CN104194590A - Wear-resisting and anti-aging alkyd resin paint for bronze sculptures - Google Patents

Abstract

The invention relates to a paint, and particularly relates to a wear-resisting and anti-aging alkyd resin paint for bronze sculptures. The paint disclosed by the invention is prepared from the following raw materials in parts by weight: 20-24 parts of alkyd resin, 20-24 parts of 582-2 amino resin, 4-6 parts of calcium propionate, 1-2 parts of sodium propionate, 2-3 parts of sodium citrate, 3-4 parts of glycidyl methacrylate, 15-20 parts of urethane acrylate, 3-5 parts of N-(hydroxymethyl) acrylamide, 6-9 parts of acrylic acid, 4-5 parts of trifluoroacetic acid, 1.5-2.5 parts of triallyl isocyanurate, 1.1-1.3 parts of an accelerant CZ, 2-3 parts of tributyl tin chloride, 3-5 parts of m-amino methylamine, 5-6 parts of aids, 10-12 parts of xylene, and 10-12 parts of butyl acetate. The paint coating disclosed by the invention is strong in coating adhesion; the paint film is high in glossiness, hard, wear-resisting, anti-aging, long in service life, corrosion-resistant and good in electric properties; the production process of the paint is simple and therefore the paint can be widely used for protecting various bronze sculpture crafts.

Description

A kind of copper sculpture paints with wear-resisting anti-aging Synolac

Technical field

The present invention relates to a kind of paint, be specifically related to wear-resisting anti-aging Synolac paint and preparation technology thereof for a kind of copper sculpture.

Background technology

Copper sculpture is a class artwork common in daily life, there is higher artistic value and enjoying value, but, copper sculpture artwork is due to itself material character and the feature of putting environment, easily there is the problems such as oxidation corrosion, affect attractive in appearance and work-ing life, in order to protect bronze, brass or copper ware, often need to varnish with lacquer in sculpture outside, and copper sculpture is had to certain requirement with paint, such as sticking power, weather-proof aging, resistance to sunlight exposure, heatproof etc., therefore, need to improve paint formulation, make the paint that is applicable to different use occasions, increase its artistic value.

Summary of the invention

The object of the invention is to, provide the wear-resisting anti-aging Synolac of a kind of copper sculpture to paint, to protect sculpture, to achieve these goals, the technical solution used in the present invention is as follows:

A kind of copper sculpture paints with wear-resisting anti-aging Synolac, it is characterized in that, material of the present invention is made up of the raw material of following weight part: Synolac 20-24, 582-2 aminoresin 20-24, calcium propionate 4-6, Sodium Propionate 1-2, Trisodium Citrate 2-3, glycidyl methacrylate 3-4, urethane acrylate 15-20, N-hydroxymethyl acrylamide 3-5, vinylformic acid 6-9, trifluoroacetic acid 4-5, iso-cyanuric acid triallyl ester 1.5-2.5, accelerant CZ 1.1-1.3, tributyl tin trichloride 2-3, between amino methylamine 3-5, auxiliary agent 5-6, dimethylbenzene 10-12, butylacetate 10-12.

Described auxiliary agent is made up of the raw material of following weight part: clay 12-15, nano titanium oxide 3-4, nano silicon 1-2, dimethyl silicone oil 1-2, altax 2-3, phenyl triethoxysilane 2-3, zinc oxide 5-6, medical stone 3-4, alum 1-2, acetyl triethyl citrate 35-40, Tenox PG 2-3, coix seed oil 3-4, vanadium diboride 2-3, l-Epicatechol 2-3; Its preparation method is that clay, medical stone are sent in calcining furnace and calcine 2-3 hour at 720-740 DEG C, then takes out, and sends in the hydrochloric acid soln of 10-15% and soaks 2-3 hour, filters, and obtains filter residue, cleans with clear water, dries, grinds to form 400-600 order powder; Gained powder mixes with other remaining component, is heated to 60-70 DEG C, and stirring reaction 40-50 minute is cooling, grinds to form slurry, to obtain final product.

Described a kind of copper sculpture paints with wear-resisting anti-aging Synolac, and its preparation technology is:

(1) calcium propionate, glycidyl methacrylate, trifluoroacetic acid, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 DEG C, reaction 3-4 hour;

(2) material of step (1) is cooled to 70-85 DEG C, adds Trisodium Citrate, vinylformic acid, iso-cyanuric acid triallyl ester, stirring reaction 3-4 hour;

(3) material of step (2) is cooled to 50-65 DEG C, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, to obtain final product.

Compared with prior art, copper sculpture provided by the invention is painted possesses following advantage: coating adhesion is strong, and gloss of film degree is high, and matter is firmly wear-resisting, weather-proof aging, long service life, protection against corrosion, electrical property is good, and production technique is relatively simple, can be widely used in all kinds of copper carving handicraft articles of protection.

Embodiment

Embodiment

The present embodiment paint is made up of following weight part raw material: Synolac 24,582-2 aminoresin 24, calcium propionate 6, Sodium Propionate 2, Trisodium Citrate 3, glycidyl methacrylate 4, urethane acrylate 20, N-hydroxymethyl acrylamide 5, vinylformic acid 8, trifluoroacetic acid 5, iso-cyanuric acid triallyl ester 2.2, accelerant CZ 1.3, tributyl tin trichloride 3, an amino methylamine 5, auxiliary agent 6, dimethylbenzene 12, butylacetate 12.

Described auxiliary agent is made up of the raw material of following weight part: clay 15, nano titanium oxide 4, nano silicon 2, dimethyl silicone oil 2, altax 3, phenyl triethoxysilane 3, zinc oxide 6, medical stone 4, alum 2, acetyl triethyl citrate 40, Tenox PG 3, coix seed oil 4, vanadium diboride 3, l-Epicatechol 3; Its preparation method is that clay, medical stone are sent in calcining furnace and at 720-740 DEG C, calcined 3 hours, then takes out, and sends in 15% hydrochloric acid soln and soaks 3 hours, filters, and obtains filter residue, cleans with clear water, dries, grinds to form 600 order powders; Gained powder mixes with other remaining component, is heated to 60-70 DEG C, and stirring reaction 50 minutes is cooling, grinds to form slurry, to obtain final product.

Described a kind of copper sculpture paints with wear-resisting anti-aging Synolac, and its preparation technology is:

(1) calcium propionate, glycidyl methacrylate, trifluoroacetic acid, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 DEG C, react 4 hours;

(2) material of step (1) is cooled to 70-85 DEG C, adds Trisodium Citrate, vinylformic acid, iso-cyanuric acid triallyl ester, stirring reaction 4 hours;

(3) material of step (2) is cooled to 50-65 DEG C, adds other leftover materials, stirring reaction, after 60 minutes, is cooled to room temperature, grinds to form 60 μ m slurries, to obtain final product.

The performance test results of the present invention's paint is:

Above-mentioned test is all followed relevant criterion and is carried out.

Claims (2)

1. a copper sculpture paints with wear-resisting anti-aging Synolac, it is characterized in that, this paint is made up of the raw material of following weight part: Synolac 20-24, 582-2 aminoresin 20-24, calcium propionate 4-6, Sodium Propionate 1-2, Trisodium Citrate 2-3, glycidyl methacrylate 3-4, urethane acrylate 15-20, N-hydroxymethyl acrylamide 3-5, vinylformic acid 6-9, trifluoroacetic acid 4-5, iso-cyanuric acid triallyl ester 1.5-2.5, accelerant CZ 1.1-1.3, tributyl tin trichloride 2-3, between amino methylamine 3-5, auxiliary agent 5-6, dimethylbenzene 10-12, butylacetate 10-12,

Described auxiliary agent is made up of the raw material of following weight part: clay 12-15, nano titanium oxide 3-4, nano silicon 1-2, dimethyl silicone oil 1-2, altax 2-3, phenyl triethoxysilane 2-3, zinc oxide 5-6, medical stone 3-4, alum 1-2, acetyl triethyl citrate 35-40, Tenox PG 2-3, coix seed oil 3-4, vanadium diboride 2-3, l-Epicatechol 2-3; Its preparation method is that clay, medical stone are sent in calcining furnace and calcine 2-3 hour at 720-740 DEG C, then takes out, and sends in the hydrochloric acid soln of 10-15% and soaks 2-3 hour, filters, and obtains filter residue, cleans with clear water, dries, grinds to form 400-600 order powder; Gained powder mixes with other remaining component, is heated to 60-70 DEG C, and stirring reaction 40-50 minute is cooling, grinds to form slurry, to obtain final product.

2. a kind of copper sculpture as claimed in claim 1 paints with wear-resisting anti-aging Synolac, and its manufacture craft is:

(1) calcium propionate, glycidyl methacrylate, trifluoroacetic acid, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 DEG C, reaction 3-4 hour;

(2) material of step (1) is cooled to 70-85 DEG C, adds Trisodium Citrate, vinylformic acid, iso-cyanuric acid triallyl ester, stirring reaction 3-4 hour;

(3) material of step (2) is cooled to 50-65 DEG C, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, to obtain final product.