CN104244915A - Composition having superior foaming ability for sulfate-free shampoo - Google Patents

Composition having superior foaming ability for sulfate-free shampoo Download PDF

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Publication number
CN104244915A
CN104244915A CN201280067407.5A CN201280067407A CN104244915A CN 104244915 A CN104244915 A CN 104244915A CN 201280067407 A CN201280067407 A CN 201280067407A CN 104244915 A CN104244915 A CN 104244915A
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CN
China
Prior art keywords
shampoo compositions
betaine
sulfate
active agent
zwitterionic surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201280067407.5A
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Chinese (zh)
Inventor
裴佑丽
姜秉夏
金大经
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Amorepacific Corp
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Amorepacific Corp
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Filing date
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Application filed by Amorepacific Corp filed Critical Amorepacific Corp
Publication of CN104244915A publication Critical patent/CN104244915A/en
Pending legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients

Abstract

The present invention relates to a composition for a sulfate-free shampoo which does not contain a sulfate-type anionic surfactant. The present invention provides the composition for the sulfate-free shampoo comprising a sultaine-type amphoteric surfactant having a SO3- at an anion-side end. Desirably, the present invention further comprises a betaine-type amphoteric surfactant having a COO- on the anion-side end. The present invention prevents hair damage or color fading from dyed hair by not containing sulfates, and has superior foaming ability by containing the sultaine-type amphoteric surfactant.

Description

Have excellent foamability without sulfate shampoo Compositions
Technical field
The present invention relates to a kind of without sulfate shampoo Compositions, this shampoo Compositions is containing sulfate system surfactant not.More specifically, the present invention relates to a kind of without sulfate shampoo Compositions, this shampoo Compositions by not comprising sulfate system surfactant to minimize fading of hair damages or hair dyeing, and by comprising sulfobetaine type zwitterionic surfactant to provide excellent foamability.
Background technology
Usually, shampoo Compositions contains the surfactant as main component, the additive further containing antiseptic, spice etc. and water.As described surfactant, substantially can use for anion surfactant that is clean and that bubble.In addition, the nonionic surfactant being used for increase-volume and emulsifying (or dispersion) is also often used.
As surfactant, sulfate can be used indispensablely.Especially, existing shampoo Compositions comprises the sulfate series anion surfactant as neccessary composition.Such as, in Korean patent publication 10-2009-0056321 etc., disclose the use as ammonium lauryl sulfate, ten diester ammonium sulfate etc., and in Korean patent publication 10-2010-0082931,10-2010-0082931 etc., disclose the use of sodium lauryl sulphate etc.These sulfate series anion surfactants, compared with other anion surfactants, owing to having excellent foaming and cleaning capacity, are therefore used in shampoo valuably.
But sulfate has problems, namely promote the damage of hair because its institute has strong and stimulating, accelerate fading of hair dyeing particularly due to its excessive cleaning capacity.
[prior art document]
[patent documentation]
Patent documentation 1: Korean patent publication 10-2009-0056321;
Patent documentation 2: Korean Patent grant number 10-0845393;
Patent documentation 1: Korean patent publication 10-2010-0082931.
Summary of the invention
Technical problem
The present invention relates to and provide without sulfate shampoo Compositions, this shampoo Compositions is containing sulfate system surfactant not, thus can minimize the damage of hair or fading of hair dyeing, and provides excellent foamability.
Technical scheme
In total, the invention provides not containing sulfate system surfactant without sulfate shampoo Compositions, this shampoo Compositions wraps in anion end and has SO 3 -sulfobetaine type zwitterionic surfactant.
In one exemplary embodiment, shampoo Compositions of the present invention can be included in anion end further and has COO -betaine type amphoteric ionic surface active agent.
beneficial effect
Sulfate system of the present invention shampoo Compositions provides the effect of fading that can minimize hair damages or hair dyeing by not containing sulfate system surfactant, and by comprising the foamability that sulfobetaine type zwitterionic surfactant also provides excellent.If when it comprises betaine type amphoteric ionic surface active agent further, the effect of the foamability of improvement also can be provided further.
Accompanying drawing explanation
Fig. 1 illustrates the result of the foam height of the shampoo Compositions measuring embodiment.
Detailed description of the invention
Below, the present invention will be illustrated.
Shampoo Compositions of the present invention is without sulfate compositions, said composition comprise for provide cleaning capacity, as the surfactant of active component, but do not comprise sulfate system ionic surface active agent.
Shampoo Compositions of the present invention is included in anion end and has SO 3 -the new type amphoteric ionic surface active agent of (sulfonic group), sulfobetaine type zwitterionic surfactant.Described sulfobetaine type zwitterionic surfactant provides excellent foamability.
In the present invention, as long as described sulfobetaine type zwitterionic surfactant is amphion and have SO at anion end 3 -(sulfonic group), be then not particularly limited.Especially, described sulfobetaine type zwitterionic surfactant can for being selected from cocamidopropyl propyl amide hydroxyl sulfo betaine, cocoyl hydroxyl sulfo betaine, cocoyl sulfobetaines, erucyl amide hydroxysultaine, hydroxyl sulfo betaine, dodecanamide propyl hydroxy sulfo lycine, dodecyl hydroxyl sulfo betaine, dodecyl dimethyl sulfobetaines (lauryl sultaine), metho cocohydroxysultaine xycinnamidopropyl hydroxysultaine, myristamide hydroxysultaine, oleamide propyl group (weight ratio) propyl-dimethyl ammonium, one or more materials in tallow amidoethyl hydroxysultaine etc.
Chemical formula 1 is the structural formula of the cocamidopropyl propyl amide hydroxyl sulfo betaine in above-mentioned sulfobetaine type zwitterionic surfactant.Especially, sulfobetaine type zwitterionic surfactant used in the present invention can for having SO at anion end as shown in chemical formula 1 3 -the material of (sulfonic group).
[chemical formula 1]
In chemical formula 1, R is hydrogen or alkyl.When R in chemical formula 1 is as alkyl, optional alkyl, aryl etc. freely.
The amount of described sulfobetaine type zwitterionic surfactant can account for the 1-30 wt% of the gross weight of shampoo Compositions of the present invention, but is not particularly limited.If when the content of described sulfobetaine type zwitterionic surfactant is less than 1 wt%, be not enough to improve foamability.And if when the content of described sulfobetaine type zwitterionic surfactant is more than 30 wt%, described compositions may scalp irritation and viscosity is high.For all these reasons, more particularly, the amount of described sulfobetaine type zwitterionic surfactant can account for the 5-20 wt% of the gross weight of shampoo Compositions of the present invention.
In one exemplary embodiment, shampoo Compositions of the present invention can comprise betaine type amphoteric ionic surface active agent further.Particularly, shampoo Compositions of the present invention can comprise sulfobetaine type zwitterionic surfactant as zwitterionic surfactant and betaine type amphoteric ionic surface active agent simultaneously.Now, due to synergy, foamability is further improved.
In the present invention, as long as described betaine type amphoteric surfactant is amphion and have COO at anion end -, be then not particularly limited.Such as, described betaine type amphoteric surfactant can for being selected from cocamido propyl betaine, coco betaine, coco dimethyl carboxymethyl betanin, dodecyl dimethyl carboxymethyl betaine, dodecyl dimethyl α-carboxy-ethyl betaine, cetyl dimethyl carboxymethyl betanin, two (2-ethoxy) carboxymethyl betaine of dodecyl, two (2-hydroxypropyl) carboxymethyl betaine of octadecyl, oleyl alcohol dimethyl gamma-carboxypropyl betanin, two (2-hydroxypropyl) α-carboxy-ethyl betaine of dodecyl, cocoyl dimethyl sulfopropyl betaine, octadecyldimethyl azochlorosulfonate propyl lycine, coconut oleoyl amine dimethyl carboxymethyl betaine, coconut oleoyl amine dimethyl sulfopropyl betaine, laurylamide dimethyl carboxymethyl betaine, cetyl amide dimethyl carboxymethyl betaine, one or more materials in octadecyl amide dimethyl sulfopropyl betaine etc.Especially, one or more materials be selected from cocamido propyl betaine, coco betaine etc. can be used.
Chemical formula 2 is the structural formula of the cocamido propyl betaine in above-mentioned betanin.Especially, betanin used in the present invention can be had COO by such as chemical formula 2 is shown in anion end -material.
[chemical formula 2]
In chemical formula 2, R is hydrogen or alkyl.When R in chemical formula 2 is as alkyl, optional alkyl, aryl etc. freely.
The amount of described betaine type amphoteric ionic surface active agent accounts for the 0.1-30 wt% of the gross weight of shampoo Compositions of the present invention, but is not particularly limited.If when the content of described betaine type amphoteric ionic surface active agent is less than 0.1 wt%, the synergy that can improve foamability may be not enough.And, if when the content of described betaine type amphoteric ionic surface active agent is more than 30 wt%, is not further improved, is unfavorable for cost control simultaneously.For all these reasons, more specifically, the amount of described betaine type amphoteric ionic surface active agent can account for the 0.5-20 wt% of the gross weight of shampoo Compositions of the present invention.
Shampoo Compositions of the present invention can comprise sulfobetaine type zwitterionic surfactant and betaine type amphoteric ionic surface active agent simultaneously, and the weight ratio of contained sulfobetaine type zwitterionic surfactant and betaine type amphoteric ionic surface active agent is 1: 0.1-10.0(sulfobetaine type zwitterionic surfactant: betaine type amphoteric ionic surface active agent).Now, due to synergy, excellent foamability can be obtained.
Shampoo Compositions of the present invention can comprise non-ionic surface active agent further, and this non-ionic surface active agent can be used for secondary ability and improves compatibilization, emulsifying (or dispersion) etc.Described non-ionic surface active agent can be selected from, and as the derivant etc. of Sorbitol, amide, amine and these materials, but is not particularly limited.Have as non-ionic surface active agent object lesson, one or more materials in the derivant etc. being selected from dehydrated sorbitol mono-fatty acid ester, sorbitan laurate esters, dodecyl diethylamine oxide, Oleum Cocois oil alkyldimethylamine oxide, cocoanut fatty acid diethanolamide, coconut oil fatty acid monoethanolamide, cocamide diethanolamine and these materials can be used.The amount of described non-ionic surface active agent accounts for the 0.1-20 wt% of shampoo Compositions gross weight of the present invention.If when the content of described non-ionic surface active agent is less than 0.1 wt%, for secondary ability and to improve the effect of compatibilization, emulsifying (or dispersion) etc. not enough.And if when described content is more than 20 wt%, viscosity can raise.
Shampoo Compositions of the present invention can comprise the conventional additive in this area further.Such as, described shampoo Compositions can comprise be selected from antiseptic, spice, pH adjusting agent, viscosity modifier, wetting agent, regulator, antibacterial etc. one or more.The amount of these additives accounts for shampoo Compositions gross weight of the present invention, as 0.001-10 wt%.Surplus as described shampoo Compositions can comprise water (e.g., pure water).In addition, except described additive, described shampoo Compositions can comprise solvent or Chinese herbal medicine extract, fruit extract, vitamin, the pigment etc. of alcohols, ketone etc. further.
Described antiseptic can be selected from methyl parahydroxybenzoate (methyl p-hydroxybenzoate), p-Hydroxybenzoate, Metagin (methylparaben), methyl chloride different plug azoles Lin ketone, Methylisothiazolinone etc., and described spice can be selected from natural perfume material (fruital, medium-height grass medicated incense, minty note etc.) or artificial perfume.And described pH adjusting agent can be selected from mineral acid, organic acid and salt thereof.Such as, described pH adjusting agent can be selected from citric acid, sodium citrate, phosphoric acid, sodium phosphate, sodium hydrogen phosphate etc.
Described viscosity modifier can be selected from coconut oleoyl amine MEA(CME), coconut oleoyl amine DEA(CDE), sodium chloride, ammonium chloride etc., and described wetting agent can be selected from carboxy vinyl polymer, glycols (as, propylene glycol), oils (natural oil, animal oil or plant wet goods) etc.Described regulator can be selected from lanolin alcohol, Wool wax alcohols,ethoxylated, polyquaternary ammonium salt-7, Polyquaternium-10, ethylene glycol monostearate etc., and described antibacterial can be selected from chlorhexidine, triclosan, conazole derivant etc.
As mentioned above, can not sulfate series anion surfactant be contained due to of the present invention without sulfate compositions, described not containing sulfate series anion surfactant can minimize fading of hair damages or hair dyeing without sulfate compositions.And, because it comprises the sulfobetaine type zwitterionic surfactant for replacing sulfate series anion surfactant, and excellent foamability can be shown.In addition, when as mentioned above it comprises sulfobetaine type zwitterionic surfactant and betaine type amphoteric ionic surface active agent, and describedly more excellent foamability can be shown without sulfate compositions by synergy.
Embodiment
Below, the present invention will be described in detail by embodiment and comparative example.But following examples are only as being illustrated as object, and the fact that those skilled in the art tackles the present invention not limited is apparent.
[embodiment and comparative example]
Cleaning-type shampoo Compositions is prepared with the composition in [table 1] and content.
In embodiment 1-2 and comparative example, lauryl sulfosuccinate acid esters disodium and laureth sulfosuccinate disodium can be used to be used to provide cleaning capacity to replace sulfate system surfactant as anion surfactant.Use sulfobetaine type zwitterionic surfactant (cocamidopropyl propyl amide hydroxyl sulfo betaine) further in embodiment 1, and use mutually commensurability sulfobetaine type zwitterionic surfactant (cocamidopropyl propyl amide hydroxyl sulfo betaine) and betaine type amphoteric ionic surface active agent (cocamido propyl betaine) further in example 2.In comparative example, replace sulfobetaine type zwitterionic surfactant time compared with embodiment 1 and use betaine type amphoteric ionic surface active agent (cocamido propyl betaine).In order to accurately contrast foamability, the total content of the surfactant in embodiment 1-2 and comparative example is all set as 18 wt%.
[table 1]
The composition > of < shampoo Compositions
< foamability test >
As follows, the foamability of the shampoo Compositions of testing example 1-2 and comparative example.
(1) prepared in embodiment 1-2 and comparative example each shampoo Compositions mixes with tap water respectively and is prepared into the diluted shampoo Compositions of 1 wt%.
(2) get the diluted shampoo Compositions that 250 mL prepare, then use agitator carry out stirring 40 seconds with optimum speed 600 rpm being used for testing foamability and form foam.
(3) height of the foam formed is measured.Repeat this measurement 3 times to embodiment 1-2 and comparative example respectively, the meansigma methods of its result is shown in [table 2].Its result is also in FIG with diagrammatic representation.
[table 2]
< foamability test result >
As shown in Table 2 and Figure 1, use the foamability of the embodiment 1-2 of sulfobetaines and replacement sulfate system surfactant and only use compared with the foamability of the comparative example of betanin more excellent.And, use the embodiment 2 of sulfobetaines and betanin to show very excellent foamability because of synergy simultaneously.

Claims (6)

1. without a sulfate shampoo Compositions, it comprises: have SO at anion end 3 -sulfobetaine type zwitterionic surfactant.
2. according to claim 1ly it is characterized in that without sulfate shampoo Compositions, the amount of described sulfobetaine type zwitterionic surfactant accounts for the 5-20 wt% of described shampoo Compositions gross weight.
3. according to claim 1ly it is characterized in that without sulfate shampoo Compositions, described shampoo Compositions comprises further: have COO at anion end -betaine type amphoteric ionic surface active agent.
4. according to claim 3ly it is characterized in that without sulfate shampoo Compositions, the amount of described betaine type amphoteric ionic surface active agent accounts for the 0.5-20wt% of described shampoo Compositions gross weight.
5. according to claim 3 without sulfate shampoo Compositions, it is characterized in that, this shampoo Compositions comprises described sulfobetaine type zwitterionic surfactant and betaine type amphoteric ionic surface active agent, and the weight ratio of described sulfobetaine type zwitterionic surfactant and betaine type amphoteric ionic surface active agent is 1: 0.1-10.0.
6. according to any one of Claims 1 to 5 without sulfate shampoo Compositions, it is characterized in that, described sulfobetaine type zwitterionic surfactant is for being selected from cocamidopropyl propyl amide hydroxyl sulfo betaine, cocoyl hydroxyl sulfo betaine, cocoyl sulfobetaines, erucyl amide hydroxysultaine, hydroxyl sulfo betaine, dodecanamide propyl hydroxy sulfo lycine, dodecyl hydroxyl sulfo betaine, dodecyl dimethyl sulfobetaines, metho cocohydroxysultaine xycinnamidopropyl hydroxysultaine, myristamide hydroxysultaine, oleamide propyl group (weight ratio) propyl-dimethyl ammonium, one or more materials in tallow amidoethyl hydroxysultaine.
CN201280067407.5A 2011-11-18 2012-11-15 Composition having superior foaming ability for sulfate-free shampoo Pending CN104244915A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR1020110121104A KR101921630B1 (en) 2011-11-18 2011-11-18 Sulfate-free shampoo composition having improved capacity for forming foam
KR10-2011-0121104 2011-11-18
PCT/KR2012/009627 WO2013073849A1 (en) 2011-11-18 2012-11-15 Composition having superior foaming ability for sulfate-free shampoo

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JP (1) JP2014533683A (en)
KR (1) KR101921630B1 (en)
CN (1) CN104244915A (en)
AU (1) AU2012337567B2 (en)
WO (1) WO2013073849A1 (en)

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JP6987770B2 (en) * 2016-02-16 2022-01-05 ローディア オペレーションズ Sulfate-free personal care composition and how to use the composition
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US10945935B2 (en) 2016-06-27 2021-03-16 The Procter And Gamble Company Shampoo composition containing a gel network
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WO2020035447A1 (en) * 2018-08-13 2020-02-20 Dsm Ip Assets B.V. Sulfate-free cosmetic rinse-off composition comprising a hyperbranched copolymer
JP7328336B2 (en) 2018-12-14 2023-08-16 ザ プロクター アンド ギャンブル カンパニー SHAMPOO COMPOSITION CONTAINING SHEET-FORMED MICROCAPSULES
US11896689B2 (en) 2019-06-28 2024-02-13 The Procter & Gamble Company Method of making a clear personal care comprising microcapsules
US11932448B2 (en) 2020-02-14 2024-03-19 The Procter & Gamble Company Bottle adapted for storing a liquid composition with an aesthetic design suspended therein
US11633072B2 (en) 2021-02-12 2023-04-25 The Procter & Gamble Company Multi-phase shampoo composition with an aesthetic design
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CN106634930B (en) * 2016-12-28 2019-04-19 陕西省石油化工研究设计院 A kind of high temperature high efficiency foam discharging agent

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AU2012337567A1 (en) 2014-06-12
AU2012337567B2 (en) 2017-04-20
KR20130055387A (en) 2013-05-28
WO2013073849A1 (en) 2013-05-23
JP2014533683A (en) 2014-12-15
KR101921630B1 (en) 2018-11-26

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