CN104260479B - A kind of high polymer alloy waterproof roll and production method thereof - Google Patents

A kind of high polymer alloy waterproof roll and production method thereof Download PDF

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Publication number
CN104260479B
CN104260479B CN201410428720.8A CN201410428720A CN104260479B CN 104260479 B CN104260479 B CN 104260479B CN 201410428720 A CN201410428720 A CN 201410428720A CN 104260479 B CN104260479 B CN 104260479B
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waterproof roll
water
layer
high polymer
proof self
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CN104260479A (en
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王鹏程
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BEIJING ZHONGLIAN TIANSHENG BUILDING MATERIALS Co Ltd
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BEIJING ZHONGLIAN TIANSHENG BUILDING MATERIALS Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/082—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/18—Layered products comprising a layer of metal comprising iron or steel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J109/00—Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09J109/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207—Heat-activated adhesive
    • B32B2037/1215—Hot-melt adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/06—Coating on the layer surface on metal layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B32B2255/205—Metallic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54—Yield strength; Tensile strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/752—Corrosion inhibitor

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention relates to a kind of high polymer alloy waterproof roll and production method thereof, high polymer alloy waterproof roll includes alloy plate layer and the polymer material layer being combined into one, and two sides of alloy plate layer are all laid with oxidation-resistant material；Waterproof roll at least side is laid with the water-tight corrosion-proof self-adhesive bed of material, the outside of the water-tight corrosion-proof self-adhesive bed of material is provided with silicon oil membrane, and the component of the water-tight corrosion-proof self-adhesion sizing material of the water-tight corrosion-proof self-adhesive bed of material and percentage by weight include the resistance rust preservative and 8～the talcum powder of 19% of solid thermoplastics acrylic resin, 3～5% of 20～the aromatic naphtha of the thermoplastic styrene butadiene rubber of 45%, 10～35%, 3～25%.The present invention has good resistance to water and corrosion resistance, uvioresistant, low temperature resistant, ageing-resistant, puncture-resistant, and construction is fast, can be with the waterproof material of the building tight one of bonding formation, it is applicable to the subway of all kinds of architectural engineering, tunnel, bridge, underground or roofing, is particularly well-suited to the waterproof construction of anti-root system of plant surface layer.

Description

A kind of high polymer alloy waterproof roll and production method thereof
Technical field
The present invention relates to a kind of waterproof roll, particularly to a kind of a kind of high polymer alloy waterproof roll being applied to construction field.
Background technology
At present, the waterproof construction of building field faces channeling water seepage and the big technical barrier of settlement influence two, how to provide effective waterproofing protection to be an extremely challenging task for structural concrete.Prior art uses pre-laid method construction, being cast directly over by liquid concrete on waterproof roll, after concrete setting, xoncrete structure and waterproof roll are bonded to be integrated, can effectively prevent moisture from penetrating into waterproof roll and the gap of xoncrete structure, improve waterproof system reliability.Alloy plate layer and macromolecular material composite of water-proof coiled material are current developing direction, but it yet suffers from many not enough, such as:
1, polymer material layer and the bonding difficulty of alloy plate layer in manufacturing process, bond insecure, easily have gap, cause coiled material integral waterproofing impaired performance；
In the waterproof roll overlay the most at present, majority is modified pitch class adhesive, not only bonding peel strength is relatively low, pitch itself is a kind of hot-fluid cold-short material, and therefore modified pitch class adhesive is high temperature resistant and poor performance at low temperatures, and this made troubles for summer and construction in winter；
3. alloy plate layer lacks effective anti-oxidant treatment, causes the easy oxidized corrosion of sheet material to cause drainage, it is impossible to carry out resource circulation utilization, cause coiled material whole service life short, and cannot reclaim, and forms solid waste rubbish, wastes resource, pollutes environment；
4. the surface of coiled material is without aluminum coated steel, and viscous pin, workman cannot be in coiled material surface assembling reinforcement；Also without special protection layer, as because of working-day claims, under the effect of ultraviolet and wind and rain, lose bonding effect and cause product rejection.
To sum up, be badly in need of at present a kind of being easy to construction, high and low temperature resistance is good, bonding peel strength is high, corrosion-resistant ageing-resistant, length in service life can be recycled and the high polymer alloy waterproof roll of environmental protection.
Summary of the invention
Present invention aim at providing a kind of high polymer alloy waterproof roll and production method thereof, solving in prior art most in waterproof roll is that modified pitch class adhesive, adhesion strength be relatively low, high temperature resistant and poor performance at low temperatures, the problem bringing difficulty of constructing to summer and winter；Also solve existing high polymer alloy waterproof roll alloy plate layer and macromolecule layer directly bond, without effective anti-oxidant treatment, cause the easy oxidized corrosion of sheet material to cause drainage, cannot be carried out resource circulation utilization, cause that coiled material whole service life is short, problem to environment；The most also solve existing coiled material surface without polymer material layer in aluminum coated steel and manufacturing process and alloy plate layer bonding difficulty, bond insecure, easily have gap, a problem causing coiled material integral waterproofing impaired performance.
For solving above technical problem, the present invention adopts the following technical scheme that；
A kind of high polymer alloy waterproof roll, including the polymer material layer being combined and alloy plate layer, it is characterised in that: the both sides of described alloy plate layer are coated with oxidation-resistant material layer；The outside of described polymer material layer and/or alloy plate layer is laid with the water-tight corrosion-proof self-adhesive bed of material, and the outside of the described water-tight corrosion-proof self-adhesive bed of material is provided with silicon oil membrane；
In the described water-tight corrosion-proof self-adhesive bed of material, component and the percentage by weight of water-tight corrosion-proof self-adhesion sizing material are as follows,
Thermoplastic styrene butadiene rubber 20～45%；
Aromatic naphtha 10～35%；
Solid thermoplastics acrylic resin 3～25%；
Resistance rust preservative 3～5%；
Talcum powder 8～19%.
As the preferred technical solution of the present invention, described alloy plate layer is the layers of foil of copper alloy, ferroalloy, ashbury metal, metal, aluminium alloy or terne metal.
As present invention further optimization technical scheme, described polymer material layer is HDPE macromolecular sheet material, EVA macromolecular sheet material, PVC macromolecular sheet material or APAO macromolecular sheet material.
As present invention further optimization technical scheme, described oxidation-resistant material layer (2) is the material layer of copper antioxidant, iron antioxidant, tin antioxidant, lead antioxidant, aluminum antioxidant agent or the slicker solder antioxidant corresponding with alloy plate layer (3) material.
As present invention further optimization technical scheme, the described water-tight corrosion-proof self-adhesive bed of material is made up of the talcum powder of the thermoplastic styrene butadiene rubber that percentage by weight is 28%, 34% aromatic naphtha, the solid thermoplastics acrylic resin of 19%, the resistance rust preservative of 4% and 15%.
Described thermoplastic styrene butadiene rubber is SBS188 butadiene-styrene rubber；Arene content >=86% in described aromatic naphtha；Described solid thermoplastics acrylic resin is BR series acrylic resin；Described resistance rust preservative is MS-105 resistance rust preservative.
It is furthermore preferred that the both sides of high polymer alloy waterproof roll lay one layer of protective cloth the most respectively.
It is furthermore preferred that described protective cloth is non-woven fabrics, chemical fabric, glass-fiber-fabric or woven cloth.
The present invention also sets the production method relating to a kind of above-mentioned a kind of high polymer alloy waterproof roll, macromolecular material requires distribution in proportion through material dispenser, enter back into three rollers to prolong pressure device and carry out prolonging pressure and be combined with alloy plate layer, it is then passed through being pulled into coating system gluing, subsequently enter cooling flattening system, enter back into deviation-rectifying system, diced system, finally carry out rolling, packaging, specifically comprise the following steps that
Step one, each composition of water-tight corrosion-proof self-adhesion sizing material is weighed by proportioning after put into hot melt case and carry out melten gel；
Step 2, the plastics of polymer material layer, rubber and additive will be formed in loading blender, it will be uniformly mixed the mixed material forming macromolecular material；
Step 3, preheating extrusion equipment, be heated to 140～190 degree by extrusion equipment by rear to front；
Step 4, with charging equipment, the mixed material of the macromolecular material in blender is squeezed into extrusion equipment, after material dispenser, be extruded into thin layer macromolecular material from extrusion equipment；
Step 5, thin layer macromolecular material is caused between the first rolling of roll unit and the second rolling, carry out prolonging pressure, form macromolecular sheet material；
Step 6, be coated in the both sides of alloy plate layer oxidation-resistant material layer formed alloy plate layer；
The alloy plate layer that step 7, macromolecular sheet material step 5 obtained and step 6 obtain carries out compound pressure of prolonging, formation composite sheet between the second rolling and the 3rd rolling；
Step 8, by composite sheet traction to application system apply water-tight corrosion-proof self-adhesion sizing material, during this period, application system must connect hot melt case, treats that hot melt adhesive temperature rises to 160 DEG C, the water-tight corrosion-proof self-adhesion sizing material after fusing is squeezed into application system and is coated becoming the water-tight corrosion-proof self-adhesive bed of material；
Step 9, deposited silicon oil membrane: silicon oil membrane is applied on the surface of the composite sheet after step 8 being processed；
Step 10, being entered cooling flattening system, deviation-rectifying system by hauling machine, finally cut to cutting equipment, rolling is molded laggard row finished product packing.
As the optional technical scheme of the present invention, described step 3 or four extrusion equipment be Single screw extrusion equipment or twin-screw extrusion equipment.In described step 8, it is that one side applies or two-sided deposited during the coating water-tight corrosion-proof self-adhesive bed of material.
Compared with prior art, the present invention's it is a technical advantage that:
1. to prolong pressure with rubber and plastic macromolecular sheet material through hot melt after anti-oxidant treatment compound for alloy plate layer material, and efficiently solving metal can not be with a difficult problem for polymer base material bonding so that it is the most described macromolecule coiled material and the character of alloy rolled material.Adding adjuvant film forming with polymer rubber for raw material, embedment underground is the most perishable, can the life-span same with building when making flush type waterproof material；Macromolecule layer has well its tension intensity high, good percentage elongation, and high and low temperature resistance is good, bonding peel strength is high, and resistance to water, corrosion resistance, lower temperature resistance and uvioresistant, ageing-resistant performance be good, puncture more resistant to root system；Alloy plate layer has the puncture well stoping root system, and has good tension intensity；
2. alloy plate layer is with alloy plate layer material as base material, and in addition antioxidant processes, in case the oxide etch of alloy plate layer, may better secure alloy, effectively extends the service life of waterproof roll；
3. the water-tight corrosion-proof self-adhesive bed of material replaces traditional modified pitch class adhesive, the water-tight corrosion-proof self-adhesive bed of material is to comprise thermoplastic elastomer, aromatic naphtha, solid thermoplastics acrylic resin, resistance rust preservative and the water-tight corrosion-proof self-adhesion sizing material thermoplastic elastomer of talc agent synthesis, there is the double grading of rubber and plastics, in it, polystyrene chain section is as hard segment, form physics cross-linked structure, impart the mechanical property that waterproof roll is good, there is high resilience, high-elongation, hot strength can reach 20～35MPa, higher than the hot strength of the elastomer typically cross-linked by chemical action；Aromatic naphtha is high temperature resistant and low temperature, the most volatile, can significantly improve the processing characteristics of rubber so that it is ageing-resistant, acid and alkali-resistance, and resistance rust antiseptic property is superior, adapts to winter or hot weather construction；Adhesive property is strong, applied widely, can bond on multiple base material, such as cement, metal-impregnated wood etc., it is possible to paving construction on moist basal plane, the time, the longest bond effect was the best；
4. the outside of waterproof roll arranges silicon oil membrane in case boning between material, provides protection, convenient construction simultaneously for coiled material.
5. construct without naked light, safety and environmental protection.
To sum up, high polymer alloy waterproof roll of the present invention has good waterproof effect and good anti-root system of plant penetrates function, can be with building generation self-adhesive, form the waterproof material of tight one, it is applicable to the subway of all kinds of architectural engineering, tunnel, bridge, underground or roofing, is particularly well-suited to the waterproof construction of anti-root system of plant surface layer.
Accompanying drawing explanation
Fig. 1 is the structural representation of the high polymer alloy waterproof roll of the embodiment 1 that the present invention relates to；
Fig. 2 is the structural representation of the high polymer alloy waterproof roll of the embodiment 2 that the present invention relates to；
Fig. 3 is the structural representation of the high polymer alloy waterproof roll of the embodiment 3 that the present invention relates to；
Fig. 4 is the structural representation of the high polymer alloy waterproof roll of the embodiment 4 that the present invention relates to；
Fig. 5 is the structural representation of the high polymer alloy waterproof roll of the embodiment 5 that the present invention designs；
Fig. 6 is the pipeline organization schematic diagram making high polymer alloy waterproof roll that the present invention relates to.
Reference: 1-polymer material layer, 2-oxidation-resistant material layer, 3-alloy plate layer, the 4-water-tight corrosion-proof self-adhesive bed of material, 5-silicon oil membrane, 6-protective cloth, 7-blender, 8-charging equipment, 9-extrusion equipment, 10-roll unit, 11-hot melt case, 12-cool down flattening equipment, 13-correcting device, 14-cutting equipment, 15-winding device, 16-packaging facilities.
Detailed description of the invention
If Fig. 1 to Fig. 5 is five embodiments, the high polymer alloy waterproof roll structure of embodiment 1 as shown in Figure 1 is silicon oil membrane 5, the water-tight corrosion-proof self-adhesive bed of material 4, polymer material layer 1, oxidation-resistant material layer 2, alloy plate layer 3 and oxidation-resistant material layer 2 from top to bottom；The structure of the high polymer alloy waterproof roll of embodiment 2 as shown in Figure 2 is polymer material layer 1, oxidation-resistant material layer 2, alloy plate layer 3, oxidation-resistant material layer 2, the water-tight corrosion-proof self-adhesive bed of material 4 and silicon oil membrane 5 from top to bottom；The structure of the high polymer alloy waterproof roll of embodiment 3 as shown in Figure 3 is silicon oil membrane 5, the water-tight corrosion-proof self-adhesive bed of material 4, polymer material layer 1, oxidation-resistant material layer 2, alloy plate layer 3 and oxidation-resistant material layer 2 from top to bottom；The structure of the high polymer alloy waterproof roll of embodiment 4 as shown in Figure 4 is protective cloth 6, polymer material layer 1, oxidation-resistant material layer 2, alloy plate layer 3 and oxidation-resistant material layer 2 from top to bottom；The structure of the high polymer alloy waterproof roll of embodiment 5 as shown in Figure 5 is polymer material layer 1, oxidation-resistant material layer 2, alloy plate layer 3 and oxidation-resistant material layer 2 from top to bottom.Below in conjunction with five embodiments, the present invention is further explained.
A kind of high polymer alloy waterproof roll, including the polymer material layer 1 being combined and alloy plate layer 3, it is characterised in that: the both sides of described alloy plate layer 3 are coated with oxidation-resistant material layer 2；The outside of described polymer material layer 1 and/or alloy plate layer 3 is laid with the water-tight corrosion-proof self-adhesive bed of material 4, and the outside of the described water-tight corrosion-proof self-adhesive bed of material 4 is provided with silicon oil membrane 5；Described alloy plate layer 31 can be the layers of foil of copper alloy, ferroalloy, ashbury metal, metal, aluminium alloy or terne metal.Described polymer material layer 1 can be HDPE macromolecular sheet material, EVA macromolecular sheet material, PVC macromolecular sheet material or APAO macromolecular sheet material.Described oxidation-resistant material layer 2 is the material layer of copper antioxidant, iron antioxidant, tin antioxidant, lead antioxidant, aluminum antioxidant agent or the slicker solder antioxidant corresponding with alloy plate layer 3 material.
Such as Fig. 1 to Fig. 3, waterproof roll at least side is laid with the water-tight corrosion-proof self-adhesive bed of material 4, and the outside of the water-tight corrosion-proof self-adhesive bed of material 4 is provided with silicon oil membrane 5.Wherein, Fig. 1 is the structural representation only arranging the water-tight corrosion-proof self-adhesive bed of material 4 in side of the embodiment 1 that the present invention relates to, Fig. 2 is the structural representation that the embodiment 2 that the present invention relates to arranges the water-tight corrosion-proof self-adhesive bed of material 4 at opposite side, and Fig. 3 is the structural representation that the both sides of embodiment 3 coiled material that the present invention relates to all arrange the water-tight corrosion-proof self-adhesive bed of material 4.As shown in Figure 4, one layer of protective cloth 6 can also respectively be laid in the both sides of waterproof roll of the present invention, and protective cloth 6 can be non-woven fabrics, chemical fabric, glass-fiber-fabric or woven cloth.As it is shown in figure 5, the upper and lower surface of described alloy plate layer 3 is laid with the structural representation of one layer of oxidation-resistant material 2.
The resistance rust preservative of the component of the water-tight corrosion-proof self-adhesion sizing material of the described water-tight corrosion-proof self-adhesive bed of material 4 and solid thermoplastics acrylic resin, 3～5% of percentage by weight 20～the aromatic naphtha of the thermoplastic styrene butadiene rubber of 45%, 10～35%, 3～25% and 8～the talcum powder of 19%, wherein, preferred percentage is thermoplastic styrene butadiene rubber, 34% aromatic naphtha, the solid thermoplastics acrylic resin of 19%, the resistance rust preservative of 4% and the talcum powder composition of 15% of 28%.Described thermoplastic styrene butadiene rubber is SBS188 butadiene-styrene rubber；Arene content >=86% in described aromatic naphtha；Described solid thermoplastics acrylic resin is BR series acrylic resin；Described resistance rust preservative is MS-105 resistance rust preservative.
The invention still further relates to the production method of above-mentioned high polymer alloy waterproof roll, as shown in Figure 6, its production line is: blender, and------------coating device--applying film device--stores material equipment-cooling flattening equipment-correcting device-cutting equipment-winding device-packaging facilities to coating device to roll unit to extrusion equipment to charging equipment to apply film device；Specific make step is as follows:
Step one, each composition of water-tight corrosion-proof self-adhesion sizing material is weighed by proportioning after put into hot melt case 11 and carry out melten gel；
Step 2, the plastics of polymer material layer 1, rubber and additive will be formed in loading blender 7, it will be uniformly mixed the mixed material forming macromolecular material；
Step 3, preheating extrusion equipment 9, be heated to 140～190 degree by extrusion equipment by rear to front；
Step 4, with charging equipment 8, the mixed material of the macromolecular material in blender 7 is squeezed into extrusion equipment 9, after material dispenser, be extruded into thin layer macromolecular material from extrusion equipment；
Step 5, thin layer macromolecular material is caused between the first rolling of roll unit 10 and the second rolling, carry out prolonging pressure, form macromolecular sheet material；
Step 6, it is coated in oxidation-resistant material layer 2 in the both sides of alloy plate layer 3；
The alloy plate layer 3 that step 7, macromolecular sheet material step 5 obtained and step 6 obtain carries out compound pressure of prolonging, formation composite sheet between the second rolling and the 3rd rolling；
Step 8, by composite sheet traction to application system apply water-tight corrosion-proof self-adhesion sizing material, rubber surface carry out apply film (silicone oil paper/film).The coating rubber membrane of another side is carried out at deposited film cooling rear haulage to second application system, then draw to application system coating self-adhering rubber film, rubber hot melt case should be connected at application system, treat that the temperature of hot melt rubber is to 160 degree, self-adhering rubber after fusing is squeezed into application system be coated becoming rubber pattern, after coating self-adhering rubber membrane process completes, carry out applying film (silicone oil paper/film) at rubber surface；
Step 9, deposited silicon oil membrane: silicon oil membrane is applied on the surface of the composite sheet after step 8 being processed；
Step 10, being entered cooling flattening system 12, deviation-rectifying system 13 by hauling machine, finally cut to cutting equipment 14, rolling is molded laggard row finished product packing.

Claims (10)

1. a high polymer alloy waterproof roll, including the polymer material layer (1) being combined and alloy plate layer (3), it is characterised in that: the both sides of described alloy plate layer (3) are coated with oxidation-resistant material layer (2)；The outside of described polymer material layer (1) and/or alloy plate layer (3) is laid with the water-tight corrosion-proof self-adhesive bed of material (4), and the outside of the described water-tight corrosion-proof self-adhesive bed of material (4) is provided with silicon oil membrane (5)；
In the described water-tight corrosion-proof self-adhesive bed of material (4), component and the percentage by weight of water-tight corrosion-proof self-adhesion sizing material are as follows,
Thermoplastic styrene butadiene rubber 20～45%；
Aromatic naphtha 10～35%；
Solid thermoplastics acrylic resin 3～25%；
Resistance rust preservative 3～5%；
Talcum powder 8～19%.
A kind of high polymer alloy waterproof roll the most according to claim 1, it is characterised in that: described alloy plate layer (3) is copper alloy layers of foil, ferroalloy layers of foil, ashbury metal layers of foil, metal layers of foil, aluminum alloy foil layers or terne metal layers of foil.
A kind of high polymer alloy waterproof roll the most according to claim 1, it is characterised in that: described polymer material layer (1) is HDPE macromolecular sheet material, EVA macromolecular sheet material, PVC macromolecular sheet material or APAO macromolecular sheet material.
A kind of high polymer alloy waterproof roll the most according to claim 1, it is characterised in that: described oxidation-resistant material layer (2) is the material layer of copper antioxidant, iron antioxidant, tin antioxidant, lead antioxidant, aluminum antioxidant agent or the slicker solder antioxidant corresponding with alloy plate layer (3) material.
A kind of high polymer alloy waterproof roll the most according to claim 1, it is characterised in that: the described water-tight corrosion-proof self-adhesive bed of material (4) is made up of the talcum powder of the thermoplastic styrene butadiene rubber that percentage by weight is 28%, 34% aromatic naphtha, the solid thermoplastics acrylic resin of 19%, the resistance rust preservative of 4% and 15%.
A kind of high polymer alloy waterproof roll the most according to claim 1, it is characterised in that: the both sides of high polymer alloy waterproof roll lay one layer of protective cloth (6) the most respectively.
A kind of high polymer alloy waterproof roll the most according to claim 6, it is characterised in that: described protective cloth (6) is non-woven fabrics, chemical fabric, glass-fiber-fabric or woven cloth.
8. the production method of a kind of high polymer alloy waterproof roll being applied to described in claim 1～7 any one, it is characterised in that specific make step is as follows:
Step one, each composition of water-tight corrosion-proof self-adhesion sizing material is weighed by proportioning after put into hot melt case (11) and carry out melten gel；
Step 2, the plastics of polymer material layer (1), rubber and additive will be formed in loading blender (7), it will be uniformly mixed the mixed material forming macromolecular material；
Step 3, preheating extrusion equipment (9), be heated to 140～190 degree by extrusion equipment by rear to front；
Step 4, with charging equipment (8), the mixed material of the macromolecular material in blender (7) is squeezed into extrusion equipment (9), after material dispenser, be extruded into thin layer macromolecular material from extrusion equipment；
Step 5, thin layer macromolecular material is caused between the first rolling of roll unit (10) and the second rolling, carry out prolonging pressure, form macromolecular sheet material；
Step 6, be coated in the both sides of alloy plate layer oxidation-resistant material layer (2) formed alloy plate layer (3)；
The alloy plate layer (3) that step 7, macromolecular sheet material step 5 obtained and step 6 obtain carries out compound pressure of prolonging, formation composite sheet between the second rolling and the 3rd rolling；
Step 8, by composite sheet traction to application system apply water-tight corrosion-proof self-adhesion sizing material, during this period, application system must connect hot melt case (11), treat that hot melt adhesive temperature rises to 160 DEG C, the water-tight corrosion-proof self-adhesion sizing material after fusing is squeezed into application system and is coated becoming the water-tight corrosion-proof self-adhesive bed of material (4)；
Step 9, deposited silicon oil membrane: silicon oil membrane is applied on the surface of the composite sheet after step 8 being processed；
Step 10, being entered cooling flattening system (12), deviation-rectifying system (13) by hauling machine, finally cut to cutting equipment (14), rolling is molded laggard row finished product packing.
The production method of a kind of high polymer alloy waterproof roll the most according to claim 8, it is characterised in that: described step 3 or four extrusion equipment (9) be Single screw extrusion equipment or twin-screw extrusion equipment.
The production method of a kind of high polymer alloy waterproof roll the most according to claim 8, it is characterised in that: it is that one side applies or two-sided deposited when described step 8 applies the water-tight corrosion-proof self-adhesive bed of material.
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