CN104291635A - Convex tempered vacuum glass provided with getter in edge sealing of sealing strips and preparing method thereof - Google Patents
Convex tempered vacuum glass provided with getter in edge sealing of sealing strips and preparing method thereof Download PDFInfo
- Publication number
- CN104291635A CN104291635A CN201310298713.6A CN201310298713A CN104291635A CN 104291635 A CN104291635 A CN 104291635A CN 201310298713 A CN201310298713 A CN 201310298713A CN 104291635 A CN104291635 A CN 104291635A
- Authority
- CN
- China
- Prior art keywords
- glass
- vacuum
- sealing
- performed polymer
- toughened
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
- Y02P40/57—Improving the yield, e-g- reduction of reject rates
Landscapes
- Joining Of Glass To Other Materials (AREA)
Abstract
Convex tempered vacuum glass provided with a getter in edge sealing of sealing strips is disclosed. The convex tempered vacuum glass is characterized in that: upper glass and lower glass are convex tempered glass; the upper glass is provided with an extraction opening; the extraction opening is provided with a sealing cover; the getter is disposed in the extraction opening; the periphery of the upper glass and the periphery of the lower glass are provided with the sealing strips; the periphery of the upper glass and the periphery of the lower glass are welded by adoption of low-temperature glass solder at normal pressure in an edge banding furnace; the extraction opening is automatically sealed by utilization of the sealing cover and metal solder in a vacuum furnace; the getter is automatically activated in a sealing process; a closed vacuum layer is formed between the upper glass and the lower glass; the sealing strips are made of tempered glass printing ink and/or polymer; the polymer is prepared into pre-polymer firstly, and then the prepolymer is prepared onto glass or tempered glass printing ink after glass tempering; the prepolymer cures at the room temperature or high temperature to form an elastomer; the prepolymer or the elastomer can automatically adapt to changes of the height of the vacuum layer; and volatile gas in the elastomer is removed at a high temperature and under high vacuum.
Description
Technical field
The present invention relates to glass post-processing technical field, particularly relate to a kind of sealed strip edge sealing convex surface toughened vacuum glass having getter and preparation method thereof.
Background technology
Vacuum glass is a kind of novel energy-saving glass, and vacuum glass not only can solve " breathing " problem of the double glazing of existing a large amount of use, and has that heat-and sound-insulating performance is good, wind pressure resistant strength is high, thickness is little and the advantage such as long service life.Vacuum glass is generally made up of two to three sheet glass, and form cavity between two adjacent sheet glass, the periphery of glass is provided with edge sealing structure, cavity forms vacuum layer after being pumped into vacuum.Vacuum glass is according to the difference forming vacuum layer mode, can be divided into two kinds, a kind of is vacuum glass without bleeding point, and the edge sealing of this vacuum glass carries out in vacuum oven, along with completing of edge sealing, between two adjacent sheet glass the cavity self-assembling formation vacuum layer closed; Another kind is the vacuum glass having bleeding point, the edge sealing of this vacuum glass carries out in High Temperature Furnaces Heating Apparatus at ambient pressure, after edge sealing completes again by prefabricated bleeding point between glass the cavity closed vacuumize, finally terminate rear enclosed bleeding point bleeding, complete the making of vacuum glass.
A series of vacuum glass without bleeding point and preparation method thereof is disclosed in the patent of the vacuum glass that present invention applicant applied in March, 2012, but when utilizing low temperature glass solder edge sealing, because low temperature glass solder is made up of many oxide, at high temperature, under vacuum, the air of solder wettable and moisture, volatile substances in solder, in the gas that solder dissolves in process of production and solder, the decomposition etc. of partial oxide all can cause in solder and produce a large amount of bubbles, greatly weaken the properties especially resistance to air loss of solder, the feasibility of this kind of mode is caused to be greatly affected.The vacuum glass of existing mass production is all the vacuum glass having bleeding point, but there is complex manufacturing technology, extraction temperature low (bleeding not thorough), monolithic vacuumizes, cost is high, production capacity is low, can not make the shortcomings such as toughened vacuum glass.In addition, it is larger that the sealed strip utilizing cryogenic glass powder or low temperature glass solder to make and upholder reach required its difficulty of height, its reason one is that glass is non-hygroscopic, be difficult to make highly higher sealed strip and upholder, two sealed strips when being glass temperings and upholder at high temperature melts, it reduces highly further.
The major way that existing vacuum glass maintains vacuum adopts electrodeless solder edge sealing and lay getter in vacuum layer, getter is for acquisition high vacuum, there is the features such as economic, easy, effective, lasting, production long lifetime, vacuum glass that is highly reliable, dominance energy are played an important role.Because the vacuum layer space of vacuum glass is very little, glass is again transparent, also need protection and the activation of considering getter, so it is very difficult for laying getter in vacuum layer.The setting method of traditional getter in vacuum glass is first under vacuo that getter is packaged, then be positioned in the groove that is opened in advance on glass, at vacuum glass edge sealing, vacuumize, seal bleeding point after, recycling laser or infrared rays etc. open the encapsulation activated degasser of getter, the shortcoming of this mode be getter encapsulating and lay complex process, getter amount very little, affect mechanical property that is attractive in appearance and glass.
Summary of the invention
Technical problem to be solved by this invention is for the existing defect having the vacuum glass of getter to exist, a kind of sealed strip edge sealing convex surface toughened vacuum glass having getter and preparation method thereof is provided, the making method technique of this vacuum glass is simple, can low-costly and in high volume, the high performance toughened vacuum glass of mechanization production, prepared toughened vacuum glass can overcome deficiency of the prior art, effectively can ensure resistance to air loss and the transparency of vacuum glass, and its intensity and heat insulation, sound-proofing properties can be increased.
In order to solve the problems of the technologies described above, the invention provides the convex surface toughened vacuum glass that a kind of sealed strip edge sealing has getter, comprise glass and lower-glass, it is characterized in that: described upper glass and described lower-glass are convex surface toughened glass, described upper glass there is bleeding point, described bleeding point has sealing cover, and getter is placed in described bleeding point, and the periphery of described upper glass and described lower-glass has sealed strip; The periphery of described upper glass and described lower-glass is by welding together in low temperature glass solder at ambient pressure edge sealing stove, described bleeding point utilizes described sealing cover and brazing metal self-closed in vacuum oven, described getter automatic activation in capping processes, the vacuum layer that between described upper glass and described lower-glass, formation one is closed; Described sealed strip is made up of toughened glass ink and/or superpolymer, described superpolymer first makes performed polymer, again described performed polymer is prepared on described glass or described toughened glass ink after glass tempering, described performed polymer is solidified into elastomerics at ambient temperature or elevated temperature, described performed polymer or elastomerics can adapt to the change of described vacuum layer height automatically, and described elastomerics gets rid of the volatile gases contained by self under high temperature, high vacuum.
In order to solve the problems of the technologies described above, the invention provides the preparation method of convex surface toughened vacuum glass or convex surface toughened vacuum glass, it comprises:
The first step, according to the shape of the vacuum glass of required making and two pieces of flat glasss up and down of size cutting desired size, makes bleeding point in the edge punching of upper glass, and carries out edging, chamfering, cleaning and drying treatment to upper and lower two blocks of glass;
Second step, prepares sealed strip at the periphery of upper and lower glass, and the sealed strip of upper glass can insert in the sealed strip of the correspondence of lower-glass; Upper lower-glass after process is loaded hot bending die, is placed in annealing furnace, is warming up to the temperature 550 ~ 750 DEG C of Glass Transition, rely on the gravity of glass self or externally applied forces to make glass form convex surface downwards, and carry out wind-cooling reinforcing process;
3rd step, selects suitable polymer monomer, first monomer whose is become the performed polymer of setting viscosity through preliminary polymerization, is then produced on toughened glass ink or upper lower-glass by performed polymer by printing, printing or the mode of mechanically spraying; Performed polymer can at room temperature be solidified into elastomerics, elastomerics by catalyzer in vacuum glass edge sealing process, be heated to the irregular change that elastomeric state adapts to vacuum layer height automatically before glass closes sheet; Performed polymer also automatically can adapt to after glass closes sheet vacuum layer height irregular change, again by hot setting elastomer-forming;
4th step, the pipe that the internal diameter producing an external diameter and bleeding point matches, formation sealing groove is upwards dug in the bottom of pipe; Inserted by pipe in bleeding point, even spread low temperature glass solder between the upper outside of pipe and upper glass, according to the size of sealing groove, make a sealing cover, the edge of sealing cover can be inserted in sealing groove; By even spread low temperature glass solder between the sealed strip of lower-glass periphery, upper and lower glass is sent in edge sealing stove after closing sheet;
5th step, heat temperature raising operation is carried out to described edge sealing stove, be warming up to more than the melt temperature of low temperature glass solder, reach edge sealing temperature, the sealed strip of upper glass embeds between the sealed strip of lower-glass under the action of gravity of glass, and the low temperature glass solder of melting by upper and lower sealed strip by upper and lower two pieces of glass cementations together; Stop heating, with stove cooling, after low temperature glass solder solidifies, two blocks of glass hermetic welded together, simultaneously low temperature glass solder also by the upper outside of pipe together with upper glass solder, the fire door opening edge sealing stove obtains double glazing;
6th step, puts into getter bleeding point, covers sealing cover, then brazing metal is put on sealing groove or sealing cover, and sends in vacuum oven; Described vacuum sole is vacuumized, limit heating, be evacuated to below 0.1Pa, be warming up to more than the temperature of fusion of brazing metal, getter automatic activation under high temperature, high vacuum, brazing metal is also fused into liquid; Liquid retention is in sealing groove, and the edge of sealing cover is also flooded in a liquid, and liquid is by bleeding point self-sealing, and getter is also sealed in vacuum layer; Stop heating, with stove cooling, brazing metal solidifies and realizes airtight sealing to bleeding point afterwards, opens vacuum oven, takes out vacuum glass;
7th step, puts into seal gum in the bleeding point of vacuum glass, Paste Product trade mark or metal decorative sheet on seal gum.
Wherein, described convex glass convex surface facing outside, convex surface bow is highly not less than 0.1mm, is preferably 1 ~ 200mm, more preferably 3 ~ 10mm.
Wherein, the periphery of described upper glass has a sealed strip at least, the periphery of described lower-glass has two sealed strips at least.
Wherein, the sealed strip of described upper glass is corresponding with the sealed strip of described lower-glass, and the sealed strip of described upper glass can insert between the sealed strip of described lower-glass.
Wherein, described vacuum glass can also comprise one block of intermediate glass, described intermediate glass is clipped between described upper glass and described lower-glass, described upper glass and described intermediate glass there is bleeding point, described bleeding point utilizes sealing cover and brazing metal self-closed in vacuum oven, and described upper glass and described lower-glass form two closed vacuum layer respectively with described intermediate glass.
Wherein, described upper glass, described intermediate glass and described lower-glass are toughened glass or semi-tempered glass.
Wherein, described upper glass, described intermediate glass and described lower-glass are coated glass or Low-E glass.
Wherein, described sealed strip adopts printing, printing or mechanically spraying toughened glass ink and/or the mode such as performed polymer or metal paste to prepare.
Wherein, described getter is powdery, granular, banded, the various ways such as tubulose, ring-type, column.
Wherein, described getter can directly put into described bleeding point, also can be contained in a container and put into described bleeding point again.
Wherein, described circular hole is a V shaped hole or is made up of the circular hole of two upper big, lower small.
Wherein, described pipe is metal circular tube or glass round tube.
Further, when described pipe is metal tube, preferably adopt the metal that thermal expansivity is close with glass, as kovar alloy etc.
Further, when described pipe is Glass tubing, the internal surface of preferred described sealing groove scribbles metal paste, by high temperature sintering on the internal surface of described sealing groove.
Wherein, described sealing groove can be the annular recesses of arbitrary shape.
Further, described sealing groove is the cross section concentric with described bleeding point is V-type or U-shaped annular recesses.
Wherein, described sealing groove and sealing cover diameter and highly preferably consider bleed-off passage and solder sealed vol and determine.
Further, the top of described sealing cover is not higher than the upper surface of described upper glass.
Wherein, described sealing cover is preferably made up of glass or metal, is preferably sintered in the edge of described sealing cover by metal paste when described sealing cover is glass.
Further, described metal paste or electric slurry contribute to welding between brazing metal with glass, and described metal paste serves as the transition layer between glass and brazing metal.
Further, described metal paste is made up of metal powder, glass powder, organic resin and solvent etc., and described metal paste can adopt commercially available prod.
Wherein, described brazing metal comprises low-temperature metal solder and solder, and described material is existing commercial commodity.
Further, the fusing point of described brazing metal is lower than the fusing point of low temperature glass solder, and during brazing metal fusing, the low temperature glass solder of edge sealing remains unchanged.
Further, the shape of described brazing metal is powdery, strip, sheet or bulk, ring-type, tubulose etc.
Wherein, in the vacuum layer of described convex surface toughened vacuum glass not or have a small amount of upholder, convex surface toughened vacuum glass mainly relies on convex shape to resist barometric point.
Wherein, above support is made up of metal, pottery, glass or high molecular polymer, matrix material, preferably adopts printing, spraying toughened glass ink or performed polymer preparation.
Wherein, above support has one deck or two-layer; Above support is printed on one block of glass, or is printed on two blocks of glass.
Wherein, above support is column, or is strip; When upholder is printed on one block of glass, preferably cylindric; When upholder is printed on two blocks of glass simultaneously, be preferably strip, and vertical pile.
Wherein, above support and sealed strip can be combined by described toughened glass ink and described superpolymer, also can be made separately by described toughened glass ink or described superpolymer.
Wherein, described toughened glass ink preferably transparent or translucent.
Wherein, described superpolymer is high molecular polymer, preferred heterogeneous chain polymer and elemento-organic polymer.
Wherein, described superpolymer preferably transparent or translucent polymkeric substance, as polyimide, polyacrylonitrile and organosilicon etc.
Wherein, described resistant to elevated temperatures superpolymer keeps shape invariance, the polymkeric substance of chemical transformation does not occur, as polymeric amide, polyimide, polyacrylonitrile and organosilicon etc. under referring to the temperature more than 160 DEG C.
Wherein, described high temperature refers to 160-460 DEG C, preferred 260-360 DEG C.
Wherein, described performed polymer refers to the polymkeric substance that a kind of molecular weight of the polymerization degree between monomer and final polymkeric substance is lower, preferably has certain viscosity and is suitable for printing, prints or the viscous body of mechanically spraying.
Wherein, catalyzer, linking agent or coupling agent etc. can be had in described performed polymer, mineral filler or metal-powder etc. can also be had, to promote the crosslinked of described performed polymer or increase described elastomeric elasticity, hardness and improve temperature tolerance and weldability etc.
Wherein, the viscous body that described performed polymer is formed through printing, printing or mechanically spraying, it keeps shape invariance, under external force shape to change under self gravitation.
Wherein, described automatic adaptation refers to that glass closes its height of described performed polymer be clipped between two sheet glass after sheet and can be compressed into the height of place vacuum layer, described automatic adaptation also can refer to glass close sheet after the described elastomerics be clipped between two sheet glass when at high temperature becoming elastomeric state its height under the gravity or the gravity of self of upper glass, compressed or be stretched to the height of place vacuum layer.
Wherein, described elastomerics refer to described performed polymer catalyzer or and temperature effect under its molecule crosslinked or cyclization and final polymkeric substance of high elastic coefficient of obtaining further.
Wherein, described high vacuum refers to that vacuum tightness is at 0.1-0.001Pa.
Wherein, described volatile gases refers to that described performed polymer is at the moisture, the catalyzer added or other small-molecule substance that are cross-linked or produce in cyclization process.
Wherein, described edge sealing stove can once heat one to several piece vacuum glass.
Wherein, described edge sealing stove and accessory has basic heating system and hot spot system, basis heating system can adopt the mode of Hot-blast Heating or resistive heating as nichrome wire, electrothermal tube, hot plate etc., and hot spot system can adopt the modes such as resistive heating, infrared heating, LASER HEATING, Electromagnetic Heating;
Further, the heating of described basis, is that burner hearth or bulk glass are heated to a lower temperature, as 300 ~ 350 DEG C, toughened glass can not be caused obviously to anneal;
Further, described local heating is that solder or glass periphery are heated to a higher temperature, as 400 ~ 450 DEG C, prevents the overall obviously annealing of toughened glass.
Wherein, described in vacuumize and bleeding point sealing, can in vacuum oven batch carry out, also can monolithic implement; Overallly can heat glass, also can local heating bleeding point.
Wherein, described vacuum oven heating, can adopt conventional heating, Infrared Heating, also can adopt induction heating, LASER HEATING, can also adopt other suitable heating unit or heater meanses.
Further, described heating, can heat bulk glass, also can local heating bleeding point.
Wherein, described seal gum preferably has secret sealing, more preferably hot melt adhesive, hot-setting adhesive or two component sealing gum.
Beneficial effect of the present invention:
Sealed strip edge sealing of the present invention have the sealed structure of its getter of convex surface toughened vacuum glass of getter simple, seal reliable, convenient for production, with low cost; Getter does not need to encapsulate under vacuo but is directly placed in bleeding point; In a vacuum furnace under high temperature, high vacuum, not only can direct activated degasser, and can effectively remove getter surface absorption gas, getter is regenerated, ensure that the gettering ability of getter; Its space of bleeding point of the present invention comparatively speaking can be very large, so more substantial getter can be laid, the vacuum tightness of the vacuum layer time that is higher but also that maintain not only can be made longer, thus be conducive to heat insulation, the sound-proofing properties that improve vacuum glass, extend its work-ing life; Under normal pressure, under low temperature glass solder edge sealing and vacuum, brazing metal sealing solves the airtight integrity problem of solder, add the tightness of vacuum layer between upper and lower glass, improve the life-span of vacuum glass, drastically increase the productivity of vacuum glass and qualification rate, reduce the production cost of vacuum glass; Toughened glass ink and superpolymer are combined by the present invention, not only effectively can improve the height of upholder and sealed strip, and can keep the height of upholder and sealed strip; The present invention can adjust the viscosity of performed polymer easily by the molecular weight of adjustment performed polymer, thus utilizes printing, to print or the mode such as mechanically spraying realizes low-costly and in high volume, upholder and sealed strip are prepared in mechanize, automatization; The present invention is by performed polymer deformability at normal temperatures and elastomerics deformability at high temperature, make upholder and sealed strip automatically can adapt to the irregular change of vacuum layer height, eliminate the impact of toughened glass planeness, thus realize the effective support to toughened vacuum glass, make the scale operation of toughened vacuum glass become possibility; The present invention can make performed polymer solidify under specified requirements by selecting suitable catalyzer or temperature, sealed strip and upholder is not only made to be easy to make, be convenient to obtain relative high height, and upholder can be made to have suitable elasticity, greatly can reduce the stress that glass bears compared with rigid support thing, thus reduce the breakage rate of glass, the qualification rate improving vacuum glass and life-span; Superpolymer has extremely low thermal conductivity, has higher sonic transmissions loss compared with rigid material compared with metallic substance, so the vacuum glass made with this upholder has better heat insulation and sound-proofing properties; High temperature required in vacuum glass edge sealing process and high vacuum, not only can make superpolymer complete volatile gases that is crosslinked but also that can get rid of contained by superpolymer, makes upholder and sealed strip can not emission gases again in the use procedure of vacuum glass; And high upholder can make that vacuum layer thickens, space is strengthened, be not only conducive to obtaining high vacuum, but also be conducive to keeping high vacuum; Toughened vacuum glass of the present invention, structure is simple, safe and reliable, convenient for production, with low cost, can mass, mechanization production, greatly can improve production efficiency and qualification rate, the reduction production cost of toughened vacuum glass.
Accompanying drawing explanation
Fig. 1 is the convex surface toughened vacuum glass structural representation having upholder of the present invention;
Fig. 2 is of the present invention pair of vacuum layer convex surface toughened vacuum glass structural representation;
In figure: 1. go up glass, 2. lower-glass, 3. bleeding point, 4. low temperature glass solder, 5. go up the sealed strip of glass, 6. the sealed strip of lower-glass, 7. brazing metal, 8. upholder, 9. intermediate glass, 10. seal gum, 11. product brands, 12. superpolymer, 13. getters, 14. sealing grooves, 15. sealing covers.
Embodiment
Below adopt embodiment and accompanying drawing to describe embodiments of the present invention in detail, to the present invention, how utilisation technology means solve technical problem whereby, and the implementation procedure reaching technique effect can fully understand and implement according to this.
Embodiment 1: see Fig. 1, two blocks of glass of toughened vacuum glass are toughened glass or semi-tempered glass, wherein one piece or low emissivity glass, its making method is as follows: first according to the shape of made vacuum glass and two pieces of flat glasss of size cutting desired size, bore a conical through-hole at the edge of upper glass 1 and form bleeding point 3, edging, chamfering and cleaning, drying are carried out to upper lower-glass, utilizes toughened glass ink to prepare sealed strip 5 and 6 by mechanical spraying technology at the periphery weld of upper lower-glass; Secondly two blocks of glass are respectively charged in two forming moulds, the forming mould that glass is housed is placed in annealing furnace, is warming up to the temperature of Glass Transition, rely on gravity to make the glass in forming mould form convex surface downwards, carry out wind-cooling reinforcing immediately, obtain tempering or semi-tempered glass; Upholder 8 is made up separately of superpolymer 12, and superpolymer 12 is polyimide, first with pyromellitic acid dianhydride and aromatic diamines for raw material, in dimethyl sulfoxide (DMSO) equal solvent, preliminary polymerization becomes performed polymer, makes performed polymer have suitable viscosity by the adjustment polymerization degree; Then on upper lower-glass, utilized by performed polymer the woven wire of tensioning or expanded metal lath to print upholder, make the top of upholder in one plane, to eliminate the impact of glass deformation on planeness, upholder 8 for minimum unit be the lattice arrangement of equilateral triangle, upholder is strip, the upholder of upper lower-glass is orthogonal, it is crosswise shape that upper lower-glass closes sheet rear support thing overlap, is prepared in by performed polymer on the sealed strip 5 and 6 of the periphery weld of upper lower-glass by mechanical spraying technology simultaneously; Produce a metal circular tube to insert in bleeding point, the lower end of pipe is upwards dug and is formed sealing groove 14, and the top of pipe is lower than the upper surface of upper glass 1; Make a sealing cover 15 according to the size of sealing groove 14, the edge of sealing cover 15 can be inserted in sealing groove 14, and the top of sealing cover 15, lower than the upper surface of upper glass 1, is bleed-off passage between sealing cover 15 and sealing groove 14; Again by even spread low temperature glass solder 4 between the outside of pipe and upper glass 1, between two sealed strips 6 of lower-glass 2 periphery, and two pieces of glass consistencies from top to bottom are stacked together, send in edge sealing stove; Edge sealing stove and accessory has basic heating system and hot spot system, first utilize basic heating system as electric heater for heating, make basal temperature rise to 300 ~ 350 DEG C, the molecule of performed polymer cyclization gradually in the process, dehydrating and curing elastomer-forming, realize the powerful support to upper glass and lower-glass; Low temperature glass solder 4 is heated to melt temperature 430 ~ 450 DEG C by recycling hot spot system such as far infra-red heater, stops heating, with stove cooling, and two blocks of glass and pipe and upper glass 1 hermetic weld together by low temperature glass solder 4; Finally getter 13 put into bleeding point, cover sealing cover 15, brazing metal 7 is put into sealing groove 14 as zinc alloy solder or is placed on sealing cover 15, send in vacuum oven, carry out vacuumizing and heating operation, be evacuated to below 0.1Pa, make the vacuum tightness that vacuum layer reaches required, elastomerics gets rid of the whole volatile gaseses contained by self gradually under high temperature, high vacuum simultaneously, to avoid elastomerics, in the use procedure of vacuum glass, phenomenon of deflation occurs, getter 13 also automatic activation under high temperature, high vacuum; Be warming up to the melt temperature more than 380 DEG C of zinc alloy solder 7 again, zinc alloy solder 7 is fused into liquid retention in sealing groove 14, and the lower end of sealing cover 15 is also flooded in a liquid, and liquid is by bleeding point self-sealing; Stop heating, with stove cooling, zinc alloy solder 7 condenses into solid, realizes airtight sealing to bleeding point, and getter 13 is also sealed in vacuum layer; Open vacuum oven, take out vacuum glass.Seal gum 10 is put into while hot as butyl rubber, the product brand 11 of covering above of seal gum 10, the upper surface flush of trade mark 11 and upper glass 1 in bleeding point.
Embodiment 2: see Fig. 2, the upper lower-glass of two vacuum layer toughened vacuum glass is toughened glass or semi-tempered glass, intermediate glass is low emissivity glass, its making method is as follows: first according to the shape of the vacuum glass of required making and three pieces of flat glasss of size cutting desired size, upper glass 1 and intermediate glass 9 bore a through hole respectively and forms bleeding point 3, the through hole wherein gone up on glass 1 is greater than the through hole on intermediate glass 9, and edging, chamfering are carried out to three blocks of glass, cleaning, drying treatment; Secondly utilize toughened glass ink to spray at the periphery weld of upper glass 1, lower-glass 2 and intermediate glass 9 and prepare sealed strip 5 and 6, intermediate glass 9 is directly sent in High Temperature Furnaces Heating Apparatus and carries out pyroprocessing, upper and lower two blocks of glass are loaded in mould, be warming up to the temperature 550 ~ 750 DEG C of Glass Transition, rely on the gravity of glass self or externally applied forces to make glass form convex surface downwards, and carry out tempering process immediately; Then superpolymer 12 is made, superpolymer 12 is silicone elastomers, with METHYL TRICHLORO SILANE, phenyl-trichloro-silicane etc. for main raw material, add two functionality monomer such as dimethyldichlorosilane(DMCS), dichloromethyl phenylsilane, above-mentioned monomer is hydrolyzed in a solvent, polycondensation, eccysis byproduct hydrogen chloride, obtains still containing the resin liquid of a small amount of silicone hydroxyl, adds a small amount of catalyzer if cobalt naphthenate etc. is as performed polymer using this resin liquid; Then by performed polymer by printing, to print or the mode of mechanically spraying is produced on toughened glass ink, performed polymer solidify to form certain intensity and hardness gradually subsequently; Respectively producing a metal circular tube inserts in the bleeding point of upper glass 1 and intermediate glass 9, and the lower end of pipe is upwards dug and formed sealing groove 14, and the top of pipe is lower than the upper surface of upper glass 1; Make a sealing cover 15 according to the size of sealing groove 14, the edge of sealing cover 15 can be inserted in sealing groove 14, and the top of sealing cover 15, lower than the upper surface of upper glass 1, is bleed-off passage between sealing cover 15 and sealing groove 14; Again fill low temperature glass solder 4 by the upper outside of pipe and between upper glass 1 and intermediate glass 9, between intermediate glass 9 and two sealed strips 6 of lower-glass 2 periphery, and described three pieces of glass consistencies from top to bottom are stacked together, ensure that sealed strip 5 is corresponding with sealed strip 6, send in edge sealing stove; Finally carry out edge sealing, the placement of getter 13 and the sealing of bleeding point 3, with embodiment 1, just brazing metal 7 changes magnesium alloy into.
All above-mentioned this intellecture properties of primary enforcement, not setting restriction this product innovation of other forms of enforcement and/or novel method.Those skilled in the art, based on the amendment of foregoing, can realize similar implementation status.But all modifications or transformation belong to the right of reservation based on product innovation of the present invention.
The above is only preferred embodiment of the present invention, and be not restriction the present invention being made to other form, any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed or be modified as the Equivalent embodiments of equivalent variations.But everyly do not depart from technical solution of the present invention content, any simple modification, equivalent variations and the remodeling done above embodiment according to technical spirit of the present invention, still belong to the protection domain of technical solution of the present invention.
Claims (10)
1. a sealed strip edge sealing has the convex surface toughened vacuum glass of getter, comprise glass and lower-glass, it is characterized in that: described upper glass and described lower-glass are convex surface toughened glass, described upper glass there is bleeding point, described bleeding point there is sealing cover, getter is placed in described bleeding point, and the periphery of described upper glass and described lower-glass has sealed strip; The periphery of described upper glass and described lower-glass is by welding together in low temperature glass solder at ambient pressure edge sealing stove, described bleeding point utilizes described sealing cover and brazing metal self-closed in vacuum oven, described getter automatic activation in capping processes, the vacuum layer that between described upper glass and described lower-glass, formation one is closed; Described sealed strip is made up of toughened glass ink and/or superpolymer, described superpolymer first makes performed polymer, again described performed polymer is prepared on described glass or described toughened glass ink after glass tempering, described performed polymer is solidified into elastomerics at ambient temperature or elevated temperature, described performed polymer or elastomerics can adapt to the change of described vacuum layer height automatically, and described elastomerics gets rid of the volatile gases contained by self under high temperature, high vacuum.
2. vacuum glass according to claim 1, it is characterized in that described vacuum glass can also comprise one block of intermediate glass, described intermediate glass is clipped between described upper glass and described lower-glass, described upper glass and described intermediate glass there is bleeding point, described bleeding point utilizes sealing cover and brazing metal self-closed in vacuum oven, and described upper glass and described lower-glass form two closed vacuum layer respectively with described intermediate glass.
3. toughened vacuum glass according to claim 1 and 2, is characterized in that the periphery of described upper glass has a sealed strip at least, and the periphery of described lower-glass has two sealed strips at least.
4. toughened vacuum glass according to claim 1 and 2, it is characterized in that there is upholder in described vacuum layer, above support has one deck or two-layer; Above support is made up of toughened glass ink and/or superpolymer, described superpolymer first makes performed polymer, again described performed polymer is prepared on described glass or described toughened glass ink after glass tempering, described performed polymer is solidified into elastomerics at ambient temperature or elevated temperature, described performed polymer or elastomerics can adapt to the change of described vacuum layer height automatically, and described elastomerics gets rid of the volatile gases contained by self under high temperature, high vacuum.
5. the toughened vacuum glass according to claim 1 or 4, is characterized in that described performed polymer has certain viscosity to be suitable for printing, to print or liquid polymer that the molecular weight of mechanically spraying is lower.
6. the toughened vacuum glass according to any one of claim 1 to 5, it is characterized in that can having catalyzer, linking agent or coupling agent in described performed polymer, mineral filler or metal-powder can also be had, to promote the crosslinked of described performed polymer or increase elasticity, the hardness of above support and improve temperature tolerance.
7. the toughened vacuum glass according to claim 1 or 4, is characterized in that described elastomerics refers to described performed polymer at catalyzer or/and its molecule crosslinked or cyclization and final polymkeric substance of high elastic coefficient of obtaining further under the effect of temperature.
8. the toughened vacuum glass according to claim 1 or 4, it is characterized in that described automatic adaptation refers to that glass closes its height of described performed polymer be clipped between two sheet glass after sheet and can be compressed into the height of place vacuum layer, described automatic adaptation or refer to glass close sheet after the described elastomerics be clipped between two sheet glass when at high temperature becoming elastomeric state its height under the gravity or the gravity of self of upper glass, compressed or be stretched to the height of place vacuum layer.
9. the toughened vacuum glass according to claim 1 or 4, is characterized in that described volatile gases refers to that described performed polymer is at the moisture, the catalyzer added or other small-molecule substances that are cross-linked or produce in cyclization process.
10. the making method of the toughened vacuum glass described in any one of claim 1 to 9, is characterized in that comprising the following steps:
The first step, according to the shape of the vacuum glass of required making and two pieces of flat glasss up and down of size cutting desired size, makes bleeding point in the edge punching of upper glass, and carries out edging, chamfering, cleaning and drying treatment to upper and lower two blocks of glass;
Second step, prepares sealed strip at the periphery of upper and lower glass, and the sealed strip of upper glass can insert in the sealed strip of the correspondence of lower-glass; Upper lower-glass after process is loaded hot bending die, is placed in annealing furnace, is warming up to the temperature 550 ~ 750 DEG C of Glass Transition, rely on the gravity of glass self or externally applied forces to make glass form convex surface downwards, and carry out wind-cooling reinforcing process;
3rd step, selects suitable polymer monomer, first monomer whose is become the performed polymer of setting viscosity through preliminary polymerization, is then produced on toughened glass ink or upper lower-glass by performed polymer by printing, printing or the mode of mechanically spraying; Performed polymer can at room temperature be solidified into elastomerics, elastomerics by catalyzer in vacuum glass edge sealing process, be heated to the irregular change that elastomeric state adapts to vacuum layer height automatically before glass closes sheet; Performed polymer also automatically can adapt to after glass closes sheet vacuum layer height irregular change, again by hot setting elastomer-forming;
4th step, the pipe that the internal diameter producing an external diameter and bleeding point matches, formation sealing groove is upwards dug in the bottom of pipe; Inserted by pipe in bleeding point, even spread low temperature glass solder between the upper outside of pipe and upper glass, according to the size of sealing groove, make a sealing cover, the edge of sealing cover can be inserted in sealing groove; By even spread low temperature glass solder between the sealed strip of lower-glass periphery, upper and lower glass is sent in edge sealing stove after closing sheet;
5th step, heat temperature raising operation is carried out to described edge sealing stove, be warming up to more than the melt temperature of low temperature glass solder, reach edge sealing temperature, the sealed strip of upper glass embeds between the sealed strip of lower-glass under the action of gravity of glass, and the low temperature glass solder of melting by upper and lower sealed strip by upper and lower two pieces of glass cementations together; Stop heating, with stove cooling, after low temperature glass solder solidifies, two blocks of glass hermetic welded together, simultaneously low temperature glass solder also by the upper outside of pipe together with upper glass solder, the fire door opening edge sealing stove obtains double glazing;
6th step, puts into getter bleeding point, covers sealing cover, then brazing metal is put on sealing groove or sealing cover, and sends in vacuum oven; Described vacuum sole is vacuumized, limit heating, be evacuated to below 0.1Pa, be warming up to more than the temperature of fusion of brazing metal, getter automatic activation under high temperature, high vacuum, brazing metal is also fused into liquid; Liquid retention is in sealing groove, and the edge of sealing cover is also flooded in a liquid, and liquid is by bleeding point self-sealing, and getter is also sealed in vacuum layer; Stop heating, with stove cooling, brazing metal solidifies and realizes airtight sealing to bleeding point afterwards, opens vacuum oven, takes out vacuum glass;
7th step, puts into seal gum in the bleeding point of vacuum glass, Paste Product trade mark or metal decorative sheet on seal gum.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310298713.6A CN104291635A (en) | 2013-07-17 | 2013-07-17 | Convex tempered vacuum glass provided with getter in edge sealing of sealing strips and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310298713.6A CN104291635A (en) | 2013-07-17 | 2013-07-17 | Convex tempered vacuum glass provided with getter in edge sealing of sealing strips and preparing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104291635A true CN104291635A (en) | 2015-01-21 |
Family
ID=52311628
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310298713.6A Withdrawn CN104291635A (en) | 2013-07-17 | 2013-07-17 | Convex tempered vacuum glass provided with getter in edge sealing of sealing strips and preparing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104291635A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112441755A (en) * | 2020-11-25 | 2021-03-05 | 四川零能昊科技有限公司 | Activation method of built-in getter of vacuum glass, coating structure and packaging structure |
| CN112897903A (en) * | 2019-11-19 | 2021-06-04 | 吉林建筑大学 | Vacuum glass and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4198254A (en) * | 1976-11-26 | 1980-04-15 | Bfg Glassgroup | Vitreous sheets with synthetic polymer spacer and process for making the same |
| CN2544073Y (en) * | 2002-09-05 | 2003-04-09 | 京东方科技集团股份有限公司 | Air discharge hole closure device for high thermal-insulation sound-insulation glass |
| CN101792253A (en) * | 2010-04-14 | 2010-08-04 | 左树森 | Encapsulation method for vacuum glass getter |
| US20120321822A1 (en) * | 2009-11-27 | 2012-12-20 | Luoyang Landglass Technology Co., Ltd | Compound Sealing Method for Vacuum Glass |
| CN102951826A (en) * | 2012-10-06 | 2013-03-06 | 戴长虹 | Metal solder-welded and strip frame-edge-sealed convex vacuum glass and manufacturing method thereof |
-
2013
- 2013-07-17 CN CN201310298713.6A patent/CN104291635A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4198254A (en) * | 1976-11-26 | 1980-04-15 | Bfg Glassgroup | Vitreous sheets with synthetic polymer spacer and process for making the same |
| CN2544073Y (en) * | 2002-09-05 | 2003-04-09 | 京东方科技集团股份有限公司 | Air discharge hole closure device for high thermal-insulation sound-insulation glass |
| US20120321822A1 (en) * | 2009-11-27 | 2012-12-20 | Luoyang Landglass Technology Co., Ltd | Compound Sealing Method for Vacuum Glass |
| CN101792253A (en) * | 2010-04-14 | 2010-08-04 | 左树森 | Encapsulation method for vacuum glass getter |
| CN102951826A (en) * | 2012-10-06 | 2013-03-06 | 戴长虹 | Metal solder-welded and strip frame-edge-sealed convex vacuum glass and manufacturing method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112897903A (en) * | 2019-11-19 | 2021-06-04 | 吉林建筑大学 | Vacuum glass and preparation method thereof |
| CN112441755A (en) * | 2020-11-25 | 2021-03-05 | 四川零能昊科技有限公司 | Activation method of built-in getter of vacuum glass, coating structure and packaging structure |
| CN112441755B (en) * | 2020-11-25 | 2023-02-21 | 四川零能昊科技有限公司 | Activation method of built-in getter of vacuum glass, coating structure and packaging structure |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103420587A (en) | Vacuum convex glass welded with seal grooves and mounting holes | |
| CN104291635A (en) | Convex tempered vacuum glass provided with getter in edge sealing of sealing strips and preparing method thereof | |
| CN104291608A (en) | Convex tempered vacuum glass edge-sealed by using sealing groove and provided with getter, and preparation method thereof | |
| CN104291628A (en) | Convex toughened vacuum glass provided with getter with edges being sealed by sealing strips and sealing grooves and manufacturing method thereof | |
| CN104291656A (en) | Microwave-welded convex tempered vacuum glass edge-sealed with sealing groove and having getter | |
| CN104291623A (en) | Microwave-welded convex tempered vacuum glass with edge sealed by using sealing strips and sealing groove and with getter | |
| CN104291646A (en) | Flat tempered vacuum glass edge-sealed with sealing bars and sealing grooves and having getter and manufacturing method thereof | |
| CN104291647A (en) | Microwave-welded flat tempered vacuum glass edge-sealed with sealing groove and having getter | |
| CN104291597A (en) | Glass-solder microwave-welded planar tempered vacuum glass edge-sealed by using bar frames | |
| CN104291607A (en) | Microwave-welded convex tempered vacuum glass with edge sealed by using sealing strips and with getter | |
| CN104291604A (en) | Planar tempered vacuum glass edge-sealed by using sealing strips and with getter, and preparation method thereof | |
| CN104291645A (en) | Flat tempered vacuum glass edge-sealed with sealing groove and having getter and manufacturing method thereof | |
| CN104291637A (en) | Microwave-welded flat tempered vacuum glass edge-sealed with sealing bar and having getter | |
| CN104291620A (en) | Microwave-welded planar tempered vacuum glass edge-sealed by using sealing strips and a sealing groove and provided with getter | |
| CN104291600A (en) | Convex toughened vacuum glass provided with extraction opening with edges being sealed by sealing grooves and manufacturing method thereof | |
| CN104291653A (en) | Convex tempered vacuum glass edge-sealed with sealing bars and having vacuumizing hole and manufacturing method thereof | |
| CN104291658A (en) | Convex tempered vacuum glass edge-sealed with sealing bar and sealing groove and having vacuumizing hole and manufacturing method thereof | |
| CN104291694A (en) | Metal solder and microwave-welded convex toughened vacuum glass with edges being sealed by groove | |
| CN104291657A (en) | Microwave-welded convex tempered vacuum glass edge-sealed with sealing bar and having vacuumizing hole | |
| CN104291648A (en) | Microwave-welded convex tempered vacuum glass edge-sealed with sealing bar and sealing groove and having vacuumizing hole | |
| CN104291660A (en) | Flat tempered vacuum glass edge-sealed with sealing bar and having vacuumizing hole and manufacturing method thereof | |
| CN104291638A (en) | Microwave-welded convex tempered vacuum glass edge-sealed with sealing groove and having vacuumizing hole | |
| CN104291703A (en) | Metal-solder-welded planar toughened vacuum glass with edges being sealed by strip borders | |
| CN104291610A (en) | Planar tempered vacuum glass edge-sealed by using sealing grooves and provided with air-exhaust port, and preparation method thereof | |
| CN104291624A (en) | Planar toughened vacuum glass provided with extraction opening with edges being sealed by sealing strips and sealing grooves and manufacturing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20150121 |
|
| WW01 | Invention patent application withdrawn after publication |