CN104263080B - A kind of aqueous double anti-forge election ink and preparation method thereof - Google Patents

A kind of aqueous double anti-forge election ink and preparation method thereof Download PDF

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Publication number
CN104263080B
CN104263080B CN201410414377.1A CN201410414377A CN104263080B CN 104263080 B CN104263080 B CN 104263080B CN 201410414377 A CN201410414377 A CN 201410414377A CN 104263080 B CN104263080 B CN 104263080B
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China
Prior art keywords
ink
election
reactive dye
sodium
forge
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CN201410414377.1A
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Chinese (zh)
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CN104263080A (en
Inventor
汪文科
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YUYAO FEIER STATIONERY Co Ltd
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YUYAO FEIER STATIONERY Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/50Sympathetic, colour changing or similar inks

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

nullThe present invention relates to a kind of aqueous double anti-forge election ink and preparation method thereof,Its component includes by weight percentage: reactive dye 2 10%、Organic fluorescence agent 1 15%、Sodium hydroxide 0.5 5%、Active dye fixing agent 3 12%、Ethanol 10 35%、Sodium phytate 2 5%、Surfactant 0.5 2%、Sodium chloride 1 3%、Sodium borate 1 3%、PVA2 4%、Water surplus,The present invention selects reactive dye and organic fluorescence agent to prepare,Harmless,Safety and environmental protection,The reactive dye selected can be combined generation covalent bond with skin fiber,Firm coloration,The fixation time is long,Directly perceived distinct and be difficult to cleaning and fade,The permeable absorption of the organic fluorescence agent selected is in skin fiber depths,Again can be by reactive dye parcel protection,Under uviol lamp, fluorescence developing is distinct,This ink can keep more than 72 hours at skin surface,Ensure that election justice is carried out.

Description

A kind of aqueous double anti-forge election ink and preparation method thereof
Technical field
The present invention relates to a kind of ink, particularly relate to a kind of aqueous double anti-forge election ink and Preparation method.
Background technology
Along with science and technology development, the method for cheating get more and more, and resist cheating imperative, When particularly relating to various election, increasing use anti-cheating election ink, this ink master Relating to the fixation on human finger skin and fingernail and ultraviolet colour developing, currently used comparison is general Time anti-cheating election ink have two kinds, a kind of is single colorless fluorescent anti-counterfeiting ink, this ink Hydromining rare-earth complex, such as europium class complex, terbium class complex, yttrium class complex, this ink Water has the disadvantage that in application process: 1, this ink does not develops the color, and needs Just colour developing under ultraviolet light, the most intuitively;2, rare-earth complex is poor to skin adsorption ability, Easily dropping, on skin, the retention time is about 24 hours, does not reaches far away committee of the United Nations Member may require that the requirement keeping more than 72 hours;3, rare earth heavy metal has injury effect to human body. Another kind is oil colour ink, and this ink has the disadvantage that in application process: 1, only exist Developing the color under visible ray, antiforge function is single;2, this ink is poor to skin adsorption ability, uses The organic solvents such as ethanol are easily wiped, and on skin, the holding time is about 24 hours, far away Do not reach UN Commission and need to keep the requirement of more than 72 hours.
Summary of the invention
For the present situation of above-mentioned prior art, the technical problem to be solved is to provide A kind of harmless, good to skin adsorption ability, firm coloration, the fixation time is long, is difficult to Clean the aqueous double anti-forge faded and elect ink and preparation method thereof.
The present invention solves the technical scheme that above-mentioned technical problem used: a kind of aqueous is dual anti- Pseudo-election ink, its component includes by weight percentage:
Reactive dye 2-10%
Organic fluorescence agent 1-15%
Sodium hydroxide 0.5-5%
Active dye fixing agent 3-12%
Ethanol 10-35%
Sodium phytate 2-5%
Surfactant 0.5-2%
Sodium chloride 1-3%
Sodium borate 1-3%
PVA2-4%
Water surplus.
Compared with prior art, it is an advantage of the current invention that: the present invention selects reactive dye and has Prepared by machine fluorescent agent, harmless, safety and environmental protection, and the reactive dye of selection can be fine with skin Dimension combines and generates covalent bond, firm coloration, and the fixation time is long, directly perceived distinct and be difficult to wash Color, the permeable absorption of the organic fluorescence agent of selection, again can be by reactive dye in skin fiber depths Parcel protection, under uviol lamp, fluorescence developing is distinct, and this ink can keep at skin surface More than 72 hours, it is ensured that election justice is carried out.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail.
A kind of aqueous double anti-forge election ink, its component includes by weight percentage:
Reactive dye 2-10%
Organic fluorescence agent 1-15%
Sodium hydroxide 0.5-5%
Active dye fixing agent 3-12%
Ethanol 10-35%
Sodium phytate (dye stabilizers) 2-5%
Surfactant 0.5-2%
Sodium chloride 1-3%
Sodium borate (dye stabilizers) 1-3%
PVA (film former) 2-4%
Water surplus.
The preparation method of a kind of aqueous double anti-forge election ink, comprises the steps:
A, dispensing, weigh component according to percentage by weight and load in container;
B, dissolving of heating, control temperature at 65-85 DEG C, accelerates component and dissolves;
C, stirring and dissolving, make component fully dissolve by stirring;
D, standing, stand 8-12 hour, precipitated impurities;
After e, cooling, fill is sealed up for safekeeping.
Described reactive dye protein fibre in finger skin is combined and generates stable covalency Key, firm coloration, intuitively distinct, and hot water, the organic solvent such as ethanol is difficult to clean to be removed, It is difficult to fade and harmless, includes procedure below in this reactive dyeing machine: 1), Inhale color: skin fiber dye extraction internally spreading from dye liquor;2), fixation: dyestuff with Skin fiber generation chemical reaction, generates covalent bond.Described organic fluorescence agent can permeate absorption In skin protein fiber depths, can be by reactive dye parcel protection, under uviol lamp, fluorescence shows Color is distinct, harmless, and described active dye fixing agent can increase the color jail of reactive dye Degree, described ethanol can rapid osmotic skin protein fiber and volatile quick-drying, make ink easy Permeating volatile, quick-drying at skin surface, described sodium hydroxide can increase the upper of reactive dye Color rate and fixation speed, described surfactant has peptizaiton, and described sodium chloride can increase Refuelling color, this ink effectively can keep more than 72 hours at skin surface, be difficult to Cleaning removal is faded, it is possible to ensure that election justice is carried out.
Last it is noted that above example is only in order to illustrate technical scheme, and Non-to its restriction;Although the present invention being described in detail with reference to previous embodiment, ability Territory it will be appreciated by the skilled person that it still can be to the technical side described in foregoing embodiments Case is modified, or replaces wherein portion of techniques feature on an equal basis;And these amendment or Person replaces, and does not make the essence of appropriate technical solution depart from various embodiments of the present invention technical scheme Spirit and scope.

Claims (1)

1. an aqueous double anti-forge election ink, it is characterised in that its component percentage by weight Include than meter:
Reactive dye 2-10%
Organic fluorescence agent 1-15%
Sodium hydroxide 0.5-5%
Active dye fixing agent 3-12%
Ethanol 10-35%
Sodium phytate 2-5%
Surfactant 0.5-2%
Sodium chloride 1-3%
Sodium borate 1-3%
PVA 2-4%
Water surplus.
CN201410414377.1A 2014-08-18 2014-08-18 A kind of aqueous double anti-forge election ink and preparation method thereof Active CN104263080B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410414377.1A CN104263080B (en) 2014-08-18 2014-08-18 A kind of aqueous double anti-forge election ink and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410414377.1A CN104263080B (en) 2014-08-18 2014-08-18 A kind of aqueous double anti-forge election ink and preparation method thereof

Publications (2)

Publication Number Publication Date
CN104263080A CN104263080A (en) 2015-01-07
CN104263080B true CN104263080B (en) 2016-08-24

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CN201410414377.1A Active CN104263080B (en) 2014-08-18 2014-08-18 A kind of aqueous double anti-forge election ink and preparation method thereof

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Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100506130B1 (en) * 2002-12-30 2005-08-05 한국조폐공사 Penetrating ink composition
CN101353494A (en) * 2007-07-23 2009-01-28 王磊 Erasable viscous ink and preparation thereof
CN102212287B (en) * 2010-04-08 2013-10-02 严俊 Printing and dyeing ink for direct inkjet textile and preparation method thereof
CN102732087B (en) * 2011-04-14 2014-03-05 北京赛腾工业标识系统有限公司 Anti-channel conflict code-spurting printing ink and its preparation method
CN102191729B (en) * 2011-04-18 2014-02-26 保定钞票纸业有限公司 Colorized transparent anti-counterfeit watermark paper and manufacturing method thereof
JP3179064U (en) * 2012-08-02 2012-10-11 株式会社イツキプリント Retroreflector

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