CN104194370A - Wood-plastic material for outdoor exhibition rack and preparation method thereof - Google Patents
Wood-plastic material for outdoor exhibition rack and preparation method thereof Download PDFInfo
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- CN104194370A CN104194370A CN201410437562.2A CN201410437562A CN104194370A CN 104194370 A CN104194370 A CN 104194370A CN 201410437562 A CN201410437562 A CN 201410437562A CN 104194370 A CN104194370 A CN 104194370A
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Abstract
The invention discloses a wood-plastic material for an outdoor exhibition rack, which comprises the following components in parts by weight: 25-40 parts of wood meal, 0.5-2 parts of flame retardant, 2-4 parts of plasticizer, 5-8 parts of inorganic filler, 3-8 parts of nano titanium dioxide, 2-5 parts of coupling agent, 5-8 parts of pollen adsorbent, 1-3 parts of composite moldproof antimicrobial agent, 10-25 parts of polypropylene, 0.5-1 part of anti-aging agent, 0.5-2 parts of antioxidant, 0.2-0.3 part of lubricant and 3-8 parts of high molecular compatilizer. The wood-plastic material for an outdoor exhibition rack, prepared according to the formula disclosed by the invention, has excellent weather resistance, water resistance and wear resistance, also has the functions of aging resistance, mold prevention and bacterium resistance, and can realize dust prevention and pollen adsorption at the same time, thereby being more suitable for manufacturing of an outdoor exhibition rack.
Description
Technical field
The present invention relates to Material Field, particularly, relate to a kind of Wood-plastic material for outdoor exhibit rack, display rack and preparation method thereof.
Background technology
In recent years increasingly exhausted with global resources, social environment consciousness is day by day surging, and timber and petroleum chemicals application have been proposed to requirements at the higher level.Under such background, this advantage that can bring into play each component in material of wood plastic composite, the use limitation that overcome because strength of wood is low, the large and organic materials Young's modulus of variability is low etc. causes, can make full use of again discarded timber and plastics, reduces environmental pollution.Along with increasing of information interchange, a lot of large-scale enterprises all will carry out the product that outdoor exhibition is shown oneself, also more and more higher to the requirement of outdoor exhibit rack, display rack material.
Summary of the invention
Goal of the invention: the technical problem to be solved in the present invention, be to provide a kind of Wood-plastic material for outdoor exhibit rack, display rack, this Wood-plastic material not only has excellent weathering resistance, water tolerance and wear resistance, also has anti-aging, mildew-resistant and function antibacterial, dustproof and absorption pollen.
The present invention is and the technical issues that need to address are to provide the preparation method of the above-mentioned Wood-plastic material for outdoor exhibit rack, display rack.
Technique means: for realizing above-mentioned technical purpose, the invention provides a kind of Wood-plastic material for outdoor exhibit rack, display rack, it comprises the component of following parts by weight: 3~8 parts of 25~40 parts of wood powders, 0.5~2 part of fire retardant, 2~4 parts, softening agent, 5~8 parts of inorganic fillers, 3~8 parts of nano titanium oxides, 2~5 parts of coupling agents, 5~8 parts, pollen sorbent material, 1~3 part of composite mildewproof antiseptic-germicide, 10~25 parts of polypropylene, 0.5~1 part, anti-aging agent, 0.5~2 part, oxidation inhibitor, 0.2~0.3 part of lubricant and high molecular weight compatibilizers.Pollen sorbent material used is Queenseter POL.By adding pollen sorbent material, can make pollen be adsorbed on the timber of preparation, thereby avoid pollen to enter into human respiratory tract.
Preferably, the described Wood-plastic material for outdoor exhibit rack, display rack comprises the component of following parts by weight: 5 parts of 30 parts of wood powders, 1.5 parts of fire retardants, 3 parts, softening agent, 6 parts of inorganic fillers, 5 parts of nano titanium oxides, 4 parts of coupling agents, 6 parts, pollen sorbent material, 2 parts of composite mildewproof antiseptic-germicides, 20 parts of polypropylene, 0.8 part, anti-aging agent, 1.5 parts, oxidation inhibitor, 0.25 part of lubricant and high molecular weight compatibilizers.
Preferably, described fire retardant is magnesium hydroxide or aluminium hydroxide.
Described softening agent is any one in hexanodioic acid propanediol polyester, sebacic acid propanediol polyester and phthalic acid polyester.
Described inorganic filler is any one in calcium carbonate, kaolin, talcum powder, titanium dioxide and ground barium sulfate.
Described anti-aging agent is 4,4'-thiobis (the 6-tertiary butyl-3-methylphenol), β-(3, tri-grades of butyl-4-hydroxy phenyls of 5-) propionic acid octadecanol ester, tricresyl phosphite fat (2,4-di-tert-butyl-phenyl), any one in two (2,4-di-tert-butyl-phenyl) pentaerythritol diphosphites.
Described oxidation inhibitor is 2,6 di tert butyl 4 methyl phenol or β-(4 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl) vinylformic acid octadecyl ester.
Described high molecular weight compatibilizer is maleic anhydride inoculated polypropylene or maleic anhydride grafted polyethylene.
Described lubricant is any one in stearic acid, Zinic stearas, Magnesium Stearate or methyl-silicone oil.
The invention allows for the preparation method of the above-mentioned Wood-plastic material for outdoor exhibit rack, display rack, comprise the steps: each component to put in high-speed mixer and mix according to parts by weight, the material mixing is sent in twin screw extruder, material the shearing of screw rod, mixing and carry under merge fully, finally by crossing the extruding pelletization of getting to know, finally the pellet after extruding pelletization is put into hot pressing die and obtain Wood-plastic material by hot-forming mode, wherein, the length-to-diameter ratio of described twin screw extruder is 20:1~60:1; The temperature of the each section of forcing machine is at 150~230 DEG C, and forcing machine rotating speed is not higher than 30rpm.
Beneficial effect: compared with prior art, the Wood-plastic material for outdoor exhibit rack, display rack of preparing by formula of the present invention not only has excellent weathering resistance, water tolerance and wear resistance, also there is anti-aging, mildew-resistant and antibacterial function, can also prevent dust and adsorb pollen, thereby be more suitable for the making of outdoor exhibit rack, display rack simultaneously.
Embodiment
According to following embodiment, the present invention may be better understood.But, those skilled in the art will readily understand, the described content of embodiment is only for the present invention is described, and should also can not limit the present invention described in detail in claims.Wherein, the composite mildewproof antiseptic-germicide of practicality of the present invention is Japanese aPIZAS antimildew and antibacterial agent; Pollen sorbent material used is Queenseter POL.
Embodiment 1
A kind of Wood-plastic material for outdoor exhibit rack, display rack, comprise the component of following parts by weight: 20 parts of 30 parts of wood powders, 1.5 parts of magnesium hydroxides, 3 parts of hexanodioic acid propanediol polyesters, 6 parts, calcium carbonate, 5 parts of nano titanium oxides, 4 parts of vinyltriethoxysilanes, 6 parts, pollen sorbent material, 2 parts of composite mildewproof antiseptic-germicides, polypropylene, 4,5 parts of 0.8 part of 4'-thiobis (the 6-tertiary butyl-3-methylphenol), 1.5 parts of 2,6 di tert butyl 4 methyl phenols, 0.25 part of Zinic stearas and maleic anhydride inoculated polypropylenes.Each component is put in high-speed mixer and mixed according to parts by weight, the material mixing is sent in twin screw extruder, material the shearing of screw rod, mixing and carry under merge fully, finally by crossing the extruding pelletization of getting to know, finally the pellet after extruding pelletization is put into hot pressing die and obtain Wood-plastic material by hot-forming mode, wherein, the length-to-diameter ratio of described twin screw extruder is 20:1~60:1; The temperature of the each section of forcing machine is at 150~230 DEG C, and forcing machine rotating speed is not higher than 30rpm.
Embodiment 2
A kind of Wood-plastic material for outdoor exhibit rack, display rack, comprise the component of following parts by weight: 25 parts of wood powders, 2 parts, aluminium hydroxide, 2 parts of sebacic acid propanediol polyesters, 8 parts of kaolin, 3 parts of nano titanium oxides, 5 parts of vinyl trichlorine base silanes, 5 parts, pollen sorbent material, 3 parts of composite mildewproof antiseptic-germicides, 10 parts of polypropylene, β-(3, tri-grades of butyl-4-hydroxy phenyls of 5-) 3 parts of 1 part of propionic acid octadecanol ester, 0.5 part of β-(4 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl) vinylformic acid octadecyl ester, 0.3 part of Zinic stearas and maleic anhydride grafted polyethylenes.Said components is mixed, and the speed with 100r/min at 28 DEG C stirs 5h, to obtain final product.Each component is put in high-speed mixer and mixed according to parts by weight, the material mixing is sent in twin screw extruder, material the shearing of screw rod, mixing and carry under merge fully, finally by crossing the extruding pelletization of getting to know, finally the pellet after extruding pelletization is put into hot pressing die and obtain Wood-plastic material by hot-forming mode, wherein, the length-to-diameter ratio of described twin screw extruder is 20:1~60:1; The temperature of the each section of forcing machine is at 150~230 DEG C, and forcing machine rotating speed is not higher than 30rpm.
Embodiment 3
A kind of Wood-plastic material for outdoor exhibit rack, display rack, comprise the component of following parts by weight: 40 parts of wood powders, 0.5 part, aluminium hydroxide, 4 parts of phthalic acid polyesters, 5 parts of talcum powder, 8 parts of nano titanium oxides, 2 parts of vinyl trichlorine base silanes, 8 parts, pollen sorbent material, 1 part of composite mildewproof antiseptic-germicide, polipropene 25 part, two (2,4-di-tert-butyl-phenyl) 8 parts of 0.5 part of pentaerythritol diphosphites, 2 parts of 2,6 di tert butyl 4 methyl phenols, 0.2 part of Magnesium Stearate and maleic anhydride inoculated polypropylenes.Said components is mixed, and the speed with 100r/min at 28 DEG C stirs 5h, to obtain final product.Each component is put in high-speed mixer and mixed according to parts by weight, the material mixing is sent in twin screw extruder, material the shearing of screw rod, mixing and carry under merge fully, finally by crossing the extruding pelletization of getting to know, finally the pellet after extruding pelletization is put into hot pressing die and obtain Wood-plastic material by hot-forming mode, wherein, the length-to-diameter ratio of described twin screw extruder is 20:1~60:1; The temperature of the each section of forcing machine is at 150~230 DEG C, and forcing machine rotating speed is not higher than 30rpm.
Embodiment 4
A kind of Wood-plastic material for outdoor exhibit rack, display rack, comprise the component of following parts by weight: 28 parts of wood powders, 1.6 parts of magnesium hydroxides, 2.8 parts of hexanodioic acid propanediol polyesters, 6.5 parts of ground barium sulfates, 5.5 parts of nano titanium oxides, 4.5 parts of vinyltriethoxysilanes, 6 parts, pollen sorbent material, 2 parts of composite mildewproof antiseptic-germicides, 22 parts of polypropylene, tricresyl phosphite fat (2,4-di-tert-butyl-phenyl) 5 parts of 0.8 part, 1.5 parts of β-(4 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl) vinylformic acid octadecyl esters, 0.25 part of methyl-silicone oil and maleic anhydride grafted polyethylenes.Said components is mixed, and the speed with 100r/min at 28 DEG C stirs 5h, to obtain final product.Each component is put in high-speed mixer and mixed according to parts by weight, the material mixing is sent in twin screw extruder, material the shearing of screw rod, mixing and carry under merge fully, finally by crossing the extruding pelletization of getting to know, finally the pellet after extruding pelletization is put into hot pressing die and obtain Wood-plastic material by hot-forming mode, wherein, the length-to-diameter ratio of described twin screw extruder is 20:1~60:1; The temperature of the each section of forcing machine is at 150~230 DEG C, and forcing machine rotating speed is not higher than 30rpm.
Claims (10)
1. the Wood-plastic material for outdoor exhibit rack, display rack, it is characterized in that, comprise the component of following parts by weight: 3~8 parts of 25~40 parts of wood powders, 0.5~2 part of fire retardant, 2~4 parts, softening agent, 5~8 parts of inorganic fillers, 3~8 parts of nano titanium oxides, 2~5 parts of coupling agents, 5~8 parts, pollen sorbent material, 1~3 part of composite mildewproof antiseptic-germicide, 10~25 parts of polypropylene, 0.5~1 part, anti-aging agent, 0.5~2 part, oxidation inhibitor, 0.2~0.3 part of lubricant and high molecular weight compatibilizers.
2. the Wood-plastic material for outdoor exhibit rack, display rack according to claim 1, is characterized in that, described fire retardant is magnesium hydroxide or aluminium hydroxide.
3. the Wood-plastic material for outdoor exhibit rack, display rack according to claim 1, is characterized in that, described softening agent is any one in hexanodioic acid propanediol polyester, sebacic acid propanediol polyester and phthalic acid polyester.
4. the Wood-plastic material for outdoor exhibit rack, display rack according to claim 1, is characterized in that, described inorganic filler is any one in calcium carbonate, kaolin, talcum powder, titanium dioxide and ground barium sulfate.
5. the Wood-plastic material for outdoor exhibit rack, display rack according to claim 1, is characterized in that, described coupling agent is vinyltriethoxysilane or vinyl trichlorine base silane.
6. the Wood-plastic material for outdoor exhibit rack, display rack according to claim 1, it is characterized in that, described anti-aging agent is 4,4'-thiobis (the 6-tertiary butyl-3-methylphenol), β-(3, tri-grades of butyl-4-hydroxy phenyls of 5-) propionic acid octadecanol ester, tricresyl phosphite fat (2,4-di-tert-butyl-phenyl), any one in two (2,4-di-tert-butyl-phenyl) pentaerythritol diphosphites.
7. the Wood-plastic material for outdoor exhibit rack, display rack according to claim 1, is characterized in that, described oxidation inhibitor is 2,6 di tert butyl 4 methyl phenol or β-(4 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl) vinylformic acid octadecyl ester.
8. the Wood-plastic material for outdoor exhibit rack, display rack according to claim 1, is characterized in that, described high molecular weight compatibilizer is maleic anhydride inoculated polypropylene or maleic anhydride grafted polyethylene.
9. the Wood-plastic material for outdoor exhibit rack, display rack according to claim 1, is characterized in that, described lubricant is any one in stearic acid, Zinic stearas, Magnesium Stearate or methyl-silicone oil.
10. the preparation method of the Wood-plastic material for outdoor exhibit rack, display rack claimed in claim 1, it is characterized in that, comprise the steps: each component to put in high-speed mixer and mix according to parts by weight, the material mixing is sent in twin screw extruder, material the shearing of screw rod, mixing and carry under merge fully, finally by crossing the extruding pelletization of getting to know, finally the pellet after extruding pelletization is put into hot pressing die and obtain Wood-plastic material by hot-forming mode, wherein, the length-to-diameter ratio of described twin screw extruder is 20:1~60:1; The temperature of the each section of forcing machine is at 150~230 DEG C, and forcing machine rotating speed is not higher than 30rpm.
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CN201410437562.2A CN104194370A (en) | 2014-08-29 | 2014-08-29 | Wood-plastic material for outdoor exhibition rack and preparation method thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105153722A (en) * | 2015-07-31 | 2015-12-16 | 濮阳市东宝科技发展有限公司 | Flame-retardant antibacterial wood plastic material and preparation method thereof |
CN106188886A (en) * | 2016-07-21 | 2016-12-07 | 芜湖昊轩环保新材料有限公司 | A kind of aging resistance corrosion resistant wood plastic composite board and preparation method thereof |
CN106543756A (en) * | 2015-09-18 | 2017-03-29 | 丹阳市丹力展览用品有限公司 | The preparation method of the compound exhibition panel of wood moulding environmental protection |
CN106832596A (en) * | 2017-03-21 | 2017-06-13 | 安媛 | Environment protection type high-strength antibacterial polypropylene bio-based plastics master batch high and preparation method thereof |
CN106976644A (en) * | 2015-12-23 | 2017-07-25 | 常熟市谷雷特机械产品设计有限公司 | For the bracket for plate in cable or optical cable transport |
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CN101531788A (en) * | 2008-03-14 | 2009-09-16 | 鹏马环保塑料有限公司 | Modified environment-friendly polyolefin material and preparation method thereof |
CN102924951A (en) * | 2012-11-26 | 2013-02-13 | 科创聚合物(苏州)有限公司 | Technique for making mouldproof antibacterial wood plastic composite |
CN103319908A (en) * | 2013-05-20 | 2013-09-25 | 黄山美森新材料科技有限公司 | Wood-plastic anticorrosion wallboard and preparation method thereof |
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2014
- 2014-08-29 CN CN201410437562.2A patent/CN104194370A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101531788A (en) * | 2008-03-14 | 2009-09-16 | 鹏马环保塑料有限公司 | Modified environment-friendly polyolefin material and preparation method thereof |
CN102924951A (en) * | 2012-11-26 | 2013-02-13 | 科创聚合物(苏州)有限公司 | Technique for making mouldproof antibacterial wood plastic composite |
CN103319908A (en) * | 2013-05-20 | 2013-09-25 | 黄山美森新材料科技有限公司 | Wood-plastic anticorrosion wallboard and preparation method thereof |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105153722A (en) * | 2015-07-31 | 2015-12-16 | 濮阳市东宝科技发展有限公司 | Flame-retardant antibacterial wood plastic material and preparation method thereof |
CN106543756A (en) * | 2015-09-18 | 2017-03-29 | 丹阳市丹力展览用品有限公司 | The preparation method of the compound exhibition panel of wood moulding environmental protection |
CN106976644A (en) * | 2015-12-23 | 2017-07-25 | 常熟市谷雷特机械产品设计有限公司 | For the bracket for plate in cable or optical cable transport |
CN106188886A (en) * | 2016-07-21 | 2016-12-07 | 芜湖昊轩环保新材料有限公司 | A kind of aging resistance corrosion resistant wood plastic composite board and preparation method thereof |
CN106832596A (en) * | 2017-03-21 | 2017-06-13 | 安媛 | Environment protection type high-strength antibacterial polypropylene bio-based plastics master batch high and preparation method thereof |
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Application publication date: 20141210 |