CN104277623A - Rosin paint - Google Patents
Rosin paint Download PDFInfo
- Publication number
- CN104277623A CN104277623A CN201410456039.4A CN201410456039A CN104277623A CN 104277623 A CN104277623 A CN 104277623A CN 201410456039 A CN201410456039 A CN 201410456039A CN 104277623 A CN104277623 A CN 104277623A
- Authority
- CN
- China
- Prior art keywords
- parts
- minute
- add
- deionized water
- emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a rosin paint which is prepared from the following raw materials in parts by weight: 0.6-1 part of maleic rosin, 0.2-0.5 part of potassium wolframate, 2-3 parts of glyceryl carboxylate, 1-2 parts of trimethyl hydroxyethyl ethylenediamine, 10-13 parts of fluorapatite, 0.7-1 part of N-hydroxymethyl acrylamide, 2-3 parts of maleic anhydride grafted polypropylene, 1.4-3 parts of dodeca alcohol ester, 0.8-1 part of potassium perfluorobutylsulfonate, 100-150 parts of ethyl acrylate, 140-200 parts of vinyl acetate, 0.7-2 parts of ammonium persulfate, 500-700 parts of deionized water, 2-3 parts of lauryl sodium sulfate and 4-6 parts of binding assistant. The maleic rosin added to the paint effectively enhances the adhesive force of the coating, improves the binding effect with the substrate, promotes the compatibility among the materials and enables the coated film to have high uniformity and smoothness, and can effectively lower the production cost.
Description
Technical field
The present invention relates generally to paint field, particularly relates to a kind of rosin coating.
Background technology
Be applied to body surface can be formed there is protection, the class I liquid I of solid-state film of decoration or property (as insulation, anticorrosion, mark etc.) or the general name of solid material, comprise oil (property) paint, water-miscible paint, powder coating.Paint is flowable liquid coating, comprises oil (property) paint and water-miscible paint.Paint take organic solvent as medium or high solid, solvent-free oil-base paint.Water-miscible paint is used water dissolving or the coating with water-dispersion.Coating is as one of the main material of house decoration, and the large percentage accounted in decorations, buys the whether qualified environment directly having influence on overall finishing effect and room of coating, sometimes even can produce harm greatly to the health of human body.At present along with the generation of various coating, the quality requirements of coating is also improved constantly, and improve constantly coating quality and can play very large help for building, life.
Summary of the invention
The object of the invention is just to provide a kind of rosin coating.
The present invention is achieved by the following technical solutions:
A kind of rosin coating, is characterized in that what it was made up of the raw material of following weight parts:
Maleated rosin 0.6-1, potassium wolframate 0.2-0.5, short and long-chain acyl triglyceride molecules 2-3, trimethyl hydroxyethylammonium quadrol 1-2, fluorapatite 10-13, N hydroxymethyl acrylamide 0.7-1, maleic anhydride inoculated polypropylene 2-3, Lauryl Alcohol ester 1.4-3, perfluorobutyl potassium 0.8-1, ethyl propenoate 100-150, vinyl acetate 140-200, ammonium persulphate 0.7-2, deionized water 500-700, sodium lauryl sulphate 2-3, adhesive aid 4-6;
Described adhesive aid is made up of each raw material of following weight parts:
Acrylate and vinyl acetate emulsion 30-37, narra micro mist 1-2, hydroxyethyl methylacrylate 2-3, ammonium persulphate 2-3, Starso 1-2, silica gel 1-2, AESA 0.8-1, deionized water 10-15;
By silica gel, ammonium persulphate mixing, add hydroxyethyl methylacrylate after stirring, at 60-70 DEG C, be uniformly mixed 3-5 minute, join in acrylate and vinyl acetate emulsion, stir;
Be mixed to join in deionized water by Starso and narra micro mist, raised temperature is 50-60 DEG C, adds AESA, stirs;
Mixed with each raw material of residue by each raw material after above-mentioned process, 300-400 rev/min of dispersed with stirring 10-20 minute, obtains described adhesive aid.
A preparation method for rosin coating, is characterized in that comprising the following steps:
(1) mixed by the 10-15% of ammonium persulphate with above-mentioned deionized water weight, stirring and dissolving, obtains initiator solution;
(2) get sodium lauryl sulphate, add the 50-60% of residue deionized water weight, stir, obtain pre-emulsion;
(3) the 40-50% mixing of the 30-40% of aforesaid propylene acetoacetic ester weight, vinyl acetate weight is got, add above-mentioned pre-emulsion, 30-35 minute is uniformly mixed at 60-65 DEG C, raised temperature is 70-75 DEG C, add above-mentioned initiator solution, treat that emulsion is blue phase, insulation 60-70 minute, obtains seed emulsion;
(4) by remaining ethyl propenoate, vinyl acetate mixing, add short and long-chain acyl triglyceride molecules, trimethyl hydroxyethylammonium quadrol, insulated and stirred 20-30 minute at 65-70 DEG C, obtains mix monomer;
(5) mixed with maleated rosin by perfluorobutyl potassium, add the 50-60% of residue deionized water weight, insulated and stirred 20-35 minute at 75-80 DEG C, is cooled to normal temperature, obtains liquid a;
(6) in above-mentioned seed emulsion, add dropping mix monomer, time for adding is 90-120 minute, after dropwising, adds liquid a, stirs, at 80-90 DEG C, be incubated 50-60 minute, cooling, filters discharging with 200-250 eye mesh screen;
(7) material above-mentioned steps (6) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described rosin coating.
Advantage of the present invention is:
Coating of the present invention add the sticking power that maleated rosin effectively improves coating, enhance and bond effect between base material, facilitate the consistency of each storeroom, such that film is even, planarization good, and can production cost be effectively reduced.The ammonium persulphate added in adhesive aid of the present invention has heat insulating effect, and acrylate and vinyl acetate emulsion and narra micro mist, hydroxyethyl methylacrylate, Starso, silica gel is mixed and modified effectively can improve cohesive strength, strengthens coatingsurface resistance and stability.
Embodiment
Embodiment 1
A kind of rosin coating, is characterized in that what it was made up of the raw material of following weight parts:
Maleated rosin 0.6, potassium wolframate 0.2, short and long-chain acyl triglyceride molecules 3, trimethyl hydroxyethylammonium quadrol 1, fluorapatite 13, N hydroxymethyl acrylamide 0.7, maleic anhydride inoculated polypropylene 2, Lauryl Alcohol ester 1.4, perfluorobutyl potassium 0.8, ethyl propenoate 150, vinyl acetate 200, ammonium persulphate 0.7, deionized water 700, sodium lauryl sulphate 2, adhesive aid 6;
Described adhesive aid is made up of each raw material of following weight parts:
Acrylate and vinyl acetate emulsion 37, narra micro mist 2, hydroxyethyl methylacrylate 2, ammonium persulphate 3, Starso 2, silica gel 2, AESA 0.8, deionized water 15;
By silica gel, ammonium persulphate mixing, add hydroxyethyl methylacrylate after stirring, at 70 DEG C, be uniformly mixed 5 minutes, join in acrylate and vinyl acetate emulsion, stir;
Be mixed to join in deionized water by Starso and narra micro mist, raised temperature is 50 DEG C, adds AESA, stirs;
Mixed with each raw material of residue by each raw material after above-mentioned process, 300 revs/min of dispersed with stirring 20 minutes, obtain described adhesive aid.
A preparation method for rosin coating, is characterized in that comprising the following steps:
(1) mixed with 15% of above-mentioned deionized water weight by ammonium persulphate, stirring and dissolving, obtains initiator solution;
(2) get sodium lauryl sulphate, add 60% of residue deionized water weight, stir, obtain pre-emulsion;
(3) get 40% of aforesaid propylene acetoacetic ester weight, 50% mixing of vinyl acetate weight, add above-mentioned pre-emulsion, at 65 DEG C, be uniformly mixed 35 minutes, raised temperature is 75 DEG C, adds above-mentioned initiator solution, treats that emulsion is blue phase, be incubated 70 minutes, obtain seed emulsion;
(4) by remaining ethyl propenoate, vinyl acetate mixing, add short and long-chain acyl triglyceride molecules, trimethyl hydroxyethylammonium quadrol, at 70 DEG C, insulated and stirred 30 minutes, obtains mix monomer;
(5) mixed with maleated rosin by perfluorobutyl potassium, add 60% of residue deionized water weight, at 80 DEG C, insulated and stirred 35 minutes, is cooled to normal temperature, obtains liquid a;
(6) in above-mentioned seed emulsion, add dropping mix monomer, time for adding is 120 minutes, after dropwising, and adds liquid a, stirs, at 90 DEG C, be incubated 50 minutes, and cooling filters discharging with 250 eye mesh screens;
(7) material above-mentioned steps (6) obtained mixes with each raw material of residue, and 1200 revs/min of dispersed with stirring 20 minutes, obtain described rosin coating.
Performance test:
Unit elongation: >=300%;
Watertightness: 0.3MPa (one hour waterproof).
Claims (2)
1. a rosin coating, is characterized in that what it was made up of the raw material of following weight parts:
Maleated rosin 0.6-1, potassium wolframate 0.2-0.5, short and long-chain acyl triglyceride molecules 2-3, trimethyl hydroxyethylammonium quadrol 1-2, fluorapatite 10-13, N hydroxymethyl acrylamide 0.7-1, maleic anhydride inoculated polypropylene 2-3, Lauryl Alcohol ester 1.4-3, perfluorobutyl potassium 0.8-1, ethyl propenoate 100-150, vinyl acetate 140-200, ammonium persulphate 0.7-2, deionized water 500-700, sodium lauryl sulphate 2-3, adhesive aid 4-6;
Described adhesive aid is made up of each raw material of following weight parts:
Acrylate and vinyl acetate emulsion 30-37, narra micro mist 1-2, hydroxyethyl methylacrylate 2-3, ammonium persulphate 2-3, Starso 1-2, silica gel 1-2, AESA 0.8-1, deionized water 10-15;
By silica gel, ammonium persulphate mixing, add hydroxyethyl methylacrylate after stirring, at 60-70 DEG C, be uniformly mixed 3-5 minute, join in acrylate and vinyl acetate emulsion, stir;
Be mixed to join in deionized water by Starso and narra micro mist, raised temperature is 50-60 DEG C, adds AESA, stirs;
Mixed with each raw material of residue by each raw material after above-mentioned process, 300-400 rev/min of dispersed with stirring 10-20 minute, obtains described adhesive aid.
2. a preparation method for rosin coating as claimed in claim 1, is characterized in that comprising the following steps:
(1) mixed by the 10-15% of ammonium persulphate with above-mentioned deionized water weight, stirring and dissolving, obtains initiator solution;
(2) get sodium lauryl sulphate, add the 50-60% of residue deionized water weight, stir, obtain pre-emulsion;
(3) the 40-50% mixing of the 30-40% of aforesaid propylene acetoacetic ester weight, vinyl acetate weight is got, add above-mentioned pre-emulsion, 30-35 minute is uniformly mixed at 60-65 DEG C, raised temperature is 70-75 DEG C, add above-mentioned initiator solution, treat that emulsion is blue phase, insulation 60-70 minute, obtains seed emulsion;
(4) by remaining ethyl propenoate, vinyl acetate mixing, add short and long-chain acyl triglyceride molecules, trimethyl hydroxyethylammonium quadrol, insulated and stirred 20-30 minute at 65-70 DEG C, obtains mix monomer;
(5) mixed with maleated rosin by perfluorobutyl potassium, add the 50-60% of residue deionized water weight, insulated and stirred 20-35 minute at 75-80 DEG C, is cooled to normal temperature, obtains liquid a;
(6) in above-mentioned seed emulsion, add dropping mix monomer, time for adding is 90-120 minute, after dropwising, adds liquid a, stirs, at 80-90 DEG C, be incubated 50-60 minute, cooling, filters discharging with 200-250 eye mesh screen;
(7) material above-mentioned steps (6) obtained mixes with each raw material of residue, and 800-1200 rev/min of dispersed with stirring 20-30 minute, obtains described rosin coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410456039.4A CN104277623A (en) | 2014-09-09 | 2014-09-09 | Rosin paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410456039.4A CN104277623A (en) | 2014-09-09 | 2014-09-09 | Rosin paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104277623A true CN104277623A (en) | 2015-01-14 |
Family
ID=52252989
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410456039.4A Pending CN104277623A (en) | 2014-09-09 | 2014-09-09 | Rosin paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104277623A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5306762A (en) * | 1992-12-09 | 1994-04-26 | Westvaco Corporation | Rosin-supported amide-modified emulsion polymers |
| CN102643590A (en) * | 2012-05-14 | 2012-08-22 | 汕头市鑫源化工有限公司 | Water-based paint and preparation method thereof |
| CN102898918A (en) * | 2012-09-18 | 2013-01-30 | 海南必凯水性涂料有限公司 | High-gloss acrylic acid emulsion for coating and manufacturing method thereof |
| CN102911376A (en) * | 2012-11-15 | 2013-02-06 | 广西梧州日成林产化工股份有限公司 | Preparation method of water-based rosin resin tackifying emulsion |
| CN103194127A (en) * | 2013-03-18 | 2013-07-10 | 福建省利得彩环保科技有限公司 | Waterborne over-printing varnish for environment-friendly paper |
-
2014
- 2014-09-09 CN CN201410456039.4A patent/CN104277623A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5306762A (en) * | 1992-12-09 | 1994-04-26 | Westvaco Corporation | Rosin-supported amide-modified emulsion polymers |
| CN102643590A (en) * | 2012-05-14 | 2012-08-22 | 汕头市鑫源化工有限公司 | Water-based paint and preparation method thereof |
| CN102898918A (en) * | 2012-09-18 | 2013-01-30 | 海南必凯水性涂料有限公司 | High-gloss acrylic acid emulsion for coating and manufacturing method thereof |
| CN102911376A (en) * | 2012-11-15 | 2013-02-06 | 广西梧州日成林产化工股份有限公司 | Preparation method of water-based rosin resin tackifying emulsion |
| CN103194127A (en) * | 2013-03-18 | 2013-07-10 | 福建省利得彩环保科技有限公司 | Waterborne over-printing varnish for environment-friendly paper |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104263122A (en) | Stable paint | |
| CN104231695A (en) | Green antibacterial coating for interior wall | |
| CN104263125A (en) | Polymer exterior wall paint | |
| CN104263127A (en) | Insulating crack-resistant coating for exterior wall | |
| CN104250504A (en) | High-viscosity silicone-acrylic paint | |
| CN104263036A (en) | Bactericidal organic silicon coating | |
| CN104231769A (en) | Polyvinyl chloride paste resin coating | |
| CN104277623A (en) | Rosin paint | |
| CN104277619A (en) | Hydrophobic self-cleaning paint | |
| CN104231771A (en) | Lightweight coating | |
| CN104231766A (en) | Sound-absorbing and heat-insulating paint | |
| CN104263139A (en) | Fiber-reinforced paint | |
| CN104263138A (en) | Soft antibacterial coating | |
| CN104277620A (en) | Environment-friendly wall coating | |
| CN104263128A (en) | Resin-base paint | |
| CN104231692A (en) | Composite organic silicon coating | |
| CN104263031A (en) | Smooth bubble-free decorative paint | |
| CN104277621A (en) | Waterproof coating for building | |
| CN104263108A (en) | Corrosion-resistant bactericidal paint | |
| CN104263029A (en) | Anti-cracking and waterproof coating for wall body | |
| CN104231828A (en) | Green and natural antibacterial coating | |
| CN104277507A (en) | Thermal-insulating coating | |
| CN104356835A (en) | Macromolecular emulsion paint | |
| CN104312358A (en) | Functional interior wall coating material | |
| CN104356838A (en) | High-temperature thermal insulation coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150114 |
|
| RJ01 | Rejection of invention patent application after publication |