CN110028690A - Metal uvioresistant root resistance polymer membranes and its production equipment and technique - Google Patents
Metal uvioresistant root resistance polymer membranes and its production equipment and technique Download PDFInfo
- Publication number
- CN110028690A CN110028690A CN201910428065.9A CN201910428065A CN110028690A CN 110028690 A CN110028690 A CN 110028690A CN 201910428065 A CN201910428065 A CN 201910428065A CN 110028690 A CN110028690 A CN 110028690A
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- Prior art keywords
- metal
- metal powder
- uvioresistant
- root resistance
- polymer membranes
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- 239000002184 metal Substances 0.000 title claims abstract description 137
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 137
- 229920005597 polymer membrane Polymers 0.000 title claims abstract description 27
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 238000000034 method Methods 0.000 title abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 103
- 229920002521 macromolecule Polymers 0.000 claims abstract description 31
- 229910002114 biscuit porcelain Inorganic materials 0.000 claims abstract description 21
- 239000004744 fabric Substances 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims description 43
- 239000002245 particle Substances 0.000 claims description 40
- 239000000758 substrate Substances 0.000 claims description 30
- 238000001125 extrusion Methods 0.000 claims description 21
- 239000010953 base metal Substances 0.000 claims description 15
- 230000006835 compression Effects 0.000 claims description 11
- 238000007906 compression Methods 0.000 claims description 11
- 239000010410 layer Substances 0.000 claims description 8
- 238000000748 compression moulding Methods 0.000 claims description 7
- 238000005516 engineering process Methods 0.000 claims description 6
- -1 polyethylene Polymers 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 5
- 229920000573 polyethylene Polymers 0.000 claims description 5
- 239000012790 adhesive layer Substances 0.000 claims description 4
- 230000003139 buffering effect Effects 0.000 claims description 4
- 229920001903 high density polyethylene Polymers 0.000 claims description 4
- 239000004700 high-density polyethylene Substances 0.000 claims description 4
- 229920002397 thermoplastic olefin Polymers 0.000 claims description 4
- 230000001737 promoting effect Effects 0.000 claims description 3
- 238000010257 thawing Methods 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims 1
- 229920001596 poly (chlorostyrenes) Polymers 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 12
- 230000003712 anti-aging effect Effects 0.000 abstract description 4
- 150000002739 metals Chemical class 0.000 abstract description 2
- 230000008447 perception Effects 0.000 abstract description 2
- 239000002585 base Substances 0.000 description 28
- 238000010586 diagram Methods 0.000 description 9
- 239000011888 foil Substances 0.000 description 7
- 230000032683 aging Effects 0.000 description 6
- 238000009434 installation Methods 0.000 description 5
- 238000000576 coating method Methods 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000003796 beauty Effects 0.000 description 2
- 229920005549 butyl rubber Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 150000001875 compounds Chemical group 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000013528 metallic particle Substances 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/241—Polyolefin, e.g.rubber
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/241—Polyolefin, e.g.rubber
- C09J7/243—Ethylene or propylene polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/245—Vinyl resins, e.g. polyvinyl chloride [PVC]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/26—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment
- C08J2323/28—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
Abstract
The invention discloses a kind of metal uvioresistant root resistance polymer membranes and its production equipments and technique, pass through the metal bisque combined closely at one layer generated above of waterproof roll with the macromolecule base of waterproof, by the uvioresistant of waterproof roll, anti-aging and root resistance performance significantly improves, and significantly extend the service life of waterproof roll, the metal bisque on surface more makes waterproof roll surface have significant identification, great aesthetic effect, cloth is spread on different location to various metals powder respectively, it may be constructed varied pattern being worth with aesthetic feeling and commercial propaganda, revolutionize the external perception of waterproof roll, make it while completing waterproof action as the extraneous adornment object of building.
Description
Technical field
The present invention relates to field of waterproof materials, concretely relate to a kind of metal uvioresistant root resistance macromolecule waterproof roll
Material and its production equipment and technique.
Background technique
Current waterproof roll is layer structure, single layer high molecular material or multi-layer compound structure, multilayered structure one
As crimp and be integrated with the laminating mode of strengthening material using high molecular material sheet material, strengthening material is generally determined according to the scene of application
Fixed, for the occasion of the plantation such as roof plant, waterproof roll needs to puncture ability with root resistance, and the root resistance of general waterproof roll is
Using the compound method of metal foil, metal foil mostly uses aluminium foil or copper foil, still, regardless of metal foil, itself and it is high
The affinity of molecular material is very poor, bonds after being heated by high molecular material with metal foil, bond strength is very low, actually makes
Only 2-3 just will appear the situation that metal foil is separated with high molecular material, metal foil is broken in.
For exposed waterproof roll, the adverse circumstances such as solar radiation, wind and weather are born, to it under outdoor solar light
Anti-uv-ray and ageing resistance requirement are very high, and the ageing-resistant performance of high molecular material itself is very low, needs to add big
Age resister and ultraviolet ray-resistant material, or one layer of antiaging coatings of covering are measured, even if in this way, the outdoor exposed waterproof roll used
Material anti-uv-ray is not also strong, and the service life is generally shorter, generally with regard to 3-5.Moreover, the additive in waterproof roll is difficult to examine
It surveys, identifies the quality of waterproof roll without intuitive method, waterproof roll is easily palmed off, and is caused largely anti-without addition in the market
The waterproof roll inferior of aging agent is throughout real high quality of products is difficult to find its track.Moreover, more commonly problem appear to is that current
Waterproof roll can be sayed without any beauty.It is exposed that current waterproof roll appearance does not take off black, pale or metal foil
Problem becomes the saboteur of the external beauty of building.There is no a kind of waterproof roll that fine appearance can be presented, people can not be allowed to see
To rear pleasing, more without conveying other fine things ability.
Summary of the invention
It is an object of the invention to overcome the shortcoming of above-mentioned traditional technology, provide one kind can root resistance, it is anti-aging and
Anti-uv-ray is strong, appearance has artistic metal uvioresistant root resistance polymer membranes and its production equipment and work
Skill is realized and is organically combined using the uvioresistant and root resistance effect and macromolecule of metal powder high intensity, efficient, environmentally-friendly and long-life,
Solve the problems, such as that water-proofing time is short.
The purpose of the present invention is what is reached by following technical measures:
Metal uvioresistant root resistance polymer membranes, including macromolecule base, it is characterised in that: in the macromolecule base
Equipped with metal bisque.Macromolecule base is made of high molecular material, and high molecular material can select polyethylene, polyvinyl chloride, chlorine
Change the high molecular materials such as polyethylene, HDPE or thermoplastic polyolefin.Metal has very strong uvioresistant and root resistance effect, utilizes
The uvioresistant and root resistance effect and macromolecule of metal powder high intensity organically combine, efficient, environmentally-friendly and long-life, solve water-proofing time
Short problem.
As a preferred embodiment, the metal bisque is made of metal powder particles and macromolecule base upper surface bonding.
Metal powder particles are tiny, and granularity is thin for 250 mesh or more.Tiny metal powder particles can be very good to bond with macromolecule base,
Partial particulate is all wrapped up by macromolecule base completely into macromolecule base, the most surface of metal powder particles on surface layer, shape
At firm connection, exposed metal powder particles not only have splendid pleasing aesthetic appearance, complete with more strong reflection ultraviolet light
Full isolation ultraviolet light is injected inside macromolecule base, to greatly alleviate the ageing process of high molecular material, makes its service life
It greatly prolongs.Moreover, the feelings of the two separation after the several years will not occur because metal powder particles are completely embedded with macromolecule base
Condition, longer life expectancy reach more than ten years, or even longer time, and in the service life of far super common waterproof roll 3-5, performance is more stable.
Product of the invention is in institute, national building materials industrial building waterproof material product quality supervision and inspection test center
The survey report done shows, heat ageing and artificial climate accelerated ageing obviously exceed national standard, under chemical resistance index, nothing
By being salt treatment, alkali process or acid processing, it is all apparently higher than national standard, shows excellent properties of the invention.And these are excellent
The acquirement of anisotropic energy is obtained after increasing pure physical separation layer i.e. metal bisque merely, and macromolecule is further being improved
Performance of the invention can also be mentioned further on the basis of the formula of base, the addition additives such as age resister and UV resistant agent
It is high.
As a preferred embodiment, the metal bisque includes one or more different metal powder particles.
As a preferred embodiment, the macromolecule base is equipped with self-adhesive layer far from the one side of metal bisque.The self-adhesion
Layer is coated with by pressure sensitive adhesive or butyl rubber.
A kind of equipment for producing above-mentioned metal uvioresistant root resistance polymer membranes, including charging extrusion device
With compression molding device, the charging extrusion device includes promoting the constant temperature charging flood dragon for melting graininess high molecular material and squeezing
The constant temperature extruder head of the high molecular material melted out, the compression molding device includes two compression rollers disposed in parallel, described
Two compression rollers accept the high molecular material and extrusion forming that constant temperature extruder head squeezes out, it is characterised in that: the constant temperature extruder head
Be equipped with metal powder particles between compression roller and dispense device, the metal powder particles dispense device include base metal powder cabin and with
The substrate dispensing device of base metal powder cabin pipeline connection, the substrate dispensing device uniformly dispense metal powder particles to constant temperature extruder head
On high molecular material between compression roller.
As a preferred embodiment, the substrate dispensing device includes the base metal powder buffering for accepting base metal powder cabin
Slot, the substrate for accepting the metal powder particles that base metal powder dashpot overflows dispense plate, and the substrate, which dispenses plate and is equipped with, to be dispensed
The shaped opening of metal powder particles.
As a preferred embodiment, the substrate dispensing device is equipped with substrate shaking device.
As a preferred embodiment, it includes that movement dispenses device that the metal powder particles, which dispense device, and the movement dispenses
Device includes pattern metal powder cabin and the pattern dispensing device that connect with pattern metal powder cabin pipeline, the pattern dispensing device it is continuous or
Person and substrate dispensing device dispense metal powder particles simultaneously.
As a preferred embodiment, it includes carriage that the movement, which dispenses device, and the pattern dispensing device is slidably installed
In on carriage.The carriage is arranged in parallel with strip Opening length direction.
As a preferred embodiment, the pattern dispensing device that the movement dispenses device can be moved along strip Opening length direction
It is dynamic.The pattern dispensing device dispenses metal powder particles phase and answers the substrate dispensing device of position that can stop the cloth for dispensing position
Spread, can also both dispense simultaneously.
The production technology of above-mentioned metal uvioresistant root resistance polymer membranes, includes the following steps:
S1, high molecular material thawing, extrusion sheet;
Metal powder cloth is spread on the sheet material of extrusion by S2;
S3 forms the sheet extrusion for dispensing metal powder.
Wherein, S2 includes at least two metal powders, at least two metal powder respectively cloth be spread on extrusion sheet it is different or
Same position.
By adopting the above-described technical solution, compared with prior art, the invention has the advantages that
The invention discloses a kind of metal uvioresistant root resistance polymer membranes and its production equipments and production technology, pass through
In the metal bisque that one layer generated above of waterproof roll is combined closely with the macromolecule base of waterproof, by the uvioresistant of waterproof roll
Line, anti-aging and root resistance performance significantly improve, and significantly extend the service life of waterproof roll, the metal bisque on surface
More make waterproof roll surface that there is significant identification, great aesthetic effect, cloth is spread on different location to various metals powder respectively, can be with
Varied pattern being worth with aesthetic feeling and commercial propaganda is constituted, the external perception of waterproof roll is revolutionized, makes it complete
At extraneous adornment object while waterproof action as building.
Present invention will be further explained below with reference to the attached drawings and specific embodiments.
Detailed description of the invention
Attached drawing 1 is the structural schematic diagram of metal uvioresistant root resistance polymer membranes embodiment 1 of the present invention.
Attached drawing 2 is the structure amplification signal of metal bisque in metal uvioresistant root resistance polymer membranes of the present invention
Figure.
Attached drawing 3 is the structural schematic diagram of metal uvioresistant root resistance polymer membranes embodiment 2 of the present invention.
Attached drawing 4 is a kind of knot for the apparatus embodiments 3 for producing metal uvioresistant root resistance polymer membranes of the present invention
Structure schematic diagram.
Attached drawing 5 is the enlarged structure schematic diagram that metal powder particles dispense device in the embodiment of the present invention 3.
Attached drawing 6 is the enlarged structure schematic diagram that substrate dispenses plate in the embodiment of the present invention 3.
Attached drawing 7 is the enlarged structure schematic diagram that substrate dispenses plate in the embodiment of the present invention 3.
Attached drawing 8 is a kind of knot for the apparatus embodiments 4 for producing metal uvioresistant root resistance polymer membranes of the present invention
Structure schematic diagram.
Attached drawing 9 is the enlarged structure schematic diagram of pattern dispensing device in the embodiment of the present invention 4.
Attached drawing 10 is the enlarged structure schematic diagram of pattern dispensing device in the embodiment of the present invention 4.
Specific embodiment
Embodiment 1: as shown in figure 1 and 2, metal uvioresistant root resistance polymer membranes, including macromolecule base
1, it is characterised in that: the macromolecule base 1 is equipped with metal bisque 2.Macromolecule base 1 is made of high molecular material, high score
Sub- material can select the high molecular materials such as polyethylene, polyvinyl chloride, thermoplastic polyolefin, HDPE.
The metal bisque 2 is made of metal powder particles 3 and macromolecule base upper surface bonding.
The metal bisque 2 includes one or more different metal powder particles.
Embodiment 2: as shown in attached drawing 3 and 2, metal uvioresistant root resistance polymer membranes, including macromolecule base
1, the one side of the macromolecule base 1 is equipped with metal bisque 2, and the macromolecule base 1 is equipped with certainly far from the one side of metal bisque 2
Adhesion coating 4.The self-adhesive layer 4 is coated with by pressure sensitive adhesive or butyl rubber.Macromolecule base 1 is made of high molecular material, high score
Sub- material can select the high molecular materials such as polyethylene, polyvinyl chloride, haloflex, thermoplastic polyolefin, HDPE.
The metal bisque 2 is made of metal powder particles 3 and 1 upper surface of macromolecule base bonding.
The metal bisque 2 includes one or more different metal powder particles.
Embodiment 3: as shown in Fig. 4, a kind of for producing above-mentioned metal uvioresistant root resistance polymer membranes
Equipment, including charging extrusion device 20 and compression molding device 30, the charging extrusion device 20 include containing polymeric particles
Polymeric particles hopper 21, accept raise the polymeric particles fallen in molecule particles hopper 21 and the constant temperature that melts propulsion into
Expect flood dragon 22 and squeeze out the constant temperature extruder head 23 of the high molecular material melted, constant temperature feeds flood dragon 22 and includes propulsion electric machine, slows down
Device, auger and the constant temperature heating device for being set in auger periphery, the compression molding device 30 include two disposed in parallel crowded
Pressure roller, two compression rollers accept the high molecular material that constant temperature extruder head 23 squeezes out and extrusion forming, the constant temperature extruder head
It is equipped with metal powder particles between 23 and compression roller and dispenses device 40, it includes base metal powder that the metal powder particles, which dispense device 40,
Storehouse 41 and the substrate dispensing device 42 connecting with 41 pipeline of base metal powder cabin, the substrate dispensing device 42 uniformly dispense metal powder
On grain to the high molecular material between constant temperature extruder head 23 and compression roller.
As shown in attached drawing 5-7, the substrate dispensing device 42 includes the base metal powder buffering for accepting base metal powder cabin 41
Slot 421, the substrate for accepting the metal powder particles that base metal powder dashpot 421 overflows dispense plate 422, and the substrate dispenses plate
422 include that the fixations of bottom dispense the activity on plate 4221 and top and dispense plate 4222, and the fixation dispenses plate 4221 and top
Activity dispenses the shaped opening 4223 for being formed between plate 4222 and dispensing metal powder particles.It is adjustable that the activity on top dispenses plate 4222
It is dispensed at a distance from plate 4221 with fixation, so that the width of adjustment bar shaped opening 4223, preferably adjusts metal powder falling speed.
As seen in figs. 6 and 7, activity dispenses plate 4222 and is installed on living hinge frame, the shown piston rod for being movably hinged frame and cylinder
Hingedly, it the relatively fixed plate 4221 that dispenses of plate 4222 is dispensed with driving activity opens and closes by the way that the piston rod of cylinder is flexible, adjust strip
Be open 4223 width, or directly closing shaped opening 4223, no longer powder out as shown in Fig. 7.
41 bottom of metal powder cabin is equipped with outflux, current limiting plate is provided on outflux, current limiting plate blocks or limitation metal
The speed of powder outflow, the amount for falling metal powder meet the requirement of metal powder cabin thickness.41 bottom of metal powder cabin is equipped with and is additionally provided with
Powder cabin vibration device 411, powder cabin vibration device 411 guarantee that the even amount of metal powder falls, and metal powder first flows into metal powder dashpot
421, prevent metal powder speed from generating very much splashing fastly, metal powder overflows after being full of in metal powder dashpot 421, and speed can be significant
Slow down, and flow out to substrate and dispense and be more evenly distributed on plate 422, ultimately forms the metal bisque of more homogeneous thickness.In attached drawing not
Outflux and current limiting plate are shown.
The substrate dispensing device 42 is equipped with substrate shaking device 423.Substrate shaking device 423 is placed in metal powder buffering
On slot 421, substrate shaking device 423 makes metal powder shake off speed and be more evenly distributed, and is capable of forming the metal of more homogeneous thickness
Bisque.Vibration device drives eccentric wheel structure using conventional motors, does not repeat.
Embodiment 4: as shown in Fig. 8, it further includes that movement dispenses dress that metal powder particles described in the present embodiment, which dispenses device,
Set, shown movement dispense device include installation base station 47, pattern metal powder cabin 43, powder cabin auger 48, pattern dispensing device 44 and
Mobile device 45, the pattern metal powder cabin 43, powder cabin auger 48, pattern dispensing device 44 are installed on installation base station 47, installation
Base station 47 is installed in rack 46 by mobile device 45, and pattern metal powder cabin 43 passes through powder cabin auger 48 and pattern dispensing device 44
Connection, the metal powder in pattern metal powder cabin 43 are advanced into pattern dispensing device 44 by powder cabin auger 48, when not needing to dispense figure
When case metal powder, powder cabin auger 48 stops promoting.Mode or embodiment 3 can also be closed using simpler closing blade
Middle activity dispenses the structure of plate 4222.
The mobile device 45 pushes pattern dispensing device 44 to move along 4223 length direction of shaped opening, and the pattern dispenses
Device 44 individually continuously dispenses metal powder or dispenses different metal powder particles simultaneously from substrate dispensing device 42.Pattern dispensing device 44
The metallic particles dispensed forms decorative pattern, pattern or the LOGO of design on waterproof roll surface, greatly changes waterproof roll
Aesthetics, make it that there is significant aesthetic feeling and appreciative value under outdoor naked state, metal powder particles will not only fade,
The macromolecule base for protecting bottom simultaneously prevents ultraviolet light etc. from encroaching on.
As shown in attached drawing 8-10, the mobile device 45 includes sliding rail 451, sliding block 452, spur rack 453,454 and of gear
Mobile stepper motor 455, the sliding rail 451 and spur rack 453 are installed in rack 46, and the sliding block 452 cooperates with sliding rail 451
Sliding setting, the gear 454 are equipped with spur rack 453, and gear 454 is installed on mobile stepper motor 455, the peace
Dress base station 47 is installed on sliding block 452, and the mobile stepper motor 455 is installed on installation base station 47, the mobile stepping electricity
The driving installation base station 47 of machine 455 moves along a straight line along sliding rail 451, and sliding rail 451 is arranged in parallel with 4223 length direction of shaped opening.
The metal powder particles of different colours, color are dispensed in different location by pattern dispensing device, so that it may be formed various
Different metal powder layer patterns makes it have the effect of decoration, beautiful, increase identification.
As shown in Fig. 8, self-adhesive coating unit 6 is equipped in the present embodiment after compression molding device 30.Reality can be prepared
Apply the waterproof roll in example 2 with self-adhesive layer.The present embodiment rest part is same as Example 3.
Embodiment 5: a kind of production technology of metal uvioresistant root resistance polymer membranes includes the following steps:
S1, high molecular material thawing, extrusion sheet;
Metal powder cloth is spread on the sheet material of extrusion by S2;
S3 forms the sheet extrusion for dispensing metal powder.
Wherein, S2 includes at least two metal powders, at least two metal powder respectively cloth be spread on extrusion sheet it is different or
Same position.
Claims (10)
1. metal uvioresistant root resistance polymer membranes, including macromolecule base, it is characterised in that: the macromolecule base
It is equipped with metal bisque, the macromolecule base is made of high molecular material, and the high molecular material is polyethylene, polychlorostyrene second
One of alkene, haloflex, thermoplastic polyolefin or HDPE.
2. metal uvioresistant root resistance polymer membranes according to claim 1, it is characterised in that: the metal powder
Layer includes one or more different metal powder particles.
3. metal uvioresistant root resistance polymer membranes according to claim 1, it is characterised in that: the macromolecule
Base is equipped with self-adhesive layer far from the one side of metal bisque.
4. a kind of for producing metal uvioresistant root resistance polymer membranes described in any one of claims 1 to 33
Equipment, including charging extrusion device and compression molding device, the charging extrusion device include promoting to melt graininess macromolecule
The constant temperature charging flood dragon of material and the constant temperature extruder head for squeezing out the high molecular material melted, the compression molding device includes two
Compression roller disposed in parallel, two compression rollers accept the high molecular material that constant temperature extruder head squeezes out and extrusion forming, special
Sign is: being equipped with metal powder particles between the constant temperature extruder head and compression roller and dispenses device, the metal powder particles dispense dress
It sets including base metal powder cabin and the substrate dispensing device being connect with base metal powder cabin pipeline, the substrate dispensing device uniformly dispenses
On metal powder particles to the high molecular material between constant temperature extruder head and compression roller.
5. a kind of equipment for metal uvioresistant root resistance polymer membranes according to claim 4, feature
Be: the substrate dispensing device includes the base metal powder dashpot for accepting base metal powder cabin, accepts base metal powder buffering
The substrate for the metal powder particles that slot overflows dispenses plate, and the substrate dispenses plate and is equipped with the shaped opening for dispensing metal powder particles.
6. a kind of equipment for metal uvioresistant root resistance polymer membranes according to claim 4, feature
Be: the substrate dispensing device is equipped with substrate shaking device.
7. a kind of equipment for metal uvioresistant root resistance polymer membranes according to claim 4, feature
Be: it includes that movement dispenses device that the metal powder particles, which dispense device, and it includes pattern metal powder cabin that the movement, which dispenses device,
The pattern dispensing device being connect with pattern metal powder cabin pipeline, the pattern dispensing device it is continuous or with substrate dispensing device cloth simultaneously
Spread metal powder particles.
8. a kind of equipment for metal uvioresistant root resistance polymer membranes according to claim 7, feature
Be: the pattern dispensing device that the movement dispenses device can be moved along strip Opening length direction.
9. a kind of production technology of metal uvioresistant root resistance polymer membranes as claimed in claim 1 or 2, including walk as follows
It is rapid:
S1, high molecular material thawing, extrusion sheet;
Metal powder cloth is spread on the sheet material of extrusion by S2;
S3 forms the sheet extrusion for dispensing metal powder.
10. a kind of production technology of metal uvioresistant root resistance polymer membranes according to claim 9, feature
It is: where S2 includes at least two metal powders, and to be spread on extrusion sheet similar and different for cloth respectively at least two metal powder
Position.
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