CN101531788A - Modified environment-friendly polyolefin material and preparation method thereof - Google Patents
Modified environment-friendly polyolefin material and preparation method thereof Download PDFInfo
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- CN101531788A CN101531788A CN200810087364A CN200810087364A CN101531788A CN 101531788 A CN101531788 A CN 101531788A CN 200810087364 A CN200810087364 A CN 200810087364A CN 200810087364 A CN200810087364 A CN 200810087364A CN 101531788 A CN101531788 A CN 101531788A
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- modified environment
- polyolefin material
- oxidation inhibitor
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/002—Methods
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/88—Adding charges, i.e. additives
- B29B7/90—Fillers or reinforcements, e.g. fibres
- B29B7/92—Wood chips or wood fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
- B29B9/14—Making granules characterised by structure or composition fibre-reinforced
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0022—Combinations of extrusion moulding with other shaping operations combined with cutting
Abstract
The invention discloses a modified environment-friendly polyolefin material which comprises components with the following weight percentages: 40 percent to 70 percent of vegetable fiber, 20 percent to 50 percent of polyolefin resin, 3 percent to 8 percent of coupling agent, 3 percent to 10 percent of nano calcium carbonate, 3 percent to 5 percent of polypropylene oxide wax and 0.3 percent to 0.5 percent of antioxidant. The preparation method comprises the following steps of: preparing materials, mixing the materials at high speed, granulating and drying for later use. The polyolefin material can not only be biochemically degraded in nature, but also can be chemically degraded by chemical fertilizers, is in accord with the general orientation of environmental protection, fully meets the requirements of European ROHS, reaches the toy safety standard of EN71/ASTM 963, contains no heavy metal, toxic elements or chemical substances damaging the ozone layer, and has the advantages of ultraviolet (UV) radiation resistance, mechanical performance against thermal and cold shocks and excellent pigmenting property.
Description
Technical field
The present invention relates to a kind of modified environment-friendly polyolefin material and manufacture method thereof.
Background technology
The existing product of making of acrylic resin or polyvinyl resin, all be injection molded with simple acrylic resin or polyvinyl resin, this product be not fine aspect bend tension modulus, notched Izod impact strength, antiultraviolet UV performance, the mechanical property of resisting thermal shock and the degradation property, especially along with the more and more attention of people to environmental protection, degradation property to plastic prod requires more and more higher, therefore, traditional product of making of acrylic resin or polyvinyl resin is subjected to the restriction of market and government more and more.Though, also there is the product of degradable acrylic resin of part or polyvinyl resin to occur at present, because its degradation property and other every performance all are not very desirable, and are promoted widely and used.
Summary of the invention
The objective of the invention is to overcome the problems referred to above, provide a kind of modified environment-friendly polyolefin material of superior performance to society, and the method for making this material.
Technical scheme of the present invention is: a kind of modified environment-friendly polyolefin material comprises following component by weight percentage:
Vegetable fibre 40_70%
Polyolefin resin 20_50%
Coupling agent 3_8%
Nano-calcium carbonate 3_10%
Its chlorinated polypropylene wax 3_5%
Oxidation inhibitor 0.3_0.5%.
Described polyolefin resin is acrylic resin or polyvinyl resin.
Described oxidation inhibitor is oxidation inhibitor AO_2 or antioxidant 1010.
Described coupling agent is a maleic anhydride inoculated polypropylene.
Described vegetable fibre comprises wood fibre, corn fibre, bamboo fibers, sugarcane rod fibers or cornstalk fiber and composition thereof.
A kind of method of making modified environment-friendly polyolefin material comprises the steps:
(A) material is prepared, and is ready to polyolefin resin particle, vegetable fibre, nano-calcium carbonate, its chlorinated polypropylene wax, oxidation inhibitor and coupling agent by above-mentioned prescription;
(B) high speed batch mixing, in high speed mixer with 120 ℃ ± 10 ℃ high-speed mixing;
(C) granulation is extruded granulating with dual-screw-stem machine with the material after mixing in 150 ℃ to 175 ℃ temperature ranges;
(D) drying, the material grain of extruding is standby with pack behind 120 ℃ ± 10 ℃ complete dryinies in drying machine.
The present invention contains the part farm waste, comprise from rice, corn, wheat, barley and bamboo and equal to gather in made high fiber and the high starch residual substance in processing back, so the present invention not only can natural biochemical degradation, and can pass through the chemical fertilizer chemical degradation, meets the environmental protection general orientation.
The present invention is by Hong Kong independent test mechanism, and be proved in all many-sides than unmodified polypropylene (polyethylene) superior performance: improved several times as the bend tension modulus, notched Izod impact strength has increased several times; In addition, the ROHS that the present invention satisfies Europe fully assert the toy safety standard that requires and meet EN71/ASTM963, does not contain the chemical substance that any heavy metal, poisonous element maybe can destroy ozone.
The present invention also has remarkable antiultraviolet UV performance, the mechanical property of resisting thermal shock and workability, so be particularly suitable for producing the kit (as clothes hanger, the hook etc. of quitting) that cargo transport clamp, collection box, outdoor Jia Furniture and some shippings are used.Can as the coating process of degradation property, processing conditions, mechanical property, perveance, fire rating and goods, make suitable synthetic adjustment according to client's application request.
Tinctorial property excellence of the present invention can be sneaked into suitable toner look kind when injection moulding, or application is applicable to that all kinds of SOLVENTS type of polypropylene copolymer paints and water-miscible paint, produces the distinct colors effect after the moulding.
Embodiment
Following vegetable fibre includes but not limited to wood fibre, corn fibre, bamboo fibers, sugarcane rod fibers or cornstalk fiber and composition thereof.Wood fibre is the wood powder more than 80 orders of wearing into wood chip; Corn fibre is the flour more than 80 orders of wearing into husk; Bamboo fibers is the bamboo powder more than 80 orders of wearing into bamboo; The sugarcane rod fibers is the above sugarcane rod fibers powder of wearing into the sugarcane rod fibers of 80 orders; Cornstalk fiber is the cornstalk fiber powder more than 80 orders of wearing into cornstalk fiber.The molecular weight of its chlorinated polypropylene wax among the following embodiment is 3000-10000; Nano-calcium carbonate is 20nm-80nm.
Embodiment 1
Wood powder 40Kg
Acrylic resin 43.5Kg
Maleic anhydride inoculated polypropylene 3Kg
Nano-calcium carbonate 10Kg
Its chlorinated polypropylene wax 3Kg
Oxidation inhibitor AO_2 0.5Kg
Be ready to acrylic resin particle, wood powder, nano-calcium carbonate, its chlorinated polypropylene wax, oxidation inhibitor AO_2, maleic anhydride inoculated polypropylene (coupling agent) by above-mentioned weight; In high-speed mixer with 110 ℃ of temperature high-speed mixing; Mix the back and extrude granulating 150 ℃ of temperature with dual-screw-stem machine; To expect that again grain with behind 110 ℃ of complete dryinies, packs standby.In the said ratio, described wood powder replaces wood powder can reach effect same with flour, bamboo powder, sugarcane rod fibers powder or cornstalk fiber powder of identical weight and composition thereof.
Embodiment 2
Flour 48Kg
Acrylic resin 34.5Kg
Maleic anhydride inoculated polypropylene 5Kg
Nano-calcium carbonate 8Kg
Its chlorinated polypropylene wax 4Kg
Oxidation inhibitor AO_2 0.5Kg
Be ready to acrylic resin particle, flour, nano-calcium carbonate, its chlorinated polypropylene wax, oxidation inhibitor AO_2, maleic anhydride inoculated polypropylene (coupling agent) by above-mentioned weight; In high-speed mixer with 120 ℃ of temperature high-speed mixing; Mix the back and extrude granulating 160 ℃ of temperature with dual-screw-stem machine; To expect that again grain with behind 120 ℃ of complete dryinies, packs standby.In the said ratio, described flour replaces wood powder can reach effect same with wood powder, bamboo powder, sugarcane rod fibers powder or cornstalk fiber powder of identical weight and composition thereof.
Embodiment 3
Bamboo powder 56Kg
Polyvinyl resin 26.7Kg
Maleic anhydride inoculated polypropylene 6Kg
Nano-calcium carbonate 6Kg
Its chlorinated polypropylene wax 5Kg
Oxidation inhibitor AO_2 0.3Kg
Be ready to polyvinyl resin particle, bamboo powder, nano-calcium carbonate, its chlorinated polypropylene wax, oxidation inhibitor AO_2, maleic anhydride inoculated polypropylene (coupling agent) by above-mentioned weight; In high-speed mixer with 130 ℃ of temperature high-speed mixing; Mix the back and extrude granulating 175 ℃ of temperature with dual-screw-stem machine; To expect that again grain with behind 130 ℃ of complete dryinies, packs standby.In the said ratio, described bamboo powder replaces wood powder can reach effect same with wood powder, flour, sugarcane rod fibers powder or cornstalk fiber powder of identical weight and composition thereof.
Embodiment 4
Sugarcane rod fibers powder 63Kg
Polyvinyl resin 21.6Kg
Maleic anhydride inoculated polypropylene 7Kg
Nano-calcium carbonate 3Kg
Its chlorinated polypropylene wax 5Kg
Oxidation inhibitor AO_2 0.4Kg
Be ready to polyvinyl resin particle, sugarcane rod fibers powder, nano-calcium carbonate, its chlorinated polypropylene wax, oxidation inhibitor AO_2, maleic anhydride inoculated polypropylene (coupling agent) by above-mentioned weight; In high-speed mixer with 110 ℃ of temperature high-speed mixing; Mix the back and extrude granulating 150 ℃ of temperature with dual-screw-stem machine; To expect that again grain with behind 110 ℃ of complete dryinies, packs standby.In the said ratio, described sugarcane rod fibers powder replaces wood powder can reach effect same with wood powder, flour, bamboo powder or cornstalk fiber powder of identical weight and composition thereof.
Embodiment 5
Cornstalk fiber powder 70Kg
Acrylic resin 20Kg
Maleic anhydride inoculated polypropylene 3Kg
Nano-calcium carbonate 3.7Kg
Its chlorinated polypropylene wax 3Kg
Oxidation inhibitor AO_2 0.3Kg
Be ready to acrylic resin particle, cornstalk fiber powder, nano-calcium carbonate, its chlorinated polypropylene wax, oxidation inhibitor AO_2, maleic anhydride inoculated polypropylene (coupling agent) by above-mentioned weight; In high-speed mixer with 120 ℃ of temperature high-speed mixing; Mix the back and extrude granulating 160 ℃ of temperature with dual-screw-stem machine; To expect that again grain with behind 120 ℃ of complete dryinies, packs standby.In the said ratio, described cornstalk fiber powder replaces wood powder can reach effect same with the wood powder of identical weight, flour, bamboo powder, sugarcane rod fibers powder and composition thereof.
Embodiment 6
Flour 33.6Kg
Polyvinyl resin 50Kg
Maleic anhydride inoculated polypropylene 8Kg
Nano-calcium carbonate 4Kg
Its chlorinated polypropylene wax 4Kg
Antioxidant 1010 0.4Kg
Be ready to polyvinyl resin particle, flour, nano-calcium carbonate, its chlorinated polypropylene wax, antioxidant 1010, maleic anhydride inoculated polypropylene (coupling agent) by above-mentioned weight; In high-speed mixer with 130 ℃ of temperature high-speed mixing; Mix the back and extrude granulating 175 ℃ of temperature with dual-screw-stem machine; To expect that again grain with behind 130 ℃ of complete dryinies, packs standby.In the said ratio, described flour replaces wood powder can reach effect same with wood powder, bamboo powder, sugarcane rod fibers powder or cornstalk fiber powder of identical weight and composition thereof.
Claims (6)
1, a kind of modified environment-friendly polyolefin material is characterized in that: comprise following component by weight percentage:
Vegetable fibre 40_70%
Polyolefin resin 20_50%
Coupling agent 3_8%
Nano-calcium carbonate 3_10%
Its chlorinated polypropylene wax 3_5%
Oxidation inhibitor 0_0.5%.
2, modified environment-friendly polyolefin material according to claim 1 is characterized in that: described polyolefin resin is acrylic resin or polyvinyl resin.
3, modified environment-friendly polyolefin material according to claim 1 and 2 is characterized in that: described oxidation inhibitor is oxidation inhibitor A0_2 or antioxidant 1010.
4, modified environment-friendly polyolefin material according to claim 3 is characterized in that: described coupling agent is a maleic anhydride inoculated polypropylene.
5, modified environment-friendly polyolefin material according to claim 4 is characterized in that: described vegetable fibre comprises wood fibre, corn fibre, bamboo fibers, sugarcane rod fibers or cornstalk fiber and composition thereof.
6, a kind of method of making modified environment-friendly polyolefin material is characterized in that, comprises the steps:
(A) material is prepared, and is ready to polyolefin resin particle, vegetable fibre, nano-calcium carbonate, its chlorinated polypropylene wax, oxidation inhibitor and coupling agent by the described prescription of claim 1;
(B) high speed batch mixing, in high speed mixer with 120 ℃ ± 10 ℃ high-speed mixing;
(C) granulation is extruded granulating with dual-screw-stem machine with the material after mixing in 150 ℃ to 175 ℃ temperature ranges;
(D) drying, the material grain of extruding is standby with pack behind 120 ℃ ± 10 ℃ complete dryinies in drying machine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810087364A CN101531788A (en) | 2008-03-14 | 2008-03-14 | Modified environment-friendly polyolefin material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810087364A CN101531788A (en) | 2008-03-14 | 2008-03-14 | Modified environment-friendly polyolefin material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101531788A true CN101531788A (en) | 2009-09-16 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200810087364A Pending CN101531788A (en) | 2008-03-14 | 2008-03-14 | Modified environment-friendly polyolefin material and preparation method thereof |
Country Status (1)
| Country | Link |
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Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967297A (en) * | 2010-10-29 | 2011-02-09 | 曾广胜 | Bagasse polypropylene composite material and preparation method thereof |
| CN102321375A (en) * | 2011-08-04 | 2012-01-18 | 宁波家联塑料科技有限公司 | Bagasse polypropylene bioplastics and preparation method thereof |
| CN102367315A (en) * | 2011-10-17 | 2012-03-07 | 常熟市星源金属涂层厂 | Corn straw fiber-filled polypropylene composite material and its preparation method |
| CN102382374A (en) * | 2011-09-28 | 2012-03-21 | 深圳市科聚新材料有限公司 | Fiber reinforced polypropylene (PP) automobile interior decoration material and preparation method thereof |
| CN102942798A (en) * | 2012-10-31 | 2013-02-27 | 游瑞生 | Raw material for preparing nano wood-plastic composite material and preparation method |
| CN103102556A (en) * | 2011-11-15 | 2013-05-15 | 上海杰事杰新材料(集团)股份有限公司 | Bamboo-plastic composite material and preparation method and application thereof |
| CN103408959A (en) * | 2013-08-16 | 2013-11-27 | 黄祖杰 | Wood-plastic composite material and preparation method thereof |
| CN104004370A (en) * | 2014-05-04 | 2014-08-27 | 安徽森泰塑木新材料有限公司 | Production technology for plastic-wood plate with mixed color |
| CN104194370A (en) * | 2014-08-29 | 2014-12-10 | 句容市石狮冲压件厂 | Wood-plastic material for outdoor exhibition rack and preparation method thereof |
| CN104448743A (en) * | 2014-12-02 | 2015-03-25 | 福州友星生物科技有限公司 | Biodegradable material and preparation method thereof |
| CN105419367A (en) * | 2015-12-18 | 2016-03-23 | 蚌埠市鑫晟新材料科技有限公司 | Eaglewood type plastic-wood board material |
| CN105419368A (en) * | 2015-12-18 | 2016-03-23 | 蚌埠市鑫晟新材料科技有限公司 | Production method of delicate fragrance type plastic board material |
| CN105462278A (en) * | 2015-12-18 | 2016-04-06 | 蚌埠市鑫晟新材料科技有限公司 | Delicate fragrance-type plastic-wood plate material |
| CN105462279A (en) * | 2015-12-18 | 2016-04-06 | 蚌埠市鑫晟新材料科技有限公司 | Production method of agilawood type plastic-wood plate material |
| CN105482346A (en) * | 2015-12-18 | 2016-04-13 | 蚌埠市鑫晟新材料科技有限公司 | Flower scent car foot mat material |
| CN105504642A (en) * | 2015-12-18 | 2016-04-20 | 蚌埠市鑫晟新材料科技有限公司 | Production method for faint scent type automobile foot mat material |
| CN105566830A (en) * | 2015-12-18 | 2016-05-11 | 蚌埠市鑫晟新材料科技有限公司 | Fragrant automobile foot pad material |
| CN107216668A (en) * | 2017-06-06 | 2017-09-29 | 欧阳水栋 | Polynary wood plastic composite |
| CN107325398A (en) * | 2017-06-19 | 2017-11-07 | 广东乐将生物科技有限公司 | A kind of airtight water proof type polypropylene film |
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2008
- 2008-03-14 CN CN200810087364A patent/CN101531788A/en active Pending
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967297B (en) * | 2010-10-29 | 2012-07-04 | 曾广胜 | Bagasse polypropylene composite material and preparation method thereof |
| CN101967297A (en) * | 2010-10-29 | 2011-02-09 | 曾广胜 | Bagasse polypropylene composite material and preparation method thereof |
| CN102321375A (en) * | 2011-08-04 | 2012-01-18 | 宁波家联塑料科技有限公司 | Bagasse polypropylene bioplastics and preparation method thereof |
| CN102321375B (en) * | 2011-08-04 | 2012-11-21 | 宁波家联塑料科技有限公司 | Bagasse polypropylene bioplastics and preparation method thereof |
| CN102382374A (en) * | 2011-09-28 | 2012-03-21 | 深圳市科聚新材料有限公司 | Fiber reinforced polypropylene (PP) automobile interior decoration material and preparation method thereof |
| CN102367315A (en) * | 2011-10-17 | 2012-03-07 | 常熟市星源金属涂层厂 | Corn straw fiber-filled polypropylene composite material and its preparation method |
| CN103102556A (en) * | 2011-11-15 | 2013-05-15 | 上海杰事杰新材料(集团)股份有限公司 | Bamboo-plastic composite material and preparation method and application thereof |
| CN102942798B (en) * | 2012-10-31 | 2015-08-19 | 游瑞生 | A kind of raw materials of nano wood-plastic matrix material and preparation method |
| CN102942798A (en) * | 2012-10-31 | 2013-02-27 | 游瑞生 | Raw material for preparing nano wood-plastic composite material and preparation method |
| CN103408959A (en) * | 2013-08-16 | 2013-11-27 | 黄祖杰 | Wood-plastic composite material and preparation method thereof |
| CN104004370A (en) * | 2014-05-04 | 2014-08-27 | 安徽森泰塑木新材料有限公司 | Production technology for plastic-wood plate with mixed color |
| CN104194370A (en) * | 2014-08-29 | 2014-12-10 | 句容市石狮冲压件厂 | Wood-plastic material for outdoor exhibition rack and preparation method thereof |
| CN104448743A (en) * | 2014-12-02 | 2015-03-25 | 福州友星生物科技有限公司 | Biodegradable material and preparation method thereof |
| CN105419367A (en) * | 2015-12-18 | 2016-03-23 | 蚌埠市鑫晟新材料科技有限公司 | Eaglewood type plastic-wood board material |
| CN105419368A (en) * | 2015-12-18 | 2016-03-23 | 蚌埠市鑫晟新材料科技有限公司 | Production method of delicate fragrance type plastic board material |
| CN105462278A (en) * | 2015-12-18 | 2016-04-06 | 蚌埠市鑫晟新材料科技有限公司 | Delicate fragrance-type plastic-wood plate material |
| CN105462279A (en) * | 2015-12-18 | 2016-04-06 | 蚌埠市鑫晟新材料科技有限公司 | Production method of agilawood type plastic-wood plate material |
| CN105482346A (en) * | 2015-12-18 | 2016-04-13 | 蚌埠市鑫晟新材料科技有限公司 | Flower scent car foot mat material |
| CN105504642A (en) * | 2015-12-18 | 2016-04-20 | 蚌埠市鑫晟新材料科技有限公司 | Production method for faint scent type automobile foot mat material |
| CN105566830A (en) * | 2015-12-18 | 2016-05-11 | 蚌埠市鑫晟新材料科技有限公司 | Fragrant automobile foot pad material |
| CN107216668A (en) * | 2017-06-06 | 2017-09-29 | 欧阳水栋 | Polynary wood plastic composite |
| CN107325398A (en) * | 2017-06-19 | 2017-11-07 | 广东乐将生物科技有限公司 | A kind of airtight water proof type polypropylene film |
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