CN104250424B - The seismic physical model material and preparation method of a kind of titanic oxide nano modified epoxy - Google Patents
The seismic physical model material and preparation method of a kind of titanic oxide nano modified epoxy Download PDFInfo
- Publication number
- CN104250424B CN104250424B CN201310258115.6A CN201310258115A CN104250424B CN 104250424 B CN104250424 B CN 104250424B CN 201310258115 A CN201310258115 A CN 201310258115A CN 104250424 B CN104250424 B CN 104250424B
- Authority
- CN
- China
- Prior art keywords
- physical model
- seismic physical
- oxide nano
- titanic oxide
- epoxy resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention discloses the seismic physical model material and preparation method of a kind of silica titanium ground rice modified epoxy.The cast material includes the following components of solidification：The weight portion of epoxy resin 100；The weight portion of 650 type curing agent 80 100；The weight portion of titanic oxide nano 1 10, preferably 56 weight portions.Methods described includes：The component is by prepared described seismic physical model material after consumption solidification.The present invention is obtained the acoustic wave propagation velocity respectively seismic physical model material of 2557m/s 2857m/s by changing titanic oxide nano ratio shared in the epoxy.In the preparation technology using silica nanometer powder doping vario-property epoxy resin, shorten hardening time, effectively raise the efficiency for preparing seismic physical model, and new material has penetrability higher, acoustic wave propagation velocity is effectively raised, is that the making of seismic physical large-sized model is laid a good foundation.
Description
Technical field
The present invention relates to earthquake model field, furtherly, it is related to a kind of titanic oxide nano modified epoxy
Seismic physical model material and preparation method.
Background technology
With going deep into that oil exploration works, difficulties in exploration is also increasing, many geological phenomenons and wave field communication theory
Needs obtain further checking with it is perfect, exploitation method also needs further development, and physical model analogue technique is earth thing
One of key technology of research is managed, is important " assistant " for being engaged in theoretical question research.
Seismic physical modeling technology is in the lab, signal to be excited and received by ultrasonic transducer, so as to utilize
Ultrasonic wave simulation field seismic wave, obtains earthquake simulation data volume, in the lab by seismic physical model, discloses seismic wave
Propagation law in complicated structure.Cast material analogue technique is the basis of forward physical model simulation, domestic at present major
Institutes and colleges and universities mainly with the method for asphalt mixtures modified by epoxy resin moulding by casting, according to high speed stratum needs, prepare velocity of wave 2600m/s's
Material, but epoxide resin material has the following disadvantages：
During one is existing formula, epoxy curing agent typically uses 650 types, because 650 type curing agent activity are low, solidification
Speed is slow, so in model casting process, hardening time is more long, the serious efficiency that have impact on molding.
During two are existing formula, the model highest velocity of wave prepared reaches 2600m/s, it is impossible to enough simulate the need of actual formation
Ask, it is unfavorable to making complicated structure model.
The content of the invention
To solve problems of the prior art, the invention provides a kind of titanic oxide nano modified epoxy
Seismic physical model material and preparation method.Hardening time is shortened, the effect for preparing seismic physical model is effectively raised
Rate, and new material has penetrability higher, effectively raises acoustic wave propagation velocity, is the system of seismic physical large-sized model
Lay a good foundation.
An object of the present invention there is provided a kind of seismic physical model of titanic oxide nano modified epoxy
Material.
Including the following components for solidifying：
The weight portion of epoxy resin 100
650 type curing agent 80-100 weight portions
Titanic oxide nano 1-10 weight portions, preferably 5-6 weight portions.
Epoxy resin is preferably epoxy resin of the viscosity in 11000-14000mPas scopes, more preferably E-51 types asphalt mixtures modified by epoxy resin
Fat.
650 type curing agent molecular weight 1000~1500, light yellow glutinous thick liquid, density (75 DEG C) 0.92~0.96g/
cm³Amine value 230~260mg KOH/g, (75 DEG C of viscosity）3000~1000mPas.Versamid composition is more multiple
It is miscellaneous, containing primary amine, secondary amine and amide groups, can cured epoxy resin at room temperature.
The particle size range of titanic oxide nano is 5-25nm.
Seismic physical model experiment is according to 1 in laboratory by the geological structure and geologic body in field:10000 equal proportions
Diminution is fabricated to geological model, and carries out forward simulation to field method of seismic prospecting with methods such as ultrasonic wave or laser ultrasonics
A kind of earthquake simulation method,
By special seismic physical model Preparation equipment and the seismic physical model material of preparation technology synthesizing new, utilize
Similarity principle builds seismic physical model, and actual physical model is approached by setting up to compare, and explores and understanding complicated structure
And in fracture cave reservoir seismic wave propagation law, for oil-gas exploration and development provides favourable foundation, while being physics mould from now on
The making of type is laid a good foundation.
The investment of seismic physical model experimental study is small, and compared with Mathematical Modeling, its biggest advantage is exactly seismic physical mould
The authenticity of type analog result, is not limited by computational methods, assumed condition, thus seismic physical model is subject to domestic and international each stone
Oily company and the great attention of university.Application of the seismic physical model experiment in oil and gas exploration, exploitation is more and more wider
It is general.It is natural in the oil such as theory of earthquake wave research and complicated structure, slit band detection, crosshole seismic research and deposit dynamic monitoring
Played an important role in gas exploration, development.
After pure epoxy resin solidification, the acoustic wave propagation velocity of material is 2600m/s, is adulterated by titanic oxide nano and changed
Property epoxy resin, be the effective ways for improving epoxide resin material velocity of wave, and because 650 type curing agent activity are relatively low, solidification
Speed is slow, so in model casting process, hardening time is more long, the serious efficiency that have impact on molding.By titanium dioxide
Nano powder doping vario-property epoxy resin seismic physical model, hardening time shortens, and the SVEL of material is increased substantially,
It is the ideal material of seismic physical model preparation, the present invention is first titanic oxide nano materials application to seismic physical model
Material Field, titanic oxide nano can uniformly disperse in the epoxy, will not produce the phenomenon of reunion, use
650 type curing agent, participate in the chemical reaction of doping vario-property material, and the material prepared has good penetrability.Due to choosing
Titanic oxide nano is taken, after doping ratio reaches 5% to titanic oxide nano in the epoxy, i.e. epoxy resin, material
Speed reach maximum 2857m/s, after continuing to increase the doping ratio of titanic oxide nano, the speed of material drops on the contrary
It is low.
The second object of the present invention is to provide a kind of seismic physical model material of titanic oxide nano modified epoxy
The preparation method of material.
Including：The component is by prepared described seismic physical model material after consumption solidification.
Curing can use the common curing in this area, preferably carry out according to the following steps in the present invention：
1. pretreatment
According to the demand of model materials, a certain amount of epoxy resin E51 is placed in 50 DEG C of 1 hours of preheating of baking oven, then
Taking-up vacuumize 30 minutes it is standby.
2. mould pretreatment
After mould is made, one layer of release materials are applied in mould inner surface, it is general to use silicon rubber as release coating,
Deng casting mold again after silicon rubber glue fixed.
3. material configuration
Material is weighed by recipe requirements after processing, first carry out uniformly 650 type curing agent and titanic oxide nano
Stirring, then addition epoxy resin makes it stir wherein.
4. cast model is vacuumized
After material is prepared and stirred, vacuumize process 10 minutes is subsequently poured into packaged mould, when its solidification
It is collapsible die after completely.
The present invention is different by changing titanic oxide nano ratio shared in the epoxy, is received by titanium dioxide
Specimen acoustic wave spread speed prepared by ground rice doping vario-property epoxy resin increases than pure epoxy resin, acoustic wave propagation velocity point
Not Wei 2557m/s-2857m/s seismic physical model material.
The effect of invention
1. the new material SVEL after titanic oxide nano doping vario-property increases, and highest velocity of wave reaches
2857m/s.
2. the new material after titanic oxide nano doping vario-property has good penetrability, and highest can reach
420mv。
3. the new material hardening time shortening after titanic oxide nano doping vario-property, effective to improve seismic physical mould
Type prepares speed.
Brief description of the drawings
The seismic physical model material velocity figure of Fig. 1 embodiments and comparative example
The acoustic wave propagation velocity of the seismic physical model material of Fig. 2 embodiments and comparative example and the graph of a relation of amplitude
The different speed of the seismic physical model material of Fig. 3 embodiments and comparative example and the graph of a relation of curing time
Specific embodiment
With reference to embodiment, the present invention is further illustrated.
Embodiment is raw materials used：
Epoxy resin E51：Phoenix brand E51 epoxy resin, trade mark WRS618, place of production jiangsu wuxi；Viscosity is in 12000-
15000mPas.
650 type curing agent：Changzhou scape China hot oil pump casting manufacture curing agent, the trade mark 650；Place of production changzhou.
Titanic oxide nano：Aladdin titanic oxide nano, trade mark 13463-67-7, place of production Shanghai
Embodiment 1~7
Epoxy resin E51 is placed in 50 DEG C of 1 hours of preheating of baking oven, is then taken out and is vacuumized 30 minutes, exclude asphalt mixtures modified by epoxy resin
Bubble in fat；
Material is weighed by recipe requirements after processing, first carry out uniformly 650 type curing agent and titanic oxide nano
Stirring；
The epoxy resin that will be handled well is added in above-mentioned material, and then stirring makes it be sufficiently mixed uniformly；
After material is prepared and stirred, vacuumize process 10 minutes is subsequently poured into packaged mould, when its solidification
It is collapsible die after completely.
Ju Ti Pei Fang is shown in Table 1.
Table 1.（Consumption is in parts by weight）
Comparative example：
It is the seismic physical model material of the epoxy resin making being modified without titanic oxide nano.Formula is shown in Table 1.
Comparative example uses pure epoxy resin, curing agent to use 650 type curing agent of high activity, and hardening time is long, influence ground
Shake physical model preparation efficiency.
To improve velocity of wave formula, curing agent still selects 650 relatively low type curing agent of activity to embodiment 1~7, due to taking
Titanic oxide nano doping vario-property is formulated so that hardening time shortens, and the effective seismic physical model that improves prepares speed.
Fig. 1 is the seismic physical model material velocity figure of embodiment and comparative example, and expression is mixed by titanic oxide nano
Miscellaneous, the material acoustic wave propagation velocity of material is improved, after doping ratio reaches 5% to titanic oxide nano in the epoxy,
The acoustic wave propagation velocity of material reaches maximum 2857m/s, after continuing the doping ratio of increase titanic oxide nano, material
Speed is reduced on the contrary, by the new seismic physical model material after titanic oxide nano doping vario-property, can effective mould
Intend subsurface rock elastic construction, make physical model, carry out physical simulation of seismic exploration Physical Experiment.
Fig. 2 is the graph of a relation of the acoustic wave propagation velocity with amplitude of the seismic physical model material of embodiment and comparative example, is shaken
The size of width is to represent the power that seismic physical model material permeability ability is represented with ultrasonic excitation seismic wave, illustrates material
Experimental performance is good and bad, and by experimental data, the epoxide resin material that can obtain mesh titanic oxide nano doping content is worn
Permeability is much larger than pure epoxy resin.
Fig. 3 is the graph of a relation of the different speed with curing time of the seismic physical model material of embodiment and comparative example,
The stability of cast material speed is illustrated, the acoustic wave propagation velocity of material prepared by embodiment tends towards stability after 8 days substantially.
Claims (3)
1. a kind of seismic physical model material of titanic oxide nano modified epoxy, it is characterised in that the cast material
It is made up of the following components for solidifying：
The weight portion of epoxy resin 100
650 type curing agent 80-100 weight portions
Titanic oxide nano 5-6 weight portions；
The particle size range of the titanic oxide nano is 5-25nm.
2. the seismic physical model material of titanic oxide nano modified epoxy as claimed in claim 1, its feature exists
In：
The epoxy resin is epoxy resin of the viscosity in 11000-14000mPas scopes.
3. a kind of system of titanic oxide nano modified epoxy seismic physical model material as claimed in claim 1 or 2
Preparation Method, it is characterised in that methods described includes：
The component is by prepared described seismic physical model material after consumption solidification.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310258115.6A CN104250424B (en) | 2013-06-26 | 2013-06-26 | The seismic physical model material and preparation method of a kind of titanic oxide nano modified epoxy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310258115.6A CN104250424B (en) | 2013-06-26 | 2013-06-26 | The seismic physical model material and preparation method of a kind of titanic oxide nano modified epoxy |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104250424A CN104250424A (en) | 2014-12-31 |
| CN104250424B true CN104250424B (en) | 2017-06-16 |
Family
ID=52185691
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310258115.6A Active CN104250424B (en) | 2013-06-26 | 2013-06-26 | The seismic physical model material and preparation method of a kind of titanic oxide nano modified epoxy |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104250424B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110819066B (en) * | 2018-08-13 | 2022-09-06 | 中国石油化工股份有限公司 | Seismic physical model material, seismic physical model and preparation method thereof |
| CN114426755A (en) * | 2020-09-29 | 2022-05-03 | 中国石油化工股份有限公司 | Simulated reservoir physical model material and preparation method thereof |
| CN113321862A (en) * | 2021-05-24 | 2021-08-31 | 黄锦鹏 | Plastic blended ultraviolet-resistant flame-retardant optical cable and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1772809A (en) * | 2005-11-10 | 2006-05-17 | 同济大学 | Polymer material for seismic physical model and its prepn |
| CN101817971B (en) * | 2010-05-27 | 2012-01-11 | 哈尔滨工业大学 | Carbon micro-tube epoxy resin wave-absorbing composite material and preparation method thereof |
| CN102443245B (en) * | 2010-10-12 | 2014-03-12 | 中国石油化工股份有限公司 | Earthquake physical model and preparation method and application thereof |
| CN102040842B (en) * | 2010-10-28 | 2012-12-26 | 华南理工大学 | Autocatalytic crosslinking type organic silicon-epoxy composite material and preparation method thereof |
-
2013
- 2013-06-26 CN CN201310258115.6A patent/CN104250424B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104250424A (en) | 2014-12-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102443245B (en) | Earthquake physical model and preparation method and application thereof | |
| CN105489099B (en) | A kind of fracture reservoir seismic physical model and preparation method thereof | |
| CN104250424B (en) | The seismic physical model material and preparation method of a kind of titanic oxide nano modified epoxy | |
| CN105001594B (en) | A kind of seismic physical model material and model | |
| CN102951875A (en) | Earthquake physical reservoir model, preparation method thereof and application thereof | |
| CN104250425B (en) | The seismic physical model material and preparation method of a kind of silica nanometer powder modified epoxy | |
| CN105863147B (en) | A kind of nano modification high durability concrete material and preparation method thereof | |
| CN103992617B (en) | A kind of doping vario-property epoxy resin seismic physical model material and preparation method | |
| CN102955168B (en) | A kind of seismic physical reservoir model and its preparation method and application | |
| Li et al. | Preparation of artificial pavement coarse aggregate using 3D printing technology | |
| CN105717535B (en) | A kind of fractured model material of variable element and preparation method thereof | |
| CN104250430B (en) | A kind of P25 nano-powders epoxy resin seismic physical model material and preparation method | |
| CN112500028B (en) | Physical property parameter variable seismic physical model, material and model manufacturing method | |
| CN103513268B (en) | A kind of seismic physical reservoir model and its preparation method and application | |
| CN104109346B (en) | The seismic physical model material and preparation method of a kind of silicon powder modified epoxy | |
| CN107513251A (en) | A kind of epoxy resin seismic physical model material of graphene doping vario-property and preparation method thereof | |
| Qian et al. | Grouting Additives and Information-Based Construction of Jet Grouting in the Water-Rich Sand Stratum | |
| CN108659439B (en) | Visual analog simulation material and preparation method thereof | |
| CN103513269A (en) | Seismic physical reservoir model and preparation method and application thereof | |
| CN104231544A (en) | Earthquake physical model material and preparation method thereof | |
| CN113526904B (en) | Stress-sensitive seismic physical model material and preparation method thereof | |
| Qu et al. | Development and Evaluation of Large-Size Phase Change Proppants for Fracturing of Marine Natural Gas Hydrate Reservoirs | |
| CN104513461B (en) | A kind of seismic physical model and its production and use | |
| CN112129612A (en) | Hydrate artificial rock core and preparation method and application thereof | |
| CN105585818B (en) | A kind of nickel modified polyurethane doping epoxy resin seismic physical model material and preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant |