limited-Liability Co
Original Assignee
Shandong Pentium Qi Ye Limited-Liability Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shandong Pentium Qi Ye Limited-Liability Co filed Critical Shandong Pentium Qi Ye Limited-Liability Co
Priority to CN201310340294.8A priority Critical patent/CN103436120B/en
Publication of CN103436120A publication Critical patent/CN103436120A/en
Application granted granted Critical
Publication of CN103436120B publication Critical patent/CN103436120B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Abstract

A kind of aqueous alkide resin modified acrylic acid emulsion metallic paint provided by the invention, is made up of the component of following weight portion: aqueous alkide resin 18~22 parts, iron oxide red 14~18 parts, 14~18 parts of barium sulfate, deionized water 3.8~4.8 parts, butyl glycol ether 1.5~2.0 parts, neutralizing amine 0.24~0.30 part, water-based metal acrylic emulsion resin 36~49 parts.Aqueous alkide resin modified acrylic acid emulsion metallic paint is with low cost, preparation technology is simple for this, by selecting the optimum proportioning of aqueous alkide resin and water-based metal acrylic emulsion, not only solve the problems such as hole is many, moisture penetration protection difference that simple emulsion painting produces, and solving that simple aqueous alkide resin painting dries slowly, hardness is low and the defect of poor water resistance, prepared metal protection paint good luster, adhesive force is good, resistance to water is strong, salt spray resistance is excellent.

Description

A kind of aqueous alkide resin modified acrylic acid emulsion metallic paint and preparation method thereof
Technical field
The invention belongs to paint field, particularly to aqueous alkide resin modified acrylic acid emulsion metallic paint, the preparation method further relating to this metal protection paint.
Background technology
The U.S. and countries in Europe remove beyond building coating, replace the coating of organic solvent to reach more than 40% with water in factory coating, if plus powdery paints and solventless coatings, having reached more than 60% without the coating of organic solvent.But, China, caused by various factors, replaces organic solvent to produce water paint with water in industrial coating so far and only accounts for the ratio less than 4%, along with the minimizing day by day of non-renewable resources, industrialized side-product CO2Discharge the existence that threaten the mankind and the earth depended on for existence, there is a growing awareness that the importance of protection environment, be the development trend of coating material production with water replacement organic solvent.
Summary of the invention
Goal of the invention: it is an object of the invention to provide a kind of without aqueous alkide resin modified acrylic acid emulsion metallic paint adding organic solvent and preparation method thereof.
Technical scheme: a kind of aqueous alkide resin modified acrylic acid emulsion metallic paint provided by the invention, component by following weight portion are made: aqueous alkide resin 18~22 parts, iron oxide red 14~18 parts, 14~18 parts of barium sulfate, deionized water 3.8~4.8 parts, butyl glycol ether 1.5~2 parts, neutralizing amine 0.24~0.3 part, water-based metal acrylic emulsion resin 36~49 parts.
Preferably, it is made up of the component of following weight portion: aqueous alkide resin 18.7-20.8 part, iron oxide red 15.4-16.3 part, barium sulfate 15.4-16.3 part, deionized water 4.1-4.5 part, butyl glycol ether 1.6-1.8 part, neutralizing amine 0.26-0.28 part, water-based metal acrylic emulsion resin 39.9-43.1 part.
More preferably, described aqueous alkide resin modified acrylic acid emulsion metallic paint is made up of the component of following weight portion: aqueous alkide resin 20 parts, iron oxide red 16 parts, 16 parts of barium sulfate, deionized water 4.3 parts, butyl glycol ether 1.7 parts, neutralizing amine 0.27 part, water-based metal acrylic emulsion resin 42 parts.
Wherein, one or more in ammonia, triethanolamine and triethylamine of described neutralizing amine.
The preparation method that present invention also offers above-mentioned aqueous alkide resin modified acrylic acid emulsion metallic paint, comprises the following steps: by aqueous alkide resin, iron oxide red, barium sulfate, deionized water, butyl glycol ether, neutralizing amine mixing, grinds, obtains just mixed liquid;Being added with acrylic emulsion resin by water-based metal just mixes in liquid, and mixing is filtered, to be obtained final product.
As preferably, fineness of grind is to less than 40 μm.
Beneficial effect: aqueous alkide resin modified acrylic acid emulsion metallic paint provided by the invention is with low cost, preparation technology is simple, by selecting aqueous alkide resin and the water-based metal optimum proportioning of acrylic emulsion resin, not only solve the problems such as hole is many, moisture penetration protection difference that simple emulsion painting produces, and solving that simple aqueous alkide resin painting dries slowly, hardness is low and the defect of poor water resistance, prepared metal protection paint good luster, adhesive force is good, resistance to water is strong, salt spray resistance is excellent.
Due to the water-based metal easy gelling of acrylic emulsion resin, it is impossible to participate in the wetting and dispersing of pigment, cause water-based metal acrylic emulsion resin can not inclusion pigment comprehensively, be difficult to be formed the paint film of densification during use;And the present invention adopts after pigment wetting is disperseed by the aqueous alkide resin that the wettability of pigment is good, add water-based metal acrylic emulsion resin-made and obtain water alcohol acid modified acroleic acid paint, prepare water alcohol acid modified acroleic acid paint compact in paint film, good antirust property.
Aqueous alkide resin modified acrylic acid emulsion metallic paint provided by the invention has that fast drying, compact in paint film, hardness is big, salt spray resistance up to 96 hours, resistance to water reach the advantage of 200 hours, possess the leading level in the world through looking into this product new.
In use, its dry run is the oxidation cross-linked process having concurrently with volatile dry to this aqueous alkide resin modified acrylic acid emulsion metallic paint, and dried paint film has higher gloss, is densification and the macromolecule membrane with hydridization interpenetrating networks.Pigment is had dispersibility and the covering property of excellence by this aqueous alkide resin dried paint film of modified acrylic acid emulsion metallic paint, is had excellent adhesive force, resistance to water and anti-corrosive properties to being coated with ground.
Detailed description of the invention
According to following embodiment, it is possible to be more fully understood that the present invention.But, as it will be easily appreciated by one skilled in the art that the concrete material proportion described by embodiment, process conditions and result thereof are merely to illustrate the present invention, and should without the present invention described in detail in restriction claims.
Aqueous alkide resin of the present invention is the alkyd resin produced by Shandong Benteng Painting Co., Ltd, list marketing.
Water-based metal acrylic emulsion of the present invention is the BC-1 emulsion produced by Shandong Benteng Painting Co., Ltd, list marketing.
Form by the formula of table 1, aqueous alkide resin, iron oxide red, barium sulfate, deionized water, butyl glycol ether, neutralizing amine are put into after stirring in pill tank, with sand mill grinding distribution to fineness less than 40 μm, obtain just mixed liquid;Acrylic emulsion resin is added and just mixes in liquid, stir 30 minutes with homogenizer, allow material be sufficiently mixed uniformly, filter, prepare seven batches of aqueous alkide resin modified acrylic acid emulsion metallic paints.
1 seven batches of aqueous alkide resin modified acrylic acid emulsion metallic paint composition of raw materials of table
By on above-mentioned 1-8# metal protection paint spray metal, observing and detect following performance parameter, result is in Table 2.
The performance parameter of 2 seven batches of aqueous alkide resin modified acrylic acid emulsion metallic paints of table
From above table it can be seen that during aqueous alkide resin consumption height, the paint film physical and mechanical properties obtained is unchanged, but water-fast, salt spray resistance changes substantially;When amount of pigment is few, the gloss of film degree obtained is better, selects suitable proportioning can obtain metal protection coating water-fast, salt water resistance function admirable.

Claims (6)

1. an aqueous alkide resin modified acrylic acid emulsion metallic paint, it is characterised in that: it is made up of the component of following weight portion: aqueous alkide resin 18~22 parts, iron oxide red 14~18 parts, 14~18 parts of barium sulfate, deionized water 3.8~4.8 parts, butyl glycol ether 1.5~2.0 parts, neutralizing amine 0.24~0.30 part, water-based metal acrylic emulsion resin 36~49 parts;
Described aqueous alkide resin modified acrylic acid emulsion metallic paint is made up of following steps:
By aqueous alkide resin, iron oxide red, barium sulfate, deionized water, butyl glycol ether, neutralizing amine mixing, grind, obtain just mixed liquid;Being added with acrylic emulsion resin by water-based metal just mixes in liquid, and mixing is filtered, to be obtained final product.
2. a kind of aqueous alkide resin modified acrylic acid emulsion metallic paint according to claim 1, it is characterised in that: it is made up of the component of following weight portion: aqueous alkide resin 18.7~20.8 parts, iron oxide red 15.4~16.3 parts, 15.4~16.3 parts of barium sulfate, deionized water 4.1~4.5 parts, butyl glycol ether 1.6~1.8 parts, neutralizing amine 0.26~0.28 part, water-based metal acrylic emulsion resin 39.9~43.1 parts.
3. a kind of aqueous alkide resin modified acrylic acid emulsion metallic paint according to claim 1, it is characterised in that: it is made up of the component of following weight portion: aqueous alkide resin 20 parts, iron oxide red 16 parts, 16 parts of barium sulfate, deionized water 4.3 parts, butyl glycol ether 1.7 parts, neutralizing amine 0.27 part, water-based metal acrylic emulsion resin 42 parts.
4. a kind of aqueous alkide resin modified acrylic acid emulsion metallic paint according to any one of claim 1-3, it is characterised in that: one or more in ammonia, triethanolamine and triethylamine of described neutralizing amine.
5. the preparation method of a kind of aqueous alkide resin modified acrylic acid emulsion metallic paint described in any one of claim 1-4, it is characterized in that: comprise the following steps: by aqueous alkide resin, iron oxide red, barium sulfate, deionized water, butyl glycol ether, neutralizing amine mixing, grind, obtain just mixed liquid;Being added with acrylic emulsion resin by water-based metal just mixes in liquid, and mixing is filtered, to be obtained final product.
6. the preparation method of a kind of aqueous alkide resin modified acrylic acid emulsion metallic paint according to claim 5, it is characterised in that: fineness of grind is to less than 40 μm.
CN201310340294.8A 2013-08-07 2013-08-07 A kind of aqueous alkide resin modified acrylic acid emulsion metallic paint and preparation method thereof Active CN103436120B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310340294.8A CN103436120B (en) 2013-08-07 2013-08-07 A kind of aqueous alkide resin modified acrylic acid emulsion metallic paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310340294.8A CN103436120B (en) 2013-08-07 2013-08-07 A kind of aqueous alkide resin modified acrylic acid emulsion metallic paint and preparation method thereof

Publications (2)

Publication Number Publication Date
CN103436120A CN103436120A (en) 2013-12-11
CN103436120B true CN103436120B (en) 2016-07-06

Family

ID=49689843

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310340294.8A Active CN103436120B (en) 2013-08-07 2013-08-07 A kind of aqueous alkide resin modified acrylic acid emulsion metallic paint and preparation method thereof

Country Status (1)

Country Link
CN (1) CN103436120B (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103642343B (en) * 2013-12-19 2016-01-27 肇庆千江高新材料科技股份公司 Aqueous automobile baking vanish and preparation method thereof and using method
CN104530855A (en) * 2014-11-20 2015-04-22 马鞍山市金韩涂料制造有限公司 Water-based rust conversion and prevention paint
CN104479525A (en) * 2014-12-01 2015-04-01 昌利锻造有限公司 Water-based antirust paint for multiple device shells and preparation method thereof
CN106928791A (en) * 2017-01-06 2017-07-07 河北晨阳工贸集团有限公司 A kind of environment-friendly water-based acrylic modified alkyd protective paint for spray coating mechanical equipment and material and preparation method thereof
CN106883739B (en) * 2017-02-16 2019-08-23 河北晨阳工贸集团有限公司 One kind living people's container environmentally friendly sealing wax and preparation method thereof
CN107384071A (en) * 2017-07-19 2017-11-24 河北晨阳工贸集团有限公司 A kind of high durable dip-coating sealing wax and preparation method thereof
CN107286822A (en) * 2017-07-31 2017-10-24 杭州鼎时新材料研究院有限公司 A kind of modified waterborne alkyd industrial antisepsis coating and preparation method
WO2022088139A1 (en) * 2020-10-31 2022-05-05 河北比尔尼克新材料科技股份有限公司 Water-based acrylic modified alkyd resin coating, preparation method therefor and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1560152A (en) * 2004-03-05 2005-01-05 徐厚训 Water paint for protecting surface of car and household electrical apparats
CN101189310A (en) * 2005-06-01 2008-05-28 阿克佐诺贝尔国际涂料股份有限公司 Aqueous coating composition
CN102746762A (en) * 2012-05-29 2012-10-24 兰州理工大学 Alkyd acrylic hybrid latex paint and preparation method thereof
CN102746761A (en) * 2012-05-29 2012-10-24 兰州理工大学 Aqueous alkyd acrylic resin paint and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1560152A (en) * 2004-03-05 2005-01-05 徐厚训 Water paint for protecting surface of car and household electrical apparats
CN101189310A (en) * 2005-06-01 2008-05-28 阿克佐诺贝尔国际涂料股份有限公司 Aqueous coating composition
CN102746762A (en) * 2012-05-29 2012-10-24 兰州理工大学 Alkyd acrylic hybrid latex paint and preparation method thereof
CN102746761A (en) * 2012-05-29 2012-10-24 兰州理工大学 Aqueous alkyd acrylic resin paint and preparation method thereof

Also Published As

Publication number Publication date
CN103436120A (en) 2013-12-11

Similar Documents

Publication Publication Date Title
CN103436120B (en) A kind of aqueous alkide resin modified acrylic acid emulsion metallic paint and preparation method thereof
CN102731052B (en) Aqueous organic-inorganic composite coating and preparation method thereof
CN102618126B (en) Nitrocellulose transparent primer and application thereof
CN100526362C (en) Water-soluble alcohol-acid resin solution and water-soluble alcohol-acid amino baking paint and preparing method
CN100526361C (en) Anticorrosive bottom lacquer of water-soluble alcohol acid, and preparation method
CN105602382A (en) Water-based metal antirust paint and preparation method thereof
CN106675355B (en) A kind of water alcohol acid coating and preparation method thereof
CN103773175B (en) A kind of environmental friendly, anti-corrosive aqueous priming paint coating and preparation method thereof
CN103937367A (en) White cathodic electrophoretic coating, and preparation method and using method thereof
CN107815215B (en) Formula of water-based stone-like coating and water-based stone-like terrace
CN106634382B (en) A kind of bottom surface unification self-drying paint of environment friendly corrosion protection quick-dry type and preparation method thereof
CN102134434A (en) High-performance water-based white sealing primer
CN109439090A (en) A kind of corrosion-resistant quick dried environment protection water paint and preparation method thereof
CN103409026A (en) Environment-friendly waterborne fire retardant coating
CN108250901B (en) High-performance water-based rust conversion paint resin and water-based rust conversion paint
CN103305096B (en) A kind of Multifunctional undercoat and preparation method thereof
CN106366929A (en) Environment-friendly antirust coating primer
CN102260445A (en) Polyester-modified acrylate resin aqueous paint, and preparation method thereof
CN104449025A (en) Method for producing oil paint
CN104017451A (en) Water-based anticorrosive finish paint for vehicle plate springs and chassis
CN106867357B (en) A kind of nanometer modified high-solid body divides epoxy primer
CN104962179B (en) It is a kind of suitable for priming paint of antitheft door and preparation method thereof
CN104710913A (en) Hyperbranched polyester delustring resin-containing non-highlight coating composition and use thereof
CN103589248A (en) Coating with marble-like texture
CN106433387A (en) Quick-drying type epoxy primer and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C53 Correction of patent for invention or patent application
CB02 Change of applicant information

Address after: 273500 Zoucheng, Shandong, west of the outer ring road, No. 3268, No.

Applicant after: Shandong Pentium Qi Ye limited-liability company

Address before: 273500 Zoucheng, Shandong, west of the outer ring road, No. 3268, No.

Applicant before: Shandong Puntium Paint Co., Ltd.

COR Change of bibliographic data

Free format text: CORRECT: APPLICANT; FROM: SHANDONG PUNTIUM PAINT CO., LTD. TO: SHANDONG PENTIUM PAINT CO., LTD.

C14 Grant of patent or utility model
GR01 Patent grant