CN104277885A - Carbide slag polymerization fuel and derivative fuel thereof - Google Patents
Carbide slag polymerization fuel and derivative fuel thereof Download PDFInfo
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- CN104277885A CN104277885A CN201410574561.2A CN201410574561A CN104277885A CN 104277885 A CN104277885 A CN 104277885A CN 201410574561 A CN201410574561 A CN 201410574561A CN 104277885 A CN104277885 A CN 104277885A
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- fuel
- carbide slag
- dimerization
- polymerization
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Abstract
The invention discloses a carbide slag polymerization fuel and a derivative fuel thereof, which relate to the field of novel fuels. The carbide slag polymerization fuel comprises the following raw materials in percentage by weight: 25-60% of carbide slags, 15-30% of salty mud, 10-40% of fly ash, 5-30% of iron tailings, 1-10% of sodium sulfate, and 0.1-8% of an exciting agent. According to the invention, by mainly using industrial waste residues such as carbide slags, salty mud, fly ash, iron tailings, sodium sulfate and the like which are large in storage quantity and pollute the environment, adding an exciting agent, and drying and crushing the obtained mixture, the polymerization fuel is formed; ad when in use, the polymerization fuel is ignited by using a magnesium rod, and then various materials are subjected to a chemical reaction so as to produce a calorific value of more than 10000 kcal/kg, so that when the fuel is applied to production and life, an effect of changing waste material into things of value is achieved, non-renewable energies are saved, and the pollution caused by industrial solid wastes to the environment is improved, therefore, an effect of energy conservation and environmental protection is achieved, and an effect of low carbon and emission reduction is also achieved, so the fuel contributes to the implementation of national policies of national recycling economy and sustainable development.
Description
Technical field
The present invention relates to New-type fuel field, specifically a kind of carbide slag dimerization fuel and derivatived fuel thereof.
Background technology
The energy is the foundation stone that human society exists.Do not have the energy, the mankind cannot survive; Do not have the energy, the mankind just do not have light and power; Let alone progressive and development.Increasing scholars believe, fossil energy is current main energy sources; And fossil energy belongs to Nonrenewable resources, tellurian reserves are limited; A large amount of exploitations, makes it to face exhaustion.To about the year two thousand fifty, the petroleum resources of main oil producing country of the world will become exhausted; The fuel of oil engine mainly will rely on alcohols, vegetable and animals oils and other fuel at that time; The reserves of coal at most can for exploitation 200 years.
Current world today coal, oil price lattice constantly rise violently, one is due to developing Asian countries and flourishing west economy body rush of demand, two be the earth has not had too many new coal, oil field can for find, therefore coal, oil price lattice can not drop, unless world economy falls into recession, cheap coal, oil epoch will terminate at this point; Because coal, oil price lattice are significantly high, fuel cost and transportation cost account for the prime cost of relevant enterprise, and if things go on like this, monetary inflation will be inevitable in a lot of country, thus affect global expanding economy.
China is one of a few energy country based on coal in the world, is also consumption of coal state maximum in the world.Compare with countries in the world, the Energy resources of China are more nervous; China is populous nation and is about to become world-class economic giant, but be not corresponding Energy resources big country, imbalance between supply and demand is very large, the shortage of fuel is now just very serious, for this reason, from now on just should active research, exploitation and local use alternative fuel.The enforcement in China's on January 1st, 2006 " new forms of energy method "; the enforcement of China's on January 1st, 2015 new " Law on Environmental Protection "; providing a lot of preferential policy to exploitation, producing and selling energy-conserving and environment-protective new forms of energy product, is the best opportunity of research, exploitation, production and sales energy-conserving and environment-protective new forms of energy product.
In existing fuel, consist predominantly of fossil oil, biomass fuel, and fossil oil has non-renewable, the production cost of biomass fuel is high; To employing chemical method special soild oxide is burnt, be feasible in principle, as the high temperature lava existed all the time in the earth earth's core, be many kinds of substance at react with, generate energy.Dimerization fuel be exactly a kind of by special soild oxide together, make intermolecular generation solid state reaction release the fuel of heat energy under the high temperature conditions.
Modern industrial production, produces a large amount of Industrial Solid Wastes, and these solid wastes cause severe contamination to environment.And the expense of innoxious, maximum these solid wastes of minimizing process cost is higher.
Summary of the invention
For solving the technical problem of above-mentioned existence, the invention provides a kind of carbide slag dimerization fuel and derivatived fuel thereof, multiple Industrial Solid Waste being mixed by a certain percentage of the weight, at high temperature reacts, produce heat, form the New-type fuel of high heating value.
The technical solution adopted in the present invention is: a kind of carbide slag dimerization fuel, includes following raw material by weight ratio: carbide slag 25-60%, salt slurry 15-30%, flyash 10-40%, iron tailings 5-30%, saltcake 1-10% and exciting agent 0.1-8%.
Described exciting agent adopts oxymuriate.
A derivatived fuel for carbide slag dimerization fuel, includes the carbide slag dimerization fuel of weight ratio 5-70% and the fossil oil of 30-95%.
A derivatived fuel for carbide slag dimerization fuel, includes the carbide slag dimerization fuel of weight ratio 10-70% and the biomass fuel of 30-90%.
A derivatived fuel for carbide slag dimerization fuel, includes the carbide slag dimerization fuel of weight ratio 10-70%, the fossil oil of 10-80% and the biomass fuel of 10-50%.
The present invention mainly utilizes the carbide slag of the large contaminate environment again of store content, rock mud, flyash, iron tailings, the industrial residues such as saltcake, add exciting agent, dry after pulverizing and form dimerization fuel, ignited by magnesium rod during use, various material carry out chemical reaction produce 10000 kilocalories/kilogram more than calorific value, for the production of and life, not only turn waste into wealth but also save the non-renewable energy, improve the pollution of Industrial Solid Waste to environment simultaneously, in formula, each solid matter has confession oxygen effect when burning, particularly with fossil oil, the derivatived fuel of biomass fuel formation used in combination, ratio of combustion is more abundant, overload capacity uses coal than separately, biomass fuel is strong, temperature of combustion is adjustable, gentle blowdown must be arranged far below analog value when using coal simultaneously, not only energy-conserving and environment-protective, and achieve low-carbon (LC), reduce discharging, for the state basic policy of national recycling economy and Sustainable development realizes contributing.
Embodiment
Describe the present invention below in conjunction with specific embodiment:
A kind of carbide slag dimerization fuel provided by the invention, includes following raw material by weight ratio: carbide slag 25-60%, rock mud 15-30%, flyash 10-20%, iron tailings 5-10%, saltcake 1-5% and exciting agent 0.1-8%.
As preferred mode, described exciting agent adopts aluminate.
In the present invention, dried by the industrial residue such as carbide slag, salt slurry, flyash, iron tailings and saltcake, pulverize that to reach 200 orders be main raw material, exciting agent is auxiliary material.Wherein, carbide slag refers to the waste residue that calcium carbide hydrolysis produces when producing acetylene gas; Salt slurry and saltcake (10 aqueous sodium persulfate) refer to the waste residue produced when producing caustic soda with salt; Flyash is the waste residue that thermal power plant's coal combustion produces when generating electricity; Iron tailings is the waste residue produced after selecting iron with iron ore.
Embodiment 1: by its weight ratio, mixes carbide slag 25%, salt slurry 30%, flyash 10%, iron tailings 10%, saltcake 1% and makes carbide slag dimerization fuel together with exciting agent 8%; Mixture is placed in heavy wall steel container; Putting in the bottom of heavy wall steel container the magnesium rod lighted makes it burn, in combustion processes, its reaction times is 3-5 minute, and temperature of reaction is 2200-3200 DEG C, heat release 10000 kilocalorie during reaction/kilogram more than, also have white smoke and the slag of carbonic acid gas, do not need oxygen in reaction process.
In embodiment 1, exciting agent adopts Potcrate.
Embodiment 2: by its weight ratio, by carbide slag 50%, salt slurry 20%, flyash 15%, iron tailings 8%, saltcake 4% and exciting agent 4%, prepares according to the method for embodiment 1 and applies dimerization fuel.
In embodiment 2, exciting agent adopts sodium chlorate.
Embodiment 3: by its weight ratio, by carbide slag 55%, salt slurry 15%, flyash 10%, iron tailings
15%, saltcake 2% and exciting agent 3%, prepare according to the method for embodiment 1 and apply dimerization fuel.
In embodiment 3, exciting agent adopts magnesium chlorate.
Also the present invention and other fuel mix can be used, improve the rejected heat energy efficiency of other fuel.
Present invention also offers a kind of derivatived fuel of carbide slag dimerization fuel, include the carbide slag dimerization fuel of weight ratio 5-70% and the fossil oil of 20-95%.
Embodiment 4: by weight the carbide slag dimerization fuel of 5% and the fossil oil of 95% are mixed and made into derivatived fuel.
Embodiment 5: by weight the carbide slag dimerization fuel of 10% and the fossil oil of 90% are mixed and made into derivatived fuel.
Embodiment 6: by weight the carbide slag dimerization fuel of 20% and the fossil oil of 80% are mixed and made into derivatived fuel.
Embodiment 7: by weight the carbide slag dimerization fuel of 70% and the fossil oil of 30% are mixed and made into derivatived fuel.
In embodiment 4-7, fossil oil adopts coal, and under equal conditions, the combustion efficacy of coal is better, and release heat energy improves the efficiency of 20-30%.And the out of stock 20-40% of desulfurization.The ash discharge quantity of slag reduces 10-20%.
Present invention also offers a kind of derivatived fuel of carbide slag dimerization fuel, include the carbide slag dimerization fuel of weight ratio 10-70% and the biomass fuel of 30-90%.
Embodiment 8: by weight the carbide slag dimerization fuel of 10% and the biomass fuel of 90% are mixed and made into derivatived fuel.
Embodiment 9: by weight the carbide slag dimerization fuel of 20% and the biomass fuel of 80% are mixed and made into derivatived fuel.
Embodiment 10: by weight the carbide slag dimerization fuel of 30% and the biomass fuel of 70% are mixed and made into derivatived fuel.
Embodiment 11: by weight the carbide slag dimerization fuel of 70% and the biomass fuel of 30% are mixed and made into derivatived fuel.
In embodiment 8-11, biomass fuel adopts stalk, wood chip or the biomass garbage pulverized, and under equal conditions, the combustion efficacy of biomass is better, and release heat energy improves the efficiency of 20-30%.
Present invention also offers a kind of derivatived fuel of carbide slag dimerization fuel, include the carbide slag dimerization fuel of weight ratio 10-70%, the fossil oil of 10-80% and the biomass fuel of 10-50%.
Embodiment 12: be mixed and made into derivatived fuel by weight by the carbide slag dimerization fuel of 10% and the fossil oil of 80% and the biomass fuel of 10%.
Embodiment 13: be mixed and made into derivatived fuel by weight by the carbide slag dimerization fuel of 20% and the fossil oil of 30% and the biomass fuel of 50%.
Embodiment 14: be mixed and made into derivatived fuel by weight by the carbide slag dimerization fuel of 70% and the fossil oil of 15% and the biomass fuel of 15%.
In embodiment 12-14, biomass fuel adopts stalk, wood chip or the biomass garbage pulverized, and fossil oil adopts coal, and under equal conditions, the combustion efficacy of coal, biomass is better, and release heat energy improves the efficiency of 20-30%.And the out of stock 20-40% of desulfurization.Ash discharge quantity of slag decline 10-20%.
The present invention is main raw material owing to employing the industrial residues such as carbide slag, salt slurry, flyash, iron tailings, saltcake, exciting agent is auxiliary material, solid waste is become high performance fuel by it, turns waste into wealth, and meets the demand for development of current national energy-saving and environmental protection, low-carbon (LC) and recycling economy; Particularly be mixed and made into powdery or granular derivatived fuel with fossil oil, biomass fuel, make ratio of combustion more abundant, overload capacity than using separately coal, biomass fuel is strong, simultaneously must blowdown far below analog value when using coal, be a kind of green fuel of energy-conserving and environment-protective; The industrial residue storages such as China's carbide slag, salt slurry, flyash, iron tailings, saltcake are large, not only took up an area but also contaminate environment, maximum innoxious, the maximum minimizing process solid waste of the present invention's energy, the price comparison becoming high performance fuel by solid waste is low, therefore the carbide slag dimerization fuel energy is developed, not only ensure that national energy security, and be the basic place setting up recycling economy, long-run development.
Certainly, above-mentioned explanation is not limitation of the present invention, and the present invention is also not limited in above-mentioned citing, and the change that those skilled in the art make in essential scope of the present invention, remodeling, interpolation or replacement also should belong to protection scope of the present invention.
Claims (5)
1. a carbide slag dimerization fuel, is characterized in that, includes following raw material by weight ratio: carbide slag 25-60%, salt slurry 15-30%, flyash 10-40%, iron tailings 5-30%, saltcake 1-10% and exciting agent 0.1-8%.
2. carbide slag dimerization fuel according to claim 1, is characterized in that, described exciting agent adopts oxymuriate.
3. a derivatived fuel for carbide slag dimerization fuel as claimed in claim 1, is characterized in that, includes the carbide slag dimerization fuel of weight ratio 5-70% and the fossil oil of 30-95%.
4. a derivatived fuel for carbide slag dimerization fuel as claimed in claim 1, is characterized in that, includes the carbide slag dimerization fuel of weight ratio 10-70% and the biomass fuel of 30-90%.
5. a derivatived fuel for carbide slag dimerization fuel as claimed in claim 1, is characterized in that, includes the carbide slag dimerization fuel of weight ratio 10-70%, the fossil oil of 10-80% and the biomass fuel of 10-50%.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410574561.2A CN104277885A (en) | 2014-10-24 | 2014-10-24 | Carbide slag polymerization fuel and derivative fuel thereof |
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| CN201410574561.2A CN104277885A (en) | 2014-10-24 | 2014-10-24 | Carbide slag polymerization fuel and derivative fuel thereof |
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| CN201410574561.2A Pending CN104277885A (en) | 2014-10-24 | 2014-10-24 | Carbide slag polymerization fuel and derivative fuel thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105062610A (en) * | 2015-08-05 | 2015-11-18 | 亿利资源集团有限公司 | Industrial solid waste constant energy environmental-protection fuel |
| CN105087100A (en) * | 2015-08-05 | 2015-11-25 | 亿利资源集团有限公司 | Industrial solid waste and solid energy environment-friendly fuel |
| CN106350147A (en) * | 2016-10-24 | 2017-01-25 | 马鞍山科宇环境工程有限公司 | High-efficiency coal-saving combustion-supporting denitration agent and preparation method thereof |
| CN110331018A (en) * | 2019-07-03 | 2019-10-15 | 王培元 | A kind of novel inorganic fuel |
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| CN101333472A (en) * | 2008-08-07 | 2008-12-31 | 陈越培 | Fuel made form red mud, ardealite, calcium carbonate and silicon dioxide |
| CN101407737A (en) * | 2008-11-20 | 2009-04-15 | 陈越培 | Non-coal mine fuel non-coal gangue fuel industrial waste slag fuel |
| CN102517116A (en) * | 2011-11-22 | 2012-06-27 | 冯恩福 | Dimerization fuel |
| CN103409197A (en) * | 2013-08-16 | 2013-11-27 | 聚合绿能科技发展（北京）有限公司 | Polymerization addition material capable of partially substituting coal as well as preparation method and application thereof |
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2014
- 2014-10-24 CN CN201410574561.2A patent/CN104277885A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101333472A (en) * | 2008-08-07 | 2008-12-31 | 陈越培 | Fuel made form red mud, ardealite, calcium carbonate and silicon dioxide |
| CN101407737A (en) * | 2008-11-20 | 2009-04-15 | 陈越培 | Non-coal mine fuel non-coal gangue fuel industrial waste slag fuel |
| CN102517116A (en) * | 2011-11-22 | 2012-06-27 | 冯恩福 | Dimerization fuel |
| CN103409197A (en) * | 2013-08-16 | 2013-11-27 | 聚合绿能科技发展（北京）有限公司 | Polymerization addition material capable of partially substituting coal as well as preparation method and application thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105062610A (en) * | 2015-08-05 | 2015-11-18 | 亿利资源集团有限公司 | Industrial solid waste constant energy environmental-protection fuel |
| CN105087100A (en) * | 2015-08-05 | 2015-11-25 | 亿利资源集团有限公司 | Industrial solid waste and solid energy environment-friendly fuel |
| CN106350147A (en) * | 2016-10-24 | 2017-01-25 | 马鞍山科宇环境工程有限公司 | High-efficiency coal-saving combustion-supporting denitration agent and preparation method thereof |
| CN110331018A (en) * | 2019-07-03 | 2019-10-15 | 王培元 | A kind of novel inorganic fuel |
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Application publication date: 20150114 |