CN104291872B - A kind of adobe of once-firing crystallite glass composite plate - Google Patents
A kind of adobe of once-firing crystallite glass composite plate Download PDFInfo
- Publication number
- CN104291872B CN104291872B CN201410490642.4A CN201410490642A CN104291872B CN 104291872 B CN104291872 B CN 104291872B CN 201410490642 A CN201410490642 A CN 201410490642A CN 104291872 B CN104291872 B CN 104291872B
- Authority
- CN
- China
- Prior art keywords
- layer
- glass ceramics
- ceramics frit
- adobe
- glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The adobe of a kind of once-firing crystallite glass composite plate, described adobe includes green body layer, ground glaze layer and glass ceramics frit layer from bottom to top, also includes the fixed layer being arranged on described glass ceramics frit layer surface；Described fixed layer is formed by the spraying of glass ceramics frit granule fixative, described glass ceramics frit granule fixative includes the mass fraction of following components: cellulose thickener 5.0 6.0%, attapulgite 2.0 2.8%, defoamer is 1.1 1.4%, dispersant is 1.2 1.8%, and surplus is solvent.Using this kind of adobe, the glass ceramics frit granule on surface will not be preheated the blower fan of band and take away when burning till, thus avoids waste and reduce the ratio of defects of crystallite glass composite plate product.
Description
Technical field
The present invention relates to a kind of architectural pottery technical field, particularly relate to a kind of once-firing devitrified glass and be combined
The adobe of plate.
Background technology
Crystallite glass composite plate technology maturation application since, its Technology development innovate, product also by
In it, there is the decorative effect that penetrating crystallite frit granule is personalized, become the high-grade decoration material on market
Material, is liked by consumers in general deeply.
The adobe of the crystallite glass composite plate of once-firing includes green body layer, ground glaze layer and crystallite glass from bottom to top
Glass layer, glass-ceramic layer is usually and is made up of glass ceramics frit granule, and adobe is repressed, after glazing stamp
Can be re-fed in kiln being fired at one layer of glass ceramics frit granule of ground glaze layer surface material distribution, be delivered into
When entering kiln, can be through the preheating zone of a lower negative pressure, some clothes melt in the fine microcrystalline glass of the superiors
Block granule is easily sucked away due to lighter weight, causes and has lacking of many glass ceramics frit granules on surface layer
Losing, it is the highest that adobe burns out rear flatness, and has pin hole or dissolution pore to occur, extremely affects devitrified glass
The quality of composite plate and aesthetic property, qualified yield rate is the highest.
Summary of the invention
It is an object of the invention to propose the once-firing devitrified glass that a kind of qualified yield rate is high and flatness is high
The adobe of composite plate.
For reaching this purpose, the present invention by the following technical solutions:
The adobe of a kind of once-firing crystallite glass composite plate, described adobe includes green body layer, the end from bottom to top
Glaze layer and glass ceramics frit layer, also include the fixed layer being arranged on described glass ceramics frit layer surface；
Described fixed layer is formed by the spraying of glass ceramics frit granule fixative, described glass ceramics frit granule
Fixative includes the mass fraction of following components: cellulose thickener 5.0-6.0%, attapulgite
2.0-2.8%, defoamer is 1.1-1.4%, and dispersant is 1.2-1.8%, and surplus is solvent.
Preferably, containing mass fraction in the ground glaze layer of above-mentioned adobe is 0.2-0.5% metallic silicon power.Preferably
Ground, the particle diameter of metallic silicon power is less than or equal to 100 μm.By adding metallic silicon power, can be formed when burning till
A lot of micro-pores of extra fine, this pore slightly adds the elasticity of ground glaze layer, makes it more preferably to regulate base
Stress difference between body layer and glass-ceramic layer, Reducing distortion.Meanwhile, because ground glaze layer is under frit layer,
After burning, it can be enclosed under glass-ceramic layer, on product antifouling property without impact.
Preferably, the dilation coefficient of described ground glaze layer is between described green body layer and described glass ceramics frit
Between the glass-ceramic layer formed after Rong Rong.
Preferably, the granular size of described glass ceramics frit is 100-200 mesh.
Preferably, the coating thickness of described fixed layer is 1-4mm.
Preferably, described cellulose thickener is hydroxyethyl cellulose, hydroxyethylmethyl-cellulose and hydroxypropyl
At least one in ylmethyl cellulose.
Preferably, described dispersant is in sodium polyacrylate, organic-silicon-modified sodium phosphate and sodium hexameta phosphate
At least one.
Preferably, described defoamer is polymethyl siloxane.
Preferably, at least one during described solvent is water, ethylene glycol and ethanol.
Beneficial effects of the present invention: 1, solve frit granule when entering klining in the face of the preheating zone of lower negative pressure
The problem being easily sucked away, it is to avoid the flaw such as substantial amounts of pin hole and bubble occurs in brick surface, yield rate is high；2、
The fixative used can use under neutral environment, and not metal ion, produces frit granule when sintering
There is not impact in raw color effects.
Accompanying drawing explanation
Fig. 1 is the preparation flow schematic diagram of the adobe of one embodiment of the present of invention；
Fig. 2 is the structural representation of the crystallite glass composite plate burnt till of one embodiment of the present of invention.
Wherein: green body layer 1, ground glaze layer 2, glass ceramics frit layer 3, fixed layer 4, glass-ceramic layer 5.
Detailed description of the invention
Further illustrate technical scheme below in conjunction with the accompanying drawings and by specific embodiment.
As it is shown in figure 1, the adobe of once-firing crystallite glass composite plate of the present invention, described adobe is from bottom to top
Including green body layer 1, ground glaze layer 2 and glass ceramics frit layer 3, also include being arranged on described glass ceramics frit
The fixed layer 4 on layer surface, it should be noted that green body layer 1 can select known formula, through ball milling except ferrum,
Punch forming after mist projection granulating, ground-coat enamel acts primarily as covering effect, the cosmetic soil that therefore more options whiteness is higher,
The glass-ceramic layer that dilation coefficient when it burns till is formed after green body layer and glass ceramics frit are melted
Between 5 (such as Fig. 2), when burning till, the thermal coefficient of expansion of glass-ceramic layer 5 and the thermal coefficient of expansion of green body layer
Matching affect the quality of crystallite glass composite plate finished product, when the thermal coefficient of expansion of glass-ceramic layer 5 is big,
The thermal coefficient of expansion hour of green body layer, brick can present " recessed " shape；Thermal coefficient of expansion when glass-ceramic layer 5
When thermal coefficient of expansion little, green body layer is big, brick body can present " convex " shape, so adding one layer of dilation
Ground glaze layer 2 between the glass-ceramic layer that coefficient is formed after green body layer 1 and glass ceramics frit are melted, can
To avoid because green body layer and glass-ceramic layer dilation coefficient differ deformation defect that is relatively big and that cause.
The adobe used in Examples below, the powder chemical constituent (wt%) of its green body layer is: SiO2:70%,
Al2O3:21%, CaO:1%, MgO:2%, K2O:2%, Na2O:3%, Fe2O3:0.5%, TiO2:
0.5%.The chemical composition of micropowder formula used is (wt%): for SiO2:68%, Al2O3:18%, Na2O:
6%, K2O:5%, TiO2:0.4%, CaO:0.6%, MgO:2%.
The preparation of ground-coat enamel: with thickness less than the Kaolin of 100 mesh, quartz, potassium feldspar, albite, Fang Xie
Stone, Talcum, dolomite, zinc oxide, zirconium English powder immixture ground-coat enamel raw material, add suitable quantity of water and 0.5%
Sodium tripolyphosphate, 0.3% methylcellulose, enter ball mill ball milling and become chemical composition to be SiO2:50%, Al2O3:
20%, CaO:9%, MgO:2%, K2O:2%, Na2O:3%, ZnO:4%, ZrO2:10%, fineness is ten thousand
Hole sizer more than 0.5% pulpous state ground-coat enamel stand-by.It should be noted that base substrate powder given here and ground-coat enamel
Preparation all can be replaced by other recipe ingredient in common knowledge, may be applicable to once-firing of the present invention micro-
In the preparation method of crystal glass composite plate.
Preparation-the embodiment 1 of frit granule agglomerant
The component of every 100kg glass ceramics frit granule fixative: hydroxyethyl cellulose (the unconcerned gram building materials in Guangzhou
Science and Technology Ltd. buys) 5.0kg, attapulgite 2.5kg, polymethyl siloxane 1.1kg, organosilicon changes
Property sodium phosphate 1.7kg, surplus is water.
The preparation method of above-mentioned frit granule agglomerant, comprises the following steps: a) be dissolved in by hydroxyethyl cellulose
In water, stir；B) add polymethyl siloxane and organic-silicon-modified sodium phosphate, stir；c)
Adding attapulgite and residue aqueous solvent, be uniformly mixing to obtain frit granule agglomerant, surveying its flow velocity is 26.8s
(30 DEG C, be coated with-4 glasss).It should be noted that organic-silicon-modified sodium phosphate can use poly-third as dispersant
Olefin(e) acid sodium or sodium hexameta phosphate are replaced and also can be realized this programme.
Preparation-embodiment 1-1 of the adobe of crystallite glass composite plate
By temperature resistant transparent glass ceramics frit granule (buying from Quincy card Robbie glaze company, 100-200 mesh)
Cloth, on the base substrate ground glaze layer surface of revenue stamp process, then sprays the crystallite that one layer of embodiment 1 prepares
Glass frit granule fixative, sends in kiln and burns till at 1200 DEG C, edging chamfering, obtains having and uniformly divides
Cloth, the glazed tile finished product of complete ice crystal texture.It should be noted that the high temperature that the present embodiment 1-1 selects is saturating
Stable the sprawling in sintering process of bright glass ceramics frit granule, forms argenteous ice crystal on cover coat
Textured pattern, glass ceramics frit granule can be obtained by the purchase of colour glaze company, and similar frit product is also
This programme can be realized.
Comparative example 1-2
By the temperature resistant transparent glass ceramics frit granule cloth identical with embodiment 1-1 in through revenue stamp process
In billet surface, then one layer of viscosity aqueous slurry being configured to by methylcellulose of spraying, send in kiln,
Burn till at 1200 DEG C, edging chamfering, obtain the crystallite glass composite plate finished product with ice crystal texture, but texture
Pin hole seen from a small amount of naked eyes of middle existence, the seriality of ice crystal texture is the strongest.
Can be compared with the crystallite glass composite plate end product quality of comparative example 1-2 by embodiment 1-1
Go out having sprayed on the temperature resistant transparent glass ceramics frit granular layer have ice crystal effect originally in embodiment 1-1
Invention glass ceramics frit granule fixative, make temperature resistant transparent glass ceramics frit particles stick on glaze,
And do not affected by lower negative pressure in the preheating zone through kiln, glaze preferably retains and is not absorbed.
In order to illustrate further, provide below glass ceramics frit granule fixative and contrast that embodiment 1 prepares
Kinematic viscosity value μ of the viscosity aqueous slurry used in embodiment 1-2 compares, and experimental data is shown in Table 1.
Kinematic viscosity value μ: be coated with-4 glasss at 30 DEG C measure liquid from the hole of predetermined hole diameter flow out needed for time
Between obtain flow velocity t, and can by t=0.223 μ+6.0 conversion draw kinematic viscosity value μ.
Table 1 embodiment group 1 glass ceramics frit granule fixative and the kinematic viscosity value of viscosity aqueous slurry
| Numbering | Flow velocity/s | Kinematic viscosity value/(mm2/s) |
| Embodiment 1-1 | 25.4 | 86.99 |
| Comparative example 1-2 | 7.4 | 8.05 |
Can obtain from table 1, its kinematic viscosity value of glass ceramics frit granule fixative in embodiment 1-1 is right
Than embodiment 1-2 uses the viscosity aqueous slurry being configured to by methylcellulose kinematic viscosity value 10 times it
Many, when in the face of the lower negative pressure of kiln preheating zone, can be the most bonding frit granule so that it is remain
It is not sucked away, is greatly improved adobe and burns till the integrity of texture and the flatness of rear surface, can avoid because of molten
Block granule is sucked away disappearance and may leave over the pin hole problems of generation, it is seen that the crystallite glass composite plate of the present invention
Yield rate high.
Comparative example 1-3
By the temperature resistant transparent glass ceramics frit granule cloth identical with embodiment 1-1 in through revenue stamp process
In billet surface, then one layer of commercially available glue of spraying, send in kiln, burn till at 1200 DEG C, edging chamfering,
Obtain the crystallite glass composite plate finished product with ice crystal texture, but texture exist pin hole seen from a small amount of naked eyes,
The seriality of ice crystal texture is the strongest.
Can be compared with the crystallite glass composite plate end product quality of comparative example 1-3 by embodiment 1-1
Go out having sprayed on the temperature resistant transparent glass ceramics frit granular layer have ice crystal effect originally in embodiment 1-1
Invention glass ceramics frit granule fixative, make temperature resistant transparent glass ceramics frit particles stick on glaze,
And do not affected by lower negative pressure in the preheating zone through kiln, glaze preferably retains and is not absorbed.
In order to illustrate further, provide below glass ceramics frit granule fixative and contrast that embodiment 1 prepares
Kinematic viscosity value μ using glue in embodiment 1-3 compares, and experimental data is shown in Table 2.
Kinematic viscosity value μ: be coated with-4 glasss at 30 DEG C measure liquid from the hole of predetermined hole diameter flow out needed for time
Between obtain flow velocity t, and can by t=0.223 μ+6.0 conversion draw kinematic viscosity value μ.
Table 2 embodiment 1 glass ceramics frit granule fixative and the kinematic viscosity value of viscosity aqueous slurry
| Numbering | Flow velocity/s | Kinematic viscosity value/(mm2/s) |
| Embodiment 1-1 | 26.8 | 85.19 |
| Comparative example 1-3 | 6.8 | 7.75 |
Can obtain from table 2, its kinematic viscosity value of glass ceramics frit granule fixative in embodiment 1-1 is right
Than embodiment 1-3 uses the kinematic viscosity value 10 times more than of glue, in the face of the lower negative pressure of kiln preheating zone
Time, can be the most bonding frit granule so that it is remain and be not sucked away, be greatly improved adobe and burn till
The integrity of the texture of rear surface and flatness, can avoid may leaving over product because frit granule is sucked away disappearance
Raw pin hole problems, it is seen that the yield rate of the crystallite glass composite plate of the present invention is high.
Preparation-the embodiment 2 of frit granule agglomerant
The preparation method of the present embodiment is basically identical with embodiment 1, except that, in the present embodiment, adopt
Component and ratio different.The component of every 100kg frit granule agglomerant: hydroxyethylmethyl-cellulose
(Dezhou Kang Rong Chemical Co., Ltd.) 5.5kg, attapulgite 3.0kg, polymethyl siloxane 1.4kg, six
Polymeric sodium metaphosphate. 2.1kg, surplus is ethanol.
Preparation-embodiment 2-1 of the adobe of crystallite glass composite plate
By temperature resistant transparent glass ceramics frit granule (buying from Quincy card Robbie glaze company, 105-145 mesh)
Cloth, on the base substrate ground glaze layer surface of revenue stamp process, then sprays the crystallite that one layer of embodiment 2 prepares
Glass frit granule fixative, sends in kiln and burns till at 1170 DEG C, edging chamfering, obtains having and uniformly divides
Cloth, the glazed tile finished product of complete ice crystal texture.It should be noted that the high temperature that the present embodiment 2-1 selects is saturating
Stable the sprawling in sintering process of bright glass ceramics frit granule, forms argenteous ice crystal on cover coat
Textured pattern, glass ceramics frit granule can be obtained by the purchase of colour glaze company, and similar frit product is also
This programme can be realized.30 DEG C, be coated with-4
Cup), kinematic viscosity value is 84.56mm2/s
Preparation-the embodiment 3 of frit granule agglomerant
The preparation method of the present embodiment is basically identical with embodiment 1, except that, in the present embodiment, adopt
Component and ratio different.The component of every 100kg frit granule agglomerant: hydroxypropyl methyl cellulose
(Dezhou Kang Rong Chemical Co., Ltd.) 6.0kg, attapulgite 2.6kg, polymethyl siloxane 1.2kg, six
Polymeric sodium metaphosphate. 1.8kg, surplus is ethylene glycol.
Preparation-embodiment 3-1 of the adobe of crystallite glass composite plate
By temperature resistant transparent glass ceramics frit granule (buying from Quincy card Robbie glaze company, 100-200 mesh)
Cloth, on the base substrate ground glaze layer surface of revenue stamp process, then sprays the crystallite that one layer of embodiment 3 prepares
Glass frit granule fixative, sends in kiln and burns till at 1190 DEG C, edging chamfering, obtains having and uniformly divides
Cloth, the glazed tile finished product of complete ice crystal texture.It should be noted that the high temperature that the present embodiment 3-1 selects is saturating
Stable the sprawling in sintering process of bright glass ceramics frit granule, forms argenteous ice crystal on cover coat
Textured pattern, glass ceramics frit granule can be obtained by the purchase of colour glaze company, and similar frit product is also
This programme can be realized.30 DEG C, be coated with-4
Cup), kinematic viscosity value is 84.98mm2/s
Preparation-the embodiment 4 of frit granule agglomerant
The preparation method of the present embodiment is basically identical with embodiment 1, except that, in the present embodiment, adopt
Component and ratio different.The component of every 100kg frit granule agglomerant: hydroxypropyl methyl cellulose
(Dezhou Kang Rong Chemical Co., Ltd.) 3.0kg, hydroxyethyl cellulose 2.4kg, attapulgite 2.7kg, poly-
Methylsiloxane 1.3kg, sodium polyacrylate 1.9kg, surplus is water and ethylene glycol.
Preparation-embodiment 4-1 of the adobe of crystallite glass composite plate
By temperature resistant transparent glass ceramics frit granule (buying from Quincy card Robbie glaze company, 110-150 mesh)
Cloth, on the base substrate ground glaze layer surface of revenue stamp process, then sprays the crystallite that one layer of embodiment 4 prepares
Glass frit granule fixative, sends in kiln and burns till at 1200 DEG C, edging chamfering, obtains having and uniformly divides
Cloth, the glazed tile finished product of complete ice crystal texture.It should be noted that the high temperature that the present embodiment 4-1 selects is saturating
Stable the sprawling in sintering process of bright glass ceramics frit granule, forms argenteous ice crystal on cover coat
Textured pattern, glass ceramics frit granule can be obtained by the purchase of colour glaze company, and similar frit product is also
This programme can be realized.30 DEG C, be coated with-4
Cup), kinematic viscosity value is 86.28mm2/s
Preparation-the embodiment 5 of frit granule agglomerant
The preparation method of the present embodiment is basically identical with embodiment 1, except that, in the present embodiment, adopt
Component and ratio different.The component of every 100kg frit granule agglomerant: hydroxypropyl methyl cellulose
(Dezhou Kang Rong Chemical Co., Ltd.) 2.5kg, hydroxyethylmethyl-cellulose 2.8kg (Guangzhou Mo Ke building materials section
Skill company limited buys), attapulgite 2.9kg, polymethyl siloxane 1.2kg, sodium hexameta phosphate 0.8kg,
Organic-silicon-modified sodium phosphate 1.0kg, surplus is second alcohol and water.
Preparation-embodiment 5-1 of the adobe of crystallite glass composite plate
By temperature resistant transparent glass ceramics frit granule (buying from Quincy card Robbie glaze company, 110-150 mesh)
Cloth, on the base substrate ground glaze layer surface of revenue stamp process, then sprays the crystallite that one layer of embodiment 5 prepares
Glass frit granule fixative, sends in kiln and burns till at 1210 DEG C, edging chamfering, obtains having and uniformly divides
Cloth, the glazed tile finished product of complete ice crystal texture.It should be noted that the high temperature that the present embodiment 5-1 selects is saturating
Stable the sprawling in sintering process of bright glass ceramics frit granule, forms argenteous ice crystal on cover coat
Textured pattern, glass ceramics frit granule can be obtained by the purchase of colour glaze company, and similar frit product is also
This programme can be realized.30 DEG C, be coated with-4
Cup), kinematic viscosity value is 88.13mm2/s
Preparation-the embodiment 6 of frit granule agglomerant
The preparation method of the present embodiment is basically identical with embodiment 1, except that, in the present embodiment, adopt
Component and ratio different.The component of every 100kg frit granule agglomerant: hydroxyethylmethyl-cellulose
(purchase of Guangzhou Mo Ke building materials Science and Technology Ltd.) 3.0kg, hydroxyethyl cellulose (the unconcerned gram building materials science and technology in Guangzhou
Company limited buys), attapulgite 2.8kg, polymethyl siloxane 1.2kg, sodium hexameta phosphate 1.4kg,
Sodium polyacrylate 0.6kg, surplus is ethylene glycol and ethanol.
Preparation-embodiment 6-1 of the adobe of crystallite glass composite plate
By temperature resistant transparent glass ceramics frit granule (buying from Quincy card Robbie glaze company, 120-200 mesh)
Cloth, on the base substrate ground glaze layer surface of revenue stamp process, then sprays the crystallite that one layer of embodiment 6 prepares
Glass frit granule fixative, sends in kiln and burns till at 1180 DEG C, edging chamfering, obtains having and uniformly divides
Cloth, the glazed tile finished product of complete ice crystal texture.It should be noted that the high temperature that the present embodiment 6-1 selects is saturating
Stable the sprawling in sintering process of bright glass ceramics frit granule, forms argenteous ice crystal on cover coat
Textured pattern, glass ceramics frit granule can be obtained by the purchase of colour glaze company, and similar frit product is also
This programme can be realized.30 DEG C, be coated with-4
Cup), kinematic viscosity value is 85.45mm2/s
Preparation-the embodiment 7 of frit granule agglomerant
The preparation method of the present embodiment is basically identical with embodiment 1, except that, in the present embodiment, adopt
Component and ratio different.The component of every 100kg frit granule agglomerant: hydroxyethyl cellulose is (wide
Zhou Moke building materials Science and Technology Ltd. buys), attapulgite 3.0kg, polymethyl siloxane 1.4kg, six is inclined
Sodium phosphate 1.8kg, surplus is ethylene glycol.
Preparation-embodiment 7-1 of the adobe of crystallite glass composite plate
By temperature resistant transparent glass ceramics frit granule (buying from Quincy card Robbie glaze company, 105-150 mesh)
Cloth, on the base substrate ground glaze layer surface of revenue stamp process, then sprays the crystallite that one layer of embodiment 7 prepares
Glass frit granule fixative, sends in kiln and burns till at 1160 DEG C, edging chamfering, obtains having and uniformly divides
Cloth, the glazed tile finished product of complete ice crystal texture.It should be noted that the high temperature that the present embodiment 7-1 selects is saturating
Stable the sprawling in sintering process of bright glass ceramics frit granule, forms argenteous ice crystal on cover coat
Textured pattern, glass ceramics frit granule can be obtained by the purchase of colour glaze company, and similar frit product is also
This programme can be realized.30 DEG C, be coated with-4
Cup), kinematic viscosity value is 85.63mm2/s。
In order to alleviate the stress difference between green body layer and glass-ceramic layer, in one embodiment of the invention,
With the addition of mass fraction in ground-coat enamel is 0.2-0.5% metallic silicon power, and the particle diameter of metallic silicon power is less than or equal to 100
μm.By adding metallic silicon power, the micro-pore of a lot of extra fine can be formed when burning till, this gas slightly
Hole adds the elasticity of ground glaze layer, makes it the stress difference more preferably regulating between green body layer and glass-ceramic layer,
Reducing distortion.Meanwhile, because ground glaze layer is under frit layer, after burning, it can be enclosed under glass-ceramic layer,
On product antifouling property without impact.Crystallite glass composite plate prepared by this embodiment, because base substrate becomes after Shao Jie
The defect of shape is only 2%, less than conventional 5%.
The know-why of the present invention is described above in association with specific embodiment.These describe and are intended merely to explain this
The principle of invention, and limiting the scope of the invention can not be construed to by any way.Based on herein
Explaining, those skilled in the art need not pay performing creative labour can associate other tool of the present invention
Body embodiment, within these modes fall within protection scope of the present invention.
Claims (4)
1. an adobe for once-firing crystallite glass composite plate, described adobe includes base substrate from bottom to top
Layer, ground glaze layer and glass ceramics frit layer, it is characterised in that: also include being arranged on described glass ceramics frit
The fixed layer on layer surface；
Described fixed layer is formed by the spraying of glass ceramics frit granule fixative, described glass ceramics frit granule
Fixative includes the mass fraction of following components: cellulose thickener 5.0-6.0%, attapulgite
2.0-2.8%, defoamer is 1.1-1.4%, and dispersant is 1.2-1.8%, and surplus is solvent；
Containing mass fraction in described ground glaze layer is 0.2-0.5% metallic silicon power；
Described cellulose thickener is that hydroxyethyl cellulose, hydroxyethylmethyl-cellulose and hydroxypropyl methyl are fine
At least one in dimension element；
Described dispersant is at least in sodium polyacrylate, organic-silicon-modified sodium phosphate and sodium hexameta phosphate
Kind；
Described defoamer is polymethyl siloxane；
Described solvent is at least one in water, ethylene glycol and ethanol.
The adobe of once-firing crystallite glass composite plate the most according to claim 1, its feature exists
In: the dilation coefficient of described ground glaze layer is shape after described green body layer and described glass ceramics frit are melted
Between the glass ceramics frit layer become.
The adobe of once-firing crystallite glass composite plate the most according to claim 1, its feature exists
In: described glass ceramics frit granular size is 100-200 mesh.
The adobe of once-firing crystallite glass composite plate the most according to claim 1, its feature exists
In: the coating thickness of described fixed layer is 1-4mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410490642.4A CN104291872B (en) | 2014-09-23 | 2014-09-23 | A kind of adobe of once-firing crystallite glass composite plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410490642.4A CN104291872B (en) | 2014-09-23 | 2014-09-23 | A kind of adobe of once-firing crystallite glass composite plate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104291872A CN104291872A (en) | 2015-01-21 |
| CN104291872B true CN104291872B (en) | 2016-09-07 |
Family
ID=52311865
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410490642.4A Active CN104291872B (en) | 2014-09-23 | 2014-09-23 | A kind of adobe of once-firing crystallite glass composite plate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104291872B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102390931A (en) * | 2011-08-02 | 2012-03-28 | 佛山石湾鹰牌陶瓷有限公司 | Method for manufacturing once calcined glass ceramic brick |
| CN102951928A (en) * | 2012-10-16 | 2013-03-06 | 广东道氏技术股份有限公司 | Microcrystal dry grain adhering agent |
-
2014
- 2014-09-23 CN CN201410490642.4A patent/CN104291872B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102390931A (en) * | 2011-08-02 | 2012-03-28 | 佛山石湾鹰牌陶瓷有限公司 | Method for manufacturing once calcined glass ceramic brick |
| CN102951928A (en) * | 2012-10-16 | 2013-03-06 | 广东道氏技术股份有限公司 | Microcrystal dry grain adhering agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104291872A (en) | 2015-01-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103588510A (en) | Method for manufacturing anti-slip glazed tile | |
| CN104261895B (en) | A kind of preparation method of once-firing crystallite glass composite plate | |
| CN104291872B (en) | A kind of adobe of once-firing crystallite glass composite plate | |
| CN104261883B (en) | A kind of preparation method of once-firing crystallite glass composite plate | |
| CN104291877B (en) | A kind of preparation method of once-firing crystallite glass composite plate | |
| CN104591802B (en) | A kind of adobe of once-firing crystallite glass composite plate | |
| CN104230395B (en) | A kind of adobe of once-firing crystallite glass composite plate | |
| CN104311158B (en) | A kind of dumb light underglaze colour throws the production method of glazed brick | |
| CN104291873B (en) | A kind of adobe of once-firing crystallite glass composite plate | |
| CN104261893B (en) | A kind of adobe of once-firing crystallite glass composite plate | |
| CN104291880B (en) | The adobe of a kind of once-firing crystallite glass composite plate | |
| CN104230389B (en) | A kind of adobe of once-firing crystallite glass composite plate | |
| CN104291878B (en) | A kind of unfired brick structure of once-firing crystallite glass composite plate | |
| CN104250116B (en) | A kind of adobe of once-firing crystallite glass composite plate | |
| CN104230393B (en) | A kind of adobe of once-firing crystallite glass composite plate | |
| CN104250114B (en) | A kind of adobe of once-firing crystallite glass composite plate | |
| CN104326770B (en) | A kind of glass-ceramic clad plate production technology | |
| CN104261682B (en) | Green brick of one-step sintered glass-ceramic composite board | |
| CN104261894B (en) | A kind of adobe of once-firing crystallite glass composite plate | |
| CN104261678B (en) | A kind of adobe of once-firing crystallite glass composite plate | |
| CN101691313A (en) | Technology for producing glass ceramic composite boards | |
| CN104261681B (en) | A kind of adobe of once-firing crystallite glass composite plate | |
| CN104230388B (en) | A kind of adobe of once-firing crystallite glass composite plate | |
| CN108558356B (en) | Thin microcrystal soft light brick and preparation method thereof | |
| CN104250110B (en) | A kind of adobe of once-firing crystallite glass composite plate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20201127 Address after: San Xing Wu Ben Cun, Jinfeng Town, Zhangjiagang City, Suzhou City, Jiangsu Province Patentee after: Zhangjiagang Hezhi Intellectual Property Co., Ltd Address before: 528000 Guangdong Province, Foshan city Chancheng District Wenhua Road No. 56 room 1603 two seven Patentee before: FOSHAN HECAI TECHNOLOGY SERVICE Co.,Ltd. |
|
| TR01 | Transfer of patent right |