CN104211416A - Skimming equipment in blast furnace tapping process - Google Patents

Skimming equipment in blast furnace tapping process Download PDF

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Publication number
CN104211416A
CN104211416A CN201410443879.7A CN201410443879A CN104211416A CN 104211416 A CN104211416 A CN 104211416A CN 201410443879 A CN201410443879 A CN 201410443879A CN 104211416 A CN104211416 A CN 104211416A
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blast furnace
skimming equipment
equipment
skimming
refractory aggregate
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CN104211416B (en
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吴雪健
杨建�
梁健
张向阳
郭锐
张艳华
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Zhu Aiqing
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Abstract

The invention discloses skimming equipment in a blast furnace tapping process, and belongs to the technical field of slag-iron separation equipment in the blast furnace tapping process. The skimming equipment in the blast furnace tapping process comprises refractory aggregate and a binding agent, wherein the refractory aggregate comprises corundum brick, mullite, zirconite, Suzhou soil, coke, converter wind quenching slag, Newman powder and copper ore; the binding agent comprises asphalt, phenolic resin, pentolite, polyurethane, cellulose acetate, butyl acrylate and guar gum. The baked skimming equipment disclosed by the invention has good abrasive resistance, thermal shock resistance and erosion resistance due to creative component proportion; the service life of the skimming equipment can reach about 50 days under the condition of not repairing, and is greatly prolonged; stable furnace condition and smooth operation of the blast furnace are well ensured; and the production cost of iron and steel enterprises is reduced.

Description

Skimming equipment in a kind of blast furnace casting process
Technical field
The present invention relates to slag sluicing system equipment technical field in blast furnace casting process, more particularly, relate to the skimming equipment in a kind of blast furnace casting process.
Background technology
Blast furnace ironmaking is most widely used iron-smelting process, and mix through the high temperature liquid iron of blast-furnace smelting and slag and flowed out by iron mouth, molten iron is being transported to converter station by hot metal ladle, torpedo tank car after blast furnace casting, carries out converter steelmaking.In order to prevent the objectionable constituent in slag from again entering molten iron, in the process of blast furnace casting, slag sluicing system equipment is needed to be separated high temperature sludge iron.In prior art, the main slag sluicing system equipment adopted is skimmer, is also called sand mouth; Skimmer connects main trough of blast furnace, under connect iron runner, bypass connects slag runner, and in the process of tapping a blast furnace, the slag in main iron hook and molten iron are because of the different natural layering of its density.Slag floats over above molten iron because density is little, is blocked rear then flow to slag runner by skimmer; Molten iron because of below its density sinks to greatly, and flows to iron runner by the gap between skimmer and main iron hook.Realize the slag of high-temperature liquid state, effective separation of iron in process of tapping a blast furnace.Skimmer is in core node position on casting house, is the exclusive node ensureing that slag iron is effectively separated, and is the device promoting that in blast furnace casting process, high-temperature liquid furnace slag, molten iron are effectively separated.
But undergo the mechanical erosion of high temperature liquid iron in skimmer process under arms, the chemical erosion of high temperature furnace slag and intermittent thermal shock are corroded.And three kinds of factor alternating actions, mutually strengthen, greatly reduce the service life of skimmer.Existing skimmer generally adopts the materials such as corundum, silicon carbide, alumina powder and pitch to make, the antiscour of skimmer, corrosion resistance, antistrip performance and thermal shock resistance are poor, make to only have 1-2 month the work-ing life of skimmer, and often within 10-15 days, just need feed supplement once.The frequent repairing of skimmer, usually affects and taps a blast furnace on schedule, causes the checking underproduction, and coke ratio raises.
The work-ing life of existing skimmer is shorter, repairing is frequent, directly affects blast furnace and taps a blast furnace on schedule, extend molten iron and deposit the stove time, not only increase a ton iron cost, bring heavy economical load to iron and steel enterprise, and bring serious potential safety hazard.Therefore, need the material composition improving slag sluicing system equipment in blast furnace casting process badly, make skimming equipment have good antiscour, anti-scour property, thus improve the service life of skimming equipment.
Through patent retrieval, there is relevant technical scheme open.As: a kind of blast-furnace iron runner skimmer precast lintel (CN200910143657.2, Shen Qing Publication day: 2010-12-01), lintel refractory castable is prefabricated forms for it, and come into operation after overbaking, prefabricated component top future insufficiency, the problem that although this application case prevents precast lintel in use causes top tension to ftracture because bottom expanded by heating is elongated, extend skimmer work-ing life, but this application case only improves the structure of skimmer, it does not improve the material composition of skimmer, the service life of skimmer needs to be improved further.
In addition, a kind of blast furnace reclaimed sand mouth material and preparation method thereof (CN201210187866.9, Shen Qing Publication day: 2013-12-11), its component and weight percent content are: its component and weight percent content are: the discarded sial material 15-20% of granularity≤0.088mm, granularity is the quartz sand 20-30% of 1-3mm, the quartz sand 10-20% of granularity≤0.088mm, the clay powder 8-15% of granularity≤0.074mm, the pitch 3-10% of granularity≤1.0mm, the coke powder 7-15% of granularity≤2.0mm, the discarded iron runner material fine powder 10-20% of granularity≤0.088mm, non-hydrate sodium metasilicate: 0.1-3%.Although this application case reduces the production cost of skimming equipment, and make to be fully utilized containing the high alumina brick etc. of aluminium silicon material and iron runner material, the material composition of skimming equipment needs perfect further, and improves the service life of skimming equipment further.
Summary of the invention
1. invent the technical problem that will solve
The object of the invention is to overcome skimming service life of equipment in prior art short, repairing, the deficiency that replacement frequency is large, provide the skimming equipment in a kind of blast furnace casting process, skimming equipment of the present invention is by creationary feed composition proportioning, not only substantially increase the work-ing life of equipment, ensure that the normal production order of blast furnace, and manufacture simple and convenient.
2. technical scheme
For achieving the above object, technical scheme provided by the invention is:
Skimming equipment in a kind of blast furnace casting process of the present invention, is made up of refractory aggregate and bonding agent, and the quality of described bonding agent is the 6%-8% of the quality of refractory aggregate.
Further, each component of described refractory aggregate is by following mass parts composition:
Further, each component of described bonding agent is by following mass parts composition:
Further, the size composition of described corundum brick is: granularity≤0.074mm:30%, 0.074-1.0mm:50%, 1-3mm:20%; The size composition of described mullite is: granularity≤0.074mm:20%, 0.074-1.5mm:40%, 1.5-3.5mm:40%.
Further, the granularity≤0.074mm of described coke.
3. beneficial effect
Adopt technical scheme provided by the invention, compared with existing known technology, there is following unusual effect:
Skimming equipment in a kind of blast furnace casting process of the present invention, the pitch that its bonding agent adopts is pelletted pitch, higher carbon content is utilized to improve the erosion-resisting characteristics of skimming equipment, and carbon element residual more in the space of skimming equipment pouring material, make skimming equipment finer and close, and creationaryly in bonding agent allocate resol into, guar gum, polyurethane(s), cellulose acetate, butyl acrylate and melon glue, substantially increase the adhesive property of bonding agent, itself and refractory aggregate are made skimming equipment according to specific proportioning, make the intensity enhancing of the skimming equipment made, thermoplasticity is high, good stability,
The corundum brick of refractory aggregate of the present invention and mullite adopt different size composition, make the size composition of refractory aggregate more reasonable, and in refractory aggregate, add zircon, Suzhou soil, coke, converter wind quench slag, Newman powder and copper ore, make to toast the skimming equipment made and can resist the mechanical erosion of high temperature liquid iron and the erosion of slag iron, there is good wear resistance, heat-shock resistance and resistance to fouling, thus improve the work-ing life of skimming equipment, greatly reduce the labour intensity of stokehold, ensure that conditions of blast furnace is stablized and direct motion preferably.
Embodiment
For understanding content of the present invention further, below in conjunction with embodiment, the invention will be further described.
Embodiment 1
Skimming equipment in a kind of blast furnace casting process of the present embodiment, is made up of refractory aggregate and bonding agent, and the quality of described bonding agent is 8% of the quality of refractory aggregate; The each component of described refractory aggregate is by following mass parts composition: corundum brick 90kg, mullite 80kg, zircon 18kg, Suzhou soil 15kg, coke 12kg, and converter wind is quenched slag 8kg, Newman powder 2kg and copper ore 2kg.
And be described at this, the size composition of described corundum brick is: granularity≤0.074mm:30% (mass percent), 0.074-1.0mm:50% (mass percent), 1-3mm:20% (mass percent); The size composition of described mullite is: granularity≤0.074mm:20% (mass percent), 0.074-1.5mm:40% (mass percent), 1.5-3.5mm:40% (mass percent); Granularity≤the 0.074mm of described coke.The granularity of the zircon of the present embodiment is 0.5-2.0mm, and the zircon allocating specified proportion into improves the thermal shock resistance of refractory aggregate, improves work-ing life; Described Suzhou soil is the remaining type kaolin of medium-low temperature fluid alteration, and the mass percentage of its composition is: Al 2o 3: 38.5%, SiO 2: 46.6%, other: 14.9%; This Suzhou soil granularity≤2.0mm.
In addition, above-mentioned converter wind slag of quenching converter slag is transported to wind by slag car quench after station, liquid converter slag flows out from the tundish of slag car, the air sprayed by laval nozzle is again dispelled, be broken into particulate state to be converter wind and to quench slag, the quench percent mass of composition of slag of this converter wind is: Al 2o 3: 3.26%, CaO:45.02%, MgO:12.85%, MnO:0.71%, Si 2o:14.61%, TFe:21.22%, f-CaO:0.48%, all the other are inevitable impurity.The mass percentage of above-mentioned Newman meal component is: TFe:62.02%, SiO 2: 5.03%, CaO:0.23%, MnO:0.15%, Al 2o 3: 0.67%, all the other are inevitable impurity, and the granularity of this Newman powder is 2.0-3.5mm.Described copper ore is exploited out from copper mine, and then become higher, the meticulous sand shape copper mine of cupric quality through ore dressing, the granularity of copper ore is 0.5-1.5mm, and this copper ore is the copper ore of black.
The each component of bonding agent of the present embodiment is by following mass parts composition: pitch 80kg, resol 25kg, guar gum 9kg, polyurethane(s) 8kg, cellulose acetate 10kg, butyl acrylate 3kg and melon glue 2kg.What deserves to be explained is, described pitch is pelletted pitch, described polyurethane(s) is containing the general designation of macromolecular cpd repeating carbamate groups on main chain, and it is formed by organic diisocyanate or polyisocyanates and dihydroxyl or polyol addition polymerization.
In addition, the cellulose acetate of the present embodiment is the natural high polymer of the chemical modification obtained after hydroxyl acetic acid esterified in cellulosic molecule, and acetyl content is 38%.Described guar gum is high molecular weight water soluble polymer, and its chemical name is guar hydroxypropyltrimonium ammonium chloride.
Skimming equipment in a kind of blast furnace casting process of the present embodiment, its concrete preparation method is as follows:
Step one: prepare refractory aggregate
(1) corundum brick 90kg is taken by mass fraction, mullite 80kg, zircon 18kg, Suzhou soil 15kg and coke 12kg, joins in stirrer successively by said components, and at stirrer for mixing 25min, stirrer rotating speed is 250r/min, obtains mixture A after mixing;
(2) take converter wind by mass fraction to quench slag 8kg, Newman powder 2kg and copper ore 2kg, and said components joined in mixture A obtained in step (1) successively, stirrer continues mix and blend 20min, prepares refractory aggregate;
Step 2: prepare bonding agent
(1) pitch 80kg is taken by mass fraction, resol 25kg, guar gum 9kg and polyurethane(s) 8kg, join in reactor successively, and be uniformly mixed 20min at the temperature of 55 DEG C, then reactor is first with the heat-up rate intensification 15min of 1 DEG C/min, insulation 10min, again with the heat-up rate intensification 5min of 2 DEG C/min, be warming up to 80 DEG C, prepare mixture B;
(2) take cellulose acetate 10kg by mass fraction, butyl acrylate 3kg and melon glue 2kg, joins in stirrer successively, and stirs 20min, mix to obtain mixture C;
(3) mixture C obtained in step (2) is joined in mixture B obtained in step (1), and continue to be uniformly mixed 30min, obtain bonding agent;
Step 3: bonding agent step 2 prepared joins in the stirrer in step one, wherein the quality of bonding agent is 8% of the quality of refractory aggregate, continues mix and blend 40min, mixes and obtain skimming equipment pouring material;
Step 4: skimming equipment pouring material step 3 made is poured in mould, then toasts, and the method for wherein toasting is as follows:
(1) hyperthermic treatment
First, be warmed up to 150 DEG C with the heat-up rate of 10 DEG C/h, insulation 3h;
Its two, be warmed up to 650 DEG C with the heat-up rate of 25 DEG C/h, insulation 5h;
Its three, be warmed up to 1100 DEG C with the heat-up rate of 35 DEG C/h, insulation 14h;
Finally, be warmed up to 1500 DEG C with the heat-up rate of 30 DEG C/h, insulation 10h;
(2) cooling process
First, cool to 1200 DEG C with the cooling rate of 25 DEG C/h, insulation 5h;
Its two, cool to 700 DEG C with the cooling rate of 40 DEG C/h, insulation 2h;
Its three, cool to 300 DEG C with the cooling rate of 20 DEG C/h, insulation 2h;
Finally, air cooling is to normal temperature, and economy-combat grinds off burr process, namely prepares skimming equipment.
Skimming equipment in a kind of blast furnace casting process of the present embodiment, owing to creationaryly in refractory aggregate having allocated zircon into, Suzhou soil, converter wind quenched slag, Newman powder and copper ore, enhance the high temperature resistance of this skimming equipment, thermal shock resistance and erosion-resisting characteristics, the corundum brick of this refractory aggregate and mullite adopt different size composition, make the size composition of refractory aggregate more reasonable; The pitch that the bonding agent of the present embodiment adopts is pelletted pitch, higher carbon content is utilized to improve the erosion-resisting characteristics of skimming equipment, and carbon element residual more in the space of skimming equipment pouring material, make skimming equipment finer and close, and creationaryly in bonding agent allocate resol, guar gum, polyurethane(s), cellulose acetate, butyl acrylate and melon glue into, substantially increase the adhesive property of bonding agent.
Skimming equipment in a kind of blast furnace casting process of the present invention, refractory aggregate and bonding agent are by creationary component proportion, the perfect pouring material of skimming equipment, then obtain skimming equipment by specific sintering method, this skimming equipment has good wear resistance, heat-shock resistance and resistance to fouling.Substantially increase the service life of blast furnace skimming equipment, skimming equipment reaches 48 days the work-ing life when not repairing, and in use do not need feed supplement, easy for installation, not only greatly reduce the labour intensity of stokehold, and provide safeguard for blast furnace taps a blast furnace on schedule, ensure that conditions of blast furnace is stablized and direct motion.
Embodiment 2
The substance of the present embodiment is with embodiment 1, and its difference is: the quality of the bonding agent of the present embodiment is 7.5% of the quality of refractory aggregate; The each component of described refractory aggregate is by following mass parts composition: corundum brick 85kg, mullite 75kg, zircon 16kg, Suzhou soil 14kg, coke 10kg, and converter wind is quenched slag 6kg, Newman powder 1kg and copper ore 1kg.The each component of bonding agent of the present embodiment is by following mass parts composition: pitch 75kg, resol 20kg, guar gum 8kg, polyurethane(s) 6kg, cellulose acetate 8kg, butyl acrylate 2kg and melon glue 1kg.
Skimming equipment in a kind of blast furnace casting process of the present embodiment, its concrete preparation method is as follows:
Step one: prepare refractory aggregate
(1) corundum brick 85kg is taken by mass fraction, mullite 75kg, zircon 16kg, Suzhou soil 14kg and coke 10kg, joins in stirrer successively by said components, and at stirrer for mixing 22min, stirrer rotating speed is 250r/min, obtains mixture A after mixing;
(2) take converter wind by mass fraction to quench slag 6kg, Newman powder 1kg and copper ore 1kg, and said components joined in mixture A obtained in step (1) successively, stirrer continues mix and blend 20min, prepares refractory aggregate;
Step 2: prepare bonding agent
(1) pitch 75kg is taken by mass fraction, resol 20kg, guar gum 8kg and polyurethane(s) 6kg, join in reactor successively, and be uniformly mixed 20min at the temperature of 55 DEG C, then reactor is first with the heat-up rate intensification 15min of 1 DEG C/min, insulation 10min, again with the heat-up rate intensification 5min of 2 DEG C/min, be warming up to 80 DEG C, prepare mixture B;
(2) take cellulose acetate 8kg by mass fraction, butyl acrylate 2kg and melon glue 1kg, joins in stirrer successively, and stirs 20min, mix to obtain mixture C;
(3) mixture C obtained in step (2) is joined in mixture B obtained in step (1), and continue to be uniformly mixed 30min, obtain bonding agent;
Step 3: bonding agent step 2 prepared joins in the stirrer in step one, wherein the quality of bonding agent is 7.5% of the quality of refractory aggregate, continues mix and blend 35min, mixes and obtain skimming equipment pouring material;
Step 4: skimming equipment pouring material step 3 made is poured in mould, then toasts, and the method for wherein toasting is as follows:
(1) hyperthermic treatment
First, be warmed up to 150 DEG C with the heat-up rate of 10 DEG C/h, insulation 3h;
Its two, be warmed up to 650 DEG C with the heat-up rate of 25 DEG C/h, insulation 5h;
Its three, be warmed up to 1100 DEG C with the heat-up rate of 35 DEG C/h, insulation 14h;
Finally, be warmed up to 1500 DEG C with the heat-up rate of 30 DEG C/h, insulation 10h;
(2) cooling process
First, cool to 1200 DEG C with the cooling rate of 25 DEG C/h, insulation 5h;
Its two, cool to 700 DEG C with the cooling rate of 40 DEG C/h, insulation 2h;
Its three, cool to 300 DEG C with the cooling rate of 20 DEG C/h, insulation 2h;
Finally, air cooling is to normal temperature, and economy-combat grinds off burr process, namely prepares skimming equipment.
Skimming equipment in a kind of blast furnace casting process of the present invention, refractory aggregate and bonding agent are by creationary component proportion, the perfect pouring material of skimming equipment, then obtain skimming equipment by specific sintering method, this skimming equipment has good wear resistance, heat-shock resistance and resistance to fouling.Substantially increase the service life of blast furnace skimming equipment, skimming equipment reaches 51 days the work-ing life when not repairing, and in use do not need feed supplement, easy for installation, not only greatly reduce the labour intensity of stokehold, and provide safeguard for blast furnace taps a blast furnace on schedule, ensure that conditions of blast furnace is stablized and direct motion.
Embodiment 3
The substance of the present embodiment is with embodiment 1, and its difference is: the quality of the bonding agent of the present embodiment is 6% of the quality of refractory aggregate; The each component of described refractory aggregate is by following mass parts composition: corundum brick 80kg, mullite 60kg, zircon 14kg, 12 parts, Suzhou soil, coke 8kg, and converter wind is quenched slag 5kg, Newman powder 1kg and copper ore 1kg; The each component of bonding agent of the present embodiment is by following mass parts composition: pitch 70kg, resol 10kg, guar gum 5kg, polyurethane(s) 5kg, cellulose acetate 7kg, butyl acrylate 2kg and melon glue 1kg.
Skimming equipment in a kind of blast furnace casting process of the present embodiment, its concrete preparation method is as follows:
Step one: prepare refractory aggregate
(1) corundum brick 80kg is taken by mass fraction, mullite 60kg, zircon 14kg, Suzhou soil 12kg and coke 8kg, joins in stirrer successively by said components, and at stirrer for mixing 20min, stirrer rotating speed is 250r/min, obtains mixture A after mixing;
(2) take converter wind by mass fraction to quench slag 5kg, Newman powder 1kg and copper ore 1kg, and said components joined in mixture A obtained in step (1) successively, stirrer continues mix and blend 20min, prepares refractory aggregate;
Step 2: prepare bonding agent
(1) pitch 70kg is taken by mass fraction, resol 10kg, guar gum 5kg and polyurethane(s) 5kg, join in reactor successively, and be uniformly mixed 20min at the temperature of 55 DEG C, then reactor is first with the heat-up rate intensification 15min of 1 DEG C/min, insulation 10min, again with the heat-up rate intensification 5min of 2 DEG C/min, be warming up to 80 DEG C, prepare mixture B;
(2) take cellulose acetate 7kg by mass fraction, butyl acrylate 2kg and melon glue 1kg, joins in stirrer successively, and stirs 20min, mix to obtain mixture C;
(3) mixture C obtained in step (2) is joined in mixture B obtained in step (1), and continue to be uniformly mixed 30min, obtain bonding agent;
Step 3: bonding agent step 2 prepared joins in the stirrer in step one, wherein the quality of bonding agent is 6% of the quality of refractory aggregate, continues mix and blend 30min, mixes and obtain skimming equipment pouring material;
Step 4: skimming equipment pouring material step 3 made is poured in mould, then toasts, and the method for wherein toasting is as follows:
(1) hyperthermic treatment
First, be warmed up to 150 DEG C with the heat-up rate of 10 DEG C/h, insulation 3h;
Its two, be warmed up to 650 DEG C with the heat-up rate of 25 DEG C/h, insulation 5h;
Its three, be warmed up to 1100 DEG C with the heat-up rate of 35 DEG C/h, insulation 14h;
Finally, be warmed up to 1500 DEG C with the heat-up rate of 30 DEG C/h, insulation 10h;
(2) cooling process
First, cool to 1200 DEG C with the cooling rate of 25 DEG C/h, insulation 5h;
Its two, cool to 700 DEG C with the cooling rate of 40 DEG C/h, insulation 2h;
Its three, cool to 300 DEG C with the cooling rate of 20 DEG C/h, insulation 2h;
Finally, air cooling is to normal temperature, and economy-combat grinds off burr process, namely prepares skimming equipment.
Skimming equipment in a kind of blast furnace casting process of the present invention, refractory aggregate and bonding agent are by creationary component proportion, the perfect pouring material of skimming equipment, then obtain skimming equipment by specific sintering method, this skimming equipment has good wear resistance, heat-shock resistance and resistance to fouling.Substantially increase the service life of blast furnace skimming equipment, skimming equipment reaches 47 days the work-ing life when not repairing, and in use do not need feed supplement, easy for installation, not only greatly reduce the labour intensity of stokehold, and provide safeguard for blast furnace taps a blast furnace on schedule, ensure that conditions of blast furnace is stablized and direct motion.

Claims (5)

1. the skimming equipment in blast furnace casting process, is characterized in that: be made up of refractory aggregate and bonding agent, and the quality of described bonding agent is the 6%-8% of the quality of refractory aggregate.
2. the skimming equipment in a kind of blast furnace casting process according to claim 1, is characterized in that: each component of described refractory aggregate forms by following mass parts:
3. the skimming equipment in a kind of blast furnace casting process according to claim 1 and 2, is characterized in that: each component of described bonding agent forms by following mass parts:
4. the skimming equipment in a kind of blast furnace casting process according to claim 2, is characterized in that: the size composition of described corundum brick is: granularity≤0.074mm:30%, 0.074-1.0mm:50%, 1-3mm:20%; The size composition of described mullite is: granularity≤0.074mm:20%, 0.074-1.5mm:40%, 1.5-3.5mm:40%.
5. the skimming equipment in a kind of blast furnace casting process according to claim 2, is characterized in that: the granularity≤0.074mm of described coke.
CN201410443879.7A 2014-09-02 2014-09-02 Skimming equipment in a kind of blast furnace casting process Expired - Fee Related CN104211416B (en)

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CN114956839A (en) * 2022-04-18 2022-08-30 南京联合荣大工程材料有限责任公司 Baffle plate for skimmer and preparation method thereof

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CN101407424A (en) * 2007-10-08 2009-04-15 联合矿产(天津)有限公司 Low-dust unshaped refractory
CN102773406B (en) * 2012-07-26 2015-05-27 汉川市石金科技有限公司 Refractory aggregate of casting coating recycled from old shell powder through investment casting
CN103255246B (en) * 2013-04-27 2014-08-13 新疆八一钢铁股份有限公司 Technology for preventing slag ladle from cracking
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114956839A (en) * 2022-04-18 2022-08-30 南京联合荣大工程材料有限责任公司 Baffle plate for skimmer and preparation method thereof

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