CN104207336A - Thick-stitch roving-based silica gel antiskid room socks and preparation method thereof - Google Patents

Thick-stitch roving-based silica gel antiskid room socks and preparation method thereof Download PDF

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Publication number
CN104207336A
CN104207336A CN201410368404.6A CN201410368404A CN104207336A CN 104207336 A CN104207336 A CN 104207336A CN 201410368404 A CN201410368404 A CN 201410368404A CN 104207336 A CN104207336 A CN 104207336A
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fiber
silica
socks
bodkin
rove
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CN104207336B (en
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陈志鹏
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ZHEJIANG MENGNA HOSIERY CO Ltd
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ZHEJIANG MENGNA HOSIERY CO Ltd
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Abstract

The invention relates to a pair of thick-stitch roving-based silica gel antiskid room socks. According to the thick-stitch roving-based silica gel antiskid room socks, the technical defects that the room socks in the prior art easily cause slip, are unstable in pattern and poor in ventilation and comfort can be solved by combining special blended short-fiber yarns and filament raw materials and combining a weft weaving thick-stitch technical process and finished product antiskid after-arrangement technology, and good effects of skid prevention, stable pattern, ventilation and comfort in the household application process can be realized.

Description

A kind of floor sock based on bodkin rove, silica-gel antiskid and preparation method thereof
Technical field
The invention belongs to socks processing technique field, particularly the machining field of floor sock, especially relate to a kind of anti-skidding, version type is stablized, the ventilative and comfortable floor sock based on bodkin rove, silica-gel antiskid and preparation method thereof.
 
Background technology
Regular socks does not have antiskid function, and people, in everyday general purpose, do not have non-skid feature, is through on pin, particularly floor sock, easily skids, inconvenience walking.
Along with spinning, weave, the lifting of the continuous advancement of Final finishing industrial technology and people's living standard, wear washability and get more and more, people pay attention to comfortableness and the ergonomics performance of socks gradually, in order to adapt to consumer demand, adopt new raw material can produce various Fresh fats material in conjunction with new spinning technology, improved by the hindlimb unload that matches again, increase, improving product wear function, making product cater to market development demand, is also the development trend of new product from now on.
The open invention book CN201110042415.1 of Chinese patent relates to a kind of antislip socks, is provided with degree of tightness part at the middle part of socks body and the narrow positions of arch of foot.But degree of tightness position can only be play to fit tightly pin recess position, and its non-skid property is very limited.
Chinese patent 201120332174.X discloses a kind of new-type antiskid socks, it is characterized in that socks lower front, arch of the foot position left and right sides is pasted with honeycomb sheet respectively.But these socks adopt common raw material to knit system, and are not suitable for use in household floor sock, and the aspect problems such as honeycomb sheet existence and stability, persistence and comfortableness.
Chinese patent 201220214919.7 relates to a kind of woman style antislip socks, comprise cashmere shell-fabric socks body, lateral surface bottom cashmere shell-fabric socks body is provided with the anti-skidding salient point of circular flexible glue of many row's equidistant arrangement, the anti-skidding salient point Heterogeneous Permutation of the adjacent two circular flexible glue of row, the diameter of the anti-skidding salient point of each circular flexible glue is between 6-15mm.But these socks adopt common raw material to knit system, and are not suitable for use in household floor sock, and flexible glue is compared with silica gel, there is the defect such as poor toughness, heat-resisting cold tolerance difference.
Chinese patent 201120136196.9 provides a kind of anti-slipping floor sock for children, and described socks body is provided with non-slip process structure, and described raised structures is arranged on bottom socks body and adopts some glue, and described rib collar is arranged on ankle position, and arranges fixed band.These socks do not make improvement in raw material, and as the comfortableness of floor sock, gas permeability aspect bad, and some glue material used, mode also do not form concrete scheme.
 
Summary of the invention
The object of the invention is to solve that floor sock of the prior art easily slips, the technological deficiency of the unstable and ventilative comfortableness difference of version type and provide a kind of anti-skidding, version type is stablized, the ventilative and comfortable floor sock based on bodkin rove, silica-gel antiskid.
Another object of the present invention be in order to provide a kind of anti-skidding, version type is stablized, the preparation method of the ventilative and comfortable floor sock based on bodkin rove, silica-gel antiskid.
In order to realize above-mentioned order ground, the present invention by the following technical solutions:
Based on a floor sock for bodkin rove, silica-gel antiskid, this floor sock based on bodkin rove, silica-gel antiskid comprise blend spun yarn and filament raw material combines and the knitting socks of anti-skidding Final finishing; Described spun yarn is formed by acrylic fibers, terylene, polyamide fibre and special health fiber blend, and described long filament is made up of terylene, spandex covered yarn, and described special health fiber is made up of calcium alginate fibre, chitin fiber and carbon nano-fiber.In the technical program, adopt high bactericidal property, high hygroscopic property, highly-flexible performance by calcium alginate fibre, the silver ion that chitin fiber and carbon nano-fiber are equipped with efficient sterilizing is mixed, again with acrylic fibers, terylene, polyamide fibre, filament raw material makes socks, then by anti-skidding for socks Final finishing, there is excellent snugness of fit, skid resistance, wear, gas permeability, solve general floorings socks gas permeability, wear, anti-skidding persistent form, the advantages such as comfortableness, outer chemical-fibres filaments, the cotton short fiber of nexine can combination comfortable with human foot, power-assisted foot flexible motion, its bactericidal effect is superior simultaneously, prevent bacteriological infection and eliminating bacteria, make it there is no bacteriological infection and keep the intact of foot, there is very strong sterilizing ability and suck ability, and it is very soft, do not injure skin, the diseases such as beriberi pin moss can be prevented.
As preferably, described bodkin be knitting machine below 96 pins, rove yarn count is at 4S-8S.
As preferably, Final finishing is the particle and the socks strong bonded that silica gel are formed rectangle and distribution at the stocking sole.
As preferably, the ratio of acrylic fibers, terylene, polyamide fibre and special health fiber is 3-4:2-3:3-5:1.
As preferably, described special health fiber is prepared by following methods: by the calcium alginate fibre of 20-25 weight portion, add after 15-20 weight portion chitin fiber mixes with the carbon nano-fiber of 25-30 weight portion and be mixed with mixed solution in the silver ion mixed liquor of dissolved in purified water, wherein in silver ion mixed liquor, the content of silver ion is that 1-1000 microgram often rises, calcium alginate fibre, chitin fiber and carbon nano-fiber are completely infused in ultrasonic vibration 45-60min after silver ion mixed liquor, add ethanol or acetone or isopropyl alcohol after centrifuge dripping to carry out wash-out and dehydrate, solvent is taken out through heated-air drying after drying, thus obtain calcium alginate, what shitosan mixed with nano-sized carbon carries silver-colored fiber.
Based on a preparation method for the floor sock of bodkin rove, silica-gel antiskid, the preparation of the described floor sock based on bodkin rove, silica-gel antiskid is obtained by following step successively:
Step one: the preparation of yarn, the primary raw material of floor sock is that acrylic fibers, polyamide fibre, terylene, special health fiber are with the spun yarn of the ratio blending of 3-4:2-3:3-5:1, described spun yarn line density is 4S-8S, and described yarn twist is 426 twists/m-790 twists/m, wherein, special health fiber is prepared by following methods: by the calcium alginate fibre of 20-25 weight portion, add after 15-20 weight portion chitin fiber mixes with the carbon nano-fiber of 25-30 weight portion and be mixed with mixed solution in the silver ion mixed liquor of dissolved in purified water, wherein in silver ion mixed liquor, the content of silver ion is that 1-1000 microgram often rises, calcium alginate fibre, chitin fiber and carbon nano-fiber are completely infused in ultrasonic vibration 45-60min after silver ion mixed liquor, add ethanol or acetone or isopropyl alcohol after centrifuge dripping to carry out wash-out and dehydrate, solvent is taken out through heated-air drying after drying, thus obtain calcium alginate, what shitosan mixed with nano-sized carbon carries silver-colored fiber,
Step 2: the preparation of floor sock, by the spun yarn described in step 1 and 150 terylene double-contracting 100D spandex covered yarns, the braiding of covering yarn feeding hosiery machine, in braiding process, spun yarn is all the time at surface weave, terylene spandex covered yarn weaves at socks nexine all the time, rib collar chain order 9-18, socks body chain order 112-168, heel chain order 19-31/19-31, stocking sole chain order 95-126, gap bridge chain order 5-8, toe chain order 19-31/19-31, toe linking region chain order 10-15, under socks after machine, undertoe is sewed up, with 140D wear-resisting polyamide fibre, undertoe is sewed up, socks are shaped, setting temperature 105-108 DEG C, shaping time 3s,
Step 3: the anti-skidding Final finishing of floor sock, socks step 2 obtained carry out silica-gel antiskid process, and the patty silica gel of 4mm diameter carries out rectangular arranged with mutual spacing 6mm, is booked the stocking sole.
As preferably, silica gel Final finishing is enclosed within by socks on the dull and stereotyped pin mould of dimension, makes that the stocking sole is concordant is exposed to outside, by high temperature supply silica gel on the stocking sole.
As preferably, the temperature of high temperature supply is 126-152 DEG C.
The invention has the beneficial effects as follows and adopt high bactericidal property, high hygroscopic property, highly-flexible performance by calcium alginate fibre, the silver ion that chitin fiber and carbon nano-fiber are equipped with efficient sterilizing is mixed, again with acrylic fibers, terylene, polyamide fibre, filament raw material makes socks, then by anti-skidding for socks Final finishing, there is excellent snugness of fit, skid resistance, wear, gas permeability, solve general floorings socks gas permeability, wear, anti-skidding persistent form, the advantages such as comfortableness, outer chemical-fibres filaments, the cotton short fiber of nexine can combination comfortable with human foot, power-assisted foot flexible motion, its bactericidal effect is superior simultaneously, prevent bacteriological infection and eliminating bacteria, make it there is no bacteriological infection and keep the intact of foot, there is very strong sterilizing ability and suck ability, and it is very soft, do not injure skin, the diseases such as beriberi pin moss can be prevented.
 
Detailed description of the invention
For making those skilled in the art know the present invention further, describe the present invention in detail by specific embodiment given below.Except as otherwise noted, the percentage adopted in the present invention is parts by weight.
Embodiment 1
Based on a preparation method for the floor sock of bodkin rove, silica-gel antiskid, the preparation of the described floor sock based on bodkin rove, silica-gel antiskid is obtained by following step successively:
Step one: the preparation of yarn, the primary raw material of floor sock be acrylic fibers, polyamide fibre, terylene, special health fiber with the spun yarn of the ratio blending of 3:2:3:1, described spun yarn line density is 4S, and described yarn twist is 426 twists/m, wherein, special health fiber is prepared by following methods: by the calcium alginate fibre of 20 weight portions, add after 15 weight portion chitin fibers mix with the carbon nano-fiber of 25 weight portions and be mixed with mixed solution in the silver ion mixed liquor of dissolved in purified water, wherein in silver ion mixed liquor, the content of silver ion is that 1 microgram often rises, calcium alginate fibre, chitin fiber and carbon nano-fiber are completely infused in ultrasonic vibration 45min after silver ion mixed liquor, add ethanol or acetone or isopropyl alcohol after centrifuge dripping to carry out wash-out and dehydrate, solvent is taken out through heated-air drying after drying, thus obtain calcium alginate, what shitosan mixed with nano-sized carbon carries silver-colored fiber,
Step 2: the preparation of floor sock, by the spun yarn described in step 1 and 150 terylene double-contracting 100D spandex covered yarns, the braiding of covering yarn feeding hosiery machine, in braiding process, spun yarn is all the time at surface weave, terylene spandex covered yarn weaves at socks nexine all the time, rib collar chain order 9, socks body chain order 112, heel chain order 19/19, stocking sole chain order 95, gap bridge chain order 5, toe chain order 19/19, toe linking region chain order 10, under socks after machine, undertoe is sewed up, with 140D wear-resisting polyamide fibre, undertoe is sewed up, socks are shaped, setting temperature 105 DEG C, shaping time 3s,
Step 3: the anti-skidding Final finishing of floor sock, socks step 2 obtained carry out silica-gel antiskid process, the patty silica gel of 4mm diameter carries out rectangular arranged with mutual spacing 6mm, be booked the stocking sole, silica gel Final finishing is enclosed within by socks on the dull and stereotyped pin mould of dimension, make the stocking sole concordant be exposed to outside, regularly shape by high temperature supply silica gel on the stocking sole, the temperature of high temperature supply is 126 DEG C.
 
Embodiment 2
Based on a preparation method for the floor sock of bodkin rove, silica-gel antiskid, the preparation of the described floor sock based on bodkin rove, silica-gel antiskid is obtained by following step successively:
Step one: the preparation of yarn, the primary raw material of floor sock be acrylic fibers, polyamide fibre, terylene, special health fiber with the spun yarn of the ratio blending of 3:3:4:1, described spun yarn line density is 6S, and described yarn twist is 550 twists/m, wherein, special health fiber is prepared by following methods: by the calcium alginate fibre of 22 weight portions, add after 18 weight portion chitin fibers mix with the carbon nano-fiber of 27 weight portions and be mixed with mixed solution in the silver ion mixed liquor of dissolved in purified water, wherein in silver ion mixed liquor, the content of silver ion is that 500 micrograms often rise, calcium alginate fibre, chitin fiber and carbon nano-fiber are completely infused in ultrasonic vibration 55min after silver ion mixed liquor, add ethanol or acetone or isopropyl alcohol after centrifuge dripping to carry out wash-out and dehydrate, solvent is taken out through heated-air drying after drying, thus obtain calcium alginate, what shitosan mixed with nano-sized carbon carries silver-colored fiber,
Step 2: the preparation of floor sock, by the spun yarn described in step 1 and 150 terylene double-contracting 100D spandex covered yarns, the braiding of covering yarn feeding hosiery machine, in braiding process, spun yarn is all the time at surface weave, terylene spandex covered yarn weaves at socks nexine all the time, rib collar chain order 15, socks body chain order 145, heel chain order 21/21, stocking sole chain order 112, gap bridge chain order 7, toe chain order 21/21, toe linking region chain order 12, under socks after machine, undertoe is sewed up, with 140D wear-resisting polyamide fibre, undertoe is sewed up, socks are shaped, setting temperature 107 DEG C, shaping time 3s,
Step 3: the anti-skidding Final finishing of floor sock, socks step 2 obtained carry out silica-gel antiskid process, the patty silica gel of 4mm diameter carries out rectangular arranged with mutual spacing 6mm, be booked the stocking sole, silica gel Final finishing is enclosed within by socks on the dull and stereotyped pin mould of dimension, make the stocking sole concordant be exposed to outside, regularly shape by high temperature supply silica gel on the stocking sole, the temperature of high temperature supply is 135 DEG C.
 
Embodiment 3
Based on a preparation method for the floor sock of bodkin rove, silica-gel antiskid, the preparation of the described floor sock based on bodkin rove, silica-gel antiskid is obtained by following step successively:
Step one: the preparation of yarn, the primary raw material of floor sock be acrylic fibers, polyamide fibre, terylene, special health fiber with the spun yarn of the ratio blending of 4:3:5:1, described spun yarn line density is 8S, and described yarn twist is 790 twists/m, wherein, special health fiber is prepared by following methods: by the calcium alginate fibre of 25 weight portions, add after 20 weight portion chitin fibers mix with the carbon nano-fiber of 30 weight portions and be mixed with mixed solution in the silver ion mixed liquor of dissolved in purified water, wherein in silver ion mixed liquor, the content of silver ion is that 1000 micrograms often rise, calcium alginate fibre, chitin fiber and carbon nano-fiber are completely infused in ultrasonic vibration 60min after silver ion mixed liquor, add ethanol or acetone or isopropyl alcohol after centrifuge dripping to carry out wash-out and dehydrate, solvent is taken out through heated-air drying after drying, thus obtain calcium alginate, what shitosan mixed with nano-sized carbon carries silver-colored fiber,
Step 2: the preparation of floor sock, by the spun yarn described in step 1 and 150 terylene double-contracting 100D spandex covered yarns, the braiding of covering yarn feeding hosiery machine, in braiding process, spun yarn is all the time at surface weave, terylene spandex covered yarn weaves at socks nexine all the time, rib collar chain order 18, socks body chain order 168, heel chain order 31/31, stocking sole chain order 126, gap bridge chain order 8, toe chain order 31/31, toe linking region chain order 15, under socks after machine, undertoe is sewed up, with 140D wear-resisting polyamide fibre, undertoe is sewed up, socks are shaped, setting temperature 108 DEG C, shaping time 3s,
Step 3: the anti-skidding Final finishing of floor sock, socks step 2 obtained carry out silica-gel antiskid process, the patty silica gel of 4mm diameter carries out rectangular arranged with mutual spacing 6mm, be booked the stocking sole, silica gel Final finishing is enclosed within by socks on the dull and stereotyped pin mould of dimension, make the stocking sole concordant be exposed to outside, regularly shape by high temperature supply silica gel on the stocking sole, the temperature of high temperature supply is 152 DEG C.
The present invention is not limited to above-mentioned particular instance, and do not deviating from spirit of the present invention extremely under real situation, those skilled in the art can make various corresponding change and distortion according to the present invention.These corresponding changes and distortion all should belong within the protection domain of claims of the present invention.

Claims (8)

1. based on a floor sock for bodkin rove, silica-gel antiskid, it is characterized in that, this floor sock based on bodkin rove, silica-gel antiskid comprise blend spun yarn and filament raw material combines and the knitting socks of anti-skidding Final finishing; Described spun yarn is formed by acrylic fibers, terylene, polyamide fibre and special health fiber blend, and described long filament is made up of terylene, spandex covered yarn, and described special health fiber is made up of calcium alginate fibre, chitin fiber and carbon nano-fiber.
2. a kind of floor sock based on bodkin rove, silica-gel antiskid according to claim 1, is characterized in that, described bodkin be knitting machine below 96 pins, rove yarn count is at 4S-8S.
3. a kind of floor sock based on bodkin rove, silica-gel antiskid according to claim 1 and 2, is characterized in that, Final finishing is the particle and the socks strong bonded that silica gel are formed rectangle and distribution at the stocking sole.
4. a kind of floor sock based on bodkin rove, silica-gel antiskid according to claim 1, is characterized in that, the ratio of acrylic fibers, terylene, polyamide fibre and special health fiber is 3-4:2-3:3-5:1.
5. the one according to claim 1 or 2 or 4 is based on bodkin rove, the floor sock of silica-gel antiskid, it is characterized in that, described special health fiber is prepared by following methods: by the calcium alginate fibre of 20-25 weight portion, add after 15-20 weight portion chitin fiber mixes with the carbon nano-fiber of 25-30 weight portion and be mixed with mixed solution in the silver ion mixed liquor of dissolved in purified water, wherein in silver ion mixed liquor, the content of silver ion is that 1-1000 microgram often rises, calcium alginate fibre, chitin fiber and carbon nano-fiber are completely infused in ultrasonic vibration 45-60min after silver ion mixed liquor, add ethanol or acetone or isopropyl alcohol after centrifuge dripping to carry out wash-out and dehydrate, solvent is taken out through heated-air drying after drying, thus obtain calcium alginate, what shitosan mixed with nano-sized carbon carries silver-colored fiber.
6. a preparation method for a kind of floor sock based on bodkin rove, silica-gel antiskid as claimed in claim 1, is characterized in that, the preparation of the described floor sock based on bodkin rove, silica-gel antiskid is obtained by following step successively:
Step one: the preparation of yarn, the primary raw material of floor sock is that acrylic fibers, polyamide fibre, terylene, special health fiber are with the spun yarn of the ratio blending of 3-4:2-3:3-5:1, described spun yarn line density is 4S-8S, and described yarn twist is 426 twists/m-790 twists/m, wherein, special health fiber is prepared by following methods: by the calcium alginate fibre of 20-25 weight portion, add after 15-20 weight portion chitin fiber mixes with the carbon nano-fiber of 25-30 weight portion and be mixed with mixed solution in the silver ion mixed liquor of dissolved in purified water, wherein in silver ion mixed liquor, the content of silver ion is that 1-1000 microgram often rises, calcium alginate fibre, chitin fiber and carbon nano-fiber are completely infused in ultrasonic vibration 45-60min after silver ion mixed liquor, add ethanol or acetone or isopropyl alcohol after centrifuge dripping to carry out wash-out and dehydrate, solvent is taken out through heated-air drying after drying, thus obtain calcium alginate, what shitosan mixed with nano-sized carbon carries silver-colored fiber,
Step 2: the preparation of floor sock, by the spun yarn described in step 1 and 150 terylene double-contracting 100D spandex covered yarns, the braiding of covering yarn feeding hosiery machine, in braiding process, spun yarn is all the time at surface weave, terylene spandex covered yarn weaves at socks nexine all the time, rib collar chain order 9-18, socks body chain order 112-168, heel chain order 19-31/19-31, stocking sole chain order 95-126, gap bridge chain order 5-8, toe chain order 19-31/19-31, toe linking region chain order 10-15, under socks after machine, undertoe is sewed up, with 140D wear-resisting polyamide fibre, undertoe is sewed up, socks are shaped, setting temperature 105-108 DEG C, shaping time 3s,
Step 3: the anti-skidding Final finishing of floor sock, socks step 2 obtained carry out silica-gel antiskid process, and the patty silica gel of 4mm diameter carries out rectangular arranged with mutual spacing 6mm, is booked the stocking sole.
7. the preparation method of a kind of floor sock based on bodkin rove, silica-gel antiskid according to right 6, it is characterized in that, silica gel Final finishing is enclosed within by socks on the dull and stereotyped pin mould of dimension, makes that the stocking sole is concordant is exposed to outside, by high temperature supply silica gel on the stocking sole.
8. the preparation method of a kind of floor sock based on bodkin rove, silica-gel antiskid according to claim 7, is characterized in that, the temperature of high temperature supply is 126-152 DEG C.
CN201410368404.6A 2014-07-30 2014-07-30 A kind of floor sock based on bodkin rove, silica-gel antiskid and preparation method thereof Active CN104207336B (en)

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Cited By (7)

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Publication number Priority date Publication date Assignee Title
CN105040259A (en) * 2015-06-16 2015-11-11 长兴县大成轻纺有限公司 Complex deodorization cloth
CN105078097A (en) * 2015-06-16 2015-11-25 长兴虹波纺织有限公司 Woolen blanket based on bulky rovings and production method thereof
CN105146770A (en) * 2015-08-31 2015-12-16 顾小民 Process for producing anti-skid floor socks
CN105200646A (en) * 2015-08-21 2015-12-30 沈汇明 Production process of ultrathin short silk stockings
CN106360816A (en) * 2016-11-17 2017-02-01 温州医科大学 Foot care dedicated socks
CN110028896A (en) * 2019-04-19 2019-07-19 王朋 A kind of silica gel product and the preparation method and application thereof with antibacterial action
CN110074472A (en) * 2019-04-17 2019-08-02 远东爱尔国际针织(蚌埠)有限公司 A kind of manufacturing process and point glue equipment of footgear

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CN101985786A (en) * 2010-10-25 2011-03-16 山东昊龙集团有限公司 Preparation method of multifunctional yarn containing silver fibers
CN102511934A (en) * 2011-12-02 2012-06-27 褚加冕 Method for preparing diabetes treating foot socks by adopting calcium alginate
CN202819647U (en) * 2012-09-04 2013-03-27 浙江梦娜袜业股份有限公司 Anti-slipping stockings of children
CN103829385A (en) * 2014-03-17 2014-06-04 浙江袜业有限公司 Novel production process of high-strength breathable socks

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CN2115663U (en) * 1992-02-28 1992-09-16 陈美华 Raised granule socks with healthful purpose of anti-bacteria and removing bad smell
CN2517267Y (en) * 2001-07-18 2002-10-23 海宁市四维弹性织物有限公司 Socks
US20080286513A1 (en) * 2007-05-15 2008-11-20 Invista North America S A R L Knit fabrics and socks made therefrom incorporating high tensile nylon staple
CN101985786A (en) * 2010-10-25 2011-03-16 山东昊龙集团有限公司 Preparation method of multifunctional yarn containing silver fibers
CN102511934A (en) * 2011-12-02 2012-06-27 褚加冕 Method for preparing diabetes treating foot socks by adopting calcium alginate
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105040259A (en) * 2015-06-16 2015-11-11 长兴县大成轻纺有限公司 Complex deodorization cloth
CN105078097A (en) * 2015-06-16 2015-11-25 长兴虹波纺织有限公司 Woolen blanket based on bulky rovings and production method thereof
CN105200646A (en) * 2015-08-21 2015-12-30 沈汇明 Production process of ultrathin short silk stockings
CN105146770A (en) * 2015-08-31 2015-12-16 顾小民 Process for producing anti-skid floor socks
CN106360816A (en) * 2016-11-17 2017-02-01 温州医科大学 Foot care dedicated socks
CN110074472A (en) * 2019-04-17 2019-08-02 远东爱尔国际针织(蚌埠)有限公司 A kind of manufacturing process and point glue equipment of footgear
CN110028896A (en) * 2019-04-19 2019-07-19 王朋 A kind of silica gel product and the preparation method and application thereof with antibacterial action

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