CN104262739B - Rat-proof buried drip irrigation pipe and manufacturing method thereof - Google Patents
Rat-proof buried drip irrigation pipe and manufacturing method thereof Download PDFInfo
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- CN104262739B CN104262739B CN201410398449.8A CN201410398449A CN104262739B CN 104262739 B CN104262739 B CN 104262739B CN 201410398449 A CN201410398449 A CN 201410398449A CN 104262739 B CN104262739 B CN 104262739B
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
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Abstract
The invention provides a rat-proof buried drip irrigation pipe. The drip irrigation pipe is made of the following components in parts by mass: 40-60 percent of high density polyethylene, 10-30 percent of low density polyethylene, 10-30 percent of linear low density polyethylene, 1-10 percent of rat-proof master batch and 1-2 percent of multifunctional master batch, wherein the rat-proof master batch is prepared from raw materials comprising ethyl cellulose microencapsulated capsaicine particles and cinnamamide. The invention further provides a manufacturing method of the drip irrigation pipe. Through adoption of a co-extrusion technology, rat-proof components exist in the drip irrigation pipe in the form of a color bar. The drip irrigation pipe has a good rat-proof effect, and acts for a longer time.
Description
Technical field
The invention belongs to agricultural irrigation equipment technical field, especially relate to a kind of drip irrigation pipe, more particularly relate to one kind
Protection against rodents type drip irrigation below the surface pipe and preparation method thereof.
Background technology
Drip irrigation is one of the most efficient fertilizer irrigation technology of field irrigation so far, can accomplish little water frequent irrigation, make moisture
Slow equably infiltration soil, can play holding effect, and form the suitable soil water, fertilizer, thermal environment to Soil structure.Buried
Formula drip irrigation technique has obvious water-saving result, has many advantages, such as following: 1, douche is embedded in below earth's surface, will not produce ground
Table runoff, reduces the water content of topsoil to greatest extent, decreases Evaporation among plants loss;2nd, hollow billet and douche be successively
Embedment underground can be using for many years, it is to avoid under-film drip irrigation is annual to lay and reclaim the trouble of drip irrigation zone and because caused by reclaiming
Arm, auxiliary pipe and pipe fitting failure loss;3rd, reduce weed growth, underground drip irrigation make earth's surface relatively dry it is suppressed that weeds send out
Bud and growth;4th, do not destroy Soil structure;5th, utilization rate of fertilizer is high, applies underground drip irrigation technique, can be in the crop time of infertility
Interior, timely and appropriate discovery nutrient and pesticide accurately and are directly delivered to crop root zone;6th, underground drip irrigation douche is moistened
Region be spherical, compare with drip surface, the volume of its humid region and surface area all greatly increase, be as root system hypertrophy expand
Dissipate, absorb nutrition and provide bigger space.
But, in storage and Field information, drip irrigation pipe can suffer that muroid is destroyed, muroid relies primarily on vision, audition, taste
Feel to experience surrounding with olfactory sensation.There is the report adding capsaicin in drip irrigation pipe, because capsaicin is had in prior art
Standby pungent has zest, and it enables to the oral mucosa of muroid and taste nerve is subject to intense stimulus to detest and reject and chew
Cut, and so that muroid is abandoned biting and distribute the drip irrigation pipe of same abnormal smells from the patient, thus reach walking quickly and keeping away effect.
But, drip irrigation pipe is permanent use after, muroid has adapted to the abnormal smells from the patient of capsaicin or capsaicin composition due to moving forward to
Extraneous and content reduces, protection against rodents decreased effectiveness will be led to, walk quickly and keep away effect and reduce.
Content of the invention
The problem to be solved in the present invention is for above-mentioned deficiency, provides that a kind of protection against rodents effect is more preferable, action time is more longlasting
Protection against rodents type drip irrigation below the surface pipe and preparation method thereof.
For solving above-mentioned technical problem, first purpose of the present invention is to provide a kind of protection against rodents type drip irrigation below the surface pipe, adopts
Technical scheme is:
A kind of protection against rodents type drip irrigation below the surface pipe, described drip irrigation pipe is to be prepared by each component including following mass fraction
: the high density polyethylene (HDPE) of 40-60%, the Low Density Polyethylene of 10-30%, the linear low density polyethylene of 10-30%, 1-
10% protection against rodents master batch, the multifunctional concentrate of 1-2%, described protection against rodents master batch is by the raw material system including Ratproof agent a and Ratproof agent b
For obtain, wherein, Ratproof agent a is ethyl cellulose microcapsule encapsulation capsaicin granule, and b is cinnamamide.
Further, described ethyl cellulose microcapsule encapsulation capsaicin granule is prepared by the following method and obtains:
(1) ethyl cellulose is added and in organic solvent, form solution c;(2) capsaicin nano-powder is added in solution c, then plus
Enter emulsifying agent, form emulsion d;(3) emulsion d is added in deionized water and agitating heating, evaporation of organic solvent, by gained
Product filter, washing, be dried after obtain ethyl cellulose microcapsule encapsulation capsaicin granule.
As preferred scheme, described organic solvent is dichloromethane.
Further, described protection against rodents master batch is prepared via a method which to obtain: weight fraction is anti-for 10-30%
The Ratproof agent b of Mus agent a, 1-10%, the Low Density Polyethylene of 40-70%, the antioxidant of 1-3%, the ethylene vinyl acetate second of 10-20%
After alkene ester mix homogeneously, heated plasticizing, extrusion, sizing, cooling, pelletizing, air-dry make.
Further, described multifunctional concentrate is fluoropolymer additive ppa.
Further, the wall thickness of described drip irrigation pipe is more than or equal to 0.4mm.
Second object of the present invention is the preparation method providing protection against rodents type drip irrigation below the surface pipe, using following technical side
Case:
Add after high density polyethylene (HDPE), Low Density Polyethylene, linear low density polyethylene and multifunctional concentrate are mixed and squeeze
Go out in machine;Protection against rodents master batch adds in little co-extrusion machine;Preheat at a temperature of 200-260 DEG C, through former in 260-280 DEG C of temperature
Under, major ingredient and protection against rodents master batch co-extrusion obtain drip irrigation pipe.
Further, drip irrigation pipe preparation adopts co-extrusion technology, and protection against rodents composition is passed through co-extrusion machine and is present in droplet with vitta form
Fill in pipe.
The present invention has the advantages and positive effects that:
1st, capsaicin is carried out micro encapsulation, ethyl cellulose is used as wall material, using its good moulding property with dredge
Aqueouss, it is to avoid drip irrigation pipe is chronically in moist environment and causes protection against rodents composition to be affected by biological in soil, chemistry, physical environment
And reduce protection against rodents effect;
2nd, the cinnamamide adding can cause muroid dyspepsia, plays secondary avoidance effect by trained reflex;
3rd, production technology adopts co-extrusion technology, by protection against rodents composition presented in vitta in drip irrigation pipe, it is to avoid giving birth to
During product, cooling water is taken away the protection against rodents composition being scattered in drip irrigation pipe surface and is caused surface protection against rodents constituent reduction, penetrating odor
Reduce.
Specific embodiment
Below in conjunction with the accompanying drawings the specific embodiment of the present invention is elaborated.
High density polyethylene (HDPE), Low Density Polyethylene, linear low density polyethylene is all purchased from China PetroChemical Corporation;
Multifunctional concentrate (ppa) is purchased from Jiangsu Lian Su macromolecular material company limited.
The preparation of embodiment 1 ethyl cellulose microcapsule encapsulation capsaicin granule
(1) 8g ethyl cellulose (wall material) is added in 60ml dichloromethane, form ethyl cellulose solution;
(2) 0.4g capsaicin nano-powder is added in ethyl cellulose solution, adds the op-10 breast of 2.5%vol
Agent, ultrasonic 30min, form emulsion;
(3) above-mentioned emulsion is instilled with the speed of 3ml/min in the deionized water of 500ml and agitating heating, drip
Bi Hou, continues to stir and be slowly heated to 60 DEG C, obtains microcapsule granule, products therefrom is filtered, be washed with deionized water after 1h
Wash, after being dried, obtain capsaicin microcapsule granule.
The preparation of embodiment 2 protection against rodents master batch
Mass fraction is 10% Ratproof agent a, 10% cinnamamide, 60% Low Density Polyethylene, 1% antioxidant
1010, after 19% ethylene vinyl acetate mix homogeneously, heated plasticizing, extrusion, sizing, cooling, pelletizing, air-dried technique system
Become protection against rodents master batch.
The preparation of embodiment 3 protection against rodents master batch
, with embodiment 2, raw material composition is different from embodiment 2, is 20% Ratproof agent a, 10% cinnamamide for preparation method,
50% Low Density Polyethylene, 1% antioxidant 1010,19% ethylene vinyl acetate.
The preparation of embodiment 4 protection against rodents master batch
, with embodiment 2, raw material composition is different from embodiment 2, is 25% Ratproof agent a, 5% cinnamamide for preparation method,
50% Low Density Polyethylene, 1% antioxidant, 19% ethylene vinyl acetate.
The preparation of embodiment 5 protection against rodents type drip irrigation below the surface pipe
By percetage by weight be 46% high density polyethylene (HDPE), 30% Low Density Polyethylene, 30% linea low density
Polyethylene and 1% multifunctional concentrate mix after add in extruder, protection against rodents master batch (from embodiment 2) by 3% adds little
In co-extrusion machine, preheat under the conditions of 200-260 DEG C, then extrude under the conditions of 260-280 DEG C through former, cool down, shape,
Traction obtains final product.
Embodiment 6, embodiment 7, embodiment 8 and embodiment 9, its preparation method is same as Example 5, and difference is
Inventory, the inventory of each embodiment is carried out according to following form.
With reference to Fudan University's Laboratory Animal Science portion mouse bite preventing method of testing, protection against rodents type drip irrigation below the surface pipe is surveyed
Examination, method is as follows.
One sample, eight samples, in each mouse cage, each group randomly places two samples.Select 250~300gsd male
Rat 20, raises at random in the mouse cage of stainless steel silk, 5, every cage, 4 cage altogether.Sample iron wire is fixed, and is positioned over mouse cage
Away from the 5~8cm of bottom.Mus material and drinking-water are sufficient, observe rat and search for food, movable and sample damage degree, and test maintains 7 days.
Protection against rodents standard: rat bites area and degree evaluation result of biting see table.
Evaluation result | Bite area |
- | 0.5/10 |
+ | 1/10 |
++ | 5/10 |
+++ | 5/10 |
++++ | 8/10 |
+++++ | 10/10 |
Each embodiment rodent-proof characteristic experimental result is as follows:
Title | Result |
Conventional drip irrigation pipe | ++ |
Embodiment 5 drip irrigation pipe | ‐ |
Embodiment 6 drip irrigation pipe | ‐ |
Embodiment 7 drip irrigation pipe | ‐ |
Embodiment 8 drip irrigation pipe | ‐ |
Embodiment 9 drip irrigation pipe | ‐ |
Above 9 embodiments of the present invention are described in detail, but described content has been only the preferable enforcement of the present invention
Example is it is impossible to be considered the practical range for limiting the present invention.All impartial changes made according to the present patent application scope and improvement
Deng all should still belong within the patent covering scope of the present invention.
Claims (6)
1. a kind of protection against rodents type drip irrigation below the surface pipe is it is characterised in that described drip irrigation pipe is by each group including following mass fraction
Point prepare: the high density polyethylene (HDPE) of 40-60%, the Low Density Polyethylene of 10-30%, the linea low density of 10-30%
Polyethylene, the protection against rodents master batch of 1-10%, the multifunctional concentrate of 1-2%;
Described protection against rodents master batch is to be prepared by the raw material including Ratproof agent a and Ratproof agent b, and wherein, Ratproof agent a is that ethyl is fine
The plain fire micro capsule capsaicine granule of dimension, b is cinnamamide.
2. protection against rodents type drip irrigation below the surface pipe according to claim 1 it is characterised in that: described ethyl cellulose microcapsule
Fructus Capsici crude granule is prepared by the following method and obtains: ethyl cellulose is added formation solution c in organic solvent by (1);(2)
Capsaicin nano-powder is added in solution c, adds emulsifying agent, form emulsion d;(3) emulsion d is added deionization
In water and agitating heating, evaporation of organic solvent, products therefrom is filtered, washs, be dried after obtain ethyl cellulose microcapsule
Fructus Capsici crude granule.
3. protection against rodents type drip irrigation below the surface pipe according to claim 1 it is characterised in that: described protection against rodents master batch is by as follows
Method prepares: by the Ratproof agent a for 10-30% for the weight fraction, the low-density of the Ratproof agent b of 1-10%, 40-70% is gathered
Ethylene, the antioxidant of 1-3%, after the ethylene vinyl acetate mix homogeneously of 10-20%, heated plasticizing, extrusion, sizing, cold
But, pelletizing, air-dry make.
4. protection against rodents type drip irrigation below the surface pipe according to claim 1 it is characterised in that: described multifunctional concentrate is fluorine-containing poly-
Compound processing aid ppa.
5. protection against rodents type drip irrigation below the surface pipe according to claim 1 it is characterised in that: the wall thickness of described drip irrigation pipe be more than etc.
In 0.4mm.
6. preparation claim 1 described in a kind of method of protection against rodents type drip irrigation below the surface pipe it is characterised in that: by high-density polyethylene
Add in extruder after alkene, Low Density Polyethylene, linear low density polyethylene and multifunctional concentrate mixing;Protection against rodents master batch adds little
In co-extrusion machine;Preheat at a temperature of 200-260 DEG C, through former at a temperature of 260-280 DEG C, major ingredient and protection against rodents master batch co-extrusion
Obtain drip irrigation pipe, drip irrigation pipe preparation adopts co-extrusion technology, and protection against rodents composition is present in drip irrigation pipe with vitta form by co-extrusion machine.
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CN104987663A (en) * | 2015-06-26 | 2015-10-21 | 佛山市粤佳信电线电缆有限公司 | Anti-mouse agent formula for cable insulation layers |
CN105062036B (en) * | 2015-07-31 | 2017-09-12 | 大禹节水(天津)有限公司 | A kind of mouse bite preventing drip irrigation tube mother material |
CN105646998A (en) * | 2016-04-07 | 2016-06-08 | 杭州科佳新材料股份有限公司 | Ultraviolet resistant, rat-and-ant-resistant, low-temperature-resistant and environment-friendly polyolefin material and preparation method |
CN106069605A (en) * | 2016-06-24 | 2016-11-09 | 大禹节水(天津)有限公司 | Pipe double-vane labyrinth type drip irrigation zone in a kind of intensive crop |
CN107873475A (en) * | 2016-09-30 | 2018-04-06 | 河南在田农业科技有限公司 | A kind of anti-insect bite drip irrigation zone of environment-friendly type |
CN107057115A (en) * | 2017-06-16 | 2017-08-18 | 成都亨通光通信有限公司 | A kind of novel ratproof optic cable sheath and preparation method thereof |
CN107629302A (en) * | 2017-09-18 | 2018-01-26 | 中国农业大学 | Anti- root intrusion and protection against rodents insect bite underground drip irrigation band |
CN109169204B (en) * | 2018-07-12 | 2021-05-28 | 安徽省农业科学院作物研究所 | Underground irrigation management method for improving tomato quality |
CN109942938A (en) * | 2019-03-08 | 2019-06-28 | 苏州中特电材有限公司 | A kind of mouse bite preventing functional agglomerate |
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JP3053480B2 (en) * | 1991-11-18 | 2000-06-19 | 日本化薬株式会社 | Animal bite prevention paint composition |
CN201319273Y (en) * | 2008-12-30 | 2009-09-30 | 安徽电缆股份有限公司 | Gopher-protected cable |
CN102391563A (en) * | 2011-07-01 | 2012-03-28 | 东莞市国美电缆有限公司 | Rat-proof insect-proof ant-proof master batch, and wire and plastic product containing same |
CN103319772A (en) * | 2013-06-17 | 2013-09-25 | 内蒙古亿利塑业有限责任公司 | Ratproof drip irrigation tape |
CN103665532B (en) * | 2013-12-11 | 2015-11-18 | 甘肃大禹节水集团股份有限公司 | A kind of Micro-pressure ultra-thin wall drip irrigation belt |
CN103756092B (en) * | 2014-01-02 | 2015-11-25 | 大禹节水(天津)有限公司 | High pressure resistant PE flexible pipe of thin-walled and preparation method thereof |
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