CN104263135A - Reflective water-resistant paint - Google Patents

Reflective water-resistant paint Download PDF

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Publication number
CN104263135A
CN104263135A CN201410452001.XA CN201410452001A CN104263135A CN 104263135 A CN104263135 A CN 104263135A CN 201410452001 A CN201410452001 A CN 201410452001A CN 104263135 A CN104263135 A CN 104263135A
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CN
China
Prior art keywords
parts
reflective
minute
raw material
deionized water
Prior art date
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Pending
Application number
CN201410452001.XA
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Chinese (zh)
Inventor
王明明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI SUNROAD ENVIRONMENTAL MATERIAL Co Ltd
Original Assignee
ANHUI SUNROAD ENVIRONMENTAL MATERIAL Co Ltd
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Priority to CN201410452001.XA priority Critical patent/CN104263135A/en
Publication of CN104263135A publication Critical patent/CN104263135A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
    • C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09D131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004—Reflecting paints; Signal paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a reflective water-resistant paint which is prepared from the following raw materials in parts by weight: 72-80 parts of polyvinyl acetate emulsion, 0.3-1 part of potassium ferrocyanide, 0.3-1 part of tea tree oil, 0.5-1 part of octadecamethacrylate, 2-3 parts of binary vinyl chloride-vinyl acetate resin, 1-2 parts of inositol, 2-3 parts of alkenyl succinate, 1-2 parts of molybdenum boride, 2-3 parts of anhydrous calcium chloride, 1-2 parts of aluminum silicate, 1-2 parts of magnesium silicate, 10-14 parts of reflective glass microbead, 1-2 parts of terpineol, 2-3 parts of chlorinated paraffin, 5-7 parts of film forming assistant and 11-20 parts of deionized water. The water-resistant paint has the advantages of favorable water resistance, favorable washing fastness, enduring and bright color and high reflection ratio, is mainly used for making various reflecting signs, vehicle number plates, reflective clothes, safety devices and the like, and has favorable safety and protectiveness.

Description

A kind of reflective waterproof paint
Technical field
The present invention relates generally to a kind of coating, particularly relates to a kind of reflective waterproof paint.
Background technology
Along with development and the refinement of domestic coating industry, market is also more and more outstanding to the requirement with special functional coating, wherein anti-aging, water-fast, acid-alkali-corrosive-resisting, the performance requriements such as fire-retardant are more increased, existing water-proof material protect light, tint retention poor, not reflective, easy to crack, easily turn yellow, and have to human body, also there is certain harm, the feature of environmental protection is poor, therefore in order to meet the requirement of every profession and trade to waterproof paint, production high-performance, widely used waterproof paint is necessary.
Summary of the invention
The object of the invention is just to provide a kind of reflective waterproof paint.
The present invention is achieved by the following technical solutions:
A kind of reflective waterproof paint, it is made up of the raw material of following weight parts:
Polyvinyl acetate emulsion 72-80, yellow prussiate of potash 0.3-1, tea tree oil 0.3-1, stearyl methacrylate 0.5-1, binary vinyl chloride-vinyl acetate resin 2-3, nucite 1-2, alkenyl succinic acid ester 2-3, molybdenum boride 1-2, Calcium Chloride Powder Anhydrous 2-3, pure aluminium silicate 1-2, Magnesium Silicate q-agent 1-2, reflective glass beads 10-14, Terpineol 350 1-2, clorafin 2-3, film coalescence aid 5-7, deionized water 11-20;
Described film coalescence aid is made up of the raw material of following weight parts:
Organosilicon crylic acid latex 40-46, oxystearic acid 2-3, alpha-bromo-cinnamaldehyde 0.4-1, plant sterol 1-2, calcium lactate 2-3, clorafin 2-3, ammonium polyphosphate 0.6-1, Xylo-Mucine 0.3-1, deionized water 70-80;
By ammonium polyphosphate, calcium lactate mixing, ball milling is even, adds oxystearic acid, is uniformly mixed 2-3 minute, obtains Preblend at 50-60 DEG C;
Xylo-Mucine is joined in above-mentioned deionized water, Terpineol 350, plant sterol, alpha-bromo-cinnamaldehyde is added after stirring, 10-20 minute is uniformly mixed at 40-50 DEG C, add above-mentioned Preblend, be stirred to normal temperature, add each raw material of residue, 300-400 rev/min of dispersed with stirring 30-40 minute, obtains described film coalescence aid.
A preparation method for reflective waterproof paint, is characterized in that comprising the following steps:
Reflective glass beads is mixed with molybdenum boride, Calcium Chloride Powder Anhydrous, ball milling evenly after add Terpineol 350, binary vinyl chloride-vinyl acetate resin, 40-50 DEG C at be uniformly mixed 3-5 minute, drip tea tree oil, add deionized water after dropwising, 70-100 rev/min of dispersed with stirring 6-12 minute;
By pure aluminium silicate, Magnesium Silicate q-agent, yellow prussiate of potash mixing, ball milling is even, adds alkenyl succinic acid ester, stirs;
Mixed with each raw material of residue by each raw material after above-mentioned process, 800-1100 rev/min of dispersed with stirring 20-30 minute, obtains described reflective waterproof paint.
Advantage of the present invention is:
Waterproof paint of the present invention, has good water-repellancy, washing fastness, and bright in luster lasting, reflecting rate is high, be mainly used in the various reflecting sign labels, number plate of vehicle, retroreflective garments, safety features etc. that make, security protectiveness is good.
Embodiment
Embodiment 1
A kind of reflective waterproof paint, it is made up of the raw material of following weight parts (kilogram):
Polyvinyl acetate emulsion 80, yellow prussiate of potash 0.3, tea tree oil 0.3, stearyl methacrylate 0.5, binary vinyl chloride-vinyl acetate resin 2, nucite 2, alkenyl succinic acid ester 2, molybdenum boride 1, Calcium Chloride Powder Anhydrous 3, pure aluminium silicate 1, Magnesium Silicate q-agent 2, reflective glass beads 14, Terpineol 350 2, clorafin 3, film coalescence aid 5, deionized water 20;
Described film coalescence aid is made up of the raw material of following weight parts:
Organosilicon crylic acid latex 46, oxystearic acid 2, alpha-bromo-cinnamaldehyde 0.4, plant sterol 2, calcium lactate 2, clorafin 2, ammonium polyphosphate 0.6, Xylo-Mucine 0.3, deionized water 80;
By ammonium polyphosphate, calcium lactate mixing, ball milling is even, adds oxystearic acid, is uniformly mixed 2 minutes, obtains Preblend at 60 DEG C;
Xylo-Mucine is joined in above-mentioned deionized water, Terpineol 350, plant sterol, alpha-bromo-cinnamaldehyde is added after stirring, 20 minutes are uniformly mixed at 50 DEG C, add above-mentioned Preblend, be stirred to normal temperature, add each raw material of residue, 400 revs/min of dispersed with stirring 40 minutes, obtain described film coalescence aid.
A preparation method for reflective waterproof paint, comprises the following steps:
Reflective glass beads is mixed with molybdenum boride, Calcium Chloride Powder Anhydrous, ball milling evenly after add Terpineol 350, binary vinyl chloride-vinyl acetate resin, be uniformly mixed 5 minutes at 50 DEG C, drip tea tree oil, after dropwising, add deionized water, 100 revs/min of dispersed with stirring 12 minutes;
By pure aluminium silicate, Magnesium Silicate q-agent, yellow prussiate of potash mixing, ball milling is even, adds alkenyl succinic acid ester, stirs;
Mixed with each raw material of residue by each raw material after above-mentioned process, 1100 revs/min of dispersed with stirring 30 minutes, obtain described reflective waterproof paint.
Performance test:
Unit elongation: >=300%;
Watertightness: 0.3MPa (one hour waterproof).

Claims (2)

1. a reflective waterproof paint, is characterized in that what it was made up of the raw material of following weight parts:
Polyvinyl acetate emulsion 72-80, yellow prussiate of potash 0.3-1, tea tree oil 0.3-1, stearyl methacrylate 0.5-1, binary vinyl chloride-vinyl acetate resin 2-3, nucite 1-2, alkenyl succinic acid ester 2-3, molybdenum boride 1-2, Calcium Chloride Powder Anhydrous 2-3, pure aluminium silicate 1-2, Magnesium Silicate q-agent 1-2, reflective glass beads 10-14, Terpineol 350 1-2, clorafin 2-3, film coalescence aid 5-7, deionized water 11-20;
Described film coalescence aid is made up of the raw material of following weight parts:
Organosilicon crylic acid latex 40-46, oxystearic acid 2-3, alpha-bromo-cinnamaldehyde 0.4-1, plant sterol 1-2, calcium lactate 2-3, clorafin 2-3, ammonium polyphosphate 0.6-1, Xylo-Mucine 0.3-1, deionized water 70-80;
By ammonium polyphosphate, calcium lactate mixing, ball milling is even, adds oxystearic acid, is uniformly mixed 2-3 minute, obtains Preblend at 50-60 DEG C;
Xylo-Mucine is joined in above-mentioned deionized water, Terpineol 350, plant sterol, alpha-bromo-cinnamaldehyde is added after stirring, 10-20 minute is uniformly mixed at 40-50 DEG C, add above-mentioned Preblend, be stirred to normal temperature, add each raw material of residue, 300-400 rev/min of dispersed with stirring 30-40 minute, obtains described film coalescence aid.
2. a preparation method for reflective waterproof paint as claimed in claim 1, is characterized in that comprising the following steps:
Reflective glass beads is mixed with molybdenum boride, Calcium Chloride Powder Anhydrous, ball milling evenly after add Terpineol 350, binary vinyl chloride-vinyl acetate resin, 40-50 DEG C at be uniformly mixed 3-5 minute, drip tea tree oil, add deionized water after dropwising, 70-100 rev/min of dispersed with stirring 6-12 minute;
By pure aluminium silicate, Magnesium Silicate q-agent, yellow prussiate of potash mixing, ball milling is even, adds alkenyl succinic acid ester, stirs;
Mixed with each raw material of residue by each raw material after above-mentioned process, 800-1100 rev/min of dispersed with stirring 20-30 minute, obtains described reflective waterproof paint.
CN201410452001.XA 2014-09-05 2014-09-05 Reflective water-resistant paint Pending CN104263135A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410452001.XA CN104263135A (en) 2014-09-05 2014-09-05 Reflective water-resistant paint

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105647307A (en) * 2016-03-04 2016-06-08 芜湖市金宇石化设备有限公司 Method for preparing loading arm coating treatment agents
GB2576888A (en) * 2018-09-04 2020-03-11 Vps Group Ltd Vehicle registration plates

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005220266A (en) * 2004-02-06 2005-08-18 Du Pont Mitsui Polychem Co Ltd Aqueous dispersion for foamed coating film and use of the dispersion
CN101709193A (en) * 2009-12-11 2010-05-19 中国建筑材料科学研究总院 Water-borne acrylic type water-proof heat-insulating paint
KR20120015069A (en) * 2010-08-11 2012-02-21 정경화 Composition for preventing the slip having superior anti-cracking property
CN104004425A (en) * 2014-06-05 2014-08-27 隋庆宇 Acrylic acid waterborne polyurethane waterproofing coatings and manufacturing technology thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005220266A (en) * 2004-02-06 2005-08-18 Du Pont Mitsui Polychem Co Ltd Aqueous dispersion for foamed coating film and use of the dispersion
CN101709193A (en) * 2009-12-11 2010-05-19 中国建筑材料科学研究总院 Water-borne acrylic type water-proof heat-insulating paint
KR20120015069A (en) * 2010-08-11 2012-02-21 정경화 Composition for preventing the slip having superior anti-cracking property
CN104004425A (en) * 2014-06-05 2014-08-27 隋庆宇 Acrylic acid waterborne polyurethane waterproofing coatings and manufacturing technology thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
郭声波等: "反光隔热防水涂料的研究", 《新型建筑材料》, no. 10, 25 October 2005 (2005-10-25), pages 46 - 49 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105647307A (en) * 2016-03-04 2016-06-08 芜湖市金宇石化设备有限公司 Method for preparing loading arm coating treatment agents
GB2576888A (en) * 2018-09-04 2020-03-11 Vps Group Ltd Vehicle registration plates

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Application publication date: 20150107