CN104178673B - A kind of magnesium alloy and preparation method thereof - Google Patents

A kind of magnesium alloy and preparation method thereof Download PDF

Info

Publication number
CN104178673B
CN104178673B CN201410463164.8A CN201410463164A CN104178673B CN 104178673 B CN104178673 B CN 104178673B CN 201410463164 A CN201410463164 A CN 201410463164A CN 104178673 B CN104178673 B CN 104178673B
Authority
CN
China
Prior art keywords
alloy
intermediate alloy
pure
annealing
ingot
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201410463164.8A
Other languages
Chinese (zh)
Other versions
CN104178673A (en
Inventor
胡贤晨
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Luoyang Shengya Magnesium Alloy Science And Technology Co ltd
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201410463164.8A priority Critical patent/CN104178673B/en
Publication of CN104178673A publication Critical patent/CN104178673A/en
Application granted granted Critical
Publication of CN104178673B publication Critical patent/CN104178673B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Manufacture And Refinement Of Metals (AREA)
  • Conductive Materials (AREA)

Abstract

The invention provides a kind of magnesium alloy, contain according to weight percent content: Al:5.2 6.2%, Cr:3.1 3.7%, Co:0.9 1.1%, Cu:2.1 2.4%, Mn:0.9 1.0%, Mo:1.05 1.1%, Ni:1.2 1.4%, W:0.5 0.7%, V:0.8 0.9%, Zn:0.11 0.14%, Si:1.1 1.3%, Ca:1.5 1.7%, Sr:1.7 1.9% surplus be Mg.The present invention also proposes the preparation method of this alloy.This alloy has excellent mechanical performances.

Description

A kind of magnesium alloy and preparation method thereof
Technical field
The invention belongs to field of magnesium alloy material, especially a kind of magnesium alloy and preparation method thereof.
Background technology
Magnesium alloy adds the alloy of other elements composition with magnesium for base.Being characterized in: density is little, specific strength is high, springform Amount is big, and shock absorbing is good, and the load-carrying ability that withstands shocks is bigger than aluminium alloy, and the corrosive nature of resistance to organic matter and alkali is good, major alloy unit Have aluminium, zinc, manganese, cerium, thorium and a small amount of zirconium or cadmium etc..Magnesium alloy also has excellent heat conductivility, electromagnetic shielding simultaneously Performance, damping capacity and machinability, and there is the series of advantages such as dimensionally stable, pollution-free, easy recovery, it is extensively application Structural material in fields such as military project national defence, Aero-Space, medical treatment.
Low yet with magnesium alloy absolute intensity, deformation at room temperature ability is poor, oxidizable burning, the defect such as perishable, limit Having made its extensive application as structural material, it is extensive that the application of current magnesium alloy can not show a candle to aluminium alloy.Therefore, magnesium alloy is improved Intensity makes it have good combination property, is the focus of novel magnesium alloy exploitation, and high-strength magnesium alloy is developed expansion simultaneously The application of magnesium alloy is significant.
Summary of the invention
The problem existed for prior art, the present invention provides the preparation method of a kind of magnesium alloy, this process cost Low and simple and easy to do, it is thus achieved that magnesium alloy there is higher intensity so that this type of magnesium alloy has more excellent than traditional commerce magnesium alloy Mechanical property more.
For reaching this purpose, the present invention by the following technical solutions:
A kind of magnesium alloy, contains according to weight percent content: Al:5.2-6.2%, Cr:3.1-3.7%, Co:0.9- 1.1%, Cu:2.1-2.4%, Mn:0.9-1.0%, Mo:1.05-1.1%, Ni:1.2-1.4%, W:0.5-0.7%, V:0.8-0.9%, Zn:0.11-0.14%, Si:1.1-1.3%, Ca:1.5-1.7%, Sr:1.7-1.9% surplus is Mg.
Further, contain according to weight percent content: Al:5.2%, Cr:3.1%, Co:0.9%, Cu:2.1%, Mn: 0.9%, Mo:1.05%, Ni:1.2%, W:0.5%, V:0.8%, Zn:0.11%, Si:1.1%, Ca:1.5%, Sr:1.7% surplus is Mg.
It addition, also provide for the preparation method of a kind of described magnesium alloy, comprise the following steps:
(1) raw material prepares: carrying out raw material preparation according to weight percent content, described raw material is in the middle of pure Mg ingot, Mg-Cr Alloy, pure Al ingot, pure Cu, Al-Co intermediate alloy, Al-Mn intermediate alloy, Al-Mo intermediate alloy, Mg-Ni intermediate alloy, Mg-W Intermediate alloy, pure Zn, Al-V intermediate alloy, Al-Si intermediate alloy, pure Ca, Al-Sr intermediate alloy;
(2) melting: by Mg-Cr intermediate alloy, pure Al ingot, pure Cu, Al-Co intermediate alloy, Al-Mn intermediate alloy, Al-Mo In the middle of intermediate alloy, Mg-Ni intermediate alloy, Mg-W intermediate alloy, pure Zn, Al-V intermediate alloy, Al-Si intermediate alloy, Al-Sr Alloy loads in resistance furnace, and by resistance furnace pumping high vacuum, in stove, vacuum is 1 × 10-1Pa, leak rate < 0.32Pa/min, and Being filled with argon gas, making vacuum is 0.23MPa, is then electrified to, and after above raw material is completely melt, adds pure Mg ingot and pure Ca, then Secondary it is heated to 785-795 DEG C, is stirred after all raw materials are completely melt, makes alloying component uniform;
(3) refining: make smelting furnace be warming up to 810~830 DEG C and refine alloy, adds RJ-5 refining while stirring Agent, refining time is 10-15 minute, stands 18-20 minute 650~670 DEG C of insulations after having refined;
(4) casting: be cast to the liquid magnesium alloy refined preheat in the swage tool that temperature is 810~830 DEG C, casting temperature Degree is 910~930 DEG C;Cast gauge is Ф 20mm~Ф 30mm, a length of 2300mm;
(5) cold working: after using kicker annealing, the mode of room temperature drawing is processed, and annealing temperature is 750 DEG C, annealing Time is 1h, must not be heat-treated in the middle of each drawing passes, passage accumulation cold deformation >=70%;
(6) annealing is heat-treated: semi-finished product carrying out annealing and is heat-treated, annealing temperature is 430~440 DEG C, is annealed into the time 1.5h。
Detailed description of the invention
Embodiment 1
A kind of magnesium alloy, contains according to weight percent content: Al:5.2%, Cr:3.1%, Co:0.9%, Cu:2.1%, Mn: 0.9%, Mo:1.05%, Ni:1.2%, W:0.5%, V:0.8%, Zn:0.11%, Si:1.1%, Ca:1.5%, Sr:1.7% surplus is Mg.
The preparation method of magnesium alloy, comprises the following steps:
(1) raw material prepares: carrying out raw material preparation according to weight percent content, described raw material is in the middle of pure Mg ingot, Mg-Cr Alloy, pure Al ingot, pure Cu, Al-Co intermediate alloy, Al-Mn intermediate alloy, Al-Mo intermediate alloy, Mg-Ni intermediate alloy, Mg-W Intermediate alloy, pure Zn, Al-V intermediate alloy, Al-Si intermediate alloy, pure Ca, Al-Sr intermediate alloy;
(2) melting: by Mg-Cr intermediate alloy, pure Al ingot, pure Cu, Al-Co intermediate alloy, Al-Mn intermediate alloy, Al-Mo In the middle of intermediate alloy, Mg-Ni intermediate alloy, Mg-W intermediate alloy, pure Zn, Al-V intermediate alloy, Al-Si intermediate alloy, Al-Sr Alloy loads in resistance furnace, and by resistance furnace pumping high vacuum, in stove, vacuum is 1 × 10-1Pa, leak rate < 0.32Pa/min, and Being filled with argon gas, making vacuum is 0.23MPa, is then electrified to, and after above raw material is completely melt, adds pure Mg ingot and pure Ca, then Secondary it is heated to 785 DEG C, is stirred after all raw materials are completely melt, makes alloying component uniform;
(3) refining: make smelting furnace be warming up to 810 DEG C and refine alloy, adds RJ-5 refining agent, refining while stirring Time is 10 minutes, stands 18 minutes 650 DEG C of insulations after having refined;
(4) casting: being cast to the liquid magnesium alloy refined preheat in the swage tool that temperature is 810 DEG C, cast temperature is 910℃;Cast gauge is Ф 20mm, a length of 2300mm;
(5) cold working: after using kicker annealing, the mode of room temperature drawing is processed, and annealing temperature is 750 DEG C, annealing Time is 1h, must not be heat-treated in the middle of each drawing passes, passage accumulation cold deformation >=70%;
(6) annealing is heat-treated: semi-finished product carrying out annealing and is heat-treated, annealing temperature is 430 DEG C, is annealed into time 1.5h.
Embodiment 2:
A kind of magnesium alloy, contains according to weight percent content: Al:5.7%, Cr:3.4%, Co:1.0%, Cu:2.3%, Mn: 0.95%, Mo:1.07%, Ni:1.3%, W:0.6%, V:0.85%, Zn:0.13%, Si:1.2%, Ca:1.6%, Sr:1.8% surplus is Mg。
The preparation method of described magnesium alloy, comprises the following steps:
(1) raw material prepares: carrying out raw material preparation according to weight percent content, described raw material is in the middle of pure Mg ingot, Mg-Cr Alloy, pure Al ingot, pure Cu, Al-Co intermediate alloy, Al-Mn intermediate alloy, Al-Mo intermediate alloy, Mg-Ni intermediate alloy, Mg-W Intermediate alloy, pure Zn, Al-V intermediate alloy, Al-Si intermediate alloy, pure Ca, Al-Sr intermediate alloy;
(2) melting: by Mg-Cr intermediate alloy, pure Al ingot, pure Cu, Al-Co intermediate alloy, Al-Mn intermediate alloy, Al-Mo In the middle of intermediate alloy, Mg-Ni intermediate alloy, Mg-W intermediate alloy, pure Zn, Al-V intermediate alloy, Al-Si intermediate alloy, Al-Sr Alloy loads in resistance furnace, and by resistance furnace pumping high vacuum, in stove, vacuum is 1 × 10-1Pa, leak rate < 0.32Pa/min, and Being filled with argon gas, making vacuum is 0.23MPa, is then electrified to, and after above raw material is completely melt, adds pure Mg ingot and pure Ca, then Secondary it is heated to 790 DEG C, is stirred after all raw materials are completely melt, makes alloying component uniform;
(3) refining: make smelting furnace be warming up to 820 DEG C and refine alloy, adds RJ-5 refining agent, refining while stirring Time is 13 minutes, stands 19 minutes 660 DEG C of insulations after having refined;
(4) casting: being cast to the liquid magnesium alloy refined preheat in the swage tool that temperature is 820 DEG C, cast temperature is 920℃;Cast gauge is Ф 25, a length of 2300mm;
(5) cold working: after using kicker annealing, the mode of room temperature drawing is processed, and annealing temperature is 750 DEG C, annealing Time is 1h, must not be heat-treated in the middle of each drawing passes, passage accumulation cold deformation >=70%;
(6) annealing is heat-treated: semi-finished product carrying out annealing and is heat-treated, annealing temperature is 435 DEG C, is annealed into time 1.5h.
Embodiment 3:
A kind of magnesium alloy, contains according to weight percent content: Al:6.2%, Cr:3.7%, Co:1.1%, Cu:2.4%, Mn: 1.0%, Mo:1.1%, Ni:1.4%, W:0.7%, V:0.9%, Zn:0.14%, Si:1.3%, Ca:1.7%, Sr:1.9% surplus is Mg.
The preparation method of described magnesium alloy, comprises the following steps:
(1) raw material prepares: carrying out raw material preparation according to weight percent content, described raw material is in the middle of pure Mg ingot, Mg-Cr Alloy, pure Al ingot, pure Cu, Al-Co intermediate alloy, Al-Mn intermediate alloy, Al-Mo intermediate alloy, Mg-Ni intermediate alloy, Mg-W Intermediate alloy, pure Zn, Al-V intermediate alloy, Al-Si intermediate alloy, pure Ca, Al-Sr intermediate alloy;
(2) melting: by Mg-Cr intermediate alloy, pure Al ingot, pure Cu, Al-Co intermediate alloy, Al-Mn intermediate alloy, Al-Mo In the middle of intermediate alloy, Mg-Ni intermediate alloy, Mg-W intermediate alloy, pure Zn, Al-V intermediate alloy, Al-Si intermediate alloy, Al-Sr Alloy loads in resistance furnace, and by resistance furnace pumping high vacuum, in stove, vacuum is 1 × 10-1Pa, leak rate < 0.32Pa/min, and Being filled with argon gas, making vacuum is 0.23MPa, is then electrified to, and after above raw material is completely melt, adds pure Mg ingot and pure Ca, then Secondary it is heated to 795 DEG C, is stirred after all raw materials are completely melt, makes alloying component uniform;
(3) refining: make smelting furnace be warming up to 830 DEG C and refine alloy, adds RJ-5 refining agent, refining while stirring Time is 15 minutes, stands 20 minutes 670 DEG C of insulations after having refined;
(4) casting: being cast to the liquid magnesium alloy refined preheat in the swage tool that temperature is 830 DEG C, cast temperature is 930℃;Cast gauge is Ф 30mm, a length of 2300mm;
(5) cold working: after using kicker annealing, the mode of room temperature drawing is processed, and annealing temperature is 750 DEG C, annealing Time is 1h, must not be heat-treated in the middle of each drawing passes, passage accumulation cold deformation >=70%;
(6) annealing is heat-treated: semi-finished product carrying out annealing and is heat-treated, annealing temperature is 440 DEG C, is annealed into time 1.5h.
The performance of the alloy that embodiment 1-3 obtains is listed in the table below

Claims (3)

1. a magnesium alloy, it is characterised in that contain according to weight percent content: Al:5.2-6.2%, Cr:3.1-3.7%, Co:0.9-1.1%, Cu:2.1-2.4%, Mn:0.9-1.0%, Mo:1.05-1.1%, Ni:1.2-1.4%, W:0.5-0.7%, V: 0.8-0.9%, Zn:0.11-0.14%, Si:1.1-1.3%, Ca:1.5-1.7%, Sr:1.7-1.9%, surplus is Mg.
2. magnesium alloy as claimed in claim 1, it is characterised in that contain according to weight percent content: Al:5.2%, Cr: 3.1%, Co:0.9%, Cu:2.1%, Mn:0.9%, Mo:1.05%, Ni:1.2%, W:0.5%, V:0.8%, Zn:0.11%, Si:1.1%, Ca:1.5%, Sr:1.7%, surplus is Mg.
3. the preparation method of magnesium alloy as claimed in claim 1 or 2, it is characterised in that:
(1) raw material prepares: carry out raw material preparation according to weight percent content, and described raw material is to close in the middle of pure Mg ingot, Mg-Cr In Al ingot golden, pure, pure Cu, Al-Co intermediate alloy, Al-Mn intermediate alloy, Al-Mo intermediate alloy, Mg-Ni intermediate alloy, Mg-W Between alloy, pure Zn, Al-V intermediate alloy, Al-Si intermediate alloy, pure Ca, Al-Sr intermediate alloy;
(2) melting: in the middle of Mg-Cr intermediate alloy, pure Al ingot, pure Cu, Al-Co intermediate alloy, Al-Mn intermediate alloy, Al-Mo Alloy, Mg-Ni intermediate alloy, Mg-W intermediate alloy, pure Zn, Al-V intermediate alloy, Al-Si intermediate alloy, Al-Sr intermediate alloy Loading in resistance furnace, by resistance furnace pumping high vacuum, in stove, vacuum is 1 × 10-1Pa, leak rate < 0.32Pa/min, and be filled with Argon gas, making vacuum is 0.23MPa, is then electrified to, and after above raw material is completely melt, adds pure Mg ingot and pure Ca, again adds Heat, to 785-795 DEG C, is stirred after all raw materials are completely melt, makes alloying component uniform;
(3) refining: make smelting furnace be warming up to 810~830 DEG C and refine alloy, adds RJ-5 refining agent, essence while stirring The refining time is 10-15 minute, stands 18-20 minute 650~670 DEG C of insulations after having refined;
(4) casting: being cast to the liquid magnesium alloy refined preheat in the swage tool that temperature is 810~830 DEG C, cast temperature is 910~930 DEG C;Cast gauge is Ф 20mm~Ф 30mm, a length of 2300mm;
(5) cold working: after using kicker annealing, the mode of room temperature drawing is processed, and annealing temperature is 750 DEG C, annealing time For 1h, must not be heat-treated in the middle of each drawing passes, passage accumulation cold deformation >=70%;
(6) annealing is heat-treated: semi-finished product carrying out annealing and is heat-treated, annealing temperature is 430~440 DEG C, is annealed into time 1.5h.
CN201410463164.8A 2014-09-12 2014-09-12 A kind of magnesium alloy and preparation method thereof Expired - Fee Related CN104178673B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410463164.8A CN104178673B (en) 2014-09-12 2014-09-12 A kind of magnesium alloy and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410463164.8A CN104178673B (en) 2014-09-12 2014-09-12 A kind of magnesium alloy and preparation method thereof

Publications (2)

Publication Number Publication Date
CN104178673A CN104178673A (en) 2014-12-03
CN104178673B true CN104178673B (en) 2016-08-24

Family

ID=51960012

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410463164.8A Expired - Fee Related CN104178673B (en) 2014-09-12 2014-09-12 A kind of magnesium alloy and preparation method thereof

Country Status (1)

Country Link
CN (1) CN104178673B (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104831136B (en) * 2015-04-15 2016-10-26 苏州维泰生物技术有限公司 A kind of medical magnesium base alloy material and preparation method thereof
CN108203782B (en) * 2016-12-19 2020-08-28 有研工程技术研究院有限公司 Magnesium alloy with electromagnetic shielding function and preparation method thereof
CN108220727B (en) * 2016-12-21 2021-01-15 湖南工程学院 Heat-resistant magnesium alloy and preparation method thereof
CN106811643A (en) * 2017-01-22 2017-06-09 安徽臣诺机器人科技有限公司 A kind of handling machinery arm machine pawl and preparation method thereof
CN108374102A (en) * 2017-03-17 2018-08-07 黄河科技学院 Component and preparation method thereof for making closed-cell foam composite material of magnesium alloy
CN106929723B (en) * 2017-04-10 2018-11-02 广西科技大学 A kind of high damping properties magnesium base alloy mechanical material and preparation method thereof
PL235559B1 (en) * 2017-10-31 2020-09-07 Politechnika Lodzka Method for production of magnesium alloys with the alloy additions that have melting temperature above 650 C and density above 1.737 g/cm3
CN110193525B (en) * 2019-06-06 2020-08-18 哈尔滨理工大学 Method for rapidly preparing magnesium alloy fine-grain wire and superfine magnesium alloy wire based on drawing process
CN112899540A (en) * 2021-01-14 2021-06-04 江苏大学 Soluble magnesium alloy for oil exploitation and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB596102A (en) * 1945-07-19 1947-12-29 Rupert Martin Bradbury A new magnesium base alloy
JP3622989B2 (en) * 1993-03-30 2005-02-23 三井金属鉱業株式会社 Molded member made of magnesium alloy and manufacturing method thereof
JP2007070685A (en) * 2005-09-06 2007-03-22 Daido Steel Co Ltd Highly workable magnesium alloy, and method for producing the same
JP5894079B2 (en) * 2009-12-07 2016-03-23 ユー アンド アイ コーポレーション Magnesium alloy

Also Published As

Publication number Publication date
CN104178673A (en) 2014-12-03

Similar Documents

Publication Publication Date Title
CN104178673B (en) A kind of magnesium alloy and preparation method thereof
CN103276264B (en) Low-cost and high-heat-strength wrought magnesium alloy and preparation method thereof
CN100430502C (en) High-strength magnesium-lithium alloy
CN101643867B (en) High performance copper casting alloy and preparation method thereof
CN104032196B (en) high-strength magnesium alloy material and preparation method thereof
CN103421999A (en) Rare earth-contained heat-resistant magnesium alloy and preparation method thereof
CN103146973B (en) High-temperature-resistant rare earth magnesium alloy
CN104046869B (en) A kind of preparation method of magnesium Li-Si alloy
CN101857934B (en) Heat-resistant magnesium alloy and preparation method thereof
CN104195396A (en) Heat-resistant rare-earth magnesium alloy containing silicon, zinc and Gd(-Y) and preparation method thereof
WO2020224627A1 (en) Alloy material and production process therefor
CN103290286A (en) As-cast high-strength-and-toughness ma.gnesium-lithium alloy and preparation method thereof
CN109797328B (en) Medium-high strength damage-resistant aluminum-lithium alloy material and preparation method and application thereof
CN103484712A (en) Bismuth brass alloy drawn pipe containing trace rare earth and manufacture method thereof
CN104178672B (en) A kind of high-strength magnesium alloy and preparation method thereof
CN104099505B (en) A kind of wrought magnesium alloy and preparation method thereof
CN103882268B (en) A kind of triangle vavle aluminum alloy materials and preparation method thereof
CN108220724A (en) A kind of magnesium alloy new material and its preparation process
CN104099507A (en) High-strength and high-toughness rare earth magnesium alloy
CN109022984B (en) Zn-containing corrosion-resistant rare earth magnesium alloy and preparation method thereof
CN104109790B (en) high-strength magnesium alloy material and preparation method thereof
CN103911534A (en) Rare earth magnesium alloy and preparation method thereof
CN102925776A (en) High-strength and high-toughness magnesium alloy
CN110983130A (en) Er-containing high-strength corrosion-resistant Al-Zn-Mg aluminum alloy and preparation method thereof
CN104313436B (en) A kind of wear-resistant magnesium alloy workpiece of high rigidity

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C41 Transfer of patent application or patent right or utility model
CB03 Change of inventor or designer information

Inventor after: Hu Xianchen

Inventor before: Yang Pan

COR Change of bibliographic data
TA01 Transfer of patent application right

Effective date of registration: 20160706

Address after: 321000 Wucheng City, Jinhua Province, Tang Town, the village of the second warehouse No. 88 Village

Applicant after: Hu Xianchen

Address before: Double gang Whampoa District of Guangzhou City, Guangdong province 510700 Industrial Zone Fuxing double sand road No. 8

Applicant before: Yang Pan

C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20180503

Address after: 471900 Yuet Tan Village, Yuetan Town, Yanshi City, Luoyang, Henan

Patentee after: LUOYANG SHENGYA MAGNESIUM ALLOY SCIENCE AND TECHNOLOGY CO.,LTD.

Address before: 321000 No. 88, Cang Er Cun, Tang Xi Town, Wucheng District, Jinhua, Zhejiang

Patentee before: Hu Xianchen

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160824

Termination date: 20210912