CN104195621B - For the electroplating bath of composite plating - Google Patents

For the electroplating bath of composite plating Download PDF

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Publication number
CN104195621B
CN104195621B CN201410434306.8A CN201410434306A CN104195621B CN 104195621 B CN104195621 B CN 104195621B CN 201410434306 A CN201410434306 A CN 201410434306A CN 104195621 B CN104195621 B CN 104195621B
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China
Prior art keywords
electroplating bath
anode
composite plating
barrier film
anode material
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CN104195621A (en
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王战
祝小威
王永宝
刘建双
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Zhengzhou Research Institute for Abrasives and Grinding Co Ltd
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Zhengzhou Research Institute for Abrasives and Grinding Co Ltd
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  • Electroplating And Plating Baths Therefor (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

Electroplating bath the present invention relates to be used for composite plating.For the electroplating bath of composite plating, including electroplating bath body, the side wall of the electroplating bath body is provided with the anode material cavity for accommodating anode metal material, the anode material cavity has towards the intrinsic opening of electroplating bath, be provided with the opening makes the freely through barrier film of anode metal ion for preventing the particulate matter inside and outside anode material receiving space from swapping, and the barrier film face where the barrier film is coplanar with the corresponding internal face of electroplating bath body or smooth connection.The above-mentioned electroplating bath for composite plating can avoid forming dead angle in electroplating bath body, and the interference that can reduce or avoid anode hang tool to be caused to liquid stream, so as to avoid influence of the anode hang tool of the prior art to concentration of solid particles and distribution consistency degree, electroplating quality is improved.

Description

For the electroplating bath of composite plating
Technical field
Electroplating bath the present invention relates to be used for composite plating.
Background technology
Composite plating refers to have an electroplate liquid of trickle solid particle dispersed, in the presence of electric field, is made solid Body particulate is deposited on workpiece together with plated metal and forms the process of composite deposite.Such as a kind of electricity of extra hard material grinding wheel Plating, be in electroplating bath by nickel and abrasive grain on co-deposition to aluminum matrix.Currently used for the electroplating bath of composite plating Structure as shown in figure 1, including for containing the electroplating bath body 91 of the electroplate liquid 95 containing solid particle and for being hung on Anode hang tool 92 on the side wall of electroplating bath body 91, anode hang tool 92 includes hook 93, titanium basket 94 and by woven dacron or polypropylene fibre The anode that the materials such as cloth make, titanium basket 94 is used to contain anode metal material, such as nickel cake, and anode is used to prevent electroplating bath sheet Particulate matter in body 91 is swapped with the particulate matter in titanium basket 94, and anode metal ion such as nickel ion can be made freely to lead to Cross.
Existing electroplating bath in use, due at the slit between anode and electroplating bath inwall formed dead angle Easily conceal solid particle, therefore concentration of solid particles is unstable in causing electroplate liquid, and then influence consolidating on composite deposite Body granule density, and waste of material can be caused, especially for price superhard abrading agent costly, waste more bright It is aobvious.In addition, anode hang tool 92 can protrude inwardly from electroplating bath inwall after hanging on electroplating bath, therefore when electroplate liquid 95 is stirred Liquid stream can be interfered, flow-disturbing phenomenon occur, so as to have influence on solid particle being uniformly distributed in electroplate liquid 95, and solid The whether uniform of distribution of particles is directly connected to quality of coating.
The content of the invention
It is an object of the invention to provide a kind of electroplating bath for composite plating, anode hang tool can be avoided to solid particle The influence of concentration and distribution consistency degree.
The present invention for composite plating electroplating bath use technical scheme be:For the electroplating bath of composite plating, including Electroplating bath body, the side wall of the electroplating bath body is provided with the anode material cavity for accommodating anode metal material, described Anode material cavity has towards the intrinsic opening of electroplating bath, is provided with the opening for preventing anode material receiving space Inside and outside particulate matter is swapped and makes the freely through barrier film of anode metal ion, the barrier film face where the barrier film with plating The corresponding internal face of groove body is coplanar or smooth connection.
The electroplating bath body includes major trough body and external cell body, and the side wall of the major trough body is provided with power supply plating solution to be passed through And cross liquid mouthful for form the opening, the external cell body is fixed on described cross at liquid mouthful and to form the anode material recessed Chamber.
The surrounding for crossing liquid mouthful is respectively provided with opening's edge.
The barrier film is made up of woven dacron or Polypropylene.
The insulating frame for being arranged between barrier film and anode metal material is provided with the opening of the electroplating bath body.
The isolation frame is to be made of titanium.
The insulating frame is embedded in the opening of the anode material cavity and thickness is less than the side wall of electroplating bath body Thickness.
The top of the anode material cavity is open architecture.
The anode material cavity is uniformly distributed along the side wall of electroplating bath body.
The electroplating bath body is shaped as cylindrical shape.
The present invention uses above-mentioned technical proposal, and the anode material cavity set on the side wall of coating bath body can accommodate anode Metal material, the barrier film at the opening of anode material cavity can prevent the particulate matter inside and outside anode material receiving space from being handed over Change and pass freely through anode metal ion, it is ensured that electroplating activity is normally carried out, and due to the barrier film face where the barrier film Or smooth connection coplanar with the corresponding internal face of electroplating bath body, therefore, it is possible to avoid forming dead angle in electroplating bath body, and And can reduce or avoid the interference that anode hang tool is caused to liquid stream, so as to avoid anode hang tool of the prior art to solid The influence of grain concentration and distribution consistency degree, improves electroplating quality.
Brief description of the drawings
Fig. 1 is the structural representation of the electroplating bath for being used for composite plating in the prior art;
Each reference is corresponding entitled in figure:91- electroplating bath bodies, 92- anode hang tools, 93- hooks, 94- titanium baskets, 95- electroplate liquids.
Fig. 2 is the structural representation of one embodiment of the electroplating bath for composite plating in the present invention;
Each reference is corresponding entitled in figure:10- electroplating bath bodies, 11- major trough bodies, the external cell bodies of 12-, 13- sun Pole material cavity, 14- openings, 20- cambered surface barrier films, 30- insulating frames, 40- anode nickels, 50- electroplate liquids.
Specific embodiment
The present invention is used for one embodiment of the electroplating bath of composite plating as shown in Fig. 2 being that one kind is used for superhard material sand The electroplating bath of plating is taken turns, including for containing the electroplating bath body 10 of the electroplate liquid 50 containing solid particle, the electroplating bath sheet Body 10 is made by materials such as PVC commonly used in the art, polypropylene, including major trough body 11 and external cell body 12, major trough body 11 Be shaped as cylindrical shape, be evenly distributed with that multiple power supply plating solutions 50 pass through on its side wall in the range of 360 degree crosses liquid mouthful, respectively Cross at liquid mouthful and be fixedly installed external cell body 12, external cell body 12 is formed for accommodating anode metal in the side wall of major trough body 11 The anode material cavity 13 of material, in the present embodiment, anode metal material is anode nickel 40.In order to be carried out effectively to anode nickel 40 Isolation, the surrounding for crossing liquid mouthful on the side wall of major trough body 11 is respectively provided with opening's edge, and hole is formed on the side wall of major trough body 11.For the ease of The addition of anode metal material, the top of external cell body 12 is open architecture so that the top of anode material cavity 13 is also to open Put structure.Major trough shape uses cylindrical shape, and flow-disturbing, more conducively the uniform of electroplate liquid will not be produced to stir during stirring electroplate liquid Mix.
Each anode material cavity 13 is made up of woven dacron or Polypropylene towards being provided with the opening 14 in electroplating bath body 10 Cambered surface barrier film 20, cambered surface barrier film 20 is used to prevent the particulate matter inside and outside anode material receiving space from swapping, but can make Anode metal ion is passed freely through.Barrier film face arc inner wall face corresponding with electroplating bath body 10 where cambered surface barrier film 20 is total to Face, to avoid forming dead angle in electroplating bath, and avoids the interference that the anode hang tool for using in the prior art causes to liquid stream.
In order that anode nickel 40 is preferably limited in anode material cavity 13, it is to avoid it damages cambered surface barrier film 20, institute The insulating frame 30 being embedded with the opening 14 of electroplating bath body 10 for being arranged between barrier film and anode metal material is stated, should Insulating frame 30 is made of titanium, and with good corrosion resistance, acts on similar to titanium basket of the prior art.Insulating frame 30 Thickness less than major trough body 11 wall degree, its thickness with cambered surface barrier film 20 and equal with the sidewall thickness of major trough body 11, so that positive Pole material cavity 13 avoids forming dead angle in anode material cavity 13 with bigger space.Using recessed in anode material The opening 14 in chamber 13 sets the structure of insulating frame 30, and the usage amount of titanium can also be reduced compared with prior art, reduces plating Groove production cost.
During stirring electroplate liquid 50, due to obstructing for no anode hang tool, the solid particle in electroplate liquid 50 can be rapid It is stirred, even suspension is in plating solution;When carrying out electroplating activity, the workpiece that will be assembled is put into the middle of major trough body 11, is opened Begin to electroplate, anode nickel 40 is dissolved into metallic nickel ions in the presence of electric current, and nickel ion can pass freely through cambered surface barrier film 20, arrive Workpiece surface is deposited to together up to the solid particle in major trough body 11, and major trough body 11, completes composite plating;And anode material is recessed The earth of positive pole solid impurity that the dissolving of 13 inner anode nickel of chamber 40 is produced then can not be by cambered surface barrier film 20, it is to avoid in pollution major trough body 11 Electroplate liquid 50, during solid particle in major trough body 11 also will not penetrate into external groove by cambered surface barrier film 20.Above-mentioned electroplating bath Because anode is external, it is ensured that space is without dead angle in electroplating bath, it is to avoid conceal solid particle, concentration of solid particles is reduced Fluctuation and waste;Also, also make clear on electroplating bath inwall because anode is external, it is ensured that electroplating bath madial wall it is flat It is sliding, it is to avoid in the prior art groove is projecting inward anode hang tool is set in stirring when the flow-disturbing problem that occurs, it is ensured that solid Grain is evenly distributed in the plating solution.
In the above-described embodiments, electroplating bath body 10 includes the major trough body 11 and external cell body 12 that are fixed together, is used for The liquid mouthful of crossing for forming the opening 14 of anode material cavity 13 crosses liquid mouthful for what surrounding was equipped with opening's edge, and barrier film is cambered surface barrier film 20.In other embodiments of the invention, electroplating bath body 10 can also be it is integrally formed, anode material cavity 13 directly into Formed during type;Liquid mouthful excessively for forming the opening 14 of anode material cavity 13 can also be provided on the side wall of major trough body 11 Gap, and the shape liquid of electroplating bath body 10 can be other shapes, such as rectangular-shape, now barrier film can be corresponding flat Face barrier film.In other embodiments, barrier film can also protrude in electroplating bath internal face or recessed anode material cavity 13 and with electricity The corresponding internal face of coating bath body 10 is in smoothing junction, can equally avoid the occurrence of dead angle, and less flow-disturbing.In addition, in other realities Apply in example, insulating frame 30 can also be not provided with the opening 14 of anode material cavity 13, directly by barrier film to anode metal Material intercept and spacing, and insulating frame 30 can also replace with other materials, such as with the identical of electroplating bath body 10 Material.Furthermore, in above-described embodiment, external cell body 12 is evenly distributed on the side wall of major trough body 11 in the range of 360 degree can be with Increase the freely through area of anode nickel ion, realize strong-current electroplating, improve electroplating efficiency, and can be larger to area work Part carries out electroplating activity, and in other embodiments, the quantity of external cell body 12 can be adjusted according to Production requirement.Certainly, According to the demand of institute's electroplated product, in other embodiments, anode metal material can also be other materials, for example copper, tin etc..

Claims (8)

1. the electroplating bath of composite plating, including electroplating bath body are used for, it is characterised in that:Set on the side wall of the electroplating bath body There is the anode material cavity for accommodating anode metal material, the anode material cavity has to be opened towards electroplating bath is intrinsic Mouthful, be provided with the opening makes anode metal ion for preventing the particulate matter inside and outside anode material receiving space from swapping Freely through barrier film, the barrier film face where the barrier film is coplanar with the corresponding internal face of electroplating bath body or smooth connection;Institute Stating electroplating bath body includes major trough body and external cell body, and the side wall of the major trough body is provided with power supply plating solution to be passed through and for being formed The liquid mouthful excessively of the opening, the external cell body is fixed on described mistake at liquid mouthful and forms the anode material cavity, anode material The top for expecting cavity is open architecture.
2. the electroplating bath for composite plating according to claim 1, it is characterised in that:The surrounding for crossing liquid mouthful has There is opening's edge.
3. the electroplating bath for composite plating according to claim 1 and 2, it is characterised in that:The barrier film is by terylene Cloth or Polypropylene are made.
4. the electroplating bath for composite plating according to claim 1 and 2, it is characterised in that:The electroplating bath body The insulating frame for being arranged between barrier film and anode metal material is provided with opening.
5. the electroplating bath for composite plating according to claim 4, it is characterised in that:The insulating frame is by titanium system Into.
6. the electroplating bath for composite plating according to claim 4, it is characterised in that:The insulating frame is embedded in institute State in the opening of anode material cavity and thickness less than electroplating bath body sidewall thickness.
7. the electroplating bath for composite plating according to claim 1 and 2, it is characterised in that:The anode material cavity It is uniformly distributed along the side wall of electroplating bath body.
8. the electroplating bath for composite plating according to claim 1 and 2, it is characterised in that:The electroplating bath body It is shaped as cylindrical shape.
CN201410434306.8A 2014-08-29 2014-08-29 For the electroplating bath of composite plating Active CN104195621B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113463168B (en) * 2021-06-28 2023-04-14 江苏澳光电子有限公司 Electroplating ion supplementing device for electroplating bath
CN113430635B (en) * 2021-06-28 2023-04-14 江苏澳光电子有限公司 Transverse drive formula electroplating ion supplementing device for plating bath

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51140838A (en) * 1975-05-30 1976-12-04 Uemura Kogyo Kk Composite plating method and apparatus therefor
JPS597357B2 (en) * 1976-06-04 1984-02-17 ソニー株式会社 Electrodeposition method
US4318792A (en) * 1980-07-07 1982-03-09 Trw Inc. Process for depositing forging lubricant on titanium workpiece
CN1004763B (en) * 1985-10-10 1989-07-12 交通部水运规划设计院 Plating bath device for electroplating iron-based composite coating
JPS63162897A (en) * 1986-12-25 1988-07-06 Nisso Kinzoku Kagaku Kk Device for electroplating particulate matter
JPH02115396A (en) * 1988-10-21 1990-04-27 Heijiro Tarumoto Composite plating method
CN204111901U (en) * 2014-08-29 2015-01-21 郑州磨料磨具磨削研究所有限公司 A kind of plating tank for composite plating

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