CN104264491B - A kind of cotton fabrics one bathes low-temperature refining, bleaching and surface cleaning processing method - Google Patents

A kind of cotton fabrics one bathes low-temperature refining, bleaching and surface cleaning processing method Download PDF

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CN104264491B
CN104264491B CN201410466945.2A CN201410466945A CN104264491B CN 104264491 B CN104264491 B CN 104264491B CN 201410466945 A CN201410466945 A CN 201410466945A CN 104264491 B CN104264491 B CN 104264491B
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bleaching
cotton fabrics
bath
fabric
processing method
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CN104264491A (en
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盛杰侦
曹机良
孟春丽
张晓静
魏媛
许志忠
程献伟
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Henan Institute of Engineering
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Henan Institute of Engineering
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Abstract

The invention discloses a kind of cotton fabrics one and bathe low-temperature refining, bleaching and surface cleaning processing method, step is as follows: add refine enzyme 3~10 g/L, cellulase 0.5~2 g/L, hydrogen peroxide 3~10g/L in a bath system, bleach-activating 2~6g/L, chelating agen 2~8 g/L and auxiliary agent 1~4 g/L, it is 6 ~ 7.5 with acid-base modifier regulation pH, fabric is put in dye bath by bath raio 1:10~100, it is warming up to 40~70 DEG C with the programming rate of 0.5~2 DEG C/min, insulation 30~100min, finally by fabric washing, dry or dry.The present invention bathes low temperature at cotton fabrics one and moves out and add bleach-activating, enzyme in system, make the refine of cotton fabrics, bleaching and any surface finish process a bath under cryogenic to implement, it is to avoid fabric strength damages, shortened process, reduce alkali consumption and energy consumption, improve dyeing and finishing working (machining) efficiency.

Description

A kind of cotton fabrics one bathes low-temperature refining, bleaching and surface cleaning processing method
Technical field
The invention belongs to dyeing and finishing technique field, relate to a kind of cotton fabrics one and bathe at low-temperature refining, bleaching and surface cleaning Reason method, the method is applicable to pure cotton knitted fabric or low-temperature neutral refine, bleaching and surface cleaning containing cotton fabrics.
Background technology
Cotton fabrics because it is comfortable and easy to wear, soft, be unlikely to deform, become the first-selection of T-shirt, underwear, fabric for sports & casual wear, but Natural cotton fiber itself is containing natural impuritys such as oils and fats, paraffin paper, ash, pectin, lignin, pigments, and above-mentioned impurity needs to pass through The operation such as kiering and bleaching is removed, and in weaving process and in the dyeing and finishing course of processing, the fine hair on cotton fabrics surface is the most naked Being exposed at fabric face, these fine hair length affect outward appearance and the fineness of fabric, need to be removed on fabric by certain processing Major part fine hair, makes fabric face bright and clean, to improve the flexibility of bafta, hygroscopicity, whiteness and fineness etc..
Normal conon knitted fabric pre-treatment generally uses high temperature scouring+high temperature oxygen bleaching process, and energy consumption is high, and fabric strength loses Greatly, and there is the risk of oxygen bleaching broken hole.Therefore exploitation low temperature pretreatment technology, reduces power consumption of polymer processing and pollutant emission, improves Product quality has important economy and social meaning.Use kiering enzyme such as pectase, lignoenzyme, lipase etc. right Bafta carries out process can make bafta obtain good refining effect, uses acyloxy compounds to live as hydrogen peroxide bleaching Agent can make bafta obtain preferably bleaching effect under cryogenic, uses cellulase that bafta is processed and can be gone Except the fine hair of surface of cotton fabric makes fabric obtain bright and clean surface.The present invention intends using kiering enzyme, acyl-oxygen base class chemical combination Thing hydrogen peroxide bleaching activator and cellulase associating one bath carry out pre-treatment to cotton fabrics, make cotton fabrics in low temperature one bath Under the conditions of complete kiering, bleaching and any surface finish arranging process.
Summary of the invention
The technical problem to be solved be for pure cotton knitted fabric and containing cotton fabrics bleaching need to be at high-temperature alkaline Under the conditions of carry out, reaction condition is violent, serious to fibre damage, and power consumption is big, and cost is high, and is unfavorable for enzyme refine, surface cleaning Process, with hydrogen peroxide bleaching one bath, the problem realized, it is provided that the gentleest efficient bath processing method of one, thus reach to protect Protect fiber injury-free, shortened process, save the energy.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of cotton fabrics one bathes low-temperature refining, bleaching and surface cleaning processing method, by enzyme refining techniques, low temperature Activated bleaching technology and enzyme clarte technical tie-up carry out pre-treatment to cotton fabric, and step is as follows:
Refine enzyme 3~10g/L, cellulase 0.5~2g/L, hydrogen peroxide 3~10g/ is added in a bath system L, bleach-activating 2~6g/L, chelating agen 2~8g/L and auxiliary agent 1~4g/L, be 6~7.5 with acid-base modifier regulation pH, will Fabric is put in dye baths by bath raio 1:10~100, is warming up to 40~70 DEG C with the programming rate of 0.5~2 DEG C/min, insulation 30~ 100min, finally by fabric washing, dry or dry.
The structure of described bleach-activating is as follows:
In formula, R is COONa, COOK, SO3Na or SO3K, m=1~14, n=1~9;
Described refine enzyme is pectase, lipase and the mixture of lignoenzyme composition, and w (pectase): w (lipase): w (lignoenzyme)=1~3:1~2:1~4.
Described chelating agen is at least one in sodium silicate, phytic acid or sodium phytate.
Described acid-base modifier be in acetic acid, hydrochloric acid, sulphuric acid, sodium carbonate, sodium bicarbonate, sodium acetate or sodium citrate extremely Few one.
Described auxiliary agent is penetrating agent JFC, nonionic penetrant DM-1230, polyether polyol, paregal O or the infiltration of low bubble At least one in agent SF.
Described cotton fabrics is pure cotton knitting grey cloth, and without slurry, containing the natural impurity of cotton fiber, fabric face has length The short fine hair differed.
Beneficial effects of the present invention: the present invention bathes low temperature at cotton fabrics one and moves out and add bleach-activating, life in system Thing enzyme, makes the refine of cotton fabrics, bleaching and any surface finish process a bath under cryogenic and implements, fabric after a bath processes Surface, without cotton seed hulls, can obtain whiteness and the hygroscopicity meeting industrial requirements, owing to this system is at the temperate condition of low-temperature neutral Lower enforcement, therefore fabric strength can be avoided to damage, shortened process, reduces alkali consumption and energy consumption, improves dyeing and finishing working (machining) efficiency.
Detailed description of the invention
Embodiment 1
A kind of cotton fabrics one bathes low-temperature refining, bleaching and surface cleaning processing method, and its process is as follows: one Bath arrangement system in add refine enzyme (mass ratio of pectase, lipase and lignoenzyme is 1:1: 1), (Shangyu Jie Hua Chemical Co., Ltd., structural formula is for cellulase, hydrogen peroxide, the novel bleach-activating of acyl-oxygen base class), auxiliary agent and chelating agen, use vinegar acid for adjusting pH To 6.5, by cotton fabrics, (pure cotton knitting grey cloth, without slurry, containing the natural impurity of cotton fiber, fabric face has length not The fine hair of one) put in dressing liquid by bath raio 1:50, it is warming up to 30 DEG C with the programming rate of 2 DEG C/min, is incubated 60min, finally By fabric washing, dry.
One bath processing prescription is as follows:
Embodiment 2
A kind of cotton fabrics one bathes low-temperature refining, bleaching and surface cleaning processing method, and its process is as follows: one Addition refine enzyme (mass ratio of pectase, lipase and lignoenzyme is 2:1:2) in bath arrangement system, (Shangyu Jie Hua Chemical Co., Ltd., structural formula is for cellulase, hydrogen peroxide, the novel bleach-activating of acyl-oxygen base class), auxiliary agent and chelating agen, with salt acid for adjusting pH to 6, By cotton fabrics, (pure cotton knitting grey cloth, without slurry, containing the natural impurity of cotton fiber, fabric face has floss different in size Hair) put in dressing liquid by bath raio 1:50, it is warming up to 45 DEG C with the programming rate of 0.5 DEG C/min, is incubated 60min, finally will knit Thing is washed, is dried.
One bath processing prescription is as follows:
Embodiment 3
A kind of cotton fabrics one bathes low-temperature refining, bleaching and surface cleaning processing method, and its process is as follows: one Bath arrangement system in add refine enzyme (mass ratio of pectase, lipase and lignoenzyme is 3:1: 2), (Shangyu Jie Hua Chemical Co., Ltd., structural formula is for cellulase, hydrogen peroxide, the novel bleach-activating of acyl-oxygen base class), auxiliary agent and chelating agen, regulate pH with sodium bicarbonate To 7.5, cotton fabrics is put in dressing liquid by bath raio 1:50, is warming up to 60 DEG C with the programming rate of 1 DEG C/min, insulation 60min, finally by fabric washing, dry.
One bath processing prescription is as follows:
Embodiment 4
A kind of cotton fabrics one bathes low-temperature refining, bleaching and surface cleaning processing method, and its process is as follows: one Bath arrangement system in add refine enzyme (mass ratio of pectase, lipase and lignoenzyme is 3:2: 4), (Shangyu Jie Hua Chemical Co., Ltd., structural formula is for cellulase, hydrogen peroxide, the novel bleach-activating of acyl-oxygen base class), auxiliary agent and chelating agen, regulate pH to 7 with sodium carbonate, Cotton fabrics is put in dressing liquid by bath raio 1:50, is warming up to 60 DEG C with the programming rate of 1.5 DEG C/min, be incubated 60min, After by fabric washing, dry.
One bath processing prescription is as follows:
Embodiment 5
A kind of cotton fabrics one bathes low-temperature refining, bleaching and surface cleaning processing method, and its process is as follows: Addition refine enzyme (mass ratio of pectase, lipase and lignoenzyme is 3:1:1) in one bath system, (Shangyu Jie Hua Chemical Co., Ltd., structural formula is for cellulase, hydrogen peroxide, the novel bleach-activating of acyl-oxygen base class), auxiliary agent and chelating agen, with salt acid for adjusting pH to 6, By cotton fabrics, (pure cotton knitting grey cloth, without slurry, containing the natural impurity of cotton fiber, fabric face has floss different in size Hair) put in dressing liquid by bath raio 1:10, it is warming up to 70 DEG C with the programming rate of 2 DEG C/min, is incubated 30min, finally by fabric Wash, dry.
One bath processing prescription is as follows:
Embodiment 6
A kind of cotton fabrics one bathes low-temperature refining, bleaching and surface cleaning processing method, and its process is as follows: In one bath system add refine enzyme (mass ratio of pectase, lipase and lignoenzyme is 1:2: 4), (Shangyu Jie Hua Chemical Co., Ltd., structural formula is for cellulase, hydrogen peroxide, the novel bleach-activating of acyl-oxygen base class), auxiliary agent and chelating agen, adjust with sodium bicarbonate Joint pH to 7.5, is put into cotton fabrics in dressing liquid by bath raio 1:50, is warming up to 40 DEG C with the programming rate of 1 DEG C/min, insulation 100min, finally by fabric washing, dry.
One bath processing prescription is as follows:
The implementation result of the present invention
It after embodiment 1~6 one bath, is tested by bafta respectively as follows, and test result is shown in Table 1.
1) Hunter whiteness (WI)
In the upper mensuration of UltraScan PRO colour photometer (HunterLab company of the U.S.), use D65 light source and 10 ° of viewing angles Observing, Hunter whiteness (WI) Hunter formula calculates:
WI=100-[(100-L)2+a2+b2]1/2 (1)
2) capillary effect
Wool effect of the fabric is pressed FZ/T 01071-2008 " textile capillary effect test method " and is measured.
3) strength loss
Strength test presses GB/T 19976-2005 " the mensuration steel ball method of textile bursting strength " the grand experiment instrument in Nantong Measuring on device company limited HD026H electronic fabric strength tester, the strength loss after fabric one bath is calculated by formula (2):
In formula: S1 is the strength before textile finishing, S2 is the strength after textile finishing.
The test result of one bath bafta implemented by table 1
Embodiment Surface smooth finish Capillary effect/cm WI Strength loss/%
Grey cloth 76.21 0
Traditional handicraft Difference, has fine hair different in size 11.31 89.76 7.43
Embodiment 1 Good, almost without long fine hair 11.28 89.21 5.21
Embodiment 2 Good, almost without long fine hair 11.17 89.43 5.33
Embodiment 3 Good, almost without long fine hair 11.42 89.65 4.54
Embodiment 4 Good, almost without long fine hair 11.14 89.78 4.69
Embodiment 5 Good, almost without long fine hair 11.35 89.62 5.02
Embodiment 6 Good, almost without long fine hair 11.24 89.45 4.77
As shown in Table 1, fabric is better than common process, capillary effect, whiteness and common process through a bath process rear surface smoothness Close, and fabric strength loss is less than common process.

Claims (4)

1. a cotton fabrics one bathes low-temperature refining, bleaching and surface cleaning processing method, it is characterised in that step is as follows: one Bath system adds refine enzyme 3~10 g/L, cellulase 0.5~2 g/L, hydrogen peroxide 3~10g/L, bleach activating Agent 2~6g/L, chelating agen 2~8 g/L and auxiliary agent 1~4 g/L, be 6 ~ 7.5 with acid-base modifier regulation pH, by fabric by bath raio 1:10~100 puts in dye bath, is warming up to 40~70 DEG C with the programming rate of 0.5~2 DEG C/min, is incubated 30~100min, After by fabric washing, dry or dry;
The structure of described bleach-activating is as follows:
In formula, R is COONa, COOK, SO3Na or SO3K, m=1~14, n=1~9;
Described refine enzyme is pectase, lipase and the mixture of lignoenzyme composition, and w (pectase): w (fat Enzyme): w(lignoenzyme)=1 ~ 3:1 ~ 2:1 ~ 4;
Described chelating agen is at least one in sodium silicate, phytic acid or sodium phytate.
Cotton fabrics one the most according to claim 1 bathes low-temperature refining, bleaching and surface cleaning processing method, and its feature exists In: described acid-base modifier is at least in acetic acid, hydrochloric acid, sulphuric acid, sodium carbonate, sodium bicarbonate, sodium acetate or sodium citrate Kind.
Cotton fabrics one the most according to claim 1 bathes low-temperature refining, bleaching and surface cleaning processing method, and its feature exists In: described auxiliary agent is in penetrating agent JFC, nonionic penetrant DM-1230, polyether polyol, paregal O or low-foaming penetrating agent SF At least one.
Cotton fabrics one the most according to claim 1 bathes low-temperature refining, bleaching and surface cleaning processing method, and its feature exists In: described cotton fabrics is pure cotton knitting grey cloth, and without slurry, containing the natural impurity of cotton fiber, fabric face has length not The fine hair of one.
CN201410466945.2A 2014-09-15 2014-09-15 A kind of cotton fabrics one bathes low-temperature refining, bleaching and surface cleaning processing method Expired - Fee Related CN104264491B (en)

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CN106149384B (en) * 2016-07-21 2018-11-23 东莞德永佳纺织制衣有限公司 A kind of dyeing and finishing method of cotton fabrics
CN107142734A (en) * 2017-06-19 2017-09-08 浙江七色彩虹印染有限公司 A kind of pretreating reagent and its method for cotton cheese dyeing pre-treatment
CN107558256A (en) * 2017-08-23 2018-01-09 辽源市杰牌印染科技有限公司 A kind of two bath method bleaching process under low bath raio
CN110565300A (en) * 2018-06-05 2019-12-13 无锡恒隆纺织品有限公司 Short fiber treatment process of fabric
CN109371716A (en) * 2018-09-17 2019-02-22 江阴捷豹针织制衣有限公司 A kind of dyeing and finishing technology of imitative mercerising single jersey
JPWO2021187426A1 (en) * 2020-03-16 2021-09-23
CN111501324A (en) * 2020-04-25 2020-08-07 常州旭荣针织印染有限公司 Low-temperature bleaching pretreatment method for cotton-containing knitted fabric
CN114775261B (en) * 2022-05-13 2024-04-26 汕头市鼎泰丰实业有限公司 Open width pretreatment method for knitted fabric
CN116334927A (en) * 2023-04-13 2023-06-27 合肥市东方美捷分子材料技术有限公司 Pretreatment processing technology of high-whiteness water-repellent elastic bandage

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CN102220684B (en) * 2011-05-06 2012-12-05 浙江传化股份有限公司 Low-temperature pretreatment process of full-cotton woven fabric
CN103046383B (en) * 2012-11-27 2016-05-04 江南大学 A kind of enzyme oxygen one is bathed cotton type fabric low temperature pre-treating method
CN103276582B (en) * 2013-04-02 2015-04-29 广东德美精细化工股份有限公司 Cotton knitted fabric scouring, bleaching, dyeing and soaping whole-process low temperature dyeing and finishing processing technology

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