CN102146181A - Master batch special for nano anion synthetic paper - Google Patents
Master batch special for nano anion synthetic paper Download PDFInfo
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- CN102146181A CN102146181A CN201010118664XA CN201010118664A CN102146181A CN 102146181 A CN102146181 A CN 102146181A CN 201010118664X A CN201010118664X A CN 201010118664XA CN 201010118664 A CN201010118664 A CN 201010118664A CN 102146181 A CN102146181 A CN 102146181A
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- synthetic paper
- negative ion
- anion
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Abstract
The invention relates to a method for preparing a master batch special for nano anion synthetic paper. The invention is characterized in that: the master batch is prepared by blending the following components: 30 to 60 parts of filler, 30 to 60 parts of polymer resin, 0.5 to 15 parts of Anion nano anion additive and 1 to 10 parts of other aids; and compared with the traditional master batch special for the synthetic paper, the master batch special for nano anion synthetic paper, which is prepared by the method, has the advantages of obviously improving printing performance, surface finishment, additional function and the like, has the functions of releasing anions, constantly resisting and killing bacteria, emitting far infrared and the like, and is beneficial to human health. The material can be widely applied to producing the synthetic paper by a rolling process, a solution cast method, a film blowing method and a bidirectional stretching method.
Description
Technical field
The present invention relates to a kind of preparation method of nano-negative ion dedicated parent material for synthetic paper.Belong to plastics, macromolecular material, matrix material, papermaking, printing, culture field.The nano-negative ion dedicated parent material for synthetic paper of this method preparation improves to some extent at aspects such as printing performance, surface smoothness and additional functions than traditional dedicated parent material for synthetic paper.Traditional synthetic paper masterbatch can't use common printed printing ink in printing process, must use ink special.The nano-negative ion dedicated parent material for synthetic paper of the present invention's preparation, printing performance obviously improves, surface smoothness improves, be suitable for synthetic paper complete processings such as curtain coating, blown film, calendering, two-way stretch, and has the release negative ion, continue antibiotic and sterilizing, functions such as emission far infrared are of value to HUMAN HEALTH.
Background technology
The synthetic paper past attempts is called as chemical industry film paper, plastic paper, polymer paper etc.It is that to replace vegetable fibre with macromolecular compound be main raw material, handles through " paper shape position ", and that makes is similar to common plant fiber paper in appearance, on performance than its more superior a kind of new type of paper.Synthetic paper is a kind of plastics type material product, also is a kind of environmentfriendly products, by various The application of new technique, makes it have the characteristic of plastics and paper simultaneously.The production process of synthetic paper is pollution-free, can 100% recycle and reuse, and be a major reform of modern paper production.
How traditional synthetic paper masterbatch is main raw material with PP, can't use common printed printing ink in printing process, must use ink special, and higher to the manufacturing technique requirent of producing synthetic paper, and function singleness, the scope of application are single relatively.These deficiencies have restricted the synthetic paper industrial expansion.Therefore, improve the dedicated parent material for synthetic paper prescription, improve printing performance, enlarge the scope of application, compound additional function (discharge negative ion, continue antibiotic and sterilizing, emission far infrared etc.) is an emphasis of future research.
Summary of the invention
The present invention relates to a kind of preparation method of nano-negative ion dedicated parent material for synthetic paper.The nano-negative ion dedicated parent material for synthetic paper of this method preparation improves to some extent at aspects such as printing performance, additional functions than traditional dedicated parent material for synthetic paper.How traditional synthetic paper masterbatch is main raw material with PP, can't use common printed printing ink in printing process, must use ink special.The nano-negative ion dedicated parent material for synthetic paper of the present invention's preparation, printing performance obviously improves, and is suitable for synthetic paper complete processings such as curtain coating, blown film, calendering, two-way stretch, and has the release negative ion, continue antibiotic and sterilizing, functions such as emission far infrared are of value to HUMAN HEALTH.
There is the character that absorbs printing-ink on the surface of natural paper, and offset printing or letterpress ink have to a certain degree infiltration, solidify at paper surface at once after printing, then are polymerizing curables.Synthetic paper is only required that it has the suitable property of individual offset printing and letterpress, and this has the character of similar natural paper with regard to the surface of wishing it.Be that the more main of so-called paper processing target is exactly to make it have the surface that this printing ink can permeate.The present invention addresses the above problem and realizes that the method for above-mentioned purpose is to add to have nanometer level microporous Anion
The nano-negative ion additive absorbs the ability of printing-ink with the raising paper surface, thereby improves printing performance.Anion
The nano-negative ion additive is ultra-fine differential, can not influence the smooth finish of paper surface, can not influence the range of application of this masterbatch.Simultaneously, Anion
The adding of nano-negative ion additive makes this masterbatch have the release negative ion, continues antibiotic and sterilizing, functions such as emission far infrared.
The preparation method of nano-negative ion dedicated parent material for synthetic paper follows these steps to carry out successively:
(1) to filler and Anion
Nano-negative ion additive coupling agent modified: filler and Anion
Nano-negative ion additive warp, adding total content is the silane resin acceptor kh-550 (interpolation thinner) of 2wt%, through high-speed stirring combination treatment 10min, vacuum drying is stand-by.
(2) get weighting agent 30-60 part after the modification, fluoropolymer resin 30-60 part, the Anion after the modification
Nano-negative ion additive 0.5-15 part, other auxiliary agents 1-10 part, 90-150 ℃ is mixing, mixing abundant back granulation, granulation gets the nano-negative ion dedicated parent material for synthetic paper through mixing, dispersion, coupling, plasticizing, cooling.
Advantage of the present invention is to have tangible raising than traditional dedicated parent material for synthetic paper at aspects such as printing performance, surface smoothness and additional functions with the nano-negative ion dedicated parent material for synthetic paper of this method preparation with positively effect, and has the release negative ion, continue antibiotic and sterilizing, functions such as emission far infrared are of value to HUMAN HEALTH.This material can be widely used in rolling process, casting method, blown film method, two-way stretch method production synthetic paper.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail:
Embodiment 1
(1) to filler (CaCO
3) and Anion
Nano-negative ion additive coupling agent modified: to CaCO
3And Anion
In the nano-negative ion additive, adding total content is the silane resin acceptor kh-550 (interpolation thinner) of 2wt%, and through high-speed stirring combination treatment 10min, vacuum drying is stand-by.
(2) get CaCO after the modification
340 parts, HDPE40 part, LDPE10 part, the Anion after the modification
4 parts of nano-negative ion additives, 5 parts of other auxiliary agents (antistatic agent, anti UV agent etc.), 100 ℃ are mixing, mixing abundant back granulation, granulation gets antiultraviolet PE nano-negative ion dedicated parent material for synthetic paper through mixing, dispersion, coupling, plasticizing, cooling.
Embodiment 2:
(1) to filler (CaCO
3And TiO
2) and Anion
Nano-negative ion additive coupling agent modified: to CaCO
3, TiO
2And Anion
In the nano-negative ion additive, adding total content is the silane resin acceptor kh-550 (interpolation thinner) of 2wt%, and through high-speed stirring combination treatment 10min, vacuum drying is stand-by.
(2) get CaCO after the modification
340 parts, TiO
210 parts, HDPE40 part, LDPE10 part, the Anion after the modification
4 parts of nano-negative ion additives, 5 parts of other auxiliary agents (antistatic agent, anti UV agent etc.), 100 ℃ are mixing, mixing abundant back granulation, granulation gets antiultraviolet PE nano-negative ion dedicated parent material for synthetic paper through mixing, dispersion, coupling, plasticizing, cooling.
Embodiment 3:
According to the processing method step of the foregoing description 1, adjust Anion
The amount of nano-negative ion additive is 6 parts, must discharge the higher PE nano-negative ion dedicated parent material for synthetic paper of negative ion amount.
Embodiment 4:
According to the processing method step of the foregoing description 1, with HDPE, LDPE replaces with PP, gets PP nano-negative ion dedicated parent material for synthetic paper.
Claims (8)
1. the preparation method of nano-negative ion dedicated parent material for synthetic paper is characterized in that being made up of following prescription: weighting agent 30-60 part, fluoropolymer resin 30-60 part, Anion
Nano-negative ion additive 0.5-15 part, other auxiliary agents 1-10 part, 90 ℃-150 ℃ are mixing; The nano-negative ion dedicated parent material for synthetic paper of this method preparation improves to some extent at aspects such as printing performance, surface smoothness and additional functions than traditional dedicated parent material for synthetic paper, and has the release negative ion, continues antibiotic and sterilizing, functions such as emission far infrared.
2. nano-negative ion dedicated parent material for synthetic paper according to claim 1 is the weighting agent 30-60 part of getting after coupling agent modified, fluoropolymer resin 30-60 part, the Anion after coupling agent modified
Nano-negative ion additive 0.5-15 part, other auxiliary agents 1-10 part, 90 ℃-150 ℃ are mixing, the granulation of mixing abundant back, granulation be through mixing, dispersion, coupling, plasticizing, cooling, obtain the nano-negative ion dedicated parent material for synthetic paper.
3. weighting agent according to claim 1 is CaCO
3, SiO
2, Al
2O
3, mica, TiO
2In a kind of, two or more mixture.
4. fluoropolymer resin according to claim 1 is a kind of, two or more the polymkeric substance among PP, HDPE, LDPE, PS, PVC, PET, the ABS.
5. nano-negative ion additive according to claim 1 is natural crystal six ring stone, tourmalinite with nanoporous, opal is a kind of or two, three kind broken through nano ultrafine powders, after the stage treatment, particle dia is at the powder of 200-10000nm.
6. the preparation method of nano-negative ion dedicated parent material for synthetic paper according to claim 1 follows these steps to carry out successively:
(1) to filler and Anion
Nano-negative ion additive coupling agent modified: filler and Anion
Nano-negative ion additive warp, adding total content is the silane resin acceptor kh-550 (interpolation thinner) of 2wt%, through high-speed stirring combination treatment 10min, vacuum drying is stand-by.
(2) get weighting agent 30-60 part after the modification, fluoropolymer resin 30-60 part, the Anion after the modification
Nano-negative ion additive 0.5-15 part, other auxiliary agents 1-10 part, 90-150 ℃ is mixing, mixing abundant back granulation, granulation gets the nano-negative ion dedicated parent material for synthetic paper through mixing, dispersion, coupling, plasticizing, cooling.
7. printing performance according to claim 1 is mainly reflected in following three aspects: white and opaque outward appearance; Satisfy the suitable property of operation of printing press; And good mutual relationship etc. arranged between the printing-ink.The present invention mainly improves the mutual relationship between synthetic paper and the printing-ink, thereby improves the printing performance of synthetic paper.The suitable property variation of the outward appearance of synthetic paper and printer operations is little.
8. release negative ion according to claim 1 continues antibiotic and sterilizing, launches far function, and the anion number that it is characterized in that discharging is at 1000/cm
3More than, far emittance is of value to HUMAN HEALTH more than 0.8.This material can be widely used in rolling process, casting method, blown film method, two-way stretch method production synthetic paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010118664XA CN102146181A (en) | 2010-02-07 | 2010-02-07 | Master batch special for nano anion synthetic paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010118664XA CN102146181A (en) | 2010-02-07 | 2010-02-07 | Master batch special for nano anion synthetic paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102146181A true CN102146181A (en) | 2011-08-10 |
Family
ID=44420666
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010118664XA Pending CN102146181A (en) | 2010-02-07 | 2010-02-07 | Master batch special for nano anion synthetic paper |
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| Country | Link |
|---|---|
| CN (1) | CN102146181A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104130501A (en) * | 2014-07-21 | 2014-11-05 | 安庆盛华纸质包装有限公司 | Synthetic paper production technology |
| CN106479055A (en) * | 2016-11-03 | 2017-03-08 | 佛山慧创正元新材料科技有限公司 | A kind of PP cable jacket material of high impact resistant and thermal resistant and its manufacture method |
| CN106674607A (en) * | 2016-12-05 | 2017-05-17 | 安徽索亚装饰材料有限公司 | Padding for improving overall characteristics of wood plastic foaming material |
| CN106939096A (en) * | 2017-05-03 | 2017-07-11 | 马志明 | A kind of nanometer PE Masterbatch |
-
2010
- 2010-02-07 CN CN201010118664XA patent/CN102146181A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104130501A (en) * | 2014-07-21 | 2014-11-05 | 安庆盛华纸质包装有限公司 | Synthetic paper production technology |
| CN106479055A (en) * | 2016-11-03 | 2017-03-08 | 佛山慧创正元新材料科技有限公司 | A kind of PP cable jacket material of high impact resistant and thermal resistant and its manufacture method |
| CN106674607A (en) * | 2016-12-05 | 2017-05-17 | 安徽索亚装饰材料有限公司 | Padding for improving overall characteristics of wood plastic foaming material |
| CN106674607B (en) * | 2016-12-05 | 2019-04-23 | 安徽索亚装饰材料有限公司 | A kind of filler improving Wood-plastic foam material overall characteristic |
| CN106939096A (en) * | 2017-05-03 | 2017-07-11 | 马志明 | A kind of nanometer PE Masterbatch |
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| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20110810 |