CN104310824A - Method for quickly drying flue gas desulfurization gypsum - Google Patents

Method for quickly drying flue gas desulfurization gypsum Download PDF

Info

Publication number
CN104310824A
CN104310824A CN201410505262.3A CN201410505262A CN104310824A CN 104310824 A CN104310824 A CN 104310824A CN 201410505262 A CN201410505262 A CN 201410505262A CN 104310824 A CN104310824 A CN 104310824A
Authority
CN
China
Prior art keywords
flue gas
gas desulfurization
additive
desulfurization gypsum
industrial waste
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201410505262.3A
Other languages
Chinese (zh)
Other versions
CN104310824B (en
Inventor
侯浩波
肖春宝
张炎
郑学根
吴全法
刘忠卫
余世金
李荣瑜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUHAN ZHONGGU NEW MATERIAL Co Ltd
China Petroleum and Chemical Corp
Original Assignee
WUHAN ZHONGGU NEW MATERIAL Co Ltd
China Petroleum and Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUHAN ZHONGGU NEW MATERIAL Co Ltd, China Petroleum and Chemical Corp filed Critical WUHAN ZHONGGU NEW MATERIAL Co Ltd
Priority to CN201410505262.3A priority Critical patent/CN104310824B/en
Publication of CN104310824A publication Critical patent/CN104310824A/en
Application granted granted Critical
Publication of CN104310824B publication Critical patent/CN104310824B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Treating Waste Gases (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a method for quickly drying flue gas desulfurization gypsum. The method comprises the following steps: adding 1.0-2.0wt% of an additive into the flue gas desulfurization gypsum, uniformly stirring, and then naturally standing until the flue gas desulfurization gypsum reaches drying requirements. According to the method, industrial waste residue is used as the additive of raw materials, and conventional energy resources do not need to be consumed. The additive is made from industrial waste residues, does not consume conventional energy resources and is simple in production process; since the raw material is the industrial waste residue, resource utilization of the industrial waste residue is achieved, and energy resources are saved simultaneously. By utilizing the method, operation is simple and convenient, the purpose of dewatering can be achieved in natural state, the effect is good, the operation period is short, and the performance of a product can not be changed due to low mixing amount of the additive.

Description

A kind of method of rapid drying desulfurated plaster
Technical field
What the present invention relates to is a kind of desulfurated plaster drying means, a kind of in particular method of rapid drying desulfurated plaster.
Background technology
The equipment such as the boiler of power station, heat power plant or other industrial enterprises or Reaktionsofen are using fire coal as the energy, and fired coal combustion produces sulfur-bearing harmful smoke in process of production, mainly sulfurous gas.At present, the minimizing topsoil carried out on a large scale in China, to create in the environmental engineering in clear water blue sky, the discharge rich and influential family of much sulfurous gas is implementing flue gas desulfurization project, especially particularly outstanding with Coal-fired Thermal Power flue gas desulfurization.No matter be newly-built or change, the sulfur dioxide emissions enterprise of the power plant that extends and other fire coals, in implemented flue gas desulfurization project, to adopt wet desulfurization of flue gas by limestone-gypsum method technique comparatively general.
Desulfurated plaster mainly exists with the form of terra alba, but produce in flue gas desulfurization technique process containing free water content in the desulfurated plaster of free-water generally 8% ~ 15% within the scope of this, still cannot directly use, need to solve the follow-up technical problem dehydrated, desulfurated plaster is finally made to change the lower product of free-water water content into, can be used as cement setting retarder afterwards or become the raw material of other industry, reach the requirement of the byproduct resource utilization recycling of wet desulphurization.Traditional desulfurated plaster drying means adopts the method for heating, drying, normally the material after pulverizing is sent into heat drying in calcining furnace, fluidizing furnace, rotary kiln and the equipment such as interval or continuous marmite, consumes a large amount of fire coals or electric power.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide a kind of method of rapid drying desulfurated plaster, by adding the rapid drying that a small amount of admixture can realize desulfurated plaster.
The present invention is achieved by the following technical solutions, the present invention includes following steps:
(1) by admixture by weight 1.0 ~ 2.0%, join in desulfurated plaster;
(2) stirred, be then naturally placed to desulfurated plaster and reach drying and require.
Described admixture comprises slag 40% ~ 60%, unslaked lime 10% ~ 20%, grog 2% ~ 20%, gypsum 5% ~ 15%, exciting agent 1 ~ 3%, and all the other are impurity, by weight.
The main component of admixture of the present invention is industrial residue, and in admixture, exciting agent is that alum and trolamine mix according to weight ratio 1:1.Admixture is met after water, can with moisture rapid reaction, the hydrated product of formation contains a large amount of crystal water, thus free water is converted into Bound moisture, reaches mummification object.
The present invention has the following advantages compared to existing technology: the admixture that the present invention utilizes industrial residue to be raw material, without the need to consuming conventional energy resources.This admixture production technique is simple, and raw material is industrial residue, while reaching industrial waste residue resourceization utilization, and save energy.Easy and simple to handle, dehydration object can be reached under state of nature, not only effective, the operational cycle is short, and due to admixture dosage low, the performance of product can not be changed.
Embodiment
Elaborate to embodiments of the invention below, the present embodiment is implemented under premised on technical solution of the present invention, give detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following embodiment.
Embodiment 1
The present embodiment comprises the following steps:
(1) by admixture by weight 1.0%, join in desulfurated plaster, admixture comprises slag 40%, unslaked lime 10%, grog 2%, gypsum 5%, exciting agent 1%, all the other are impurity, and by weight, exciting agent is that alum and trolamine mix according to weight ratio 1:1;
(2) stirred, then naturally placed 3h, 24h, 48h, measured the water content of desulfurated plaster respectively.
Embodiment 2
Admixture by weight 1.5% in the present embodiment, admixture comprises slag 60%, unslaked lime 20%, grog 20%, gypsum 15%, exciting agent 3%, and all the other are impurity, and by weight, other embodiments are identical with embodiment 1.
Embodiment 3
Admixture by weight 2.0% in the present embodiment, admixture comprises slag 50%, unslaked lime 15%, grog 10%, gypsum 10%, exciting agent 2%, and all the other are impurity, and by weight, other embodiments are identical with embodiment 1.
As shown in table 1 to desulfurated plaster change of moisture content under embodiment 1, embodiment 2 and embodiment 3 different addition quantity admixture:
Desulfurated plaster water content under table 1 different addition quantity admixture
Analyze from table 1, after the desulfurated plaster mummification 24h after admixture 1.0% admixture, water content can be reduced to 1.30%, more satisfactory, can be used for desulfurated plaster subsequent disposal and disposes and recycling.Compared with furnace drying method, the present invention reaches rapid drying desulfurated plaster object, simultaneously save energy, reduce costs.

Claims (2)

1. a method for rapid drying desulfurated plaster, is characterized in that, comprises the following steps:
(1) by admixture by weight 1.0 ~ 2.0%, join in desulfurated plaster;
(2) stirred, be then naturally placed to desulfurated plaster and reach drying and require.
2. the method for a kind of rapid drying desulfurated plaster according to claim 1, is characterized in that: described admixture comprises slag 40% ~ 60%, unslaked lime 10% ~ 20%, grog 2% ~ 20%, gypsum 5% ~ 15%, exciting agent 1 ~ 3%, all the other are impurity, by weight.
CN201410505262.3A 2014-09-26 2014-09-26 A kind of method of rapid draing desulfurated plaster Active CN104310824B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410505262.3A CN104310824B (en) 2014-09-26 2014-09-26 A kind of method of rapid draing desulfurated plaster

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410505262.3A CN104310824B (en) 2014-09-26 2014-09-26 A kind of method of rapid draing desulfurated plaster

Publications (2)

Publication Number Publication Date
CN104310824A true CN104310824A (en) 2015-01-28
CN104310824B CN104310824B (en) 2016-09-07

Family

ID=52366175

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410505262.3A Active CN104310824B (en) 2014-09-26 2014-09-26 A kind of method of rapid draing desulfurated plaster

Country Status (1)

Country Link
CN (1) CN104310824B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112047653A (en) * 2020-09-14 2020-12-08 胡礼梅 Desulfurized gypsum rotation type stoving recovery unit

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101234857A (en) * 2008-02-29 2008-08-06 江苏瑞和化肥有限公司 Method for drying granular phosphogypsum by using sulfuric acid tail gas
CN103274615A (en) * 2013-06-03 2013-09-04 郑州市鼎力干燥设备有限公司 Desulfurization gypsum drying and calcining equipment, and production process

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101234857A (en) * 2008-02-29 2008-08-06 江苏瑞和化肥有限公司 Method for drying granular phosphogypsum by using sulfuric acid tail gas
CN103274615A (en) * 2013-06-03 2013-09-04 郑州市鼎力干燥设备有限公司 Desulfurization gypsum drying and calcining equipment, and production process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112047653A (en) * 2020-09-14 2020-12-08 胡礼梅 Desulfurized gypsum rotation type stoving recovery unit
CN112047653B (en) * 2020-09-14 2022-01-28 山西鑫途化工有限公司 Desulfurized gypsum rotation type stoving recovery unit

Also Published As

Publication number Publication date
CN104310824B (en) 2016-09-07

Similar Documents

Publication Publication Date Title
CN103771734B (en) A kind of mass-producing calcination processing utilizes the method for electrolytic manganese residues
CN103771817B (en) A kind of desulfurated plaster foam concrete and preparation method thereof
WO2018166220A1 (en) Method for co-producing sulphoaluminate cement and sulfur by using desulfurized gypsum and aluminum ash
CN106904849A (en) The system and method that a kind of utilization Industrial Solid Waste produces sulphate aluminium cement co-producing sulfuric acid
CN102701694B (en) Non-calcined desulfurization gypsum hydraulic compound gel system and quick steam-curing process thereof
CN105218057B (en) A kind of green lightweight aggregate concrete and its preparation technology
CN102838153A (en) Method for producing vitriol and calcium oxide by decomposing gypsum
CN103708808B (en) A kind of sinter fume semi-dry desulphurization ash autoclaved brick and production method thereof
CN110817925A (en) Method for resource utilization of desulfurized fly ash
CN102351444A (en) Method for producing high grade cement clinker from full waste residues through rapidly calcining at low temperature
CN105565693A (en) Preparation method of composite gypsum cementing material
CN104844024A (en) High-performance gel material prepared by using sludge industrial waste residue and preparation method thereof
CN105621909B (en) It is a kind of to mix modified Desulphurization and the cement of rice hull ash again
CN108002769A (en) A kind of concrete prepared using desulfurizing byproduct
CN102219424B (en) Method for preparing CSA (calcium sulfoaluminate) concrete expansion agent by utilizing petroleum coke desulfurization ash
CN103803828A (en) Modified desulfurization ash for cement and concrete and preparation method thereof
CN105541150A (en) An active admixture prepared by utilizing semi-dry process desulfurized fly ash
CN106220057B (en) A kind of coal base solid waste foaming thermal-insulating and preparation method thereof
CN108545974A (en) It is a kind of using sludge ash as the preparation method of the environmental protection brick of main material
CN101215113A (en) Method for producing cement retarder by carbide slag desulfurization
CN104310824A (en) Method for quickly drying flue gas desulfurization gypsum
CN108585575B (en) Cement retarder and preparation method and application thereof
CN104147917B (en) Fume desulphurization method
CN103539424A (en) Thermal insulation plate production method
CN105174994A (en) Method for preparing sludge ceramsite by regenerating pottery sand and flue dust

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant