CN104310824B - A kind of method of rapid draing desulfurated plaster - Google Patents

A kind of method of rapid draing desulfurated plaster Download PDF

Info

Publication number
CN104310824B
CN104310824B CN201410505262.3A CN201410505262A CN104310824B CN 104310824 B CN104310824 B CN 104310824B CN 201410505262 A CN201410505262 A CN 201410505262A CN 104310824 B CN104310824 B CN 104310824B
Authority
CN
China
Prior art keywords
desulfurated plaster
additive
weight
rapid draing
raw material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201410505262.3A
Other languages
Chinese (zh)
Other versions
CN104310824A (en
Inventor
侯浩波
肖春宝
张炎
郑学根
吴全法
刘忠卫
余世金
李荣瑜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUHAN ZHONGGU NEW MATERIAL Co Ltd
China Petroleum and Chemical Corp
Original Assignee
WUHAN ZHONGGU NEW MATERIAL Co Ltd
China Petroleum and Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUHAN ZHONGGU NEW MATERIAL Co Ltd, China Petroleum and Chemical Corp filed Critical WUHAN ZHONGGU NEW MATERIAL Co Ltd
Priority to CN201410505262.3A priority Critical patent/CN104310824B/en
Publication of CN104310824A publication Critical patent/CN104310824A/en
Application granted granted Critical
Publication of CN104310824B publication Critical patent/CN104310824B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Treating Waste Gases (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

A kind of method that the invention discloses rapid draing desulfurated plaster, comprises the following steps: by additive by weight 1.0~2.0%, join in desulfurated plaster;Being stirred for uniformly, placement to desulfurated plaster reaches to be dried and requires the most naturally.The present invention utilizes the additive that industrial residue is raw material, it is not necessary to consume conventional energy resource.This additive production technology is simple, and raw material is industrial residue, while reaching industrial waste residue resourceization utilization, saves the energy.Easy and simple to handle, i.e. can reach dehydration purpose under nature, the most effective, the operation cycle is short, and owing to admixture dosage is low, the performance of product will not be changed.

Description

A kind of method of rapid draing desulfurated plaster
Technical field
The present invention relates to a kind of desulfurated plaster drying means, in particular a kind of quick The method of drying desulfurized gypsum.
Background technology
The equipment such as the boiler of power plant, steam power plant or other industrial enterprises or reacting furnace are with fire coal As the energy, fired coal combustion produces sulfur-bearing harmful smoke, mainly titanium dioxide in process of production Sulphur.At present, atmosphere pollution, the environment in creation clear water blue sky are reduced what China carried out on a large scale In protection engineering, the discharge rich and influential family of many sulfur dioxide is implementing flue gas desulfurization project, especially Especially prominent with Coal-fired Thermal Power flue gas desulfurization.The power plant that the most newly-built still change, extends and The sulfur dioxide (SO2) emissions enterprise of his fire coal, in the flue gas desulfurization project implemented, to use stone Lime stone-gypsum wet flue gas desulfurizing technique is the most universal.
Desulfurated plaster is mainly presented in calcium sulphate dihydrate, but flue gas desulfurization technique mistake In the desulfurated plaster containing free water produced in journey, free water content is typically at 8%~15% this model In enclosing, still cannot directly use, need to solve the follow-up technical problem dehydrated, finally Make desulfurated plaster be changed into the product that free water water content is relatively low, can be used as cement retarder afterwards Or become the raw material of other industry, reach wet desulphurization byproduct resource recycling want Ask.Traditional desulfurated plaster drying means uses the method for heating, drying, it is common that after pulverizing Material send into calcining furnace, fluidized bed furnace, rotary kiln and intermittently or serially the equipment such as marmite heat It is dried, consumes substantial amounts of fire coal or electric power.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that a kind of rapid draing takes off The method of sulphur gypsum, can realize the fast rapid-curing cutback to desulfurated plaster by adding a small amount of additive Dry.
The present invention is achieved by the following technical solutions, and the present invention comprises the following steps:
(1) by additive by weight 1.0~2.0%, join in desulfurated plaster;
(2) it is stirred for uniformly, the most naturally places and reach to be dried requirement i.e. to desulfurated plaster Can.
Described additive includes slag 40%~60%, quick lime 10%~20%, grog 2%~20%, Gypsum 5%~15%, exciting agent 1~3%, remaining is impurity, by weight.
The additive of the present invention be mainly composed of industrial residue, in additive, exciting agent is bright Alum and triethanolamine mix according to weight ratio 1:1.After water met by additive, can be fast with moisture Speed reaction, the hydrated product of formation contains the substantial amounts of crystallization water, thus Free water is converted into knot Heshui, reaches mummification purpose.
The present invention has the advantage that the present invention utilizes industrial residue for raw material compared to existing technology Additive, it is not necessary to consume conventional energy resource.This additive production technology is simple, and raw material is industry Waste residue, while reaching industrial waste residue resourceization utilization, saves the energy.Easy and simple to handle, natural Dehydration purpose is i.e. can reach under state, the most effective, the operation cycle is short, and due to additional Agent volume is low, will not change the performance of product.
Detailed description of the invention
Elaborating embodiments of the invention below, the present embodiment is with the technology of the present invention side Implement under premised on case, give detailed embodiment and concrete operating process, but Protection scope of the present invention is not limited to following embodiment.
Embodiment 1
The present embodiment comprises the following steps:
(1) by additive by weight 1.0%, joining in desulfurated plaster, additive includes Slag 40%, quick lime 10%, grog 2%, gypsum 5%, exciting agent 1%, remaining is impurity, By weight, exciting agent is alum and triethanolamine mixes according to weight ratio 1:1;
(2) it is stirred for uniformly, the most naturally places 3h, 24h, 48h, measure de-respectively The water content of sulphur gypsum.
Embodiment 2
Additive by weight 1.5% in the present embodiment, additive includes slag 60%, quick lime 20%, grog 20%, gypsum 15%, exciting agent 3%, remaining is impurity, by weight, its His embodiment is identical with embodiment 1.
Embodiment 3
Additive by weight 2.0% in the present embodiment, additive includes slag 50%, quick lime 15%, grog 10%, gypsum 10%, exciting agent 2%, remaining is impurity, by weight, its His embodiment is identical with embodiment 1.
Desulfurated plaster under embodiment 1, embodiment 2 and embodiment 3 different addition quantity additive is contained Water yield change is as shown in table 1:
Desulfurated plaster water content under table 1 different addition quantity additive
Analyze from table 1, fill water content after the desulfurated plaster mummification 24h after 1.0% additive Can be reduced to 1.30%, the most more satisfactory, can be used for desulfurated plaster subsequent treatment dispose and Recycling.Compared with furnace drying method, the present invention reaches rapid draing desulfurated plaster purpose, Save the energy simultaneously, reduce cost.

Claims (1)

1. the method for a rapid draing desulfurated plaster, it is characterised in that comprise the following steps:
(1) by additive by weight 1.0~2.0%, join in desulfurated plaster;
(2) it is stirred for uniformly, the most naturally places and reach to be dried requirement i.e. to desulfurated plaster Can;
Described additive includes slag 40%~60%, quick lime 10%~20%, grog 2%~20%, Gypsum 5%~15%, exciting agent 1~3%, remaining is impurity, by weight;Described exciting agent Mixed according to weight ratio 1:1 by alum and triethanolamine.
CN201410505262.3A 2014-09-26 2014-09-26 A kind of method of rapid draing desulfurated plaster Active CN104310824B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410505262.3A CN104310824B (en) 2014-09-26 2014-09-26 A kind of method of rapid draing desulfurated plaster

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410505262.3A CN104310824B (en) 2014-09-26 2014-09-26 A kind of method of rapid draing desulfurated plaster

Publications (2)

Publication Number Publication Date
CN104310824A CN104310824A (en) 2015-01-28
CN104310824B true CN104310824B (en) 2016-09-07

Family

ID=52366175

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410505262.3A Active CN104310824B (en) 2014-09-26 2014-09-26 A kind of method of rapid draing desulfurated plaster

Country Status (1)

Country Link
CN (1) CN104310824B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112047653B (en) * 2020-09-14 2022-01-28 山西鑫途化工有限公司 Desulfurized gypsum rotation type stoving recovery unit

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101234857A (en) * 2008-02-29 2008-08-06 江苏瑞和化肥有限公司 Method for drying granular phosphogypsum by using sulfuric acid tail gas
CN103274615A (en) * 2013-06-03 2013-09-04 郑州市鼎力干燥设备有限公司 Desulfurization gypsum drying and calcining equipment, and production process

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101234857A (en) * 2008-02-29 2008-08-06 江苏瑞和化肥有限公司 Method for drying granular phosphogypsum by using sulfuric acid tail gas
CN103274615A (en) * 2013-06-03 2013-09-04 郑州市鼎力干燥设备有限公司 Desulfurization gypsum drying and calcining equipment, and production process

Also Published As

Publication number Publication date
CN104310824A (en) 2015-01-28

Similar Documents

Publication Publication Date Title
CN103771734B (en) A kind of mass-producing calcination processing utilizes the method for electrolytic manganese residues
CN104478255B (en) A kind of magnesium oxysulfide concrete containing magnesia FGD waste liquid and preparation method thereof
WO2018166220A1 (en) Method for co-producing sulphoaluminate cement and sulfur by using desulfurized gypsum and aluminum ash
CN102838153A (en) Method for producing vitriol and calcium oxide by decomposing gypsum
CN107512857B (en) Method and device for preparing building gypsum by phosphogypsum
CN109127650A (en) A method of utilizing cement kiln intermediate product harmless treatment electrolytic manganese residues
CN104692689A (en) Method and device for producing modified calcium oxide expansion agent after dry desulfurization of flue gas
CN110817925A (en) Method for resource utilization of desulfurized fly ash
CN102701694A (en) Non-calcined desulfurization gypsum hydraulic compound gel system and quick steam-curing process thereof
CN102351444A (en) Method for producing high grade cement clinker from full waste residues through rapidly calcining at low temperature
WO2019232687A1 (en) Ultra-rapid-hardening special inorganic cement material and preparation method therefor
CN102114387B (en) Process for preventing cement clinker produced from high-sulfur raw material from skinning
CN105621909B (en) It is a kind of to mix modified Desulphurization and the cement of rice hull ash again
CN105801067B (en) A kind of grey material modified method applied to wall plastering material of flue gas desulfurization
CN105217581B (en) A kind of method of chemical gypsum and carbide slag comprehensive utilization
CN104310824B (en) A kind of method of rapid draing desulfurated plaster
CN102219424B (en) Method for preparing CSA (calcium sulfoaluminate) concrete expansion agent by utilizing petroleum coke desulfurization ash
CN103803828A (en) Modified desulfurization ash for cement and concrete and preparation method thereof
CN103241717A (en) Drying and calcining process and device for coproduction of sulfuric acid and cement from gypsum
CN101215113A (en) Method for producing cement retarder by carbide slag desulfurization
CN103253637A (en) Method for producing sulfuric acid and calcium oxide by utilizing gypsum
WO2022100420A1 (en) Apparatus and method for recycling flue gas byproduct in glass or glass fiber industry
CN103539424A (en) Thermal insulation plate production method
CN103964714A (en) Method for preparing high-performance gypsum-based composite cementing material by calcium sulfite type FGD (Flue Gas Desulfurization) gypsum
CN104353348B (en) Dry method desulfurizing agent containing rare earth

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant