CN103642374A - Environmentally friendly anti-rust paint and preparation method therefor - Google Patents
Environmentally friendly anti-rust paint and preparation method therefor Download PDFInfo
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- CN103642374A CN103642374A CN201310413144.5A CN201310413144A CN103642374A CN 103642374 A CN103642374 A CN 103642374A CN 201310413144 A CN201310413144 A CN 201310413144A CN 103642374 A CN103642374 A CN 103642374A
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Abstract
The invention provides an environmentally friendly anti-rust paint. The anti-rust paint is prepared from the following raw materials, by weight, 56-60 parts of alkyd resins, 10-13 parts of titanium dioxide powder, 10-12 parts of eleostearic acid, 16-19 parts of xylene, 4-5 parts of linoleic acid, 6-10 parts of neopentyl glycol, 6-8 parts of propylene glycol, 24-26 parts of 582-2 amino resins, 4-5 parts of zinc naphthenate, 1-2 parts of tetra-n-butyltin, 3-4 parts of acrylonitrile, 6-7 parts of isoprene, 12-14 parts of diethylenetriamine and 3-4 parts of film-forming resins. The anti-rust paint employs environmentally friendly raw materials, and is nonhazardous to human body and the biological environment. The anti-rust paint has advantages of low cost, strong adhesive force, aging resistance, high temperature resistance and corrosion resistance. The anti-rust paint has good brushability, and can be directly sprayed or brushed on surfaces of rusty steel. The anti-rust paint is mainly used for workpieces which need rust removal and rust protection, such as bridges, vehicles, containers, ships, steel windows, mechanical equipment, pipelines or the like.
Description
Technical field
The present invention relates to metal rust preventing technical field, be specifically related to a kind of environment-friendly antirust paint and preparation method thereof.
Background technology
Metallic corrosion is the very serious problem that people face.The metal that scrap because of metallic corrosion every year in the whole world reaches more than several hundred million tons, and financial loss accounts for 1.5%~2.5% of total value of production in national economy.Metal rusting is the most general, loss is maximum a kind of corrosion.Antirust work is always one of great scientific research task both domestic and external, and people work out the corrosion that many kinds of measures prevented and suppressed metal, and antirust with coating is a kind of effective means.
Summary of the invention
The object of this invention is to provide a kind of environment-friendly antirust paint and preparation method thereof, various metals is had to antirust function.
Technical scheme of the present invention is as follows:
An environment-friendly antirust paint, is characterized in that, its feed composition by following weight part is prepared from:
Synolac 56-60, titanium dioxide 10-13, eleostearic acid 10-12, dimethylbenzene 16-19, linolenic acid 4-5, neopentyl glycol 6-10, propylene glycol 6-8,582-2 aminoresin 24-26, zinc naphthenate 4-5, tetrabutyl tin 1-2, vinyl cyanide 3-4, isoprene 6-7, diethylenetriamine 12-14, film-forming resin 3-4.
Described environment-friendly antirust paint, is characterized in that: described film-forming resin is prepared from by the raw material of following weight part:
Alcohol ester 12 17-19,2-amino-2-methyl-1-propanol 2-3, sorbitol monooleate 1-2, ethyl acetate 8-10, mica powder 3-4, wintergreen oil 1-2, nano-sized carbon 0.1-0.2, titanate coupling agent TMC-TTS2-3; Preparation method: 2-amino-2-methyl-1-propanol, sorbitol monooleate, ethyl acetate, mica powder, wintergreen oil, nano-sized carbon are mixed, and grinding distribution, is then warming up to 78-85 ℃, adds other remaining component, between stirring reaction 1-2 hour, obtains.
The preparation method of described environment-friendly antirust paint, is characterized in that, comprises the following steps:
(1) first dimethylbenzene, eleostearic acid, linolenic acid, neopentyl glycol, propylene glycol are joined to hybrid reaction 20-25 minute in reactor;
(2) Synolac, titanium dioxide, 582-2 aminoresin, zinc naphthenate, tetrabutyl tin, vinyl cyanide, isoprene, diethylenetriamine, film-forming resin are joined successively to abundant dispersed with stirring in the mixed material of step (1), then use 400 order filter-cloth filterings.
Beneficial effect of the present invention:
Rust-inhibiting paint of the present invention, starting material environmental protection, to people, the equal toxicological harmless of coenocorrelation, cost is low, strong adhesion, ageing-resistant, high temperature resistant, corrosion-resistant, and brushing performance is good, can direct spraying or the steel surface that getting rusty of brushing.Being mainly used in bridge, vehicle, freight container, boats and ships, steel sash, mechanical means and pipeline etc. needs on the workpiece of derusting rust-proofing.
Embodiment:
Embodiment
An environment-friendly antirust paint, its feed composition by following weight (kg) is prepared from:
Synolac 57, titanium dioxide 12, eleostearic acid 12, dimethylbenzene 18, linolenic acid 5, neopentyl glycol 9, propylene glycol 7,582-2 aminoresin 25, zinc naphthenate 4, tetrabutyl tin 2, vinyl cyanide 3, isoprene 6, diethylenetriamine 13, film-forming resin 3.
Concrete preparation method, comprises the following steps:
1, the preparation of film-forming resin:
(kg) takes alcohol ester 12,2-amino-2-methyl-1-propanol 3, sorbitol monooleate 2, ethyl acetate 9, mica powder 3, wintergreen oil 2, nano-sized carbon 0.2, titanate coupling agent TMC-TTS3 by weight, 2-amino-2-methyl-1-propanol, sorbitol monooleate, ethyl acetate, mica powder, wintergreen oil, nano-sized carbon are mixed, grinding distribution, then be warming up to 79 ℃, add other remaining component, between stirring reaction 1-2 hour, obtain.
2, the preparation of environment-friendly antirust paint, make according to the following steps:
(1) first dimethylbenzene, eleostearic acid, linolenic acid, neopentyl glycol, propylene glycol are joined in reactor to hybrid reaction 22 minutes;
(2) Synolac, titanium dioxide, 582-2 aminoresin, zinc naphthenate, tetrabutyl tin, vinyl cyanide, isoprene, diethylenetriamine, film-forming resin are joined successively to abundant dispersed with stirring in the mixed material of step (1), then use 400 order filter-cloth filterings.
Performance test:
Rust proof paint embodiment being obtained according to GB/T1727 carries out performance test: wherein, resistant to saline solution test is undertaken by GB/T1763, be specially according to the general preparation method > of < < paint film > and prepare paint film, after being coated with the 1st road paint, within dry 48 hours, brush the 2nd road paint film, after 7 days, carry out resistance to salt water and can test; 24h in 3% salt water resistance is steeped in the test of described salt water resistance, non-foaming, do not come off, non-corrosive is qualified, otherwise is defective;
Viscosity test is Tu-4 glass.
The concrete outcome of performance test is as shown in table 1:
The performance test results of the rust proof paint that table 1 embodiment obtains
Claims (3)
1. an environment-friendly antirust paint, is characterized in that, its feed composition by following weight part is prepared from:
Synolac 56-60, titanium dioxide 10-13, eleostearic acid 10-12, dimethylbenzene 16-19, linolenic acid 4-5, neopentyl glycol 6-10, propylene glycol 6-8,582-2 aminoresin 24-26, zinc naphthenate 4-5, tetrabutyl tin 1-2, vinyl cyanide 3-4, isoprene 6-7, diethylenetriamine 12-14, film-forming resin 3-4.
2. environment-friendly antirust paint according to claim 1, is characterized in that: described film-forming resin is prepared from by the raw material of following weight part:
Alcohol ester 12 17-19,2-amino-2-methyl-1-propyl alcohol 2-3, sorbitol monooleate 1-2, ethyl acetate 8-10, mica powder 3-4, wintergreen oil 1-2, nano-sized carbon 0.1-0.2, titanate coupling agent TMC-TTS 2-3; Preparation method: 2-amino-2-methyl-1-propyl alcohol, sorbitol monooleate, ethyl acetate, mica powder, wintergreen oil, nano-sized carbon are mixed, and grinding distribution, is then warming up to 78-85 ℃, adds other remaining component, between stirring reaction 1-2 hour, obtains.
3. the preparation method of environment-friendly antirust paint according to claim 1, is characterized in that, comprises the following steps:
(1) first dimethylbenzene, eleostearic acid, linolenic acid, neopentyl glycol, propylene glycol are joined to hybrid reaction 20-25 minute in reactor;
(2) Synolac, titanium dioxide, 582-2 aminoresin, zinc naphthenate, tetrabutyl tin, vinyl cyanide, isoprene, diethylenetriamine, film-forming resin are joined successively to abundant dispersed with stirring in the mixed material of step (1), then use 400 order filter-cloth filterings.
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CN201310413144.5A CN103642374B (en) | 2013-09-10 | 2013-09-10 | A kind of Environment-friendlyantirust antirust paint and preparation method thereof |
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CN201310413144.5A CN103642374B (en) | 2013-09-10 | 2013-09-10 | A kind of Environment-friendlyantirust antirust paint and preparation method thereof |
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CN103642374B CN103642374B (en) | 2016-08-10 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104194590A (en) * | 2014-07-28 | 2014-12-10 | 铜陵市远程艺术制品有限责任公司 | Wear-resisting and anti-aging alkyd resin paint for bronze sculptures |
CN104387582A (en) * | 2014-11-19 | 2015-03-04 | 福建名源化工科技有限公司 | Method for producing novel environment-friendly rust-resisting material |
CN104817922A (en) * | 2015-04-23 | 2015-08-05 | 柳州凡一科技有限公司 | Rust-proof high-temperature resistant coating for agricultural machinery |
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JP2003313492A (en) * | 2002-02-21 | 2003-11-06 | Toshiba Corp | Thermosetting coating material, method for coating therewith, and object coated therewith |
CN1625588A (en) * | 2002-04-30 | 2005-06-08 | 罗特麦克电子私人有限公司 | No under coat anticorrosion composite without chromate and preparation method thereof |
CN101434809A (en) * | 2008-12-19 | 2009-05-20 | 安庆菱湖漆业有限公司 | Low temperature quick-drying amino paint for automobile chassis and production method thereof |
CN101492588A (en) * | 2009-02-23 | 2009-07-29 | 衡阳市化工研究所有限公司 | Interpenetrating polymer network anticorrosion paint and production method thereof |
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2013
- 2013-09-10 CN CN201310413144.5A patent/CN103642374B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003313492A (en) * | 2002-02-21 | 2003-11-06 | Toshiba Corp | Thermosetting coating material, method for coating therewith, and object coated therewith |
CN1625588A (en) * | 2002-04-30 | 2005-06-08 | 罗特麦克电子私人有限公司 | No under coat anticorrosion composite without chromate and preparation method thereof |
CN101434809A (en) * | 2008-12-19 | 2009-05-20 | 安庆菱湖漆业有限公司 | Low temperature quick-drying amino paint for automobile chassis and production method thereof |
CN101492588A (en) * | 2009-02-23 | 2009-07-29 | 衡阳市化工研究所有限公司 | Interpenetrating polymer network anticorrosion paint and production method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104194590A (en) * | 2014-07-28 | 2014-12-10 | 铜陵市远程艺术制品有限责任公司 | Wear-resisting and anti-aging alkyd resin paint for bronze sculptures |
CN104387582A (en) * | 2014-11-19 | 2015-03-04 | 福建名源化工科技有限公司 | Method for producing novel environment-friendly rust-resisting material |
CN104817922A (en) * | 2015-04-23 | 2015-08-05 | 柳州凡一科技有限公司 | Rust-proof high-temperature resistant coating for agricultural machinery |
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CN103642374B (en) | 2016-08-10 |
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Address after: No. 3636 Qifeng Road, Shizishan Economic Development Zone, Tongling City, Anhui Province, 244031 Patentee after: Tongling Side Technology Co.,Ltd. Address before: No. 3636 Qifeng Road, Shizishan Economic Development Zone, Tongling City, Anhui Province, 244031 Patentee before: TONGLING SIDE TECHNOLOGY Co.,Ltd. |
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