CN104218220A - Manufacturing method of positive active material for lithium battery - Google Patents
Manufacturing method of positive active material for lithium battery Download PDFInfo
- Publication number
- CN104218220A CN104218220A CN201310218573.7A CN201310218573A CN104218220A CN 104218220 A CN104218220 A CN 104218220A CN 201310218573 A CN201310218573 A CN 201310218573A CN 104218220 A CN104218220 A CN 104218220A
- Authority
- CN
- China
- Prior art keywords
- atom
- lithium
- active material
- cobalt
- lithium battery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
The invention discloses a manufacturing method of a positive active material for a lithium battery, and the manufacturing method is as follows: first, a lithium compound, a compound containing nickel, cobalt and manganese atoms and titanium oxide are mixed for calcining, a calcined lithium composite oxide is milled into powder, and attached to the surface of a lithium battery positive pole, and after electrifying, the lithium composite oxide powder is absorbed on the surface of the lithium battery positive pole to form the positive active material. The manufacturing method is simple, the positive active material is prepared by a an industrially advantageous method, and is convenient and simple.
Description
Technical field
The invention belongs to battery manufacture technical field, be specifically related to a kind of positive pole active material for lithium cell manufacture method, to produce the lithium battery of cycle characteristics excellence.
Background technology
In recent years, along with the universal and miniaturization of the portable machines such as mobile phone, notebook computer, the battery with nonaqueous electrolyte such as lithium battery are progressively used as its power supply.And from tackling nearest environmental problem, the traction-type cell using it as electric automobile etc. also causes concern gradually.As positive pole active material for lithium cell, conventionally extensively adopt LiCoO
2(cobalt acid lithium) is as the material that can form 4V level battery.Use LiCoO
2during as positive active material, discharge capacity is about 160mA/g, is practical as LiCo0
2the cobalt of raw material be scarce resource, and skewness, so Expenses Cost, raw material supplying is unstable.
Summary of the invention
Goal of the invention: the present invention is directed to the deficiencies in the prior art, propose a kind of use and can give lithium battery a kind of positive pole active material for lithium cell manufacture method of excellent cycle characteristics especially.
Technical scheme: a kind of positive pole active material for lithium cell manufacture method, described manufacture method is first by lithium compound, the mode that the compound that comprises nickle atom, cobalt atom and manganese atom and titanium oxide are 1.08-1.12 according to lithium atom with respect to the atomic ratio Li/{Ni+Co+Mn+Ti} of nickle atom, cobalt atom, manganese atom and titanium atom is mixed, and calcining; Again the resulting lithium composite xoide of calcining is milled into powder, invests lithium battery anode surface, after energising, be just adsorbed in lithium battery anode surface.
As preferably, described nickle atom: cobalt atom: the atomic ratio of manganese atom is 1:0.5~1:0.5~5.
As preferably, described calcining heat is 800-1200 ℃.
As preferably, described in comprise nickle atom, manganese atom and cobalt atom compound be cohesion shape complex hydroxide.
Beneficial effect: utilize manufacture method of the present invention simple, this positive active material can be manufactured by industrial favourable method, convenient succinct.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described:
Embodiment 1:
A kind of positive pole active material for lithium cell manufacture method, first by lithium compound, the mode that the compound that comprises nickle atom, cobalt atom and manganese atom and titanium oxide are 1.08 according to lithium atom with respect to the atomic ratio Li/{Ni+Co+Mn+Ti} of nickle atom, cobalt atom, manganese atom and titanium atom is mixed, and calcining; Again the resulting lithium composite xoide of calcining is milled into powder, invests lithium battery anode surface, after energising, be just adsorbed in lithium battery anode surface; Above-mentioned nickle atom: cobalt atom: the atomic ratio of manganese atom is 1:0.5~1:0.5~5; Above-mentioned calcining heat is 800 ℃; The above-mentioned compound that comprises nickle atom, manganese atom and cobalt atom is cohesion shape complex hydroxide.
Embodiment 2:
A kind of positive pole active material for lithium cell manufacture method, first by lithium compound, the mode that the compound that comprises nickle atom, cobalt atom and manganese atom and titanium oxide are 1.10 according to lithium atom with respect to the atomic ratio Li/{Ni+Co+Mn+Ti} of nickle atom, cobalt atom, manganese atom and titanium atom is mixed, and calcining; Again the resulting lithium composite xoide of calcining is milled into powder, invests lithium battery anode surface, after energising, be just adsorbed in lithium battery anode surface; Above-mentioned nickle atom: cobalt atom: the atomic ratio of manganese atom is 1:0.5~1:0.5~5; Above-mentioned calcining heat is 1000 ℃; Stating the compound that comprises nickle atom, manganese atom and cobalt atom is cohesion shape complex hydroxide.
Embodiment 3:
A kind of positive pole active material for lithium cell manufacture method, first by lithium compound, the mode that the compound that comprises nickle atom, cobalt atom and manganese atom and titanium oxide are 1.12 according to lithium atom with respect to the atomic ratio Li/{Ni+Co+Mn+Ti} of nickle atom, cobalt atom, manganese atom and titanium atom is mixed, and calcining; Again the resulting lithium composite xoide of calcining is milled into powder, invests lithium battery anode surface, after energising, be just adsorbed in lithium battery anode surface; Above-mentioned nickle atom: cobalt atom: the atomic ratio of manganese atom is 1:0.5~1:0.5~5; Above-mentioned calcining heat is 800-1200 ℃; The above-mentioned compound that comprises nickle atom, manganese atom and cobalt atom is cohesion shape complex hydroxide.
Claims (4)
1. a positive pole active material for lithium cell manufacture method, it is characterized in that: described manufacture method is first by lithium compound, the mode that the compound that comprises nickle atom, cobalt atom and manganese atom and titanium oxide are 1.08-1.12 according to lithium atom with respect to the atomic ratio Li/{Ni+Co+Mn+Ti} of nickle atom, cobalt atom, manganese atom and titanium atom is mixed, and calcining; Again the resulting lithium composite xoide of calcining is milled into powder, invests lithium battery anode surface, after energising, be just adsorbed in lithium battery anode surface.
2. positive pole active material for lithium cell manufacture method according to claim 1, is characterized in that: described nickle atom: cobalt atom: the atomic ratio of manganese atom is 1:0.5~1:0.5~5.
3. positive pole active material for lithium cell manufacture method according to claim 1, is characterized in that: described calcining heat is 800-1200 ℃.
4. positive pole active material for lithium cell manufacture method according to claim 1, is characterized in that: described in comprise nickle atom, manganese atom and cobalt atom compound be cohesion shape complex hydroxide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310218573.7A CN104218220A (en) | 2013-06-04 | 2013-06-04 | Manufacturing method of positive active material for lithium battery |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310218573.7A CN104218220A (en) | 2013-06-04 | 2013-06-04 | Manufacturing method of positive active material for lithium battery |
Publications (1)
Publication Number | Publication Date |
---|---|
CN104218220A true CN104218220A (en) | 2014-12-17 |
Family
ID=52099507
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310218573.7A Pending CN104218220A (en) | 2013-06-04 | 2013-06-04 | Manufacturing method of positive active material for lithium battery |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104218220A (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1022792A1 (en) * | 1999-01-25 | 2000-07-26 | SANYO ELECTRIC Co., Ltd. | Positive electrode for non-aqueous electrolyte cell and manufacturing method of the same |
CN102479951A (en) * | 2010-11-19 | 2012-05-30 | 日本化学工业株式会社 | Anode material for lithium secondary battery, method of fabricating the same and lithium secondary battery |
-
2013
- 2013-06-04 CN CN201310218573.7A patent/CN104218220A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1022792A1 (en) * | 1999-01-25 | 2000-07-26 | SANYO ELECTRIC Co., Ltd. | Positive electrode for non-aqueous electrolyte cell and manufacturing method of the same |
CN102479951A (en) * | 2010-11-19 | 2012-05-30 | 日本化学工业株式会社 | Anode material for lithium secondary battery, method of fabricating the same and lithium secondary battery |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103840151B (en) | Tertiary cathode material of a kind of special mono-crystalline structures and preparation method thereof | |
WO2017000741A1 (en) | Lithium manganese phosphate-coated lithium nickel cobalt manganese oxide cathode material and preparation method thereof | |
CN105185977B (en) | A kind of preparation method of lithium ion battery negative material | |
CN102082259A (en) | Lithium secondary battery electrodes and production method thereof | |
CN103943822A (en) | Nickel-based positive active material of lithium ion secondary battery and preparation method thereof | |
CN103928668B (en) | Lithium ion battery and preparation method of anode material thereof | |
CN103178252B (en) | A kind of anode material for lithium-ion batteries and preparation method thereof | |
CN103682292B (en) | The lithium titanate material preparation method of high-tap density | |
CN104218241A (en) | Lithium ion battery anode lithium-rich material modification method | |
CN106532041A (en) | Sodium manganese fluosilicate positive electrode material for sodium ion battery and preparation method for sodium manganese fluosilicate positive electrode material | |
CN105428628A (en) | Preparation method of porous spherical high-voltage lithium ion battery positive electrode material | |
CN103715422B (en) | Electrolysis prepares the method for the nickelic system positive electrode of lithium ion battery | |
CN106935830A (en) | A kind of lithium ion battery composite cathode material and its preparation method and application | |
CN103000879A (en) | Preparation method of spinel type lithium-nickel-manganese oxide with one-dimensional porous structure | |
CN102055020A (en) | Method for solving problem of air expansion of power lithium battery with cathode made of lithium titanate | |
CN103441239A (en) | Synthetic method for nanoscale ternary cathode material | |
CN103280576B (en) | The positive electrode of lithium rechargeable battery and manufacture method thereof | |
CN103647059A (en) | Lithium ion battery anode material with coating layer and preparation method thereof | |
CN103078082B (en) | High-volume V2O5 film anode material for lithium ion battery | |
CN104201334A (en) | Lithium-rich manganese-based anode material for lithium ion battery and preparation method | |
CN104716315A (en) | Preparation method of lithium ion batteries cathode material solid solution with core-shell structure | |
CN104218220A (en) | Manufacturing method of positive active material for lithium battery | |
CN104362339A (en) | Pure phase Li2FeSiO4 and preparation method of Li2FeSiO4 carbon-coated modified product | |
CN103956465A (en) | Method for preparing lithium ion battery positive electrode lithium iron borate material by using coprecipitation technology | |
CN103594713A (en) | Manufacturing method of lithium iron phosphate electrode material |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20141217 |