CN104278539A - Environment-friendly type PVC (polyvinyl chloride) synthetic leather and production method thereof - Google Patents

Environment-friendly type PVC (polyvinyl chloride) synthetic leather and production method thereof Download PDF

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Publication number
CN104278539A
CN104278539A CN201410453129.8A CN201410453129A CN104278539A CN 104278539 A CN104278539 A CN 104278539A CN 201410453129 A CN201410453129 A CN 201410453129A CN 104278539 A CN104278539 A CN 104278539A
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parts
pvc
synthetic leather
powder
layer
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Inventor
臧德如
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ANHUI HUI'AN ARTIFICAL LEATHER Co Ltd
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ANHUI HUI'AN ARTIFICAL LEATHER Co Ltd
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Priority to CN201410453129.8A priority Critical patent/CN104278539A/en
Publication of CN104278539A publication Critical patent/CN104278539A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/183—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0065—Organic pigments, e.g. dyes, brighteners
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077—Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/121—Permeability to gases, adsorption
    • D06N2209/123—Breathable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/28—Artificial leather

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

The invention discloses environment-friendly type PVC (polyvinyl chloride) synthetic leather. The environment-friendly type PVC synthetic leather is prepared from the following raw materials in parts by weight: 30-60 parts of polyvinyl chloride resin SG-5 (PVCSG-5), 15-30 parts of polyvinyl chloride resin SG-8 (PVCSG-8), 10-15 parts of egg shell powder, 3-6 parts of rice bran, 2-5 parts of rice husk, 2-4 parts of wollastonite powder, 0.2-0.5 part of aluminum oxide, 40-70 parts of trioctyl citrate, 15-30 parts of trimethyl citrate, 1-2 parts of isopropanolamine, 0.5-1 parts of lactose, 0.2-0.5 part of calcium chloride, 0.5-1.5 parts of dioctyl sodium sulfosuccinate, 1-2 parts of turkey red oil, 0.5-1 part of polyamide epichlorohydrin, 5-10 parts of pigment and 5-10 parts of modifying additives. The PVC synthetic leather uses agricultural wastes as filling materials, is environmentally-friendly, can improve the air permeability and toughness and is suitable for practical production use, and energy can be saved.

Description

A kind of environmental protection type PVC synthetic leather and production method thereof
Technical field
The present invention relates to polymeric material field, be specifically related to a kind of environmental protection type PVC synthetic leather and production method thereof.
Background technology
At present, synthetic leather is mainly divided into polyvinyl chloride (PVC) synthetic leather and polyurethane (PU) synthetic leather two kinds.PU synthetic leather feel and presentation quality good, but on the high side, service life is not long, and at present more ripe PU synthetic leather technique needs a large amount of DMF that uses as solvent, and environmental effect is bad; PVC synthetic leather price is low, and physical property can reach quality requirement, and shortcoming is that feel and presentation quality are slightly poor, and poor air permeability, limit it and use widely.Appropriate application industry, agricultural residue and with this improve formula and technique, be both conducive to the performance improving synthetic leather, the object of energy-conserving and environment-protective can have been reached again simultaneously.
Summary of the invention
The object of this invention is to provide a kind of environmental protection type PVC synthetic leather.
The present invention is achieved by the following technical solutions:
A kind of environmental protection type PVC synthetic leather, comprises base cloth layer and layer of PVC, wherein:
Layer of PVC is obtained by the raw material of following weight parts:
PVC SG-5 30-60, PVC SG-8 15-30, egg shell powder 10-15, rice bran 3-6, rice husk 2-5, wollastonite in powder 2-4, aluminium oxide 0.2-0.5, trioctyl lemon acid 40-70, trimethyl citrate 15-30, isopropanolamine 1-2, lactose 0.5-1, calcium chloride 0.2-0.5, dioctyl sodium sulfosuccinate 0.5-1.5, turkey red oil 1-2, polyamideepichlorohydrin 0.5-1, colorant 5-10, modified additive 5-10;
Wherein modified additive is made up of the raw material of following weight portion:
Wood pulp fibre 10-15, talcum powder 5-10, corncob cellulose 10-15, cornstarch 1-5, sodium carboxymethylcellulose 3-6, calgon 1-3, nano titanium oxide 0.2-1, Tissuemat E 0.5-1, sweet mellow wine 1-2, oleic acid 0.1-0.3, dodecyl dimethyl benzyl ammonium bromide 1-2;
The preparation method of modified additive is:
Appropriate 5-10% acetum is added after being mixed with talcum powder, dodecyl dimethyl benzyl ammonium bromide by wood pulp fibre, 600-800r/min filters and drying after stirring 1-2h, add nano titanium oxide, 800-1000 DEG C of calcining 1-2h, reprocessing 2-4h after being cooled to 200-400 DEG C, corncob cellulose and cornstarch is added after cooling, all the other raw materials are added after 100-150 DEG C of process 2-3h, after mixing, preliminary grinding evenly, 60-80 DEG C, 200-400r/min stirs 2-4h, be ground to 500-1000 order after cooling, obtain final product;
A production method for environmental protection type PVC synthetic leather, comprises the following steps:
(1) by rice bran and rice husk, the rear 100-150 DEG C of process 30-60min of egg shell powder mixing, appropriate 2-6% acetum is added after cooling, add lactose, calcium chloride and isopropanolamine simultaneously, 200-400r/min adds wollastonite in powder and aluminium oxide after stirring 15-30min, dry after grinding 10-20min, continue to be ground to 500-1000 order, obtain active powder;
(2) active powder is mixed with all the other raw materials, first with 200-400r/min stirring at low speed 15-30min, then with 1000-1500r/min high-speed stirred 45-90min, 100-200 order filters, and adds banbury, 140-160 DEG C of plasticizing, open refining for 140-170 DEG C again, obtain layer of PVC slurry;
(3) using aqueous polyurethane as binding agent, by layer of PVC slurry and base cloth by four-roll calender calender lamination at 160-180 DEG C, speed is 40-60 m/min, and cooling rolling, product is through surface effect process, and quality test results is qualified, can dispatch from the factory.
Advantage of the present invention is:
1. the present invention uses agricultural residue rice bran, rice husk and egg shell powder as stuffing, and both energy-conserving and environment-protective are conducive to again the permeability improving synthetic leather;
2., for trioctyl lemon acid and the trimethyl citrate safety and environmental protection of plasticizer, decrease the potential threat to environment and human body, and function admirable;
3., by improving recipe optimization, enhancing toughness and the pliability of synthetic leather, thus improving feel and the quality of synthetic leather.
Detailed description of the invention
Non-limiting examples of the present invention is as follows:
Embodiment 1
A kind of environmental protection type PVC synthetic leather, comprises base cloth layer and layer of PVC, wherein:
Layer of PVC is made up of the raw material of following weight (kg):
PVC SG-5 45, PVC SG-8 20, egg shell powder 12, rice bran 4, rice husk 4, wollastonite in powder 3, aluminium oxide 0.3, trioctyl lemon acid 50, trimethyl citrate 20, isopropanolamine 1.5, lactose 0.7, calcium chloride 0.4, dioctyl sodium sulfosuccinate 1, turkey red oil 1.5, polyamideepichlorohydrin 0.6, colorant 8, modified additive 8;
Wherein modified additive is made up of the raw material of following weight (kg):
Wood pulp fibre 12, talcum powder 8, corncob cellulose 12, cornstarch 4, sodium carboxymethylcellulose 5, calgon 2, nano titanium oxide 0.5, Tissuemat E 0.8, sweet mellow wine 1.5, oleic acid 0.2, dodecyl dimethyl benzyl ammonium bromide 1.5;
The preparation method of modified additive is:
Appropriate 5% acetum is added after being mixed with talcum powder, dodecyl dimethyl benzyl ammonium bromide by wood pulp fibre, 600r/min filters and drying after stirring 2h, add nano titanium oxide, 1000 DEG C of calcinings 1h, reprocessing 2h after being cooled to 400 DEG C, corncob cellulose and cornstarch is added after cooling, add all the other raw materials after 100 DEG C of process 2h, after mixing, preliminary grinding evenly, 60 DEG C, 400r/min stirs 2h, be ground to 800 orders after cooling, obtain final product;
Its production method comprises the following steps:
(1) by rice bran and rice husk, the rear 125 DEG C of process 30min of egg shell powder mixing, appropriate 4% acetum is added after cooling, add lactose, calcium chloride and isopropanolamine simultaneously, 400r/min adds wollastonite in powder and aluminium oxide after stirring 15min, dry after grinding 15min, continue to be ground to 500 orders, obtain active powder;
(2) active powder mixed with all the other raw materials, first with 400r/min stirring at low speed 30min, then with 1500r/min high-speed stirred 45min, 100 orders filter, and add banbury, 140 DEG C of plasticizings, then 160 DEG C are opened refining, obtain layer of PVC slurry;
(3) using aqueous polyurethane as binding agent, by layer of PVC slurry and base cloth by four-roll calender calender lamination at 160 DEG C, speed is 50 ms/min, and cooling rolling, product is through surface effect process, and quality test results is qualified, can dispatch from the factory.
Through properties of product test, this product warp direction stretching load 269.8N, broadwise tensile load 211.2N, warp-wise elongation at break 10.3%, broadwise elongation at break 15.6%, warp-wise tears load 17.3N, broadwise tears load 19.2N, and degradation does not ftracture, and meets the requirement of industry standard.

Claims (2)

1. an environmental protection type PVC synthetic leather, comprises base cloth layer and layer of PVC, it is characterized in that:
Described layer of PVC is obtained by the raw material of following weight parts:
PVC SG-5 30-60, PVC SG-8 15-30, egg shell powder 10-15, rice bran 3-6, rice husk 2-5, wollastonite in powder 2-4, aluminium oxide 0.2-0.5, trioctyl lemon acid 40-70, trimethyl citrate 15-30, isopropanolamine 1-2, lactose 0.5-1, calcium chloride 0.2-0.5, dioctyl sodium sulfosuccinate 0.5-1.5, turkey red oil 1-2, polyamideepichlorohydrin 0.5-1, colorant 5-10, modified additive 5-10;
Described modified additive is made up of the raw material of following weight portion:
Wood pulp fibre 10-15, talcum powder 5-10, corncob cellulose 10-15, cornstarch 1-5, sodium carboxymethylcellulose 3-6, calgon 1-3, nano titanium oxide 0.2-1, Tissuemat E 0.5-1, sweet mellow wine 1-2, oleic acid 0.1-0.3, dodecyl dimethyl benzyl ammonium bromide 1-2;
The preparation method of described modified additive is:
Appropriate 5-10% acetum is added after being mixed with talcum powder, dodecyl dimethyl benzyl ammonium bromide by wood pulp fibre, 600-800r/min filters and drying after stirring 1-2h, add nano titanium oxide, 800-1000 DEG C of calcining 1-2h, reprocessing 2-4h after being cooled to 200-400 DEG C, corncob cellulose and cornstarch is added after cooling, all the other raw materials are added after 100-150 DEG C of process 2-3h, after mixing, preliminary grinding evenly, 60-80 DEG C, 200-400r/min stirs 2-4h, be ground to 500-1000 order after cooling, obtain final product.
2. the preparation method of a kind of environmental protection type PVC synthetic leather according to claim 1, is characterized in that, comprise the following steps:
(1) by rice bran and rice husk, the rear 100-150 DEG C of process 30-60min of egg shell powder mixing, appropriate 2-6% acetum is added after cooling, add lactose, calcium chloride and isopropanolamine simultaneously, 200-400r/min adds wollastonite in powder and aluminium oxide after stirring 15-30min, dry after grinding 10-20min, continue to be ground to 500-1000 order, obtain active powder;
(2) active powder is mixed with all the other raw materials, first with 200-400r/min stirring at low speed 15-30min, then with 1000-1500r/min high-speed stirred 45-90min, 100-200 order filters, and adds banbury, 140-160 DEG C of plasticizing, open refining for 140-170 DEG C again, obtain layer of PVC slurry;
(3) using aqueous polyurethane as binding agent, by layer of PVC slurry and base cloth by four-roll calender calender lamination at 160-180 DEG C, speed is 40-60 m/min, and cooling rolling, product is through surface effect process, and quality test results is qualified, can dispatch from the factory.
CN201410453129.8A 2014-09-04 2014-09-04 Environment-friendly type PVC (polyvinyl chloride) synthetic leather and production method thereof Pending CN104278539A (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105133366A (en) * 2015-07-17 2015-12-09 浙江锦尚合成革有限公司 Environment-protective synthetic leather and preparation method thereof
CN105155293A (en) * 2015-07-17 2015-12-16 浙江锦尚合成革有限公司 Anti-microbial synthetic leather and preparation method thereof
CN105176053A (en) * 2015-07-17 2015-12-23 浙江锦尚合成革有限公司 Synthetic leather slurry and preparation method thereof
CN105291527A (en) * 2015-10-27 2016-02-03 芜湖市鸿坤汽车零部件有限公司 Mould-proof PVC synthetic leather and production method thereof
CN105297466A (en) * 2015-10-27 2016-02-03 芜湖市鸿坤汽车零部件有限公司 PVC synthetic leather containing green tea extracts and production method thereof
CN105295224A (en) * 2015-10-27 2016-02-03 芜湖市鸿坤汽车零部件有限公司 PVC synthetic leather containing honeysuckle extracts and production method thereof
CN105297469A (en) * 2015-10-27 2016-02-03 芜湖市鸿坤汽车零部件有限公司 PVC synthetic leather containing folium artemisiae argyi extracts and production method thereof
CN105401458A (en) * 2015-10-27 2016-03-16 芜湖市鸿坤汽车零部件有限公司 Deodorized PVC synthetic leather and production method thereof
CN105401456A (en) * 2015-10-27 2016-03-16 芜湖市鸿坤汽车零部件有限公司 Licorice root powder-containing PVC synthetic leather and production method thereof
CN105401457A (en) * 2015-10-27 2016-03-16 芜湖市鸿坤汽车零部件有限公司 Mothproof PVC synthetic leather and production method thereof
CN105507048A (en) * 2016-01-05 2016-04-20 嘉善贝马五金配件有限公司 Herb cellulose composition and preparation method and application thereof
CN106349608A (en) * 2016-10-11 2017-01-25 佛山市飞时达新材料科技有限公司 Environment-friendly polyvinyl chloride cable material and manufacturing method thereof
CN108708185A (en) * 2018-04-23 2018-10-26 佛山市高明尚昂科技有限公司 A kind of biodegradable synthetic leather and preparation method thereof
EP3797989A1 (en) * 2019-09-26 2021-03-31 TMG - Tecidos Plastificados e Outros Revestimentos para a Indústria Automóvel, S.A. A thermal stabilizer material, method of obtaining and uses thereof

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JPH05311581A (en) * 1992-04-30 1993-11-22 Kanto Leather Cloth Co Ltd Production of sheetlike material
KR100873655B1 (en) * 2007-07-27 2008-12-12 (주)아이앤에스 Flame retarded pvc foam artificial leather and manufacturing method thereof
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CN101831098A (en) * 2010-04-20 2010-09-15 安徽中诚塑业科技有限公司 Degradable agricultural film
CN102505513A (en) * 2011-11-05 2012-06-20 合肥市安山涂层织物有限公司 Gas-permeable moisture-absorption type environmentally-friendly polyvinyl chloride synthetic leather and manufacturing method thereof
CN102995451A (en) * 2012-10-23 2013-03-27 合肥市安山涂层织物有限公司 Twist-resisting polyvinyl chloride synthetic leather and manufacturing method thereof
CN102995452A (en) * 2012-10-23 2013-03-27 合肥市安山涂层织物有限公司 Polyvinyl chloride synthetic leather for gloves and manufacturing method thereof

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Publication number Priority date Publication date Assignee Title
JPH05311581A (en) * 1992-04-30 1993-11-22 Kanto Leather Cloth Co Ltd Production of sheetlike material
KR100873655B1 (en) * 2007-07-27 2008-12-12 (주)아이앤에스 Flame retarded pvc foam artificial leather and manufacturing method thereof
CN101349013A (en) * 2008-08-29 2009-01-21 黄成源 Method for making ecological type artificial leather or similar leather object and automatic assembly line thereof
CN101831098A (en) * 2010-04-20 2010-09-15 安徽中诚塑业科技有限公司 Degradable agricultural film
CN102505513A (en) * 2011-11-05 2012-06-20 合肥市安山涂层织物有限公司 Gas-permeable moisture-absorption type environmentally-friendly polyvinyl chloride synthetic leather and manufacturing method thereof
CN102995451A (en) * 2012-10-23 2013-03-27 合肥市安山涂层织物有限公司 Twist-resisting polyvinyl chloride synthetic leather and manufacturing method thereof
CN102995452A (en) * 2012-10-23 2013-03-27 合肥市安山涂层织物有限公司 Polyvinyl chloride synthetic leather for gloves and manufacturing method thereof

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105133366A (en) * 2015-07-17 2015-12-09 浙江锦尚合成革有限公司 Environment-protective synthetic leather and preparation method thereof
CN105155293A (en) * 2015-07-17 2015-12-16 浙江锦尚合成革有限公司 Anti-microbial synthetic leather and preparation method thereof
CN105176053A (en) * 2015-07-17 2015-12-23 浙江锦尚合成革有限公司 Synthetic leather slurry and preparation method thereof
CN105176053B (en) * 2015-07-17 2018-06-19 浙江锦尚合成革有限公司 A kind of synthetic leather slurry and preparation method thereof
CN105297466A (en) * 2015-10-27 2016-02-03 芜湖市鸿坤汽车零部件有限公司 PVC synthetic leather containing green tea extracts and production method thereof
CN105297469A (en) * 2015-10-27 2016-02-03 芜湖市鸿坤汽车零部件有限公司 PVC synthetic leather containing folium artemisiae argyi extracts and production method thereof
CN105401458A (en) * 2015-10-27 2016-03-16 芜湖市鸿坤汽车零部件有限公司 Deodorized PVC synthetic leather and production method thereof
CN105401456A (en) * 2015-10-27 2016-03-16 芜湖市鸿坤汽车零部件有限公司 Licorice root powder-containing PVC synthetic leather and production method thereof
CN105401457A (en) * 2015-10-27 2016-03-16 芜湖市鸿坤汽车零部件有限公司 Mothproof PVC synthetic leather and production method thereof
CN105295224A (en) * 2015-10-27 2016-02-03 芜湖市鸿坤汽车零部件有限公司 PVC synthetic leather containing honeysuckle extracts and production method thereof
CN105291527A (en) * 2015-10-27 2016-02-03 芜湖市鸿坤汽车零部件有限公司 Mould-proof PVC synthetic leather and production method thereof
CN105507048B (en) * 2016-01-05 2018-08-07 嘉善贝马五金配件有限公司 A kind of herbaceous plant cellulose composition, preparation method and applications
CN105507048A (en) * 2016-01-05 2016-04-20 嘉善贝马五金配件有限公司 Herb cellulose composition and preparation method and application thereof
CN106349608A (en) * 2016-10-11 2017-01-25 佛山市飞时达新材料科技有限公司 Environment-friendly polyvinyl chloride cable material and manufacturing method thereof
CN108708185A (en) * 2018-04-23 2018-10-26 佛山市高明尚昂科技有限公司 A kind of biodegradable synthetic leather and preparation method thereof
EP3797989A1 (en) * 2019-09-26 2021-03-31 TMG - Tecidos Plastificados e Outros Revestimentos para a Indústria Automóvel, S.A. A thermal stabilizer material, method of obtaining and uses thereof
WO2021059252A1 (en) * 2019-09-26 2021-04-01 Tmg Tecidos Plastificados E Outros Revestimentos Para A Industria Automovel Sa A thermal stabilizer material, method of obtaining and uses thereof
CN114269560A (en) * 2019-09-26 2022-04-01 汽车工业用Tmg塑化织物及其他涂料公司 Heat stabilizer material, method for obtaining same and use thereof

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