CN104245758B - 聚合引发系统和制造高度反应性烯烃官能聚合物的方法 - Google Patents

聚合引发系统和制造高度反应性烯烃官能聚合物的方法 Download PDF

Info

Publication number
CN104245758B
CN104245758B CN201280069469.XA CN201280069469A CN104245758B CN 104245758 B CN104245758 B CN 104245758B CN 201280069469 A CN201280069469 A CN 201280069469A CN 104245758 B CN104245758 B CN 104245758B
Authority
CN
China
Prior art keywords
group
groups
basic
alkyl
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201280069469.XA
Other languages
English (en)
Chinese (zh)
Other versions
CN104245758A (zh
Inventor
鲁道夫·弗斯
菲利浦·狄米特夫
拉吉夫·库玛
雅各·艾莫特
华均
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Infineum International Ltd
University of Massachusetts Amherst
Original Assignee
Infineum International Ltd
University of Massachusetts Amherst
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Infineum International Ltd, University of Massachusetts Amherst filed Critical Infineum International Ltd
Publication of CN104245758A publication Critical patent/CN104245758A/zh
Application granted granted Critical
Publication of CN104245758B publication Critical patent/CN104245758B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymerization Catalysts (AREA)
  • Prostheses (AREA)
CN201280069469.XA 2011-12-16 2012-12-14 聚合引发系统和制造高度反应性烯烃官能聚合物的方法 Active CN104245758B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/328,569 US9034998B2 (en) 2011-12-16 2011-12-16 Polymerization initiating system and method to produce highly reactive olefin functional polymers
US13/328,569 2011-12-16
PCT/US2012/069822 WO2013090764A1 (en) 2011-12-16 2012-12-14 Polymerization initiating system and method to produce highly reactive olefin functional polymers

Publications (2)

Publication Number Publication Date
CN104245758A CN104245758A (zh) 2014-12-24
CN104245758B true CN104245758B (zh) 2016-10-05

Family

ID=47630508

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280069469.XA Active CN104245758B (zh) 2011-12-16 2012-12-14 聚合引发系统和制造高度反应性烯烃官能聚合物的方法

Country Status (7)

Country Link
US (1) US9034998B2 (enExample)
EP (1) EP2604635B1 (enExample)
JP (1) JP5945605B2 (enExample)
CN (1) CN104245758B (enExample)
CA (1) CA2859545C (enExample)
SG (1) SG11201403295PA (enExample)
WO (1) WO2013090764A1 (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9034998B2 (en) 2011-12-16 2015-05-19 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9156924B2 (en) * 2013-03-12 2015-10-13 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9631038B2 (en) * 2013-10-11 2017-04-25 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9771442B2 (en) * 2015-05-13 2017-09-26 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
WO2017151339A1 (en) 2016-03-03 2017-09-08 Tpc Group Llc Low-fluoride, reactive polyisobutylene
US10047174B1 (en) 2017-06-28 2018-08-14 Infineum International Limited Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10167352B1 (en) 2017-06-28 2019-01-01 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US10174138B1 (en) * 2018-01-25 2019-01-08 University Of Massachusetts Method for forming highly reactive olefin functional polymers
US10829573B1 (en) 2019-05-21 2020-11-10 Infineum International Limited Method for forming highly reactive olefin functional polymers
EP3943518A1 (en) 2020-07-22 2022-01-26 Indian Oil Corporation Limited Polymerization catalyst system and process to produce highly reactive polyisobutylene

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3850897A (en) * 1971-11-26 1974-11-26 Snam Progetti Procedure for the production of polymers and copolymers of isobutylene
EP0436775A2 (en) * 1989-12-28 1991-07-17 Ceskoslovenska akademie ved New Polymers and copolymers and method and initiation system for their preparation
US20040059076A1 (en) * 1999-11-15 2004-03-25 Webb Robert Norman Process for polymerizing cationically polymerizable monomers
CN1753918A (zh) * 2002-12-20 2006-03-29 埃克森美孚化学专利公司 基本上不含长支链的聚合物
WO2006074211A1 (en) * 2005-01-05 2006-07-13 University Of Massachusetts Polymerization of olefins
CN101955558A (zh) * 2009-07-15 2011-01-26 北京化工大学 制备高反应活性聚异丁烯及其共聚物的引发体系
CN102007149A (zh) * 2008-03-25 2011-04-06 雪佛龙奥伦耐有限责任公司 通过用单硫化物猝灭生产亚乙烯基封端的聚烯烃
CN102046671A (zh) * 2008-04-14 2011-05-04 雪佛龙奥伦耐有限责任公司 利用准活性聚烯烃和不饱和酸性试剂制备的共聚物、使用所述共聚物的分散剂及其制备方法
CN102137875A (zh) * 2008-06-24 2011-07-27 南密西西比大学 通过用烷氧基硅烷或醚猝灭制备外烯烃封端的聚烯烃

Family Cites Families (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2682531A (en) 1951-03-31 1954-06-29 Standard Oil Dev Co Zirconium tetrachloride-ether complexes as low temperature polymerization catalyst
DE2702604C2 (de) 1977-01-22 1984-08-30 Basf Ag, 6700 Ludwigshafen Polyisobutene
GB9025839D0 (en) 1990-11-28 1991-01-09 Bp Chem Int Ltd Cationic polymerisation of 1-olefins
US5286823A (en) 1991-06-22 1994-02-15 Basf Aktiengesellschaft Preparation of highly reactive polyisobutenes
US5350819A (en) 1993-02-19 1994-09-27 Exxon Chemical Patents Inc. Carbocationic catalysts and process for using said catalysts
WO1994028036A1 (en) 1993-05-20 1994-12-08 Exxon Chemical Patents Inc. Heterogeneous lewis acid-type catalysts
US5710225A (en) 1996-08-23 1998-01-20 The Lubrizol Corporation Heteropolyacid catalyzed polymerization of olefins
DE19704482A1 (de) 1997-02-06 1998-08-13 Basf Ag Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten
DE19734176A1 (de) 1997-08-07 1999-02-11 Basf Ag Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten
US6407186B1 (en) 1997-12-12 2002-06-18 Basf Aktiengesellschaft Method for producing low-molecular, highly reactive polyisobutylene
CA2330529A1 (en) 1998-06-12 1999-12-16 Univation Technologies Llc Olefin polymerization process using activated lewis acid-base complexes
US6407170B1 (en) 1999-06-24 2002-06-18 The Lubrizol Corporation Dispersants prepared from high polydispersity olefin polymers
US6346585B1 (en) 1999-06-24 2002-02-12 The Lubrizol Corporation Ammonium heteropolyacid catalized polymerization of olefins
US6562913B1 (en) 1999-09-16 2003-05-13 Texas Petrochemicals Lp Process for producing high vinylidene polyisobutylene
DE19952030A1 (de) 1999-10-28 2001-05-03 Basf Ag Verfahren zur Herstellung von hochreaktiven Polyisobutenen
DE10035298A1 (de) 2000-07-18 2002-01-31 Basf Ag Verfahren zur Herstellung von Polysiobutenen
WO2002040553A1 (de) 2000-11-17 2002-05-23 Basf Aktiengesellschaft Verfahren zur desaktivierung und rückgewinnung von bortrifluorid bei der herstellung von polyisobutenen
DE10061715A1 (de) * 2000-12-12 2002-06-13 Basf Ag Verfahren zur Herstellung von Homo- und Copolymeren des Isobutens
DE10118182A1 (de) 2001-04-11 2002-10-17 Basf Ag Verfahren zur Aufarbeitung eines flüssigen Reaktionsaustrages der kationischen Polymerisation von Isobuten
DE10211418A1 (de) 2002-03-15 2003-09-25 Bayer Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
AU2003254173A1 (en) * 2002-08-13 2004-02-25 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
AU2003297458A1 (en) 2002-12-20 2004-07-22 Exxonmobil Chemical Patents Inc. Polymerization processes
DE10303212A1 (de) 2003-01-24 2004-08-05 Basf Ag Verfahren zur Herstellung von Polyisobuten
DE10356768A1 (de) 2003-12-04 2005-07-07 Universität Karlsruhe (TH) - Körperschaft des öffentlichen Rechts Verfahren zur Herstellung von Salzen schwach koordinierender Anionen, derartige Salze sowie deren Verwendung
DE102005055818A1 (de) 2005-11-21 2007-05-24 Basf Ag Verfahren zur Herstellung von hochreaktiven Isobutenhomo- oder -copolymeren mittels metallhaltiger Katalysatorkomplexe
WO2008095933A1 (de) 2007-02-09 2008-08-14 Basf Se Verfahren zur polymerisation von ethylenisch ungesättigten monomeren
TW200846017A (en) * 2007-04-03 2008-12-01 Fancl Corp Apoptosis inhibitory agent
WO2010139684A1 (de) 2009-06-05 2010-12-09 Basf Se Verbindung aus einem protonierten aromaten und einem schwach koordinierenden anion als polymerisationskatalysator für isobuten oder ein isobuten-haltiges monomerengemisch
EP2496613B1 (de) 2009-11-04 2015-07-01 Basf Se Verfahren zur herstellung von homo- oder copolymeren
US8349977B2 (en) 2010-02-17 2013-01-08 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
US9562117B2 (en) 2010-11-30 2017-02-07 Basf Se Preparation of derivatives of isobutene copolymers
US9034998B2 (en) 2011-12-16 2015-05-19 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers
US9156924B2 (en) 2013-03-12 2015-10-13 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3850897A (en) * 1971-11-26 1974-11-26 Snam Progetti Procedure for the production of polymers and copolymers of isobutylene
EP0436775A2 (en) * 1989-12-28 1991-07-17 Ceskoslovenska akademie ved New Polymers and copolymers and method and initiation system for their preparation
US20040059076A1 (en) * 1999-11-15 2004-03-25 Webb Robert Norman Process for polymerizing cationically polymerizable monomers
CN1753918A (zh) * 2002-12-20 2006-03-29 埃克森美孚化学专利公司 基本上不含长支链的聚合物
WO2006074211A1 (en) * 2005-01-05 2006-07-13 University Of Massachusetts Polymerization of olefins
CN102007149A (zh) * 2008-03-25 2011-04-06 雪佛龙奥伦耐有限责任公司 通过用单硫化物猝灭生产亚乙烯基封端的聚烯烃
CN102046671A (zh) * 2008-04-14 2011-05-04 雪佛龙奥伦耐有限责任公司 利用准活性聚烯烃和不饱和酸性试剂制备的共聚物、使用所述共聚物的分散剂及其制备方法
CN102137875A (zh) * 2008-06-24 2011-07-27 南密西西比大学 通过用烷氧基硅烷或醚猝灭制备外烯烃封端的聚烯烃
CN101955558A (zh) * 2009-07-15 2011-01-26 北京化工大学 制备高反应活性聚异丁烯及其共聚物的引发体系

Also Published As

Publication number Publication date
SG11201403295PA (en) 2014-09-26
EP2604635A1 (en) 2013-06-19
JP5945605B2 (ja) 2016-07-05
WO2013090764A1 (en) 2013-06-20
EP2604635B1 (en) 2014-11-26
US9034998B2 (en) 2015-05-19
JP2015504941A (ja) 2015-02-16
US20130158217A1 (en) 2013-06-20
CA2859545C (en) 2019-01-08
CA2859545A1 (en) 2013-06-20
CN104245758A (zh) 2014-12-24

Similar Documents

Publication Publication Date Title
CN104245758B (zh) 聚合引发系统和制造高度反应性烯烃官能聚合物的方法
CN104558304B (zh) 生产高反应性烯烃官能聚合物的聚合引发体系和方法
EP2778181B1 (en) Polymerization initiating system and method to produce highly reactive olefin functional polymers
CA2928600C (en) Polymerization initiating system and method to produce highly reactive olefin functional polymers
CA3031293C (en) Method for forming highly reactive olefin functional polymers
JP7548724B2 (ja) 高度反応性オレフィン機能性ポリマーを形成するための改善された方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant