CN104282355B - A kind of copper-coated magnesium alloy wire rod and preparation method thereof - Google Patents

A kind of copper-coated magnesium alloy wire rod and preparation method thereof Download PDF

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Publication number
CN104282355B
CN104282355B CN201410598674.6A CN201410598674A CN104282355B CN 104282355 B CN104282355 B CN 104282355B CN 201410598674 A CN201410598674 A CN 201410598674A CN 104282355 B CN104282355 B CN 104282355B
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magnesium alloy
copper
wire rod
coated
alloy
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CN104282355A (en
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李聪
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Shunde District, Foshan City, the synthesis of new Electrical Alloy Co., Ltd.
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Quzhou Liancheng Environmental Protection Technology Co Ltd
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Abstract

The invention provides a kind of copper-coated magnesium alloy wire rod, contain according to weight percent content: Al:10 12%, Eu:0.5 1.5%, Re:0.2 0.6%, Ca:1.2 1.6%, Th:0.5 1.5%, Nd:2.1 2.3%, Co:0.7 1.3%, Ta:0.8 1.0%, Dy:0.05 0.15%, W:0.2 0.4%, Rh:0.7 0.9%, Sb:2.1 2.3%, Bi:2.1 2.3%, Ho:0.3 0.5%, surplus is Mg and the copper strips of 30 40%.The present invention also proposes the preparation method of this copper-coated magnesium alloy wire rod.This alloy has excellent conductive performance.

Description

A kind of copper-coated magnesium alloy wire rod and preparation method thereof
Technical field
The invention belongs to field of magnesium alloy material, especially a kind of copper-coated magnesium alloy wire rod and preparation method thereof.
Background technology
Magnesium alloy is as the commercial metal structural timber of lightweight, because of its have that light specific gravity, specific strength specific stiffness be high, damping vibration attenuation drops that dry ability is strong, liquid condition shaping superior performance, there is the series of advantages such as dimensionally stable, pollution-free, easy recovery simultaneously and be described as 21 century " green structural material ".It is structure lightened ideal material, in the industry such as automobile, Aero-Space, national defence and 3C Product, has wide commercial application prospect.Poor yet with magnesium alloy deformation at room temperature ability, oxidizable burning, the defect such as perishable, limit magnesium alloy and be more widely used, it is extensive that the application of current magnesium alloy can not show a candle to aluminium alloy.Such as the epoch spread unchecked at this electronics, wire rod is widely used in the fields such as electric wire, electronics, computer, medical treatment, communication, Aero-Space, military project, and conventional wire majority is copper cash or aluminum steel.Although copper cash has preferable electric conductivity, but mechanical strength is inadequate, and price is high, heavier-weight, and copper material also needs a large amount of import, although aluminum steel low cost, its electric conductivity and mechanical strength are poor, and toughness is worse.Therefore, improve magnesium alloy strength and make it have good combination property, be the focus of novel magnesium alloy exploitation, and the exploitation of magnesium alloy bar/wire rod is significant to the application expanding magnesium alloy.Therefore need a kind of low price on market, lightweight, high intensity, the wire rod conducted electricity very well substitute copper cash and aluminum steel.
Summary of the invention
It is an object of the invention to provide a kind of copper-coated magnesium alloy wire rod, this copper-coated magnesium alloy wire rod is with low cost, and technique is simple, the most lightweight and have good plasticity, intensity, heat treatment performance and electric conductivity.
It is a further object to provide the preparation method of a kind of copper-coated magnesium alloy wire rod.
For reaching this purpose, the present invention by the following technical solutions:
A kind of copper-coated magnesium alloy wire rod, contains according to weight percent content: contain according to weight percent content: Al:10-12%, Eu:0.5-1.5%, Re:0.2-0.6%, Ca:1.2-1.6%, Th:0.5-1.5%, Nd:2.1-2.3%, Co:0.7-1.3%, Ta:0.8-1.0%, Dy:0.05-0.15%, W:0.2-0.4%, Rh:0.7-0.9%, Sb:2.1-2.3%, Bi:2.1-2.3%, Ho:0.3-0.5%, surplus is the copper strips of Mg and 30-40%.
Further, contain according to weight percent content: Al:10%, Eu:0.5%, Re:0.2%, Ca:1.2%, Th:0.5%, Nd:2.1%, Co:0.7%, Ta:0.8%, Dy:0.05%, W:0.2%, Rh:0.7%, Sb:2.1%, Bi:2.1%, Ho:0.3%, surplus is the copper strips of Mg and 30%.
The preparation method of described copper-coated magnesium alloy wire rod, comprises the following steps:
(1) raw material prepares: carrying out raw material preparation according to weight percent content, described raw material is pure Mg ingot, Mg-Eu intermediate alloy, pure Al ingot, pure Re, Al-Th intermediate alloy, Al-Ca intermediate alloy, Al-Co intermediate alloy, Mg-Nd intermediate alloy, Mg-Ta intermediate alloy, pure Dy, Al-Sb intermediate alloy, Al-W intermediate alloy, pure Rh, Al-Bi intermediate alloy, Al-Ho intermediate alloy;
(2) melting: carry out molten alloy in resistance furnace under conditions of SF6 gas and sodium chloride coverture are protected; all raw materials in step (1) are added in resistance furnace; temperature controls at 1100 DEG C~1200 DEG C; mechanical agitation 5 minutes after all raw materials are completely melt; after standing 30 minutes; carry out dragging for slag, obtain magnesium alloy smelting liquid;
(3) refine: carrying out refine by passing through the magnesium alloy smelting liquid RJ-5 refining agent dragging for slag gained in step (2), refining temperature is 1200 DEG C~1300 DEG C, and refining time is 15 minutes, obtains magnesium alloy refining liquid;
(4) molding: the magnesium alloy refining liquid of gained in step (3) is cast into Ф 0.5cm, the magnesium alloy bar of long 100cm;Mould therefor preheating temperature is 400 DEG C~500 DEG C, and cast temperature is 1100 DEG C~1200 DEG C;
(5) solution treatment: in 900 DEG C~1000 DEG C, the magnesium alloy bar of gained in step (4) is carried out solution treatment, and the time is 42 hours:
(6) quenching: magnesium alloy bar through solution treatment in step (5) is carried out shrend, puts into the magnesium alloy bar after quenching in the resistance furnace of 300 DEG C and carries out artificial aging 60 hours, prepare magnesium alloy blank;
(7) magnesium alloy bar/wire rod processed: the magnesium alloy blank of gained in step (6) is heated to 600 DEG C~700 DEG C, after being incubated 3 hours, the method using multi-pass small deformation amount, magnesium alloy blank is made the magnesium alloy bar/wire rod of a diameter of 0.3 centimetre;
(8) copper strips hacking: the copper strips accounting for all raw material weight percentage ratio 30% is carried out surface grinding process by hard steel wire brush;
(9) copper-coated magnesium alloy wire rod blank processed: with copper strips through surface grinding process in step (8), the magnesium alloy bar/wire rod of gained in step (7) is wrapped in centre, make copper-coated magnesium alloy wire rod blank with the pressure of 1-3MPa;
(10) copper-coated magnesium alloy wire rod processed: under argon shield, copper-coated magnesium alloy wire rod blank is carried out argon arc welding; by brazing together; after forming copper-coated magnesium alloy wire rod; the method of multi-pass small deformation amount is used to be drawn into the copper-coated magnesium alloy wire rod of 0.3cm with drawbench; at a temperature of 250 DEG C~300 DEG C, carry out Ageing Treatment 42 hours again, after cooling, i.e. obtain copper-coated magnesium alloy wire rod.
The copper-coated magnesium alloy wire rod Main Ingredients and Appearance that the invention have the advantage that the present invention is magnesium alloy, thus reduce and cost, and magnesium alloy bar/wire rod with the addition of Eu, Dy, Nd and Ho rare earth element can be effectively improved the intensity of copper-coated magnesium alloy wire rod, heat treatment performance and electric conductivity.
Detailed description of the invention
Embodiment 1
A kind of creep resistance Dow metal, contains according to weight percent content: Al:10%, Eu:0.5%, Re:0.2%, Ca:1.2%, Th:0.5%, Nd:2.1%, Co:0.7%, Ta:0.8%, Dy:0.05%, W:0.2%, Rh:0.7%, Sb:2.1%, Bi:2.1%, Ho:0.3%, surplus is the copper strips of Mg and 30%, and its preparation method comprises the following steps:
(1) raw material prepares: carrying out raw material preparation according to weight percent content, described raw material is pure Mg ingot, Mg-Eu intermediate alloy, pure Al ingot, pure Re, Al-Th intermediate alloy, Al-Ca intermediate alloy, Al-Co intermediate alloy, Mg-Nd intermediate alloy, Mg-Ta intermediate alloy, pure Dy, Al-Sb intermediate alloy, Al-W intermediate alloy, pure Rh, Al-Bi intermediate alloy, Al-Ho intermediate alloy;
(2) melting: carry out molten alloy in resistance furnace under conditions of SF6 gas and sodium chloride coverture are protected; all raw materials in step (1) are added in resistance furnace; temperature controls at 1100 DEG C; mechanical agitation 5 minutes after all raw materials are completely melt; after standing 30 minutes; carry out dragging for slag, obtain magnesium alloy smelting liquid;
(3) refine: carrying out refine by passing through the magnesium alloy smelting liquid RJ-5 refining agent dragging for slag gained in step (2), refining temperature is 1200 DEG C, and refining time is 15 minutes, obtains magnesium alloy refining liquid;
(4) molding: the magnesium alloy refining liquid of gained in step (3) is cast into Ф 0.5cm, the magnesium alloy bar of long 100cm;Mould therefor preheating temperature is 400 DEG C, and cast temperature is 1100 DEG C;
(5) solution treatment: the magnesium alloy bar of gained in step (4) is carried out in 900 DEG C solution treatment, and the time is 42 hours;
(6) quenching: magnesium alloy bar through solution treatment in step (5) is carried out shrend, puts into the magnesium alloy bar after quenching in the resistance furnace of 300 DEG C and carries out artificial aging 60 hours, prepare magnesium alloy blank;
(7) magnesium alloy bar/wire rod processed: the magnesium alloy blank of gained in step (6) is heated to 600 DEG C, after being incubated 3 hours, the method using multi-pass small deformation amount, magnesium alloy blank is made the magnesium alloy bar/wire rod of a diameter of 0.3 centimetre;
(8) copper strips hacking: the copper strips accounting for all raw material weight percentage ratio 30% is carried out surface grinding process by hard steel wire brush;
(9) copper-coated magnesium alloy wire rod blank processed: with copper strips through surface grinding process in step (8), the magnesium alloy bar/wire rod of gained in step (7) is wrapped in centre, make copper-coated magnesium alloy wire rod blank with the pressure of 1MPa;
(10) copper-coated magnesium alloy wire rod processed: under argon shield, copper-coated magnesium alloy wire rod blank is carried out argon arc welding; by brazing together; after forming copper-coated magnesium alloy wire rod; the method of multi-pass small deformation amount is used to be drawn into the copper-coated magnesium alloy wire rod of 0.3cm with drawbench; at a temperature of 250 DEG C, carry out Ageing Treatment 42 hours again, after cooling, i.e. obtain copper-coated magnesium alloy wire rod.
Embodiment 2 :
A kind of creep resistance Dow metal, contains according to weight percent content: Al:11%, Eu:1.0%, Re:0.4%, Ca:1.4%, Th:1.0%, Nd:2.2%, Co:1.0%, Ta:0.9%, Dy:0.1%, W:0.3%, Rh:0.8%, Sb:2.2%, Bi:2.2%, Ho:0.4%, surplus is the copper strips of Mg and 35%, and its preparation method comprises the following steps:
(1) raw material prepares: carrying out raw material preparation according to weight percent content, described raw material is pure Mg ingot, Mg-Eu intermediate alloy, pure Al ingot, pure Re, Al-Th intermediate alloy, Al-Ca intermediate alloy, Al-Co intermediate alloy, Mg-Nd intermediate alloy, Mg-Ta intermediate alloy, pure Dy, Al-Sb intermediate alloy, Al-W intermediate alloy, pure Rh, Al-Bi intermediate alloy, Al-Ho intermediate alloy;
(2) melting: carry out molten alloy in resistance furnace under conditions of SF6 gas and sodium chloride coverture are protected; all raw materials in step (1) are added in resistance furnace; temperature controls at 1150 DEG C; mechanical agitation 5 minutes after all raw materials are completely melt; after standing 30 minutes; carry out dragging for slag, obtain magnesium alloy smelting liquid;
(3) refine: carrying out refine by passing through the magnesium alloy smelting liquid RJ-5 refining agent dragging for slag gained in step (2), refining temperature is 1250 DEG C, and refining time is 15 minutes, obtains magnesium alloy refining liquid;
(4) molding: the magnesium alloy refining liquid of gained in step (3) is cast into Ф 0.5cm, the magnesium alloy bar of long 100cm;Mould therefor preheating temperature is 450 DEG C, and cast temperature is 1150 DEG C;
(5) solution treatment: the magnesium alloy bar of gained in step (4) is carried out in 950 DEG C solution treatment, and the time is 42 hours;
(6) quenching: magnesium alloy bar through solution treatment in step (5) is carried out shrend, puts into the magnesium alloy bar after quenching in the resistance furnace of 300 DEG C and carries out artificial aging 60 hours, prepare magnesium alloy blank;
(7) magnesium alloy bar/wire rod processed: the magnesium alloy blank of gained in step (6) is heated to 650 DEG C, after being incubated 3 hours, the method using multi-pass small deformation amount, magnesium alloy blank is made the magnesium alloy bar/wire rod of a diameter of 0.3 centimetre;
(8) copper strips hacking: the copper strips accounting for all raw material weight percentage ratio 30% is carried out surface grinding process by hard steel wire brush;
(9) copper-coated magnesium alloy wire rod blank processed: with copper strips through surface grinding process in step (8), the magnesium alloy bar/wire rod of gained in step (7) is wrapped in centre, make copper-coated magnesium alloy wire rod blank with the pressure of 2MPa;
(10) copper-coated magnesium alloy wire rod processed: under argon shield, copper-coated magnesium alloy wire rod blank is carried out argon arc welding; by brazing together; after forming copper-coated magnesium alloy wire rod; the method of multi-pass small deformation amount is used to be drawn into the copper-coated magnesium alloy wire rod of 0.3cm with drawbench; at a temperature of 270 DEG C, carry out Ageing Treatment 42 hours again, after cooling, i.e. obtain copper-coated magnesium alloy wire rod.
Embodiment 3 :
A kind of creep resistance Dow metal, contains according to weight percent content: Al:12%, Eu:1.5%, Re:0.6%, Ca:1.6%, Th:1.5%, Nd:2.3%, Co:1.3%, Ta:1.0%, Dy:0.15%, W:0.4%, Rh:0.9%, Sb:2.3%, Bi:2.3%, Ho:0.5%, surplus is the copper strips of Mg and 40%, and its preparation method comprises the following steps:
(1) raw material prepares: carrying out raw material preparation according to weight percent content, described raw material is pure Mg ingot, Mg-Eu intermediate alloy, pure Al ingot, pure Re, Al-Th intermediate alloy, Al-Ca intermediate alloy, Al-Co intermediate alloy, Mg-Nd intermediate alloy, Mg-Ta intermediate alloy, pure Dy, Al-Sb intermediate alloy, Al-W intermediate alloy, pure Rh, Al-Bi intermediate alloy, Al-Ho intermediate alloy;
(2) melting: carry out molten alloy in resistance furnace under conditions of SF6 gas and sodium chloride coverture are protected; all raw materials in step (1) are added in resistance furnace; temperature controls at 1200 DEG C; mechanical agitation 5 minutes after all raw materials are completely melt; after standing 30 minutes; carry out dragging for slag, obtain magnesium alloy smelting liquid;
(3) refine: carrying out refine by passing through the magnesium alloy smelting liquid RJ-5 refining agent dragging for slag gained in step (2), refining temperature is 1300 DEG C, and refining time is 15 minutes, obtains magnesium alloy refining liquid;
(4) molding: the magnesium alloy refining liquid of gained in step (3) is cast into Ф 0.5cm, the magnesium alloy bar of long 100cm;Mould therefor preheating temperature is 500 DEG C, and cast temperature is 1200 DEG C;
(5) solution treatment: the magnesium alloy bar of gained in step (4) is carried out in 1000 DEG C solution treatment, and the time is 42 hours:
(6) quenching: magnesium alloy bar through solution treatment in step (5) is carried out shrend, puts into the magnesium alloy bar after quenching in the resistance furnace of 300 DEG C and carries out artificial aging 60 hours, prepare magnesium alloy blank;
(7) magnesium alloy bar/wire rod processed: the magnesium alloy blank of gained in step (6) is heated to 700 DEG C, after being incubated 3 hours, the method using multi-pass small deformation amount, magnesium alloy blank is made the magnesium alloy bar/wire rod of a diameter of 0.3 centimetre;
(8) copper strips hacking: the copper strips accounting for all raw material weight percentage ratio 30% is carried out surface grinding process by hard steel wire brush;
(9) copper-coated magnesium alloy wire rod blank processed: with copper strips through surface grinding process in step (8), the magnesium alloy bar/wire rod of gained in step (7) is wrapped in centre, make copper-coated magnesium alloy wire rod blank with the pressure of 3MPa;
(10) copper-coated magnesium alloy wire rod processed: under argon shield, copper-coated magnesium alloy wire rod blank is carried out argon arc welding; by brazing together; after forming copper-coated magnesium alloy wire rod; the method of multi-pass small deformation amount is used to be drawn into the copper-coated magnesium alloy wire rod of 0.3cm with drawbench; at a temperature of 300 DEG C, carry out Ageing Treatment 42 hours again, after cooling, i.e. obtain copper-coated magnesium alloy wire rod.
Below the present invention is described in detail, the above, only the preferred embodiments of the invention, when not limiting the scope of the present invention, the most all made impartial change according to the application scope and modified, all should still be belonged in covering scope of the present invention.

Claims (3)

1. a copper-coated magnesium alloy wire rod, it is characterised in that contain according to weight percent content: Al:10-12%, Eu:0.5-1.5%, Re:0.2-0.6%, Ca:1.2-1.6%, Th:0.5-1.5%, Nd:2.1-2.3%, Co:0.7-1.3%, Ta:0.8-1.0%, Dy:0.05-0.15%, W:0.2-0.4%, Rh:0.7-0.9%, Sb:2.1-2.3%, Bi:2.1-2.3%, Ho:0.3-0.5%, surplus is the copper strips of Mg and 30-40%.
2. copper-coated magnesium alloy wire rod as claimed in claim 1, it is characterised in that: contain according to weight percent content: Al:10%, Eu:0.5%, Re:0.2%, Ca:1.2%, Th:0.5%, Nd:2.1%, Co:0.7%, Ta:0.8%, Dy:0.05%, W:0.2%, Rh:0.7%, Sb:2.1%, Bi:2.1%, Ho:0.3%, surplus is the copper strips of Mg and 30%.
3. the preparation method of a copper-coated magnesium alloy wire rod as claimed in claim 1, it is characterised in that:
(1) raw material prepares: carrying out raw material preparation according to weight percent content, described raw material is pure Mg ingot, Mg-Eu intermediate alloy, pure Al ingot, pure Re, Al-Th intermediate alloy, Al-Ca intermediate alloy, Al-Co intermediate alloy, Mg-Nd intermediate alloy, Mg-Ta intermediate alloy, pure Dy, Al-Sb intermediate alloy, Al-W intermediate alloy, pure Rh, Al-Bi intermediate alloy, Al-Ho intermediate alloy;
(2) melting: carry out molten alloy in resistance furnace under conditions of SF6 gas and sodium chloride coverture are protected; all raw materials in step (1) are added in resistance furnace; temperature controls at 1100 DEG C~1200 DEG C; mechanical agitation 5 minutes after all raw materials are completely melt; after standing 30 minutes; carry out dragging for slag, obtain magnesium alloy smelting liquid;
(3) refine: carrying out refine by passing through the magnesium alloy smelting liquid RJ-5 refining agent dragging for slag gained in step (2), refining temperature is 1200 DEG C~1300 DEG C, and refining time is 15 minutes, obtains magnesium alloy refining liquid;
(4) molding: the magnesium alloy refining liquid of gained in step (3) is cast into Ф 0.5cm, the magnesium alloy bar of long 100cm;Mould therefor preheating temperature is 400 DEG C~500 DEG C, and cast temperature is 1100 DEG C~1200 DEG C;
(5) solution treatment: in 900 DEG C~1000 DEG C, the magnesium alloy bar of gained in step (4) is carried out solution treatment, and the time is 42 hours:
(6) quenching: magnesium alloy bar through solution treatment in step (5) is carried out shrend, puts into the magnesium alloy bar after quenching in the resistance furnace of 300 DEG C and carries out artificial aging 60 hours, prepare magnesium alloy blank;
(7) magnesium alloy bar/wire rod processed: the magnesium alloy blank of gained in step (6) is heated to 600 DEG C~700 DEG C, after being incubated 3 hours, the method using multi-pass small deformation amount, magnesium alloy blank is made the magnesium alloy bar/wire rod of a diameter of 0.3 centimetre;
(8) copper strips hacking: the copper strips accounting for all raw material weight percentage ratio 30% is carried out surface grinding process by hard steel wire brush;
(9) copper-coated magnesium alloy wire rod blank processed: with copper strips through surface grinding process in step (8), the magnesium alloy bar/wire rod of gained in step (7) is wrapped in centre, make copper-coated magnesium alloy wire rod blank with the pressure of 1-3MPa;
(10) copper-coated magnesium alloy wire rod processed: under argon shield, copper-coated magnesium alloy wire rod blank is carried out argon arc welding; by brazing together; after forming copper-coated magnesium alloy wire rod; the method of multi-pass small deformation amount is used to be drawn into the copper-coated magnesium alloy wire rod of 0.3cm with drawbench; at a temperature of 250 DEG C~300 DEG C, carry out Ageing Treatment 42 hours again, after cooling, i.e. obtain copper-coated magnesium alloy wire rod.
CN201410598674.6A 2014-10-31 2014-10-31 A kind of copper-coated magnesium alloy wire rod and preparation method thereof Expired - Fee Related CN104282355B (en)

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CN105132775A (en) * 2015-09-10 2015-12-09 苏州莱特复合材料有限公司 Light composite magnesium-based alloy material and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3677745A (en) * 1969-02-24 1972-07-18 Cooper Range Co Copper base composition
CN101202130A (en) * 2007-12-06 2008-06-18 崔晓明 Aluminum-magnesium alloy conductor containing rare earth covering by cuprum as well as manufacturing method and usage thereof
CN102230202A (en) * 2011-06-21 2011-11-02 哈尔滨工业大学 Copper-plating method of MB2 magnesium alloy wires
CN102254634A (en) * 2011-07-04 2011-11-23 珠海光乐电力母线槽有限公司 Method for manufacturing metal composite material and material manufactured by same
CN102290115A (en) * 2011-07-04 2011-12-21 珠海光乐电力母线槽有限公司 Metal composite material and manufacturing method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3677745A (en) * 1969-02-24 1972-07-18 Cooper Range Co Copper base composition
CN101202130A (en) * 2007-12-06 2008-06-18 崔晓明 Aluminum-magnesium alloy conductor containing rare earth covering by cuprum as well as manufacturing method and usage thereof
CN102230202A (en) * 2011-06-21 2011-11-02 哈尔滨工业大学 Copper-plating method of MB2 magnesium alloy wires
CN102254634A (en) * 2011-07-04 2011-11-23 珠海光乐电力母线槽有限公司 Method for manufacturing metal composite material and material manufactured by same
CN102290115A (en) * 2011-07-04 2011-12-21 珠海光乐电力母线槽有限公司 Metal composite material and manufacturing method thereof

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